Inductively Coupled Plasma Reactive Ion Etching Research Articles

Performance improvement of blue light micro-light emitting diodes (< 20 μm) by neutral beam etching process

In this study, micro-light emitting diodes array (μLEDs) with dimensions of 5 μm and 15 μm chip size were fabricated using Neutral Beam Etching (NBE) processes. Size-dependent issues of μLEDs processed by traditional inductively coupled plasma-reactive ion etching (ICPRIE) were alleviated by NBE technology, which exhibited lower equivalent resistance, turn-on voltage, and Ideality factor as compared with those of μLEDs by ICPRIE. Additionally, higher light output power of μLEDs processed by NBE with both 5 μm and 15 μm resulted in higher EQE 7.6 % and 7.7 % than those of μLEDs processed by ICPRIE. Furthermore, the size effect led to a decrease in EQEmax values of the ICPRIE sample by 0.4 %, but only a 0.1 % decay in NBE. Overall, samples fabricated by the NBE process exhibited superior optoelectronic characteristics. Finally, non-radiative recombination behaviors on the mesa sidewall were verified by cathodoluminescence analysis, showing significant decay in ICPRIE samples but not in NBE samples. These results demonstrated the potential of the NBE process for fabricating small chip sizes blue-light μLEDs required for high-brightness, high-efficiency, and high-resolution μLED displays.

Wet and dry etching of ultrawide bandgap LiGa5O8 and LiGaO2

Crystalline thin films of LiGa5O8 have recently been realized through epitaxial growth via mist-chemical vapor deposition. The single crystal, spinel cubic LiGa5O8 films show promising fundamental material properties and, therefore, make LiGa5O8 a potential enabling material for power electronics. In this work, chemical resistance and etch susceptibility were investigated for the first time on crystalline LiGa5O8 thin films with various wet chemistries. It was found that LiGa5O8 is very chemically resistive to acid solutions, with no apparent etching effects observed when placed in concentrated acid solutions of HCl, H2SO4, HF, or H3PO4 at room temperature. In contrast, orthorhombic (010) LiGaO2 shows effective etching in HCl solutions at varying dilution concentrations, with etch rates measured between 8.6 [1000:1 (DI water: HCl concentration)] and 6092 nm/min (37 wt. % HCl). The inductively coupled plasma reactive ion etching (ICP-RIE) of LiGa5O8 using BCl3/Ar and CF4/Ar/O2 gas chemistries was investigated. The etching rate and surface morphology of etched surfaces were examined as a function of RIE and ICP power. Using a CF4/Ar/O2 gas chemistry with an RIE power of 75 W and an ICP power of 300 W resulted in smooth etched planar surfaces while maintaining an etch rate of ∼24.6 nm/min. Similar dry etching studies were performed for LiGaO2. It was found that the BCl3/Ar gas chemistry was better suited for LiGaO2 etching, with similar surface morphology quality being obtained after etching as prior etching when a RIE power of 15 W and an ICP power of 400 W is utilized.

Multiple fano resonances based on all-dielectric metastructure for refractive index sensing

We investigate an optical refractive index sensor based on an all-dielectric metastructure in the near-infrared regime for achieving high sensitivity and high quality factor (Q-factor). By introducing the asymmetry in the metastructure, four sharp Fano resonances with high Q-factor are generated owing to the transition from symmetry-protected bound states in the continuum (BIC) to quasi-BIC, and the magnetic quadrupole (MQ) resonance, magnetic dipole (MD) resonance, and toroidal dipole (TD) resonance are analyzed by a combination of the field distributions. By evaluating the sensing performance with finite difference time domain (FDTD), the highest Q-factor can reach 6900, the modulation depth is close to 100 %, the sensitivity can reach 288 nm/RIU, and the figure of merit (FOM) is 888 RIU−1. Furthermore, the sensor is prepared using electron beam lithography (EBL), and inductively coupled plasma reactive ion etch (ICP-RIE), and high sensitivity is achieved in liquids with different refractive indices in the near-infrared. The results show a good sensing performance of the designed metastructure. Our findings will give access to the development of applications in non-linear devices, narrow-band filters, optical switches, and quantum nanophotonics.

