Increasing Illumination Intensity Research Articles

Synthesis, spectral analysis, and DFT studies of the novel pyrano[3,2-c] quinoline-based 1,3,4-thiadiazole for enhanced solar cell performance

In this study, we synthesized a novel compound, 3-(5-amino-1,3,4-thiadiazol-2-yl)-6-ethyl-4-hydroxy-2H-pyrano[3,2-c]quinoline-2,5(6H)-dione (ATEHPQ), through a condensation reaction between 6-ethyl-4-hydroxy-2,5-dioxo-5,6-dihydro-2H-pyrano [3,2-c]quinoline-3-carboxaldehyde and thiosemicarbazide, followed by oxidative cyclization. We characterized ATEHPQ using elemental analysis, IR, 1H and 13C NMR spectroscopy, and mass spectrometry. Density Functional Theory (DFT) calculations with the B3LYP/6–311++G(d,p) basis set were employed to optimize the molecular geometry and analyze global reactivity descriptors, including HOMO-LUMO energies. The Molecular Electrostatic Potential (MEP) map was used to identify reactive sites, and drug-likeness studies indicated potential pharmaceutical applications. Notably, ATEHPQ showed a higher first hyperpolarizability (βtot) compared to urea, suggesting its suitability for nonlinear optical applications. We also determined the Miller indices for ATEHPQ's preferred orientations using a specialized program. Williamson–Hall analysis revealed an average crystal size of 26.08 nm and a lattice strain of 6.3 × 10−3. The thin films exhibited three distinct absorption peaks at 2.8, 3.41, and 4.21 eV, with a direct energy gap of 2.43 eV. Dispersion parameters from the single oscillator model provided oscillator and dispersion energies of 3.12 eV and 14.21 eV, respectively, with a high-frequency dielectric constant of 4.71. The ATEHPQ thin films, when combined with n-Si, demonstrated significant improvements in photovoltaic performance: the open-circuit voltage (Voc) rose from 0.13 V to 0.521 V, the short-circuit current (Isc) increased from 0.253 mA to 2.94 mA, the fill factor (FF) improved from 0.238 to 0.33, and the efficiency (η) grew from 0.71 % to 4.64 % with increased illumination intensity. These results highlight the excellent photovoltaic and photodetection capabilities of ATEHPQ thin films, underscoring their potential for advanced optoelectronic and solar cell applications.

Comparative study of cadmium telluride solar cell performance on different TCO‐coated substrates under concentrated light intensities

AbstractConcentrating photovoltaics is an attractive route for achieving high power output with thin film solar cells, using low‐cost optics. In this work, the performance of CdTe:As thin film solar cells on two different transparent conducting oxide (TCO)‐coated substrates is investigated and compared under varying concentrated light intensities (1–6.3 Suns). Samples tested had CdZnS/CdTe:As devices deposited atop of either a soda‐lime glass with a fluorine‐doped tin oxide TCO or an ultra‐thin glass (UTG) with an aluminium zinc oxide TCO and ZnO high‐resistive transparent (HRT) layer. Device current density was found to increase linearly with increased light intensities, for both sample configurations. Power conversion efficiencies of both device samples decreased with increased light intensity, due to a decrease in fill factor. The fill factor, for both sample configurations, was affected by reducing shunt resistance with increasing illumination intensity. The two device types performed differently at the high illumination intensities due to their series resistance. Light‐soaking devices under 6.3 Suns illumination intensity for 90 min showed no significant performance degradation, indicative of relatively stable devices under the highest illumination intensity tested. Efficiency limiting factors are assessed, evaluated and discussed.

Exploring the Multi-Sensory Coupling Relationship of Open Space on a Winter Campus

