Increasing Flow Rate Research Articles

Fe3O4/Au@SiO2 nanocomposites with recyclable and wide spectral photo-thermal conversion for a direct absorption solar collector

The Fe3O4-based photothermal materials have been widely applied for the recycling of heavy metal nanoparticles to avoid secondary pollution in the utilization of solar energy owing to excellent magnetic properties. However, the narrow absorption band of Fe3O4 or metal nanoparticles limits their capacity for solar energy harvesting. In this paper, a recyclable and wide spectral photo-thermal conversion system (Fe3O4/Au@SiO2) based on Fe3O4 nanospheres and SiO2-modified Au nanorods (NRs) is prepared. Owing to the strong coupling effect between Fe3O4 and different Au NRs, the wide and strong absorption band from 400 nm to 1100 nm is obtained. Under the influence of magnetic field, the temperature change of nanofluids (NFs) at different positions can be controlled. When the concentration is 0.0467 vol%, the solar energy absorption fraction reaches 96.50 %. Besides, the photothermal performance of Fe3O4/Au@SiO2 NFs at different flow rates is investigated and the results show that temperature rise decreases as increasing flow rate. Finally, a water evaporator device based Fe3O4/Au@SiO2 NFs is developed. The maximum water evaporation rate of 2.6 kg m−2 h−1 can be reached and the movement of evaporator on water can be operated using magnetic field, showing great photothermal conversion performance and recovery potential in practical applications.

Computational fluid dynamics modeling of gas bubble separation efficiency in downhole separators and vertical / inclined annulus: An experimental validation and analysis

This study presents a comprehensive investigation into gas bubble separation efficiency in a vertical downhole separator using computational fluid dynamics (CFD) modeling, which is validated with experimental data. The research aims to provide detailed insights into the separation mechanisms and the factors affecting them, such as liquid velocity, gas bubble sizes, and positions. Using an Euler-Lagrange multiphase model, the behavior of individual gas bubbles within the liquid-gas mixture was simulated. The results demonstrate that separation efficiency decreases as the liquid flow rate increases. This reduction in efficiency occurs because the increased liquid flow rate drags more bubbles within the stream, making it harder for them to separate. The separation process is primarily driven by the buoyancy force acting on the bubbles and the velocity profile of the liquid flow. Smaller bubbles, which tend to be near the casing wall, separate more efficiently, while larger bubbles are predominantly located between the second and third quarters of the annulus space. The "quarters" refer to radial divisions from the casing wall to the tubing wall, with the first quarter closest to the casing wall and the fourth quarter closest to the tubing wall. The study introduces a nonlinear regression model based on the numerical results to predict liquid slug separation efficiency. This model, validated against experimental data, accurately predicts separation efficiency and offers a robust methodology for estimating the efficiency of gravity-driven gas-liquid separators. This methodology is crucial for refining separator design and improving the operational efficiency of downhole separation systems, which are vital for enhancing the performance of pumping systems in oil and gas wells. The contributions of this study include a deeper understanding of the downhole separation process, the development of a simplified model for assessing bubble separation efficiency, and the potential application of the proposed methodology to different gas-liquid separator designs and inclination angles, thereby informing the design and operation of downhole separation systems.

Stretch-induced hepatic endothelial mechanocrine promotes hepatocyte proliferation