Performance comparison of InGaN-based 40–80 μm micro-LEDs fabricated with and without plasma etching

The fabrication of InGaN-based blue 4✕4 array micro-LEDs (μLEDs) with 40 μm ✕40 μm chip size and 2✕2 array μLEDs with 80 μm ✕80 μm chip size etching by the inductive coupled plasma reactive ion etching (ICPRIE) and defect-free neutral beam etching (NBE) processes was studied in this work. In μLEDs of this size, the influence of defects formation in the sidewalls on EQE was evaluated. There was almost no difference in EQE between μLEDs array etched by the NBE process no matter 40 μm ✕40 μm and 80 μm ✕80 μm, but the dependence was observed in the ICPRIE. Even with this size, it was found that the size effect of EQE is smaller than that in case of using ICPRIE for defect-free neutral beam etching. This impact is substantial since μLED predominantly operated at low current density, around 1–5 A/cm2. Consequently, the reduction of defect density, encompassing both internal and sidewall defects, becomes imperative even in 40–80 μm InGaN-based μLEDs. This not only improves the overall efficiency of μLEDs but also fortifies the brightness stability of μLED displays if process etching by NBE. It was also found that the etching shape had an influence on EQE. It could be attributed to fact that the etching profile angle of NBE was more vertical than that of ICPRIE. Because the different angles of the mesa resulted in different light intensity. The μLEDs emitting with a wavelength of 450 nm, the light extraction efficiency and intensity at a mesa angle 58° of NBE etching μLEDs was about 8% lower than those of an angle (38°) of ICPRIE etching μLEDs by simulation.

Tuning of the Effective Refractive Index of Crystalline Si Thin Films with Controlled Modification of Nanohole Dimensions By Dry-Etching

Silicon thin films with holes are composite materials with noteworthy optical properties that can be controllably fabricated by state-of-the-art Si process technologies. For light with wavelengths larger than the hole sizes and spacing, typically by a factor of 10, the perforated Si thin films behave like an effective (refractive index) medium. Under these conditions, the optical properties of the films can be modelled by the effective medium approximation (EMA). By manipulating the volumetric air fraction (holes) of such films, the refractive index can be modified accordingly. Such a property can be exploited to tune the index contrast in various photonic devices such as filters and waveguides.This work presents a novel scalable method that combines charged sphere colloidal lithography (CSCL) and dry-etching to pattern Si thin films. We demonstrate controlled tuning of the effective refractive index by controlled lateral dry-etching of the holes. The fabricated nanoholes are spatially disordered in a 220 nm thick crystalline Si film. CSCL is performed using polystyrene particles of 60 (P60) and 100 (P100) nm diameter. The CSCL step results in a disordered arrangement of the particles with average spatial separations of 2-4 times their diameter. Using Cr as a mask, cylindrical holes are etched into Si by inductively coupled plasma-reactive ion-etching (ICP-RIE) using a pseudo-Bosch process. An additional isotropic ICP-RIE dry-etch step is introduced to widen the holes in a controlled manner, utilizing CF4 and O2 gas mixture. Importantly, this hole-widening step is time-controlled to ensure that the holes do not overlap laterally. Finally, the Cr mask is removed by wet-etching.By analyzing scanning electron microscopic (SEM) images, we estimate the lateral etch rates for the P60 and P100 samples are approximately 0.76 nm/s and 0.52 nm/s, respectively. Using this process, the average hole diameter can be increased systematically up to circa 68-97%, compared to their original diameters, while avoiding overlap. The effective refractive index of the perforated Si thin films is determined using the optical air fill factor obtained from modelling the spectroscopic ellipsometry data with Bruggeman effective medium approximation. The determined optical air fill factor varies from circa 20% to 50% with hole widening. The ellipsometry data provides the true air fill factor of the samples directly; SEM analysis could also be used, however, it is complex and cannot determine the actual porosity of the films. The ellipsometry results show that the determined refractive index is constant in the 1500 - 4000 nm wavelength range. The refractive index decreases from 3.42 for unstructured Si film to 2.9 and 2.7 for the as-etched perforated Si films of P60 and P100 samples, respectively. With controlled lateral etching of the holes, the effective refractive index systematically decreases further to approximately 2.1 for the P60 and P100 samples, which is a 39% reduction compared to Si refractive index. The determined effective indices represent averaged values accounting for possible structural birefringence, which can be used as a guideline to design photonic devices such as filters.The presented findings indicate that the effective refractive index of perforated Si thin films can be engineered by controlling the lateral dimensions of holes. While this conclusion relates specifically to crystalline Si thin films, the same concept may also be applied to other perforated dielectric thin films. Figure 1