Exploring the combined effects of multisensory interactions in open spaces can help improve the comfort of campus environments. Nine typical spaces on a university campus in Fuzhou were selected for this study. Subjects perceived the environment and then completed an on-site subjective questionnaire. At the same time, meteorological data (global radiation, air temperature, globe temperature, wind speed, relative humidity, and illumination intensity) were measured to determine the interactions between visual and acoustic and thermal perceptions. Differences in the meteorological parameters between the measuring points were described using a one-way ANOVA and Tukey’s post hoc test, and a chi-square test of independence was used to determine significant associations between thermal, acoustic, and visual comfort, which in turn led to the study of interactions between visual, acoustic, and thermal comfort using a two-way ANOVA. The following conclusions were drawn: (1) the Thermal Comfort Vote (TCV) increased with the increasing Acoustic Comfort Vote (ACV) at all levels of thermal stress. (2) The highest and lowest Acoustic Sensation Vote (ASV) values for each sound type were derived from either “slightly cold” or “warm” conditions. Both the Thermal Comfort Vote (TCV) and the Acoustic Comfort Vote (ACV) were positively correlated. (3) When “neutral”, the Thermal Sensation Vote (TSV) increased with increasing illumination intensity (LUX). (4) The Sunlight Sensation Vote (SSV) increased with the increasing Universal Thermal Climate Index (UTCI) when illumination intensity (LUX) was moderate and bright. (5) The highest and lowest Acoustic Sensation Vote (ASV) values for each sound type came from either “slightly cold” or “warm” conditions.

Accelerated molecular vibrational decay and suppressed electronic nonlinearities in plasmonic cavities through coherent Raman scattering

Molecular vibrations and their dynamics are of outstanding importance for electronic and thermal transport in nanoscale devices as well as for molecular catalysis. The vibrational dynamics of <100 molecules are studied through three-color time-resolved coherent anti-Stokes Raman spectroscopy using plasmonic nanoantennas. This isolates molecular signals from four-wave mixing (FWM) while using exceptionally low nanowatt powers to avoid molecular damage via single-photon lock-in detection. FWM is found to be strongly suppressed in nanometer-wide plasmonic gaps compared to plasmonic nanoparticles. Simultaneous time-resolved incoherent anti-Stokes Raman spectroscopy allows us to separate the contributions of vibrational population decay (T1) and dephasing (T2). With increasing illumination intensity, the ultrafast vibrational dephasing rates of biphenyl-4-thiol molecules are accelerated at least tenfold, while phonon population decay rates remain constant. The extreme plasmonic field enhancement within nanogaps opens up prospects for measuring single-molecule vibrationally coupled dynamics and diverse molecular optomechanics phenomena. Published by the American Physical Society 2024

Photoresponse, thermal and electrical behaviors of MXene-based polysulfone nanocomposite

The Ti3C2Tx MXene nanosheet was prepared by 40% (v/v) hydrofluoric acid etching at 20 °C for 48 h and delamination of bulk MAX Ti3AlC2 precursor material. A 2D nanomaterial MXene Ti3C2Tx as a nanofiller was introduced to polysulfone (PSulfone) matrix. MXene and PSulfone/MXene nanocomposite systems were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscope, Fourier-transform infrared and thermogravimetric analysis instruments. Dielectric and electrical characterization of PSulfone/MXene nanocomposite was carried out. The electrical resistance of Ti3C2Tx MXene from measurement current (I)–voltage (V) was measured as 116 Ω. Pure PSulfone matrix exhibits typical insulator behavior, and MXene exhibits a good conductor behavior. But, when MXene was added to the pure PSulfone matrix, the resistance of the MXene/PSulfone nanocomposite increased moderately compared to that of pure MXene. In spite of the excess of surface functional groups, MXene showed surprisingly good electron transport across the surface, while in the case of PSulfone/MXene nanocomposite, the insulating behavior of PSulfone significantly reduced the electron transport of MXene. The semiconductor behavior of PSulfone/Ti3C2Tx MXene nanocomposite indicates that MXene provides efficient charge carrier transfer in the nanocomposite system. By comparing the TGA results between the PSulfone and different weight ratios of PSulfone/Ti3C2Tx MXene nanocomposites, it was determined that MXene nanosheets had a significant effect in slightly accelerating the thermal degradation of PSulfone. Optical conductivity was investigated by preparing a film of PSulfone/MXene nanocomposite on an interdigital contact. It was observed that the optical current values changed depending on the increasing illumination intensity. Considering current–voltage measurements, the photocurrent generation potential of PSulfone/MXene nanocomposite shows that it can be used in photodevice production.

