Synchronous induction coilgun (SICG) typically includes an array of drive coils and a conductive armature. The structure of the drive coil and armature can greatly affect the launching performance of SICG. The traditional drive coils and armatures have a cylinder-shaped structure for simplicity and ease of fabrication. In this article, a novel structural SICG with stepped drive coil and stepped armature (SA) is proposed and investigated. As a comparison, four structural SICGs are researched by static and transient simulations. The static simulation results show that the stepped drive coil makes the magnetic field larger and the center of the magnetic field moves backward toward the tail end. The transient simulation results indicate that the SA improves the eddy current distribution and the positive propulsion force and weakens the reverse electromagnetic force and the armature capture effect at the same time. As a result of integrating the above characteristics, the new structural SICG with stepped drive coil and SA makes the optimal trigger position of armature move backward by 7 mm and improves the muzzle velocity by 4.79% and the launch efficiency by 9.82%.