Background & Aims: Partial hepatectomy (PHx)-induced liver regeneration causes the increase in relative blood flow rate within the liver, which dilates hepatic sinusoids and applies mechanical stretch on liver sinusoidal endothelial cells (LSECs). Heparin-binding EGF-like growth factor (HB-EGF) is a crucial growth factor during liver regeneration. We aimed to investigate whether this sinusoidal dilation-induced stretch promotes HB-EGF secretion in LSECs and what the related molecular mechanism is. Approach & Results: In vivo PHx, ex vivo liver perfusion and in vitro LSEC mechanical stretch were applied to detect HB-EGF expression in LSECs and hepatocyte proliferation. Knockdown or inhibition of mechanosensitive proteins were used to unravel the molecular mechanism in response to stretch. This stretch triggers amplitude- and duration-dependent HB-EGF up-regulation in LSECs, which is mediated by Yes-associated protein (YAP) nuclear translocation and binding to TEAD. This YAP translocation is achieved in two ways: On one hand, F-actin polymerization-mediated expansion of nuclear pores promotes YAP entry into nucleus passively. On the other hand, F-actin polymerization up-regulates the expression of BAG family molecular chaperone regulator 3 (BAG-3), which binds with YAP to enter nucleus cooperatively. In this process, β1-integrin serves as a target mechanosensory in stretch-induced signaling pathways. This HB-EGF secretion-promoted liver regeneration after 2/3 PHx is attenuated in endothelial cell-specific Yap1-deficient mice. Conclusions: Our findings indicate that mechanical stretch-induced HB-EGF up-regulation in LSECs via YAP translocation can promote the hepatocyte proliferation during liver regeneration through a mechanocrine manner, which deepens the understanding of the mechanical-biological coupling in liver regeneration.

EXPERIMENTAL STUDY ON THE FRACTURE CONDUCTIVITY IN SHALE OIL PRODUCTION

Unconventional oil and gas resources, such as shale oil and gas, are gradually attracting great attention from all countries of the world. Horizontal drilling and large-scale hydraulic fracturing technology are used to efficiently extract oil from shale formation. Effective placement of the proppant in the fractures and high long-term conductivity are the keys to solve the problems of oil well flow rate increase in shale oil and gas fields. In this work, the sieve analysis method and FCMS-V fracture conductivity determination device, as well as scanning electron microscope are used. They are used to experimentally investigate the filtration characteristics of hydraulic fracturing fractures and establish the key factors affecting the filtration characteristics. The object of the study is the core of the oil-saturated DG shale formation of Songliao Basin. Also in this paper, the indentation and crushing mechanism of proppant under reservoir conditions is studied. The influence of various factors was evaluated qualitatively and quantitatively. The following studies were conducted: the effect of sand granule size on conductivity, the effect of grain size distribution on conductivity, the effect of proppant concentration on conductivity, the effect of fracture closure pressure on conductivity, and the effect of proppant indentation on conductivity. The granule sizes of the proppant used range from 30/50 to 70/140 mesh. Proppant concentration: 2,5; 5; 10 kg/m2. Ratios of granule sizes for used mixtures: 1:1:1, 1:2:7, 1:4:5.And crack clamping pressure from 20 to 40 MPa. As a result of the study, dependences of initial and long-term fracture conductivity on clamping pressure, granulometric composition of proppant and its concentration were obtained. Using a scanning electron microscope, the degree of indentation and crushing of proppant under reservoir conditions in two media, namely shale core and steel plates, was visually evaluated. The results of experimental studies can be used to optimize the shale oil development system and have scientific and practical significance for shale oil production in continental deposits.

Influence of nanoparticle concentration on the flow regimes of crude oil – Nanosuspension in a microchannel

This paper presents the results of an investigation into the effect of silica nanoparticles on two-phase flow regimes in a Y-shaped microchannel. The following fluids were subjected to investigation: oil, water, and a water-based suspension containing SiO2 nanoparticles at a weight concentration of 1 ≤ φ ≤ 10 %. A systematic investigation of the flow regimes revealed the following: slug, parallel, and droplet regimes. The ranges of existence of the obtained flow regimes were determined and flow regime maps were constructed as a function of fluid flow rates and dimensionless numbers. The results of the study demonstrated that the slug length and frequency of slug formation are influenced by varying silica concentrations. Furthermore, the correlation between slug length and nanoparticle concentration remains consistent as the suspension flow rate increases. The dependence of the ratio of oil layer width to channel width for suspensions with varying nanoparticle concentrations was quantified. A mathematical simulation of two-phase flow of immiscible fluids was conducted. The results of the numerical simulation demonstrated the existence of the flow regimes that had been previously identified through experimentation. The aforementioned methodology may therefore be employed for the investigation of the two-phase immiscible flow of oil and nanosuspension.

