Increase In Toughness Research Articles

Mode-I dynamic fracture evolution and energy dissipation of basalt fiber reinforced reactive powder concrete

Dynamic fracture experiments on basalt fiber reinforced reactive powder concrete (BFRRPC) were conducted using notched semi-circular bending (NSCB) specimens, aiming to investigate the Mode-I dynamic fracture characteristics. Based on the split Hopkinson pressure bar (SHPB) and digital image correlation (DIC) systems, this study focused on investigating the dynamic fracture toughness, fracture process zone (FPZ), crack propagation, fractal dimension of fracture path, and energy evolution of BFRRPC with different basalt fiber contents. The results show the basalt fiber break, pull-out and interface fracture in the matrix in the microscopic experiment results, which are the intrinsic reasons for the enhancement of fracture toughness in RPC due to the fiber presence. The increases in fracture toughness of BFRRPC range between 24.7% and 42.7%, with a notable enhancement observed when incorporating 1.0% basalt fiber content. The crack and the FPZ tip of BFRRPC can be located effectively by the method of displacement-strain mixed calibration. The addition of 1.0% basalt fiber content effectively delays the crack initiation in specimens, with crack initiation occurring earlier as the loading level increases. The CTOD and FPZ tip opening displacement have nothing to do with the loading level. Basalt fibers can lead to relatively lower and stable fractal dimensions of BFRRPC, effectively reducing the cracking degree and increasing the roughness of cracks. Basalt fiber effectively enhances the fracture energy of RPC. The dissipated energy is mainly composed of the energy consumed by the fracture (fracture energy) of BFRRPC, with the overall residual kinetic energy ratio (the ratio of residual kinetic energy to dissipated energy) generally below 1.90%.

Modelling of dislocations pile-ups at crack tip. Application to silicon

ABSTRACT The mechanical analysis of plastic zones at crack tip has progressed very little since the publication of the founding BCS model, 60 years ago. This two-dimensional model, and those that followed, consider the plastic zone as a pile-up of dislocations of one sign only. They assume that the crack absorbs the part of the dislocation loop of the opposite sign. Here the real three-dimensional problem is addressed and we demonstrate that the crack front behaves as an obstacle. This change of paradigm requires the plastic zone to be modelled as a two-sign dislocation pile-up. The model fits well with experimental observations in bulk silicon. In addition, the presence of dislocations of opposite signs completely modifies the amplitude of crack shielding. The closer the dislocation is to the crack front, the more significant the effect. Therefore, the increase in toughness observed experimentally is linked to the part of the loop attached to the crack front, and not to the expanding part of the loop. This conclusion is in direct contradiction to that provided by previous models.

Full bio-based flame retardant towards multifunctional polylactic acid: Crystallization, flame retardant, antibacterial and enhanced mechanical properties

The preparation of flame-retardant high-performance polylactic acid (PLA) composites by adding green flame retardants have always been a challenge. In this work, an intumescent flame-retardant PCR based on phytic acid, chitosan, and resveratrol was successfully designed. Adding 4 wt% of PCR, the PLA-PCR composite was classified as UL-94 V-0 grade, with a LOI value increasing from 19.7 % (pure PLA) to 26.0 %, a peak heat release rate decreasing from 433 to 344 kW/m2. Owing to excellent compatibility of PCR, the mechanical strength and toughness of PLA-PCR composites have been improved, as reflected by a ~ 16 % increase in tensile strength, a ~ 73 % increase in impact strength and a ~ 57 % increase in toughness. In addition, PCR also presented plasticization effect on PLA, making it easier to process. This work provided a highly efficient and environmental-friendly modification approach for the development of multifunctional polymers.