Fluorine-Based Low-Damage Selective Etching Process for E-Mode p-GaN/AlGaN/GaN HFET Fabrication

In this study, we conducted an optimization of a low-damage selective etching process utilizing inductively coupled plasma-reactive ion etch (ICP-RIE) with a fluorine-based gas mixture. This optimization was carried out for the fabrication of p-GaN gated AlGaN/GaN enhancement-mode (E-mode) heterojunction field-effect transistors (HFETs). The optimum process conditions resulted in an etch selectivity of 21:1 (=p-GaN:Al0.2Ga0.8N) with a p-GaN etch rate of 5.2 nm/min and an AlGaN etch rate of 0.25 nm/min. In comparison with an oxygen-based selective etching process, the fluorine-based selective etching process demonstrated reduced damage to the etched surface. This was confirmed through current–voltage characteristics and surface roughness inspections. The p-GaN gated AlGaN/GaN E-mode device, fabricated using the optimized fluorine-based selective etching process, achieved a high threshold voltage of 3.5 V with a specific on-resistance of 5.3 mΩ.cm2 for the device and with a gate-to-p-GaN gate distance of 3 μm, a p-GaN gate length of 4 μm, and a p-GaN gate-to-drain distance of 12 μm. The catastrophic breakdown voltage exceeded 1350 V.

Impact of etching process on Al2O3/GaN interface for MOSc-HEMT devices combining ToF-SIMS, HAXPES and AFM

In this work we present the effect of inductively coupled plasma reactive ion etching (ICP-RIE) combined with atomic layer etching (ALE) on the Al2O3/GaN interface for MOSc-HEMT devices. Time of flight secondary ion mass spectrometry (ToF-SIMS) and hard x-ray photoelectron spectroscopy (HAXPES) highlight an increase of the N/Ga ratio near the interface after etching. ToF-SIMS profiles also show the presence of impurities (H, C, B) at this interface. Atomic force microscopy (AFM) also illustrates a change of the GaN surface morphology for the etched sample.

Improved electrical properties of micro light-emitting diode displays by ion implantation technology

Generally, the inductively coupled plasma-reactive ion etching (ICP-RIE) mesa technology was used to remove p-GaN/MQWs and expose n-GaN for electrical contact in a fabricated micro light-emitting diode (μLED). In this process, the exposed sidewalls were significantly damaged which result in small-sized μLED presenting a strong size-dependent influence. Lower emission intensity was observed in the μLED chip, which can be attributed to the effect of sidewall defect during etch processing. To reduce the non-radiative recombination, the ion implantation using an As+ source to substitute the ICP-RIE mesa process was introduced in this study. The ion implantation technology was used to isolate each chip to achieve the mesa process in the μLED fabrication. Finally, the As+ implant energy was optimized at 40 keV, which exhibited excellent current–voltage characteristics, including low forward voltage (3.2 V @1 mA) and low leakage current (10–9 A@− 5 V) of InGaN blue μLEDs. The gradual multi-energy implantation process from 10 to 40 keV can further improve the electrical properties (3.1 V @1 mA) of μLEDs, and the leakage current was also maintained at 10–9 A@− 5 V.

Impact of Sidewall Conditions on Internal Quantum Efficiency and Light Extraction Efficiency of Micro‐LEDs

AbstractThe sidewall condition is a key factor determining the performance of micro‐light emitting diodes (µLEDs). In this study, equilateral triangular III‐nitride blue µLEDs are prepared with exclusively m‐plane sidewall surfaces to confirm the impact of sidewall conditions. It is found that inductively coupled plasma‐reactive ion etching (ICP‐RIE) causes surface damages to the sidewall and results in rough surface morphology. As confirmed by time‐resolved photoluminescence (TRPL) and X‐ray photoemission spectroscopy (XPS), tetramethylammonium hydroxide (TMAH) eliminates the etching damage and flattens the sidewall surface. After ICP‐RIE, 100 µm2‐µLEDs yield higher external quantum efficiency (EQE) than 400 µm2‐µLEDs. However, after TMAH treatment, the peak EQE of 400 µm2‐µLEDs increases by ≈10% in the low current regime, whereas that of 100 µm2‐µLEDs slightly decreases by ≈3%. The EQE of the 100 µm2‐µLEDs decreases after TMAH treatment although the internal quantum efficiency (IQE) increases. Further, the IQE of the 100 µm2‐µLEDs before and after TMAH treatment is insignificant at temperatures below 150 K, above which it becomes considerable. Based on PL, XPS, scanning transmission electron microscopy, and scanning electron microscopy results, mechanisms for the size dependence of the EQE of µLEDs are explained in terms of non‐radiative recombination rate and light extraction.

