When manufacturing products, it becomes increasingly important to consider ecological factors in addition to conventional key performance indicators such as manufacturing costs, time or quality. The greatest leverage for creating the most sustainable form of product manufacture is in the early stages of technology planning, because emissions can be avoided in the long term through the selection of sustainable technologies. However, there are methods that allow ecological factors to be taken into account during technology planning to supplement the usual key performance indicators, but the level of detail and the applicability are not yet sufficient. In order to support decision makers in the planning and evaluation of technology chains, this paper develops a methodology that supports technology chain selection. For this purpose, an economic-ecological key performance indicator was developed which combines manufacturing costs, material flow costs and environmental impacts determined through life cycle assessment to enable a holistic view.