Comprehensive analysis of mode-I cracking in ice: Exploring full-range rate dependency

Ice, as a crystalline material, demonstrates a unique response in its mode-I fracture toughness to variations in loading rates, characterized by an initial decrease and subsequent increase in toughness. This phenomenon has been explored in limited studies. In this work, an extensive numerical analysis of mode-I ice cracking is conducted by using the distinct lattice spring model (DLSM). Norton-Bailey Drucker-Prager DLSM (NB-DP-DLSM) is initially employed to investigate the classical explanations of creep and stress relaxation for the anomaly observed in ice’s fracture toughness at lower loading rates, but this approach does not successfully replicate the experimentally observed strain rate dependency. Then, two rate-dependent constitutive models are introduced to further examine the mode-I fracture mechanics of ice. Our numerical simulations of three-point bending tests show that the relationship between fracture toughness and strain rate at lower levels is more accurately captured by rate-dependent models. For higher strain rates, our numerical modeling of notched semi-circular bending tests indicates that a rate-independent constitutive model can replicate the loading rate dependency of ice’s mode-I fracture toughness. In conclusion, these observations suggest that a reverse-stage-like dynamic constitutive model for DLSM can potentially capture the full range of loading rate dependencies observed in ice.

Constructing a multifunctional reactive MXene-based additive for micro-crosslinking polyurea elastomer to achieve superior mechanical properties and enhanced fire safety

The widespread application of polyurea (PUA) in protective coatings typically requires excellent flame retardancy due to real-world usage scenarios. However, the addition of flame retardant additives often compromises the material’s mechanical properties. In this study, a multifunctional reactive additive, MX-SP-NH2, was creatively prepared by covalently grafting spirocyclic pentaerythritol bisphosphorate disphosphoryl chloride (SPDPC) onto MXene (Ti3C2Tx) surfaces, followed by the introduction of 1,3-propanediamine (PDA) by the reaction with SPDPC. MX-SP-NH2 was then incorporated into PUA, participating in its crosslinking process and significantly enhancing both its mechanical strength and flame retardancy. Compared to the control PUA sample, the micro-crosslinked PUA sample with just 1.0 wt% MX-SP-NH2 demonstrated a 184.3% increase in tensile strength, a 126.1% increase in elongation at break, and a 436.3% increase in toughness. The flammability characterization revealed that the peak heat release rate, peak smoke production rate, and peak CO production rate were reduced by 31.7%, 28.9%, and 61.5%, respectively, indicating a substantial improvement in fire safety. Additionally, the flame retardant PUA-based flexible strain sensors demonstrated stable electrical signal responsiveness. This work has opened up new potential applications of PUA in flexible electronics.

A biodegradable, osteo-regenerative and biomechanically robust polylactide bone screw for clinical orthopedic surgery

Poly (L-lactic acid) (PLLA) has emerged as a promising orthopedic implant material due to its favorable strength and biodegradability. However, challenges such as low toughness and limited osteoinductivity hinder its widespread use in bone fixation. This study focuses on enhancing the toughness and osteogenic activity of PLLA-based orthopedic implants. Inspired by reinforcement techniques in the construction industry, we designed a structure comprising flexible fibers enveloped by PLLA/hydroxyapatite (HA) crystalline phases. Initially, PLLA/poly (butylene succinate-co-adipate) (PBSA)/HA composites with “sea-island” morphology were prepared through melt-compounding. Subsequently, the highly oriented PBSA fibers were in situ formed during microinjection molding for bone screw fabrication. Comprehensive investigation into the structural-mechanical property relationship revealed a significant increase in elongation at break (from 5.4 % to 59.4 % with an optimal PBSA/HA ratio), while maintaining a high stiffness and a slight decrease in tensile strength (from 62 MPa to 56 MPa). The flexural tests of the resulting composite bone screws demonstrated a significant increase in toughness. Additionally, the in vivo studies corroborated the osteogenic potential of the microinjection molded bone screws by using hematoxylin and eosin (HE) and Masson staining. The methodology presented in this study offers a promising approach for advancing PLLA-based fixation devices in bone repair applications.

A multi-linear constitutive relation considering the temperature effect on quasi-static mode I delamination in UD/MD laminates

In this study, a multi-linear constitutive relation taking into account temperature and fiber bridging is proposed for characterizing delamination behavior in composite laminates under various temperature conditions. An approach combining analytical solution and J-integral is also established for determining the cohesive parameters in the multi-linear constitutive relation. To validate the proposed constitutive relation, mode I quasi-static delamination experiments of unidirectional (UD) and multidirectional (MD) carbon/bismaleimide laminates are carried out at 25 ℃ (room temperature), 80 °C and 130 ℃. The experimental results show that the increasing temperature resulted in a monotonic increase in the fracture toughness of the UD laminates while affect the fracture toughness of MD laminates slightly. A FE model is established with the implementation of the proposed multi-linear constitutive relation using UMAT subroutine. Good agreements between the experimental and simulated results demonstrate the validity of the proposed constitutive relation, with the relative difference of peak load between predicted and experimental values less than 8.2 % and the relative difference of initial and steady-state fracture toughness between predicted and tested results less than 15 %. This study provides the possibility to numerically study the temperature effect on the delamination behavior of laminates and has promising applications in the damage tolerance design of composite structures.