Effect of Surface Texture on Light Extraction Efficiency for LEDs

The light extraction efficiency of an LED is dependent on its surface texture. However, the surface of the p-GaN layer is not easy to be etch with inverted hexagonal pyramid structures (IHPS) with small top widths and large depths using existing methods. Therefore, it is important to discuss the expected effect of the conditions of thermal annealing and inductively coupled plasma (ICP) reactive ion etching (RIE) for the generation of nano-pin-holes in the photoresist and fabrication of the top surface structure of GaN-based LEDs, in order to enhance the light output power. In this study, the following four items will be discussed: (1) the effect of thermal annealing on the composition of the photoresist; (2) the effect of thermal annealing and ICP RIE on the generation of the nano-pin-holes in the photoresist; (3) the effect of ICP RIE on the IHPS; and (4) the effect of surface texture of the IHPS on the light output power. It has been found that a nano-pin-hole structure in the photoresist etching mask is needed for the fabrication of many IHPS on the LED surface. A maskless via-hole etching technique was used for texturing the photoresist to produce nano-pore structures with diameters of less than 50 nm. The relationship between the light extraction efficiency and the surface texture is discussed in detail. The simulation results show the best light extraction efficiency (LEE) ratio of 358% to be obtained when the distance between two neighboring IHPS patterns (DBNP) is 300 nm. This in turn allowed the formation of IHPS with small top widths and large depths on the LED surface. A LEE ratio of 305% was obtained with the fabrication of IHPS with a top width of 290 nm, a depth of 170 nm and a DBNP of 180 nm on the LED surface.

Development of high uniformity Al1-xScxN piezoelectric film stack dry etching process on 8-inch silicon wafers

This paper have investigated the basic properties of inductively coupled plasma reactive ion etching (ICP-RIE) of scandium doped aluminum nitride (Al1-xScxN) thin films on 8-inch silicon wafers, and presented a pretreatment scheme which can effectively improve the etching uniformity and wafer yield in the mass fabrication of Al1-xScxN-MEMS (micro-electromechanical systems) devices. Based on BCl3/Ar pretreatment and Cl2/Ar main etching scheme, an etching rate of 128 nm/min is obtained, with the low nonuniformity, and selectivity of 1.8 with respect to the loss of molybdenum (Mo) electrode is achieved, respectively. The relationship between etching parameters and etching uniformity is revealed in detail by the 5-step Al1-xScxN etching model. Meanwhile, to optimize the etching compatibility in the fabrication of Al1-xScxN-piezoelectric MEMS devices, a variety of etching masks (e.g. photoresist and silicon dioxide) are respectively used to obtain the consistent sidewall profile at different locations, with photoresist of 24° and silicon dioxide of 57°.

Atomic layer etching of nanowires using conventional reactive ion etching tool

Innovative material and processing concepts are needed to further enhance the performance of complementary metal-oxide-semiconductor (CMOS) transistors-based circuits as the scaling limits are being reached. To supplement that, we report on the development of an atomic layer etching (ALE) process to fabricate small and smooth nanowires using a conventional dry etching tool. Firstly, a negative tone resist (hydrogen silsesquioxane) is spin-coated on Silicon Germanium-on-insulator (SiGeOI) samples and electron beam lithography is performed to create nanopatterns. These patterns act as an etch mask and are transferred into the SiGeOI layer using an inductively-coupled plasma reactive ion etching (ICP-RIE) process. Subsequently, an SF6 and Ar+ based ALE process is employed to smoothen the nanowires and reduce their widths. SF6 modifies the surface of the samples, while in the next step Ar+ removes the modified surface. To investigate the effect of this process on the nanowire width, several ALE cycles are performed. The etched features are inspected using scanning electron microscopy. With the increasing number of ALE cycles, a reduction in the width is observed. An etch per cycle of 1.1 Å is obtained.