Investigation of electrical, dielectric and interface state densities of Al/p-Si structures with PTCDA interlayer under different light intensities

In our study; we investigated illumination intensity-dependent electrical and dielectric properties of the Al/p-type Si metal-semiconductor (MS) structures with perylenetetracarboxylic dianhydride (PTCDA) interface using current-voltage (I–V) and capacitance-conductance-voltage (C-G/ω--V) measurements. Thin film layer with PTCDA interface was coated on p-type Si by Spin Coating method. The structure of PTCDA organic semiconductor powder examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrical parameters such as ideality factors (n), barrier heights (Φbo), rectification ratios (RR), saturation currents (I0) and series resistances (RS) were obtained from both thermionic emission (TE) theory and Cheng theory and compared with each other. Dielectric properties such as dielectric constant (ε′), dielectric loss (ε''), loss tangent (tanδ), electrical conductivity (σac), and interface state densities (NSS) were obtained from C–V and G/ω-V measurements. It was seen that the values of ε′, ε'', tanδ, and NSS decreases with increasing illumination while σac increase with increasing illumination intensity. Experimental results show that Al/PTCDA/p-type Si semiconductor structure can improve efficiency in electronic devices.

The effects of illumination on the current conduction mechanisms of the Au/C20H12/n-Si Schottky barrier diode (SBD)

Using the I-V characteristics both in the dark and under varied illumination-intensities (50–250 mW.cm−2) by 50 mW.cm−2 steps in the wide range bias-voltage (±5 V), specific fundamental electrical and photo effects parameters of the Au/C20H12/n-Si SBD were examined. Due to the creation of electron–hole pairs and their drift in opposite directions under the influence of an electric field, the value of photocurrent in the reverse bias (Iph) increases when illumination density is increased. The barrier height (ΦB0) tended to decrease due to the increase in photocurrent, while the diode’s ideality factor (n) increased with increasing illumination intensity. Also, the Schottky structure’s open-circuit voltage (Voc), short circuit current (Isc), filling factor (FF), and efficiency (η) were determined to be 0.358 V, 95.5 μA, 33%, and 0.028% under 50 mW.cm−2, respectively. The Rs and Rsh values found using Ohm’s law are a vital function of illumination and voltage which decrease with increasing illumination intensity. Additionally, using the forward bias I-V data and accounting for the bias dependent of the effective barrier height (Φe) and ideality factor n(V) for different illumination intensities, the energy density distribution profile of surface states (Nss) was obtained. According to these results, the organic interlayer consisting of C20H12 is light-sensitive and suitable for optoelectronic devices such as photodetectors and photodiodes.

Photoresponse of the Al/n-Si Schottky diode with nanorod ZnO interface layer prepared by hydrothermal method

In this study, ZnO nanorods (ZnO-NR) were prepared on n-Si wafer by hydrothermal method. Structural and morphologic properties of ZnO nanostructures were investigated through XRD and SEM method. The illumination impacts on the current-voltage (I-V) measurements of the prepared Al/ZnO-NR/n-Si diode were explored in the dark and different illumination intensities (20–100 mW/cm2) between ± 1.5 V bias voltage range. The Schottky diode barrier height value had an increasing trend with increasing illumination intensity from 20 to 100 mW/cm2 while the ideality factor had a decreasing trend with the increase of photocurrent. The temporary photocurrent increases as illumination intensity increases. The slope (α) of the logI_ph-logP curve was obtained as 0.618 and this slope confirmed that this ZnO nanorod shows photoconducting behavior. The short-circuit current (I_sc) and open-circuit voltage (V_oc) values were obtained to be 774.08 μA and 0.24 V under 100 mW/cm2 illumination intensity, respectively. It was concluded that the prepared Al/ZnO-NR/n-Si diode can be used in the optoelectronic applications, especially for the photodiode industry.

On the Kinetics of Light‐Induced Enhancement Effect in Silicon Heterojunction Solar Cells

Silicon heterojunction (SHJ) solar cells are one of the promising technologies for next‐generation high‐efficiency crystalline silicon solar cells in photovoltaic industry. Recently, an interesting light‐induced performance enhancement (LIE) effect has been observed in SHJ solar cells. Herein, the kinetics and stability of the LIE effect during repeated cycles of light soaking and subsequent dark annealing at 150 °C are investigated. It is found that VOC of SHJ solar cells increases with light soaking time following stretched exponential, but can be reverted by subsequent dark annealing. This means that LIE effect in SHJ solar cells is not stable. The underlying mechanism of this phenomenon should be attributed to the hydrogen motion in a‐Si:H layers. It is also demonstrated that increasing illumination intensity leads to faster (shorter time constant) and stronger (higher saturation level of ΔVOC) LIE effect.

Conversion of Mevalonate to Isoprenol Using Light Energy in Escherichia coli without Consuming Sugars for ATP Supply.