End anchorage‐reinforcement CFRP systems for heat‐damaged beams with side NSM CFRP rope

AbstractThe efficiency of retrofitting systems with side near surface mounted (SNSM) CFRP ropes in boosting the flexural performance of intact/heat‐damaged reinforced concrete (RC) beams was investigated using a total of 14 RC beams (250 × 150 × 1450 mm) in two groups. In the first group, the beams were strengthened using SNSM CFRP ropes of a parabolic profile without and with end fan or hock anchorages, coupled with the implantation of lateral and/or vertical CFRP dowels in the high‐shear zone. The beams of the second group were repaired using similar configurations after being heated to 400°C in an electrical furnace for 2 h. A control beam in each group was designated as a reference. The mechanical performance and cracking sequence in all beams was evaluated under four‐point loading test setup. Heat‐damage resulted in reductions in load capacity and stiffness at 11% and 10%, yet an increase in toughness and displacement ductility by 18% and 20%, respectively. Implementing end hocks with end vertical and lateral dowels prevented concrete‐cover separation; imparting the best enhancement in structural performance for the repaired and post‐heated beams. All beams experienced flexural failure mode except for the heat‐damaged one, repaired with end‐hock anchorage without lateral doweling.

Experimental and Numerical Research on Fracture Properties of Mass Concrete Under Quasi-Static and Dynamic Loading

The dynamic fracture behavior of mass concrete is crucial to the dynamic analysis and safety evaluation of concrete dams subjected to strong earthquake shocks in the framework of fracture mechanics. In the presented research, cylindrical specimens with a ring of preset cracks were cast by three-graded mass concrete, and direct tension tests were performed with two loading rates considered, i.e., 10−6/s for quasi-static loading and 10−3/s for dynamic loading. The load–crack mouth opening displacement (P-CMOD) curves were obtained, from which the fracture toughness, fracture energy, and characteristic length of the mass concrete were obtained. In this process, the influence of the eccentricity in the tests was compensated by the numerical modeling of the tests. Next, the crack propagation process of the mass concrete was modeled using the extended finite element method. From the test results, it is found that, under quasi-static loading, the crack generally propagates along the interface between the aggregates and the matrix, while, under dynamic loading, more aggregates are fractured. As compared to the case of quasi-static loading, the energy absorption capacity, fracture energy, and fracture toughness increase for dynamic loading, while the characteristic length decreases. Moreover, the numerically predicted P-CMOD curves agree reasonably well with the experimental measurements.

Boosting the Strength and Toughness of Polymer Blends via Ligand-Modulated MOFs.

Mechanically robust and tough polymeric materials are in high demand for applications ranging from flexible electronics to aerospace. However, achieving both high toughness and strength in polymers remains a significant challenge due to their inherently contradictory nature. Here, a universal strategy for enhancing the toughness and strength of polymer blends using ligand-modulated metal-organic framework (MOF) nanoparticles is presented, which are engineered to have adjustable hydrophilicity and lipophilicity by varying the types and ratios of ligands. Molecular dynamics (MD) simulations demonstrate that these nanoparticles can effectively regulate the interfaces between chemically distinct polymers based on their amphiphilicity. Remarkably, a mere 0.1wt.% of MOF nanoparticles with optimized amphiphilicity (ML-MOF(5:5)) delivered ≈3.4- and ≈34.1-fold increase in strength and toughness of poly (lactic acid) (PLA)/poly (butylene succinate) (PBS) blend, respectively. Moreover, these amphiphilicity-tailorable MOF nanoparticles universally enhance the mechanical properties of various polymer blends, such as polypropylene (PP)/polyethylene (PE), PP/polystyrene (PS), PLA/poly (butylene adipate-co-terephthalate) (PBAT), and PLA/polycaprolactone (PCL)/PBS. This simple universal method offers significant potential for strengthening and toughening various polymer blends.