CF4/O2 inductively coupled plasma etching of silicate glass for antifogging applications

Fogging of glass surfaces is a highly undesirable phenomenon that significantly impairs optical transmittance. This paper demonstrates inductively coupled plasma reactive ion etching (ICP-RIE) of silicate glass in the mixture of CF4 and O2 gases with the aim of rendering the glass surface superhydrophilic and antifogging. Maskless ICP-RIE as well as ICP-RIE of the glass surface through the lithographic Al masks with design periods of 400 and 500 nm was performed. The optical transmittance of the etched glass in the range of 350–900 nm was at least 85%. The maskless etching increased the water wettability of the glass, but the superhydrophilic state was still not achieved. However, real-time fogging experiments have demonstrated the usefulness of maskless etching for reduction of the glass fogging. The ICP-RIE of the glass surface through the lithographic masks resulted in pillar-like and pit-like textures. The average roughness of the textured glass surface, compared to the maskless etching, increased more than 10 times. Both textures were suitable to impart superhydrophilicity (Θ < 1°) to the silicate glass surface and ensured at least 85% optical transmittance during real-time fogging tests.

High-Q Thin-Film Lithium Niobate Microrings Fabricated with Wet Etching.

Thin-film lithium niobate (TFLN) has been widely used in electro-optic modulators, acoustic--optic modulators, electro-optic frequency combs, and nonlinear wavelength converters owing to the excellent optical properties of lithium niobate. The performance of these devices is highly dependent on the fabrication quality of TFLN. Although state-of-the-art TFLN microrings with an intrinsic quality factor (Q-factor) exceeding 1 × 107 have been realized by inductively coupled plasma-reactive ion etching (ICP-RIE) and chemical mechanical polishing (CMP), ICP-RIE has moderate throughput, moderate reproducibility, and high cost in etching TFLN, while CMP features moderate throughput and low cost in etching TFLN. Here, a wet etching method for TFLN, leading to the fabrication of a micro-racetrack with an intrinsic Q-factor of over 9.27 × 106 is developed. The suitability of this method to fabricate a narrow coupling gap between the bus waveguide and microring enables the coupling conditions of the microring to be customized. This method features a high throughput, a high reproducibility, and a low cost in etching TFLN, showing the potential to boost the mass production of integrated LN photonic devices with high fidelity and affordabilitydramatically.

Controlling the etch selectivity of silicon using low-RF power HBr reactive ion etching

Silicon nanostructures with high aspect-ratio (AR) features have played an important role in many fields. In this study, we report the fabrication of high AR silicon nanostructures using an inductively coupled plasma reactive ion etching (ICP-RIE) process by controlling the voltage bias at the substrate. The results show that by reducing the radio frequency (RF) bias power to 10 W, the etch selectivity of silicon to photoresist can be enhanced up to 36 times. Using the photoresist as a mask, this process can fabricate 300 nm-period one-dimensional (1D) grating structures with a height up to 807 nm, an improvement of 3.75-fold compared with structures fabricated by normal bias power. Furthermore, the analysis of the etch rate shows that the etch rate decreases over time in 1D gratings but remains constant in 2D pillar arrays, which can be attributed to the removal of the sidewall passivation. By including an O2 ICP-RIE step to remove the remaining polymer mask, the highest AR of 2D pillar structures that can be achieved is 8.8. The optical characterization of the fabricated structures demonstrates effective antireflection properties, where the measurements show that the reflectivity can be suppressed from 35% to 0.01% near normal incidence and 35% to 2.4% at 65° incident angle. The demonstrated low-RF power ICP-RIE process can create high AR nanostructures without the need for an inorganic mask and can find applications in integrated circuits, photonics, and functional nanostructures.