Bioconversion of key intermediate metabolites such as mevalonate into various useful chemicals is a promising strategy for microbial production. However, the conversion of mevalonate into isoprenoids requires a supply of adenosine triphosphate (ATP). Light-driven ATP regeneration using microbial rhodopsin is an attractive module for improving the intracellular ATP supply. In the present study, we demonstrated the ATP-consuming conversion of mevalonate to isoprenol using rhodopsin-expressing Escherichia coli cells as a whole-cell catalyst in a medium that does not contain energy cosubstrate, such as glucose. Heterologous genes for the synthesis of isoprenol from mevalonate, which requires three ATP molecules for the series of reactions, and a delta-rhodopsin gene derived from Haloterrigena turkmenica were cointroduced into E. coli. To evaluate the conversion efficiency of mevalonate to isoprenol, the cells were suspended in a synthetic medium containing mevalonate as the sole carbon source and incubated under dark or light illumination (100 μmol m-2 s-1). The specific isoprenol production rates were 10.0 ± 0.9 and 20.4 ± 0.7 μmol gDCW-1 h-1 for dark and light conditions, respectively. The conversion was successfully enhanced under the light condition. Furthermore, the conversion efficiency increased with increasing illumination intensity, suggesting that ATP regenerated by the proton motive force generated by rhodopsin using light energy can drive ATP-consuming reactions in the whole-cell catalyst.

Theoretical comparison of real-time feedback-driven single-particle tracking techniques.

Real-time feedback-driven single-particle tracking is a technique that uses feedback control to enable single-molecule spectroscopy of freely diffusing particles in native or near-native environments. A number of different real-time feedback-driven single-particle tracking (RT-FD-SPT) approaches exist, and comparisons between methods based on experimental results are of limited use due to differences in samples and setups. In this study, we used statistical calculations and dynamical simulations to directly compare the performance of different methods. The methods considered were the orbital method, the knight's tour (grid scan) method, and MINFLUX, and we considered both fluorescence-based and interferometric scattering (iSCAT) approaches. There is a fundamental trade-off between precision and speed, with the knight's tour method being able to track the fastest diffusion but with low precision, and MINFLUX being the most precise but only tracking slow diffusion. To compare iSCAT and fluorescence, different biological samples were considered, including labeled and intrinsically fluorescent samples. The success of iSCAT as compared to fluorescence is strongly dependent on the particle size and the density and photophysical properties of the fluorescent particles. Using a wavelength for iSCAT that is negligibly absorbed by the tracked particle allows for an increased illumination intensity, which results in iSCAT providing better tracking for most samples. This work highlights the fundamental aspects of performance in RT-FD-SPT and should assist with the selection of an appropriate method for a particular application. The approach used can easily be extended to other RT-FD-SPT methods.

Self-powered visible-UV light photodiodes based on ZnO nanorods-silicon heterojunctions with surface modification and structural enhancement

The letter reports the visible-UV light response of Al/ZnONRs/ZnOseed/p-Si/Al type photodiodes (PDs) with surface modification and structural enhancement. The PDs, which are referred to as PD10–2, PD10–4, PD20–2, PD20–3, and PD20–4 according to molar concentration (mM) and time (hour), were produced for improving the performances. Basic electronic parameters were obtained from the I-V data of Al/ZnONRs/ZnOseed/p-Si/Al type PDs by using thermionic emission (TE) theory, Ohm's law, and Cheung's methods. In accordance with the literature, the results showed that the potential barrier height (ФBo) values decreased with the increasing illumination intensity, while the ideality factor (n) values increased. In addition, voltage-dependent series resistance (Rs) values of the PDs under dark and different visible-UV light intensities were calculated by using Ohm's law and Cheung's method. It was observed that the Rs values decreased with increasing light intensities. On the other hand, the photosensitivity characteristics of the PDs at visible-UV light intensities were investigated depending on the applied voltage. While the photosensitivity value of the produced PD10–2 device reached the maximum value of 6.9 × 103 at the short-circuit voltage Vsc= 0 V, the open-circuit voltage Voc showed better photosensitivity with a minimum value of 0.0702 in the self-powered mode. In addition, the responsivity (R) and the detectivity (D*) values of Al/ZnONRs/ZnOseed/p-Si/Al type PDs were calculated. Herein, the R and D* values decreased with increasing power density at zero-bias voltage in accordance with the literature. Also, the R and D* values of the PD10–2 device are higher and lower than other devices, respectively. The linear dynamic range (LDR) value of the PD10–2 device reaches ~78 dB with a maximum value at Vbias= 0 V, while the dark current is 0.21 nA with a minimum value, self-powered mode. It is concluded that the PD10–2 device is suitable for photodiode applications in self-powered mode.