Three-dimensional numerical simulations and experimental studies on the viscoelastic rheological and deformation behavior of polymer catheter in gas-assisted extrusion processing

Gas-assisted extrusion is an effective method for improving the deformation behavior of polymer catheters during extrusion. However, the underlying mechanisms that dictate how geometrical and constitutive models influence the complex rheological behavior of the melt are not yet fully understood, which hinders further utilization and optimization. In this study, the three-dimensional (3D) gas–liquid–gas model for catheter gas-assisted extrusion was constructed. Subsequently, the Bird–Carreau model and the Phan–Thien–Tanner (PTT) model were employed in finite element numerical simulations to analyze the complex behavior. For comparative analysis, simplified two-dimensional (2D) model numerical simulations were also conducted. Additionally, experiments on catheter gas-assisted extrusion and parameterization studies of key constitutive model parameters were performed. The findings indicate that the 3D model, when integrated with the PTT constitutive model, demonstrates superior predictability and aligns more closely with experimental results. Furthermore, as the flow rate increases, discrepancies among different models diminish, and the distance required for the melt and gas to achieve motion equilibrium decreases. The internal mechanisms behind these phenomena are elucidated through the analysis of velocity and stress field distributions. This research enhances our understanding of the complex rheological behavior in polymer catheter gas-assisted extrusion, providing valuable insights for both academic research and industrial production in this field.

Experimental evaluation and artificial neural network modeling of heat transfer performance of aerosolized magnesium oxide nanoparticles flow through pipes

This study presents a novel approach to modeling the convective heat transfer coefficient (CHTC) of aerosolized magnesium oxide (MgO) nanoparticles in a circular pipe using artificial neural network (ANN) technique, by leveraging experimental data. The work addresses a gap in existing research on the heat transfer characteristics of nanoaerosols under varying thermal and flow conditions. MgO nanoparticles (30-50 nm) were dispersed in compressed air at volume fractions of 0.005, 0.01, and 0.05 to generate the nanoaerosol. This aerosol was then driven through the pipe at volumetric flow rates between 10 and 50 liters per minute (lpm). The pipe was subjected to controlled heat fluxes of 4546.83 W/m², 9093.66 W/m², and 13640.49 W/m² to evaluate the aerosol heat transfer coefficient (AHTC). Experimental results demonstrated that incorporating MgO nanoparticles significantly enhanced the heat transfer coefficient by up to 1.4 %, 111 %, and 89.7 % at the specified heat flux values, corresponding to increases in the volumetric flow rate from 10 lpm to 50 lpm, respectively. An ANN-based correlation was developed to model the heat transfer coefficient in relation to heat flux, particle volume fraction, and volumetric flow rate. This model accurately predicted the experimental data, achieving a mean absolute percentage error (MAPE) of 9.9 × 10-5, a mean square error (MSE) of 0.038433, and a coefficient of determination (R²) of 0.99. These findings confirm the ANN model's efficacy in predicting the enhancement of the nanoaerosol heat transfer coefficient and provide a robust tool for future thermal management applications involving nanofluids.