Energy Dissipation and Toughening of Covalent Networks via a Sacrificial Conformation Approach.

Covalent polymer networks find wide utility in diverse engineering applications owing to their desirable stiffness and resilience. However, the rigid covalent chemical structure between crosslinking points imposes limitations on enhancing their toughness. Although the incorporation of sacrificial chemical bonds has shown promise in improving toughness through energy dissipation, composite networks struggle to maintain both rapid recovery and stiffness. Consequently, a significant challenge persists in achieving a covalent network that combines high strength, stiffness, toughness, and fast recovery performance. To address this challenge, we propose a novel sacrificial structure termed "sacrificial conformation." In this approach, β-cyclodextrin is covalently embedded into the network skeleton as the sacrificial conformation element. Compared to traditional covalent networks (LCN), well-designed cyclodextrin-embedded covalent network (CCN) exhibit a 100-fold increase in Young's modulus and a 60-fold increase in toughness. Importantly, CCN maintains excellent elasticity, ensuring swift recovery after deformation. This sacrificial conformational strategy enables efficient energy dissipation without necessitating the rupture of chemical bonds, thereby overcoming the limitations of traditional approaches. This advancement holds great promise for the design and fabrication of advanced elastomers and hydrogels with superior mechanical properties and dynamic behavior.

Energy Dissipation and Toughening of Covalent Networks via a Sacrificial Conformation Approach

Covalent polymer networks find wide utility in diverse engineering applications owing to their desirable stiffness and resilience. However, the rigid covalent chemical structure between crosslinking points imposes limitations on enhancing their toughness. Although the incorporation of sacrificial chemical bonds has shown promise in improving toughness through energy dissipation, composite networks struggle to maintain both rapid recovery and stiffness. Consequently, a significant challenge persists in achieving a covalent network that combines high strength, stiffness, toughness, and fast recovery performance. To address this challenge, we propose a novel sacrificial structure termed "sacrificial conformation." In this approach, β‐cyclodextrin is covalently embedded into the network skeleton as the sacrificial conformation element. Compared to traditional covalent networks (LCN), well‐designed cyclodextrin‐embedded covalent network (CCN) exhibit a 100‐fold increase in Young's modulus and a 60‐fold increase in toughness. Importantly, CCN maintains excellent elasticity, ensuring swift recovery after deformation. This sacrificial conformational strategy enables efficient energy dissipation without necessitating the rupture of chemical bonds, thereby overcoming the limitations of traditional approaches. This advancement holds great promise for the design and fabrication of advanced elastomers and hydrogels with superior mechanical properties and dynamic behavior.

Reinforcement and Controlling the Stability of Poly(ε-caprolactone)-Based Polymeric Materials via Reversible and Movable Cross-Links Employing Cyclic Polyphenylene Sulfide.

Due to its biodegradation ability, poly(ε-caprolactone) (PCL) is a suitable alternative for packaging materials; however, its biodegradation can also lead to instability in its usage. Cyclic polyphenylene sulfide (7U) has been shown to form rotaxane structures with PCL by simple blending to generate the π-π stacking effect and movable cross-link. A 2-fold increase in toughness and no decrease in Young's modulus for the PCL-based polyurethane with 7U are observed. The rotaxane structures mainly exist in the amorphous regions and have no impact on the crystallinity of PCL. Under the catalysis of lipase in aqueous solution, the stability of PCL is improved due to the 7U's suppression of the attack from the enzymes on PCL. After dissolution of the PCL films in the organic solvent, the dispersion of 7U and the breakage of the cross-links lead to little suppression on degradation during the catalysis of lipase. Thus, the controlled stability of PCL using 7U can prolong the life span of the biodegraded PCL materials.