Hydrogen-Assisted Molecular Beam Epitaxy of SiGeSn

Since its first synthesis in 2003 [1], the ternary alloy semiconductor SiGeSn has seen an increasing interest due to its unique properties in the field of Group-IV semiconductors [2–6]. SiGeSn not only allows the decoupling of its bandgap and lattice-constant by what it is predestined for the epitaxy of strain-reduced heterostructures on the Si platform. Furthermore, SiGeSn becomes a direct bandgap semiconductor at high Sn concentrations. Considering these properties, SiGeSn is an attractive material system for optoelectronic applications. An exemplary heterojunction optoelectronic device is the single confinement heterostructure laser diode, the still missing key component for the monolithic integration of the optical on-chip communication on Si.However, one of the greatest challenges faced by many Group-IV researchers is the epitaxy of SiGeSn bulk alloys with high crystal quality. The temperature induced segregation of Sn results in interstitial Sn atoms and subsequently in acceptor-like defect states, as it was already reported for GeSn [7].In this work, we show the molecular beam epitaxy (MBE) of SiGeSn structures under Hydrogen ambient. First of all, we determined the concentration of the acceptor-like defect states of undoped SiGeSn NA,defect on the basis of capacitance-voltage (C-V) measurements of SiGeSn pin diodes. Furthermore, we investigated Hydrogen-assisted epitaxy as an approach for the reduction of the acceptor-like defect states.All epitaxy experiments were performed in a 6” MBE system, where Si, Ge and Sn are used as matrix materials and B and Sb as dopants respectively. In particular, we investigated the influence of molecular (H2) as well as atomic (H) Hydrogen on the epitaxy process and therefore the quality of the grown structures. For this purpose, the MBE system was upgraded with a Hydrogen atom beam source for the generation of an atomic Hydrogen flux.Since the Sn segregation is affected mostly by the substrate temperature, this critical growth parameter is measured in-situ using an infrared pyrometer, which allows the observation of the dynamic processes on the sample surface [8] and the precise control of the substrate temperature at TSub = 200 °C during the SiGeSn epitaxy.All SiGeSn structures are based on Ge virtual substrates (Ge-VS) on Si(001) [9], followed by a 400 nm thick additional Ge buffer layer. In order to fulfil lattice matching of SiGeSn on Ge, a constant ratio of Si and Sn of Si/Sn = 3.67 was kept for all structures. The Sn concentration was varied in the range of 5 % < cSn < 10 %. For material characterization, 300 nm thick undoped SiGeSn layers were grown on this substrate layer stack (see Fig. 1a). A detailed characterization of the crystallinity and the surface roughness was performed using X-ray diffraction (XRD) and atomic force microscopy (AFM), respectively. The comparison of AFM micrographs of SiGeSn layers, grown with and without Hydrogen assistance (see Fig. 1b) show a clear reduction of the surface roughness due to Hydrogen assisted epitaxy.In order to determine NA,defect, C-V measurements on SiGeSn pin diodes (see Fig. 1c) were performed. The diode layer structure, also based on the previously described substrate layer stack, starts with a 400 nm thick p-doped SiGeSn bottom layer with an acceptor concentration of NA = 5x1019 cm-3, followed by an 300 nm thick undoped SiGeSn layer and a closing 200 nm thick n-doped SiGeSn top layer with a donor concentration of ND = 5x1019 cm-3. Subsequently, pin diodes were fabricated using a single mesa process consisting of four basic steps: Mesa structuring using inductive coupled plasma reactive ion etching (ICP-RIE) with HBr, mesa passivation with plasma enhanced chemical vapor deposition (PECVD) grown SiO2, oxide window opening using RIE with CHF3 and metallization using sputtered Al. An exemplary device can be seen in the scanning electron microscopy (SEM) image in Fig. 1d.The SiGeSn pin diodes were electrically characterised by means of C-V measurements using a Keithley 4200 semiconductor characterisation system. For further evaluation, the C-V characteristics of the pin diodes show linear behaviour when plotted on a C-2-V-scaled diagram (Fig. 1e). Under the assumption of a strongly asymmetric pn junction, (ND >> NA,defect), the slope m of the C-2-V characteristics is proportional to NA,defect. In this manner, we determined NA,defect for several SiGeSn pin diodes in dependence of the alloy composition. The results, as shown in Fig. 1f, show an acceptor-like defect concentration between 1017 cm-3 < NA,defect < 1018 cm-3, which is comparable with results reported by other groups for GeSn [7].In our presentation, we will discuss Hydrogen-assisted epitaxy as a promising approach for improving the SiGeSn crystal quality. Figure 1

Etching characteristics of low-k SiCOH thin films under fluorocarbon-based plasmas

Low dielectric constant (low-k) SiCOH thin films were prepared on silicon (Si) wafers using plasma enhanced chemical vapor deposition (PECVD) of the precursor tetrakis(trimethylsilyloxy)silane (TTMSS). The deposition RF plasma power was 20 and 100 W. The k-values were 2.14 and 3.2 for the films deposited at 20 and 100 W, respectively. The deposited films then underwent an inductively coupled plasma-reactive ion etching (ICP-RIE) using fluorocarbon-based etching gas of CF4, CF4+O2, and CF4+Ar. After etching, the etch rate and refractive index for the films deposited at 100 W were higher than those at 20 W. The surface roughness decreased for the films at 20 W but increased for those at 100 W after etching. Contact angles decreased indicating a hydrophilic surface after etching. Prominent absorption bands from the Fourier transform infrared (FTIR) spectra were observed as C–Hx stretching, Si–CH3 bending, Si–O–Si stretching, and Si–(CH3)x bending vibration modes. X-ray photoelectron spectroscopy (XPS) showed a significant fluorine concentration on the film surface. From high resolution scans for C1s and F1s in the XPS, dominant peaks were observed as C–H/C–C and C–F3 after etching, respectively. After etching, the k-values and leakage current densities increased from those of as-deposited films.

