This study optimizes CO2 adsorption using hydrochar from de-oiled flaxseed (FDOP), a waste byproduct of the oil extraction industry, through hydrothermal carbonization (HTC). The aim is to enhance CO2 capture sustainably and cost-effectively. Using Response Surface Methodology (RSM), in optimal conditions achieved 1153.26mg/g CO2 adsorption capacity under 215.15°C synthesis temperature, 3.05h synthesis time, 0.99M acid concentration, 8.997bar pressure, and 25.07°C adsorption temperature. Statistical analysis (F-value: 44.48, R²: 0.9705) confirmed strong model reliability. Kinetic analysis showed both physical and chemical adsorption, while thermodynamic analysis revealed exothermic behavior (ΔH° values: -46.697kJ/mol for M-225, -40.230kJ/mol for MA-203). After 10 regeneration cycles, the adsorption capacity was reduced by only 2.8% and 3.1%, indicating excellent recyclability. This study highlights FDOP-derived hydrochar as a highly efficient, low-cost adsorbent, offering industrial applications for carbon capture and waste management.
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