Droplet motions directed by an expansion section in the T-junctions

The controlled motion of droplets in microfluidic chips is a preliminary requirement to realize their functions. The influence of the expansion section on the droplet motion is mainly investigated in the T-junction. The droplet dynamic characteristics are analyzed at the junction and the applicable flow rate of the expansion section is explored. The expansion section can reduce the entered length and motion time of the droplet when droplets flow into the channel with it, and finally avoid the possibility of droplet splitting. Even under a large difference of the branch flow rate, the expansion section can direct the droplet into its located channel. It is found that with the increase in continuous phase flow rate, the effect of the expansion section on the droplet motion behavior is gradually weakened until it disappears. Moreover, the critical conditions of it can be obtained by theoretical calculation. The expansion section can direct droplet motion in both symmetric and asymmetric junctions. However, it is mainly achieved by influencing the interfacial tension of the droplets in the symmetric junction, while the key force is related to the droplet motion in the asymmetric junction. Specifically, the expansion section influences the differential pressure force to direct the droplet in the flow into the side branch (with expansion section) mode, but it varies the interfacial tension of the droplet in the flow into the main branch mode.

Computational investigation of both geometric and fluidic compressible turbulent thrust vectoring, using a Coanda based nozzle

This study addresses the challenge of enhancing aircraft maneuverability, particularly for vertical landing and takeoff, focusing on the fluidic aerial Coanda high efficiency orienting jet nozzle that employs the Coanda effect to achieve thrust vectoring. This research advances understanding of the interplay between geometric and fluidic factors in thrust vectoring. Stationary, turbulent, and compressible flow conditions are assumed, employing Favre-averaged Reynolds-averaged Navier–Stokes approach with the standard k-ε model. Computational solutions were obtained using a pressure-based finite volume method and a structured computational grid. The key findings include thrust vectoring enhancement due to an increase in the total mass flow rate, septum position (at no shock wave-related issues), and Reynolds number. In addition, shock wave formation (at specific mass flow rates and septum positions) considerably affects thrust vectoring. These insights are crucial for optimizing Coanda-based nozzle design in advanced propulsion systems, including in unmanned aircraft vehicles.

Exploring cavitation dynamics and noise reduction in hydraulic machinery with bionic leading edge impeller

Cavitation and induced noise are common issues in the operation of mixed-flow pumps, affecting their stability. Studying these phenomena is of both academic and engineering interest. Previous research has mainly focused on modifying the impeller blade profile or optimizing the pump structure to reduce cavitation and noise. In this paper, we apply a bionic design to the mixed-flow pump impeller by mimicking the natural shape of a humpback whale's pectoral fin on the leading edge of the blade. We compare the cavitation suppression and noise reduction effects of this design with those of a conventional mixed-flow pump. Unsteady flow calculations for the original pump at different flow rates revealed that at its rated speed, increasing flow rates led to lower pressure in the low-pressure region on the suction surface of the impeller, expanding the cavitation-prone area. By applying the bionic design, we studied the unsteady cavitation flow and its induced noise. Results showed that the impeller and guide vane experienced larger pressure pulsations at the rotation frequency and its multiples. The bionic modification increased the cavitation initiation speed and reduced the cavity volume within the runner. With an NPSH (net positive suction head) of 6.76, the void volume in the bionic pump was only 79% of that in the original pump, and the head increased by 16%. Additionally, the bionic design reduced the maximum far-field sound pressure level by 12.5%, achieving significant noise reduction. This study demonstrates that the bionic design effectively controls dynamic flow separation, reduces flow-induced noise, and enhances the mixed-flow pump's performance. These findings have important theoretical and practical implications for optimizing mixed-flow pump design, improving energy efficiency, and reducing noise.

Feasibility study on the heat transfer enhancement of gap flow induced by wasted vibration of linear compressor body