Development of a Composite Filament Based on Polypropylene and Garlic Husk Particles for 3D Printing Applications

Lignocellulosic waste materials are among the most abundant raw materials on Earth, and they have been widely studied as natural additives in materials, especially for polymer composites, with interesting results when it comes to improving physiochemical properties. The main components of these materials are cellulose, hemicellulose, and lignin, as well as small amounts of other polysaccharides, proteins, and other extractives. Several kinds of lignocellulosic materials, mainly fibers, have been evaluated in polymer matrices, and recently, the use of particles has increased due to their high surface area. Garlic is a spice seed that generates a waste husk that does not have applications, and there are no reports of industrial use of this kind of lignocellulosic material. Additive manufacturing, also known as 3D printing, is a polymer processing technique that allows for obtaining complex shapes that are hard to obtain with ordinary techniques. The use of composites based on synthetic polymers and lignocellulosic materials is a growing field of research. In the present work, the elaboration and evaluation of 3D-printed polypropylene–garlic husk particle (PP-GHP) composites are reported. First, the process of obtaining a filament by means of a single extrusion was carried out, using different GHP contents in the composites. Once the filament was obtained, it was taken to a 3D printer to obtain probes that were characterized using differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) was performed with the aim of evaluating the thermal behavior of the 3D-printed PP-GHP composites. According to the obtained results, the crystallization process and thermal stability of the PP-GHP composites were modified with the presence of GHP compared with pristine PP. Dynamic mechanical analysis (DMA) showed that the addition of GHP decreased the storage modulus of the printed composites and that the Tan δ peak width increased, which was associated with an increase in toughness and a more complex structure of the 3D-printed composites. X-ray diffraction (XRD) showed that the addition of GHP favored the presence of the β-phase of PP in the printed composites.

Bamboo fiber-enhanced UHPC: Early hydration and microstructural/mesoscale analysis

This study investigates the impact of incorporating bamboo fibers, a natural and renewable material, into ultra-high performance concrete (UHPC) on its early hydration, mechanical properties, internal relative humidity, autogenous shrinkage, and microstructure. The results show that adding bamboo fibers significantly improves various UHPC properties. Bamboo fibers regulate hydration and prolong the hydration process through their water absorption and retention abilities. With a fiber content of 1.0 vol percent (vol%), the compressive strength increases by 10.2 %, reaching 97.1 MPa, and at 2.0 vol%, flexural strength and toughness increase by 37.9 % and 739.5 %, respectively. Additionally, bamboo fibers help maintain internal relative humidity above 98 % during the first 7 days of curing and reduce autogenous shrinkage by up to 55.9 %. The fibers also optimize the microstructure by minimizing voids, with a 1.0 % fiber content reducing the void ratio to 1.64 %. This reduces large voids and improves the material's density. Overall, bamboo fibers show great promise in enhancing UHPC's structural performance and environmental adaptability while being a sustainable and cost-effective material.

Effect of short-time high-temperature stabilization on the microstructure and tensile property of severely deformed Al-Mg-Sc alloy

In this paper, the effect of short-time high-temperature stabilization on the microstructure and tensile property of the Al-Mg-Sc alloy deformed by equal channel angular pressing (ECAP) has been investigated. The results show that the 2-pass ECAP cannot completely refine the grain, and the distribution of the deformed structure is inhomogeneous. After short-time stabilization, the grain of the material is refined, the shear zone becomes small grains with a size of about 1 μm, and the non-uniform deformation structure is alleviated. This change results in a small reduction in strength but a large increase in toughness. Short-time stabilization also improves the workability of the material. Re-deforming the material by another 2 pass ECAP, the sample with short-time stabilization demonstrates fewer internal defects, a more uniform structure, and finer grains.

Aerated Concrete, Based on the Ash of Thermal Power Plants, Nanostructured with Water-Soluble Fullerenols

This study is devoted to the synthesis of aerated concrete by a non-autoclave method using ash from thermal power plants and a nanopreparation. Fullerenol-m was used as a nanopreparation. The fullerenol-m content in the sealing water of aerated concrete changed in the range of 0.00 ÷ 0.03 mas.%. The main performance characteristics of the nanostructured aerated concrete were studied, namely the compressive strength, impact toughness, thermal conductivity, density and moisture content. A significant improvement in the performance characteristics of the nanomodified aerated concrete compared to unmodified samples was demonstrated, which was most clearly manifested as an increase in impact toughness by several (three to five) times. The best performance characteristics of the modified aerated concrete were observed at a fullerenol-m concentration relative to the added cement within 0.022–0.028 wt.%. The authors attribute such a strong change and improvement in the physical, chemical and operational properties of aerated concrete when modified with fullerenol-m to the fact that fullerenol-m (a few thousandths of wt.%) has a very strong structuring effect on the sealing water and, as a consequence, on the resulting aerated concrete.

