Polymer-polymer tribological components with sliding contacts usually are lighter, cheaper and more corrosion resistant in aqueous environment, presenting some advantages over the classic metal-polymer equivalents under certain conditions, such as in wear resistant external coatings for pipes in industry. Reciprocating sliding wear of polypropylene (PP) against polyamide 6 (PA6) in dry and aqueous environments (distilled water and synthetic sea water) was mapped as a function of contact pressure (2.4–7.2 MPa) and sliding speed (36–108 mm/s), aiming the identification of favorable operating conditions (low wear). Mild wear regime (k = 1.3–5.3 × 10−6 mm3/N m) was found for PP in all conditions, except for the highest sliding speed in dry environment, where there was a severe regime (k = 0.5–0.8 × 10−3 mm3/N m). Meanwhile, the PA6 counter-body always operated in the mild wear regime for all studied conditions. Wear mechanisms in the mild regime were: surface fatigue microcracks, film transfer and abrasion for both materials and, for PA6 only, also wear by roll formation. At higher speed, frictional heating (0.14 < μ < 0.25) and low thermal diffusivity of the materials resulted in high contact temperatures (up to 120 °C), which is enough to promote the removal of molten or softened material in the PP, typical of severe wear regime. The mild-to-severe wear regime transition observed for PP-PA6 tribopair occurs at a much lower sliding speed than in metal-polymer pairs, which may limit the applicability of these tribosystems. For PA6, the severity of surface damage as a function of the environment increased from dry to distilled water and sea water condition, as this material is susceptible to attack by polar solutions, which degrades its mechanical properties.
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