Refrigerators account for 20–30 % of household electricity consumption, with the compressor contributing to 80 % of the total consumption. Therefore, it is essential to increase the compressor efficiency. One approach to enhance compressor performance involves increasing heat dissipation to lower the temperature of the suction system and boost the refrigerant density entering the suction chamber. To achieve that innovatively, we harnessed the waste vibration of the linear compressor body to create a gap flow between the body and the housing, enhancing compressor performance by augmenting heat dissipation. Measurements of gap flow temperature, cylinder surface temperature, and heat flux on the cylinder surface were conducted, varying the RPM, gap size, and the shape of the gap flow path. We also observed variations in the gap flow rate with RPM and stroke. The results revealed that gap temperature and heat flux increased with higher RPM and smaller gap size, and the application of ribs to the gap flow path proved to be more effective in enhancing temperature and heat flux. Additionally, it is anticipated that heat flux will further increase with a longer stroke as the flow rate increases. Therefore, to optimize heat dissipation through gap flow using the waste vibration of the compressor body, it is advantageous to employ a smaller gap size, higher RPM, longer stroke, and apply ribs to the gap flow path. Future research should focus on verifying the effectiveness of increased heat dissipation and improved Energy Efficiency Ratio (EER) through actual compressor experiments.

Index-Based Alteration of Long-Term River Flow Regimes Influenced by Land Use Change and Dam Regulation

The growing population and expansion of rural activities, along with changing climatic patterns and the need for water during drought periods, have led to a rise in the water demand worldwide. As a result, the construction of water storage structures such as dams has increased in recent years to meet the water needs. However, dam construction can bring significant alterations to the natural flow regime of rivers, and it is therefore essential to understand the potential effects of human structures on the hydrological regime of rivers to reduce their destructive impacts. This study analyzes the hydrological changes in the Shahrchai River in response to the Shahrchai Dam construction in Urmia, Iran. The study period was from 1950 to 2017 at the Urmia Band station. The Indicators of Hydrological Alteration (IHA) were used to analyze the hydrological changes before and after regulating, accounting for land use changes and climatic factors. The results revealed the adverse effects of the Shahrchai Dam on the hydrological indices. The analysis showed an increase in the average flow rate during the summer season and a decrease in other seasons. However, the combined effects of water transferring for drinking purposes, a decrease in permanent snow cover upstream of the dam, and an increase in water use for irrigation and agricultural purposes resulted in a decrease in the released river flow. Furthermore, the minimum and maximum daily flow rates decreased by approximately 85% and 65%, respectively, after the construction of the Shahrchai Dam. Additionally, the number of days with maximum flow rates increased from 117 days in the pre-dam period to 181 days in the post-dam period. As a concluding remark, the construction of the Shahrchai Dam, land use/cover changes, and a decrease in permanent snow cover had unfavorable effects on the hydrological regime of the river. Therefore, the hydrological indicators should be adjusted to an acceptable level compared to the natural state to preserve the river ecosystem. The findings of this study are expected to guide water resource managers in regulating the sustainable flow regime of permanent rivers.

The role of Nature-Based Solutions for the water flow management in a Mediterranean urban area

Due to climate change and rapid urban sprawl, central Mediterranean regions are subjected to short but intensive storm events resulting in a significant increase of flow rates and runoff volumes in low-lying coastal urban areas. Within the framework of green urban infrastructures (GUIs), a suitable combination of Nature-Based Solutions (NBS) with traditional grey infrastructures should be adopted to mitigate flood risk effects in urban and sub-urban areas contributing at the same time to achieve multiple benefits for both the environment and the community. The aim of this study is (i) to evaluate flood hazard maps for identifying the areas within a Sicilian hydrological river basin (Toscano catchment) with a high risk of flooding by implementing the HEC-RAS model at catchment scale; (ii) to quantify the peak flow and floodplain area reduction; (iii) to assess the effectiveness of small-scale NBS (green roofs, porous pavements, rain gardens and rain barrel), in terms of peak flow and runoff volume reductions, at urban block scale by using the EPA SWMM model Model simulations are performed integrating the hydraulic (HEC-RAS) and hydrological (EPA SWMM) models for return periods of 10, 50 and 200 years. The results showed that the estimated peak flow (m3 s−1) obtained from the simulations performed at catchment scale for each T in the current scenario (without NBS) using HEC-RAS and EPA SWMM models are very close to each other (R2 = 0.99). In addition, the utopian scenario simulation showed the HEC-RAS model sensitivity to CN calibration achieving a peak flow reduction up to about 60% with the floodplain area decreasing up to about 17%. Finally, the model EPA SWMM shows its sensitivity to NBS implementation at urban block scale with a peak flow reduction up to about 16% and a runoff volume (mm) reduction up to about 24%. These reductions decrease as T increases with a higher NBS mitigation effects for the lowest T. The results highlighted that the integration of NBS in urban areas could have hydrological and hydraulic positive effects, particularly in terms of peak flow and runoff volume reduction. Furthermore, the results suggest that small-scale NBS have a potential to be effective to smaller rainfall events, but a combination with large-scale NBS is necessary to cope with extreme events.