Morpho-structural and optoelectronic properties of diamond like carbon–germanium (DLC-Ge) composite thin films produced by magnetron sputtering

Diamond-like carbon films have found various areas of application due to their particularly durable characteristics. To enhance the electrical and optoelectronic characteristics of the material, diamond-like carbon was co-deposited with Ge on p-type Si wafer using the DC magnetron sputtering technique, from which diamond-like carbon-germanium nanocomposites were obtained. The structural properties of the nanocomposites were assessed using electron microscopy techniques. The chemical structure of the nanocomposite films was confirmed using energy dispersive spectroscopy and Raman spectroscopy. The electrical properties of the nanocomposite films were investigated via various electrical parameters as determined through current-voltage, capacitance–voltage, and conductance–voltage graphs. Photoresponsive and photosensitivity properties were also assessed using a solar simulator at various illumination intensities. It was concluded that nanocomposite thin films were responsive to light, where photosensitivity and photoresponsivity increased with increasing illumination intensity. The electrical characteristics of the nanocomposite films were associated with the frequency of the AC voltage applied.

Influence of solvent additive on the performance and aging behavior of non-fullerene organic solar cells

The performance of organic solar cells has improved significantly in recent years due to the use of non-fullerene acceptors (NFA). While processing additives are typically added to the active layer blends to enhance device performance in NFA organic solar cells, their impact on device degradation remains unclear. In this work we have compared the performance, in pristine and degraded state, between air-processed slot-die coated NFA ITO-free organic solar cells with and without the processing additive DIO, using a structure of PET/Ag/ZnO/PBDB-T:ITIC/FHC PEDOT:PSS. We observed an improvement in the power conversion efficiency of the devices when adding DIO, from 4.03% up to 4.97%. The evolution of the performance for both devices under ISOS-L1 life testing protocol reveals that the drop in efficiency is mainly due to a decay of JSC for both cells. In the short time scale the efficiency of non-DIO cells decays faster than the DIO cells, whereas in the long time scale the efficiency of non-DIO cells tends to stabilize sooner. Carrier mobilities estimated from impedance measurements decrease with time at similar rate for both degraded samples. Besides, DIO devices present a steep increase of the series resistance with time causing a decrease of the FF and thus of the efficiency. Moreover, in both degraded devices, the open-circuit voltage saturates with increasing illumination intensity. Numerical simulations reveal that a reduced anode work function of 5 eV is needed to fit experimental data.

Combined effects of visual-acoustic-thermal comfort in campus open spaces: A pilot study in China's cold region

To investigate the combined effects of thermal, acoustic and visual comfort in open spaces, this study selected five typical spaces on a university campus with five common sounds (broadcasting music, running water & birdsong, wind (a gentle breeze) & insects, crowds, and machines) in a cold region of China. 418 volunteers were asked to complete a subjective sensory questionnaire in a randomly combined audio-visual environment while meteorological measures were taken on-site. Four primary outcomes emerged. First, broadcasting music improved individual subjective thermal comfort votes (TCV). Under the moderate heat stress (0.5 ≤ thermal sensation vote [TSV] ＜ 2.5), a comfortable acoustic environment helped reduce individuals' subjective TSV and increase TCV. Second, the subjective acoustic comfort vote (ACV) of broadcasting music, wind & insect sound and machine noise decreased with the increase of Universal Thermal Climate Index (UTCI); respondents perceived crowds, machines and wind & insects louder when TCV = 2 and −2. Third, under no thermal stress (−0.5 ≤ TSV ＜ 0.5)/moderate heat stress (0.5 ≤ TSV ＜ 2.5), TSV increased with increasing illumination intensity (LUX). Under the strong heat stress (2.5 ≤ TSV ≤ 3), there was no significant difference in TCV among subjective visual comfort vote (VCV) levels. Finally, when the LUX class was neutral/slightly bright, respondents felt darker in thermo-neutrality. Additionally, VCV and TCV were positively correlated under each LUX class.