Scalable Fabrication of Nanogratings on GaP for Efficient Diffraction of Near-Infrared Pulses and Enhanced Terahertz Generation by Optical Rectification

We present a process flow for wafer-scale fabrication of a surface phase grating with sub-micron feature sizes from a single semiconductor material. We demonstrate this technique using a 110-oriented GaP semiconductor wafer with second-order nonlinearity to obtain a nanostructured device (800 nm lateral feature size and a 245 nm height modulation) with applications relevant to near-infrared optical diffraction and time-resolved terahertz (THz) technologies. The fabrication process involves a plasma-enhanced chemical deposition of a SiO2 layer on the wafer followed by contact photolithography and inductively coupled plasma reactive ion etching (ICP-RIE). We discuss the required radiation dosage, exposure times, temperatures and other key parameters to achieve high-quality nanogratings in terms of filling ratio, edge profile, and overall shape. The phase-grating properties, such as the pitch, spatial homogeneity, and phase retardation, are characterized with an atomic force microscope, scanning electron microscope and a non-invasive optical evaluation of the optical diffraction efficiency into different orders. We demonstrate an application of this device in a time-domain THz spectroscopy scheme, where an enhanced THz spectral bandwidth is achieved by optical rectification of near-infrared laser pulses incident on the grating and efficiently diffracted into the first orders. Finally, the reported process flow has the potential to be applied to various materials by considering only slight adjustments to the ICP-RIE etching steps, paving the way to scalable fabrication of sub-micron patterns on a large range of substrates.

Fabrication of lithium niobate metasurfaces via a combination of FIB and ICP-RIE

Lithium niobate (LN) metasurfaces have emerged as a new platform for manipulating electromagnetic waves. Here, we report a fabrication technique for LN nano-grating metasurfaces by combining focused ion beam (FIB) milling with inductively coupled plasma reactive ion etching (ICP-RIE). Steep sidewalls with angles larger than 80° are achieved. Sharp quasi-bound states in the continuum are observed from our metasurfaces. The measured transmission spectra show good agreement with the numerical simulations, confirming the high quality of the fabricated metasurfaces. Our technique can be applied to fabricate the LN metasurfaces with sharp resonances for various applications in optical communications, on-chip photonics, laser physics, sensing, and so on.

Femtomolar Dengue Virus Type-2 DNA Detection in Back-gated Silicon Nanowire Field-effect Transistor Biosensor

Background: Dengue is known as the most severe arboviral infection in the world spread by Aedes aegypti. However, conventional and laboratory-based enzyme-linked immunosorbent assays (ELISA) are the current approaches in detecting dengue virus (DENV), requiring skilled and well-trained personnel to operate. Therefore, the ultrasensitive and label-free technique of the Silicon Nanowire (SiNW) biosensor was chosen for rapid detection of DENV. Methods: In this study, a SiNW field-effect transistor (FET) biosensor integrated with a back-gate of the low-doped p-type Silicon-on-insulator (SOI) wafer was fabricated through conventional photolithography and Inductively Coupled Plasma – Reactive Ion Etching (ICP-RIE) for Dengue Virus type-2 (DENV-2) DNA detection. The morphological characteristics of back-gated SiNW-FET were examined using a field-emission scanning electron microscope supported by the elemental analysis via energy-dispersive X-ray spectroscopy. Results and Discussion: A complementary (target) single-stranded deoxyribonucleic acid (ssDNA) was recognized when the target DNA was hybridized with the probe DNA attached to SiNW surfaces. Based on the slope of the linear regression curve, the back-gated SiNW-FET biosensor demonstrated the sensitivity of 3.3 nAM-1 with a detection limit of 10 fM. Furthermore, the drain and back-gate voltages were also found to influence the SiNW conductance changed. Conclusion: Thus, the results obtained suggest that the back-gated SiNW-FET shows good stability in both biosensing applications and medical diagnosis throughout the conventional photolithography method.