Thermo-fluid dynamic numerical analysis of vestibule functions in a solar updraft tower

Solar updraft towers (SUTs) represent a promising avenue for renewable energy generation, leveraging solar energy to drive their operation. Although the collector of SUTs is generally vacant, ongoing research have focused on auxiliary structures inside the collector aimed at enhancing the overall efficiency. This study delved into the computational fluid dynamics (CFD) analysis of a SUT model featuring a 5 m radius collector and a 12 m height chimney. Specifically, we investigated the vestibule functions which created by implementing baffle inside the SUT collector with various radial locations. Through rigorous examination, the thermo-fluid dynamic effects of both roof-mounted and bottom-mounted baffles on SUT performance were explored, aiming to ascertain the optimal vestibule parameters. The vestibule was found to mitigate the backward flow leakage, isolate the inner room from the outside air, and enhance the heat exchange efficiency of the main flow. Notably, when the roof-mounted baffle was positioned at a radial location of 4.5 m, a remarkable 11.4 % and 28.1 % increase in the mass flow rate at the chimney outlet and kinetic power were achieved, respectively. These findings highlight the significant performance improvements achievable through the incorporation of a vestibule within SUTs of a given scale.

Research on jet electrochemical machining with coaxial megasonic assistance

In order to address the problem of poor localization in electrochemical machining (ECM), a coaxial megasonic assisted jet ECM method was proposed. Based on theoretical analysis, experiments were conducted to compare the effects of various electrolyte flow rates, electrolytic voltage and megasonic power levels on pit ECM. The results indicate that, in the range of experimental parameters, the increase of electrolyte flow rate and megasonic power can increase the machining depth, so as to improve the depth-diameter ratio of ECM pits. The use of coaxial megasonic-assisted jet ECM can enhance the depth-diameter ratio of etched pits compared to the without megasonic one. When applying a megasonic power of 22 W, the dimensions of the ECM pit were measured as 0.81 mm in depth and 5.73 mm in diameter, resulting in an depth-diameter ratio of 0.140. Under the same conditions, without megasonic assistance, the pit diameter is reduced to 0.65 mm while the pit depth increases to 6.36 mm, resulting in a depth-diameter ratio of 0.102. Additionally, The results also demonstrate that, the increase of electrolytic voltage makes the depth to diameter ratio of pit further increase on the original basis. With an electrolyte flow rate of 0.9 L/min and a megasonic power of 22 W, the use of electrolysis voltage of 50 V increased the depth-diameter ratio of etched pits to 0.173. Using the above preferred parameters, electrolytic milling of the wide groove is carried out. The depth-diameter ratio of the wide groove is increased from 0.039 to 0.059 by appending coaxial megasonic. This further verified the effectiveness of the coaxial megasonic-assisted jet ECM method.