Epithelial Complications in Various Corneal Collagen Crosslinking Protocols

This literature review describes epithelial complications that occur after corneal collagen crosslinking. Currently, the standard, different variants of the transepithelial and accelerated protocols, as well as their combination, are used. Moreover, in most cases, there are problems and complications associated with de-epithelialization or with impact to the preserved epithelium, both with special substances that destroy tight connections between epithelial cells, and with UV radiation, which supplied with increased illumination intensity and in a shorter time. At the same time, the development of many new options for various modifications and protocols for the corneal collagen crosslinking in order to preserve the epithelium and, thereby, provide the comfort and safety for the patient, can lead to a vicious circle in the form of epithelial complications and a decrease in the effect of the procedure. Therefore, it is important to conduct more complete, standardized studies aimed at a comprehensive assessment of all aspects and parameters of the corneal crosslinking procedure.

Kinetics of the Light and Elevated Temperature Induced Degradation and Regeneration of Quasi-Monocrystalline Silicon Solar Cells

We investigate the degradation and regeneration behavior of quasi-monocrystalline silicon passivated emitter and rear cells under illumination at elevated temperatures. The decrease and increase of the solar cell efficiencies over time is accelerated under increased temperature or illumination intensity. We examine the defect activation kinetics and determine rate constants both for the degradation and regeneration. We apply temperatures in the range of 37-140 °C and illumination intensities in the range of 0.1-1.4 suns. These conditions typically occur when operating solar modules in the field. The rate constants are strongly increased with increasing temperature and increasing illumination intensity. We perform multiple regressions fits of the degradation and regeneration data with different approaches for the illumination intensity dependence. A linear illumination intensity dependence on the rates of degradation and regeneration is found. Activation energies for the degradation and regeneration of (0.89 ± 0.04) eV and (1.07 ± 0.07) eV, respectively, are extracted that allow for identification of the defect activation and deactivation mechanisms.

Photonic resonator interferometric scattering microscopy

Interferometric scattering microscopy is increasingly employed in biomedical research owing to its extraordinary capability of detecting nano-objects individually through their intrinsic elastic scattering. To significantly improve the signal-to-noise ratio without increasing illumination intensity, we developed photonic resonator interferometric scattering microscopy (PRISM) in which a dielectric photonic crystal (PC) resonator is utilized as the sample substrate. The scattered light is amplified by the PC through resonant near-field enhancement, which then interferes with the <1% transmitted light to create a large intensity contrast. Importantly, the scattered photons assume the wavevectors delineated by PC’s photonic band structure, resulting in the ability to utilize a non-immersion objective without significant loss at illumination density as low as 25 W cm−2. An analytical model of the scattering process is discussed, followed by demonstration of virus and protein detection. The results showcase the promise of nanophotonic surfaces in the development of resonance-enhanced interferometric microscopies.

The Electrical Properties of Fabricated Pentacene Based Phototransistor with Polystyrene Gate Insulator

In this study, the fabrication of top contact pentacene based phototransistor having polystyrene gate dielectric has been carried out. To analyze the surface morpholgy of polystyrene insulator and pentacene active layer, scanning electron microscopy (SEM) has been used. The electrical characterization of pentacene based phototransistor and also the effect of illumination on the output characteristics have been investigated. The obtained mobility value and on/off ratio of the transistor are 5×10-3 cm2/Vs and ~102, respectively. The increase of the drain current with increasing illumination intensity indicates that the light acts as an additional terminal. Also, this fabricated device behaves as a phototransistor because of its reaction to the illumination.

Real-Time Tracking the Electrochemical Synthesis of Au@Metal Core-Shell Nanoparticles toward Photo Enhanced Methanol Oxidation.

Single particle plasmon scattering can provide real-time imaging information on the synthesis of nanomaterials. Here, an electrochemical deposition strategy is reported to synthesize plasmonic Au@Metal core-shell nanoparticles (Au@M NPs), which exhibit localized surface plasmon resonance (LSPR) properties. Because of the excellent catalytic activity of the methanol oxidation reaction (MOR), Pt, Pd, and Rh were reduced on the surface of Au NPs to form monometallic and bimetallic shells. Under dark field microscopy (DFM), the scattering changes could be utilized to track the surface nucleation and bulk deposition process. The synthesized Au@M NPs, which combined the plasmonic and electrocatalytic features, showed greatly enhanced activity for MOR. Under LSPR excitation, the electroxidation process toward MOR was accelerated and increased approximately linearly with increased illumination intensity, which could be mostly attributed to the generation of energetic charge carriers. This strategy of real-time plasmonic tracking electrochemical deposition at the single particle level is facile and universal, which could be extended to the precise synthesis of other plasmonic core-shell nanomaterials and the investigation of the pathway of plasmon accelerated chemical conversion.