Influence of Y2O3 doping on the aging behavior and mechanical properties of ATZ ceramics

The aim of this study was to investigate the influence of the Y2O3 content on the mechanical properties and aging behavior of ATZ ceramic. For this purpose, an ATZ ceramic consisting of 80 wt% stabilized ZrO2 and 20 wt% Al2O3 with varying Y2O3 stabilizer content between 2 and 3 mol% was prepared. The samples were analyzed regarding their sintered density, grain size, hardness and fracture toughness. The results show an increase in fracture toughness and a decrease in hardness with decreasing Y2O3 content. In addition, the aging stability was assessed by analyzing the phase composition determined by X-ray diffraction after aging the samples for up to 150 hours in steam atmosphere at 134 °C and 2 bar. The aging stability decreases with decreasing stabilizer content. Nevertheless, by producing a very fine-grained material, high aging stability can be achieved despite reduced Y2O3 content.

Effects of binary sintering additives (SmF3-Sm2O3) and sintering temperature on β-SiAlON ceramic tool materials

β-SiAlON ceramic tool materials were fabricated via spark plasma sintering using binary sintering additives (SmF3-Sm2O3). The effects of SmF3 addition and sintering temperature on the densification, phase composition, microstructure and mechanical properties were studied. Furthermore, the corrosion behavior of β-SiAlON ceramic tool materials due to excessive SmF3 at high sintering temperatures (≥1700 °C) was revealed. The results indicated that SmF3 could promote the densification and generation of β-SiAlON. Higher SmF3 content and sintering temperature increased the aspect ratio and average grain size of β-SiAlON, which made fracture toughness increase and Vickers hardness decrease. The best density, fracture toughness and hardness of β-SiAlON ceramic tool materials were 3.204 g/cm3, 6.45 ± 0.07 MPa m1/2 and 16.72 ± 0.09 GPa. However, β-SiAlON was corroded by excessive SmF3 during high temperature sintering, resulting in deterioration in densification and properties.

PREDICTION OF STRENGTH DEPENDING ON THE INFLUENCE OF THE CHEMICAL COMPOSITION IN THE 40КХНМ ALLOY

Introduction. The study is devoted to the analysis of the influence of the chemical composition of the 40КХНМ alloy on its hardness. The relevance of the work lies in the fact that mechanical tests require significant material and time costs. For the operational assessment of metal quality criteria, it is proposed to apply mathematical modeling in the work. Materials and methods. A study of the effect of the chemical composition on the hardness of the 40KHNM alloy, which meets the requirements of the state standard 51397, was carried out. The results of the experiment. In the course of research, it was found that changes in the chemical composition of the 40КХНМ alloy significantly affect its mechanical properties, including hardness and resistance to shock loads. An increase in the content of carbon, molybdenum and chromium in the alloy leads to an increase in its hardness. This is with the formation of stronger carbide and molybdenum phases in the structure of the alloy, which leads to an improvement in its mechanical properties. Increased hardness makes the alloy more resistant to wear and increases its durability in operating conditions. An increase in the nickel content in the alloy leads to an increase in its resistance to shock loads. This is caused by an increase in plasticity and impact toughness of the alloy with an increased nickel content. Higher resistance to shock loads makes the alloy suitable for use in conditions that require high resistance to shocks, for example, in the production of machine parts and equipment. A mathematical model of the dependence of the strength of the alloy on the percentage content of the components of the chemical composition was built, which allows to control the indicators of the strength of the alloy in the process of its manufacture. Conclusions. The research results confirm that changes in the chemical composition of the 40КХНМ alloy have a significant impact on its mechanical properties. As a result of the experiments, it was established that the chemical composition of the metal significantly affects the hardness of the material. By changing the composition of the metal, it was possible to achieve a significant increase in hardness to levels that meet the requirements of quality standards. These results are an important step in optimizing the production processes and improving the properties of the final products from the 40КХНМ alloy.