Cadmium sequestration with MgCuAl-layered double hydroxide@montmorillonite nanocomposite in batch and circulated fluidized bed column experiments

In this study, montmorillonite cationic clay coated with MgCuAl-Layered double hydroxide nanoparticles was investigated for its capacity to adsorb cadmium ion (Cd2+) from aqueous solutions. Montmorillonite, MgCuAl−LDH, and a novel MgCuAl-Layered double hydroxide@montmorillonite nanocomposite (MCA−LDH@MMt) were characterized using various mechanisms including BET surface areas, XRD, TEM, FTIR, and SEM/EDS analysis. The adsorption behaviour of MCA−LDH@MMt towards Cd2+ ion was studied using batch and continuous flow systems. pH, contact time, initial Cd2+concentration, MCA−LDH@MMt dose and particle size, agitation speed, and temperature were examined in the batch system. The higher removal efficiency of Cd2+was reported at pH 5 at 70 mg/l initial concentration and 0.2 g/100 ml best adsorbent dose with 150 rpm. The adsorption of Cd2+ on MCA−LDH@MMt followed Langmuir model and yielded a maximum adsorption capacity of 129.82 mg/g. While the pseudo-second-order model better simulates the cadmium kinetics data, and adsorption rate parameters values showing that the adsorption process was chemisorption and the rate-determining step of controlling cadmium adsorption onto MCA−LDH@MMt not intra-particle diffusion. A three-phase, commonly known as gas-liquid-solid circulated fluidized bed column was used to continuously eliminate Cd2+. Four influencing parameters were studied: liquid and air flow rate, bed height, and initial Cd2+concentration. The adsorption efficiency of Cd2+in a continuous system increased when the liquid flow rate decreased and the bed height increased. The time required for MCA−LDH@MMt to reach saturation increases as the bed height and the air flow rate increase. Column data were described using Bohart-Adams, Thomas, and Yoon and Nelson models of adsorption for given experimental conditions. The Bohart-Adams could represent the initial regime of the breakthrough curves, while the Thomas model was better at describing the whole curve of metal ion adsorption for a given experimental condition.

Effects of CrC interlayer on tribocorrosion properties of DLC-coated TC4 alloy in a 0.9 wt% NaCl solution

In this study, DLC coatings with varying thicknesses of CrC interlayers were fabricated on the surface of TC4 alloy by regulating the flow rate of C2H2. The effects of the interlayer layer on the microstructure, mechanical properties, corrosion resistance, and tribocorrosion resistance of DLC coatings were systematically investigated. The results show that as the C2H2 flow rate increases, the CrC interlayer exhibits the structure transitions from columnar crystals to amorphous, resulting in improved hardness. The hardness of the CrC40 interlayer reaches 17.2 GPa, significantly higher than the 9.3 GPa of the Cr underlayer. The CrC interlayer notably enhances the mechanical properties and adhesion strength of DLC coatings. The corrosion current density of the CrC40/DLC coating is 3.07 × 10−8 A/cm2, significantly lower than that of the DLC coating with only a Cr underlayer. Under high load conditions of 20 N, the tribocorrosion rate of the CrC40/DLC coating is reduced to 2.09 × 10−7 mm3.(N.m)−1, representing a significant decrease of 93.9 % compared to the DLC coating. The CrC40/DLC coating exhibits strong adhesion strength, appropriate internal stress and a relatively hard CrC40 interlayer, showing exceptional tribocorrosion resistance.

Preparation, microstructure and properties of Yb2O3-x optical hydrophobic films for infrared windows

In order to improve the adaptability of infrared windows in harsh wet environments, Yb2O3-x films were prepared by ion assisted reactive thermal evaporating deposition. The surface morphology, microstructure, composition, optical properties, hardness, residual stress and hydrophobicity of Yb2O3-x films were comprehensively characterized. The effects of the oxygen flow rate on the properties of the Yb2O3-x films had been explored. It is found that the root-mean-square roughness of the films increases as the flow rate increases from 10 sccm to 35 sccm. The crystallization characteristics are closely related to the oxygen flow rate, and the film prepared at 15 sccm exhibits the best crystallinity. X-ray photoelectron spectroscopy (XPS) testing shows that the ratio of Yb to lattice oxygen decreases, while the content of trivalent Yb ions in the film increases with increasing oxygen flow rate. Thin film prepared at lowest oxygen flow rate exhibits highest optical absorption, which is related to oxygen defects in the films. Moreover, films prepared at 15 sccm, 25 sccm and 35 sccm show good transparency in the long-wave infrared band. The hardness of the film prepared at 15 sccm is about 9 GPa. Due to change in density of the thin film, the compressive stress of the film decreases with increase of oxygen flow rate. The hydrophobicity of the film is affected by the surface chemical composition and surface roughness, and the maximum water contact angle is 100°. In a word, the Yb2O3-x films are found to be excellent hydrophobic protective coatings for infrared windows.

Synergistic interplay of photobioreactor mixing and static mixer configuration on Rhodoseupdomonas palustris’s growth and biohydrogen production

Inducing light/dark (L/D) cycles through mixing or recirculating the media in a photobioreactor improves light utilization for biohydrogen production during photoferentation. However, the mutual shading effect is a key challenge for photofermentation using purple non-sulphur bacteria (PNSB). In this study, mixing was explored as a mitigating methodology through the investigation of three different static mixer configurations: concentric, spiral, and half-moon, across four laminar flowrates: 1.2 L/min, 0.71 L/min, 0.31 L/min and 0.15 L/min. At 0.15 L/min, the half-moon and spiral static mixers significantly improved specific and cumulative hydrogen production by 11.2-fold and 114 %, respectively. Also, recirculating the fluid via a peristaltic pump resulted in a significant shearing effect, impacting cell viability. Inducing L/D cycles via a static mixer was thus beneficial for hydrogen production over an increased flow rate. Additionally, biomass productivity increased by up to 70 %, reaching a cell dry weight of 7.0 g/L with the spiral static mixer configuration at 0.15 L/min flow rate. Interestingly, this study found that the static mixers only significantly increased specific hydrogen production and light conversion efficiency at the lowest flow rate of 0.15 L/min, beyond which they showed no significant improvement in biohydrogen production. This indicates that high L/D cycling frequencies are unnecessary to alleviate the mutual shading effect for R. palustris, which is advantageous for upscaling. These findings emphasise the potential of static mixers as an alternative to increase light conversion efficiency and industrial hydrogen production.

Structural, mechanical, corrosion, and early biological assessment of tantalum nitride coatings deposited by reactive HiTUS

This study examined microstructure, mechanical, corrosion properties and initial biological evaluation of the tantalum nitride (Ta-xN, where x – nitrogen flow rate during deposition) coatings prepared by reactive High Utilization Sputtering (HiTUS) at various nitrogen flow rates (x = 0, 2, 4, 6, and 8 sccm). Coatings were deposited on a novel Mg alloy (Mgbal.-Zn0.9-Y2.05-Al0.25 at. %) containing long-period stacking ordered (LPSO) phases. The coatings' structure was analyzed using a combination of SEM/FIB/TEM techniques, while XRD determined the phase composition. The mechanical parameters investigated included hardness, indentation modulus, and scratch behavior. The corrosion resistance of the coatings with respect to the bare substrate was evaluated in chloride-containing solutions. The wettability and early biological assessment of the coatings were also examined. The phase evolution strongly influenced the hardness and indentation modulus. The Ta-xN coatings made at x = 2 sccm nitrogen corresponding to HCP-Ta2N exhibited the highest hardness and indentation modulus. An increase in nitrogen flow rates resulted in the formation of FCC structure with slightly reduced hardness and indentation modulus. In addition, Ta-xN coatings (x ≥ 4sccm) showed superior corrosion resistance compared to BCC structured α-Ta, enhancing the corrosion performance of the Mg-LPSO bulk substrate. Finally, at the early incubation stage (24 h), L929 fibroblasts exhibited better cell attachment to the Ta-6N coating than to the bare Mg-LPSO substrate.