Increase In Torrefaction Temperature Research Articles

Investigating the physical characteristics and antibacterial properties of the cork back from Quercus variabilis

This study presents for the first time results on structure feature, basic physical properties, torrefaction treatment, adsorption property, component content and antimicrobial properties of the cork back from Quercus variabilis. The cork back consisted of numerous white stone cell bundles with a dense and firm texture and irregularly shaped cells exhibiting considerable deformation and wrinkles. The cork back had the average density of 0.37 g/cm3, average hardness of 91.60 HA and the average thickness was 31.44 % of the total cork thickness. The average colorimetric parameters values of L*, a*, and b* of the cork back were 21.92, 2.34, and 6.42, respectively. Increasing torrefaction temperature increased the quality loss of the cork back, decreased energy yield and volatile matter content, and increased ash and fixed carbon content. With the elevation of fixed carbon, the higher calorific value of the cork back also increased. Following high-temperature torrefaction at 300 °C, the higher calorific value of cork back was 24.00 MJ/kg which increased by 30.29 % compared to untreated cork back. The cork back powder had significant adsorption performance for methylene blue and the maximum adsorption capacity could reach 511.61 mg/g. Compared with cork，the cork back had a high content of lignin and polysaccharides, with a suberin content of only 4.07 %. The total extractives content in cork back was 7.49 %. The water extractives of the cork back exhibited the most significant inhibitory effect on Escherichia coli, with the lowest inhibitory concentration recorded at 2 mg/mL. This research offers essential data for the processing and utilization of the cork back, which contributes to enhance the utilizing efficiency of cork resources.

Emissions and combustion characteristics of torrefied wood pellets

The influence of torrefaction temperature on the durability, combustion characteristics, and emissions of CO, CO2, NOX, and particulate matter (PM) from biomass pellets was studied. The pellets were torrefied under inert conditions at 225, 250, and 300 °C for 60 min. Physical properties, such as weight loss, fines percentage, pellet durability index (PDI), and water absorption, were evaluated using ISO standards. The weight loss increased with higher torrefaction temperatures. Torrefied pellets had lower water absorption than untreated pellets. Fines percentage increased with torrefaction temperature while PDI decreased. Torrefied pellets at 300 °C had the lowest PDI (82.7%), while 225 °C had the highest (98.0%). The energy density and heating values increased with torrefaction temperature from 22.0 MJ/kg at 225 °C to 29.9 MJ/kg at 300 °C compared to 18.9 MJ/kg for untorrefied pellets. There were reductions in CO, CO2, and NOX emissions with an increase in torrefaction temperature while PM slightly reduced. This study found that torrefied biomass pellets had lower CO2 emissions than raw pellets.

Two-step synthesis of biochar using torrefaction and microwave-assisted pyrolysis: Understanding the effects of torrefaction temperature and catalyst loading

The study focused on synthesizing the biochar from sawdust using torrefaction followed by pyrolysis. Sawdust was torrefied at different temperatures (125 °C, 150 °C, and 175 °C) using a conventional hot air oven. The obtained torrefied biochar was subjected to Microwave-assisted pyrolysis at a power of 300 W for 10 min. Graphite was used as a susceptor, and KOH was used as a catalyst. The maximum biochar product yield varied from 24 to 48 wt% and increased with torrefaction temperature. The average heating rates ranged from 54.5 to 74.6 °C/min. At 10 g of KOH, higher heating rates were obtained. The pyrolysis index analyzed varied between 97.5 and 111.5 and decreased with the increase in torrefaction temperature. The obtained biochar was analyzed using SEM, BET, XRD, FTIR, ICP-OES, and Raman spectroscopy. Porous structure formation enhanced, and the concentrations of Ca, Al, and Fe decreased with the increase in torrefaction temperature.

Aromatic hydrocarbons rich bio-oil production from Miscanthus pyrolysis by coupling torrefaction and MoO3/ZSM-5 dual catalysis process

The valorization of Miscanthus pyrolysis by coupling torrefaction and MoO3/ZSM-5 dual catalysis process was studied to generate the aromatic hydrocarbons rich bio-oil, biochar, and combustible gas. With the optimal conditions of torrefied Miscanthus at 280 °C, MoO3/ZSM-5 catalysis process converted 24.17 % bio-oil, 30.27 % biochar, and 45.56 % gas. The coupled system accessed bio-oil phase deoxygenation by reducing the oxygen-containing compound content to 6.27 %. The aromatic yield reached 91.38 %, with an outstanding benzene, toluene and xylene (BTX) selectivity of 52.24 %. Isolating investigations revealed that torrefaction declined the oxygen content of Miscanthus to 5.24 %, increasing their calorific value and promoting subsequent catalytic pyrolysis through deoxygenation. When only using the ZSM-5 catalyst, the increase in torrefaction temperature enhanced aromatic hydrocarbon compounds conversion in the bio-oil, leading to a boost in their content from 55.01 % to 75.97 %. Correspondingly, MoO3 promoted deoxygenation, decreased the ketone content from 40.4 % to 21.92 %, and inhibited the generation of aldehydes. The combination of MoO3 and ZSM-5 with torrefaction delivered a superimposed effect on yielding aromatic hydrocarbons and BTX, which allowed a promising product upgrading method for obtaining high-quality bio-oil.

CO2 capture performance of CaO-based sorbent modified with torrefaction condensate during calcium looping cycles

In this work, the organic acid-rich torrefaction condensate (TC) from biomass torrefaction process was attempted to replace commercial acetic acid (AC) for acidification treatment of CaO sorbent to improve its CO2 capture performance during calcium looping cycles. The results showed that TC-modified sorbents exhibited a much slower carbonation reactivity decay than the AC-modified one over the cycles. According to the results of characterizations (thermal decomposition, morphology, phase composition, and N2 adsorption), the enhanced cyclic stability was probably due to the presence of carbon deposition from the decomposition of heavy tar in TC, which might act as a spacer and protective overlay to slow down the sintering of CaO particles. In addition, more carbon deposition could be dispersed in-situ into the TC-modified sorbents by increasing torrefaction temperature and TC addition amount, resulting in more thorough carbon deposition overlay and better sintering resistance. However, excessive carbon deposition (>50 wt%) leaded to slightly lower carbonation conversions and rates in the first two or three cycles. But this deficiency would disappear in subsequent cycles, as some carbon deposition was consumed by the carbon dioxide released during calcination. And the carbonation conversion of TC-modified sorbent with a carbon deposition content of 69.1 wt% was still as high as 81.5% after 10 cycles.

Perubahan sifat fisis dan mekanis pelet bambu andong (Gigantochloa pseudoarundinaceae) setelah perlakuan torefaksi

Torrefaction has been well known to improve the properties of various biomass pellets. However, the study on torrefaction of andong bamboo pellet is still limited. This study aimed to evaluate the changes in the physical and mechanical properties of Andong bamboo (Gigantochloa pseudoarundinaceae) pellets resulting from torrefaction. The pellets were torrefied at 200°C, 240°C, and 280°C using an electric furnace for 50 min. The physical properties analyzed were color, moisture content, density, water adsorption, and resistance to water immersion. A compressive strength test examined the mechanical property. The results showed that the color of bamboo pellets torrefied at 200°C, 240°C, and 280°C were changed, showing overall color change (∆E*) values of more than 12. The lightness (L*) of the pellet remarkably decreased with the increase of torrefaction temperature. In other words, the pellet became darker with increasing temperature. The yellow/blue chromaticity (b*) was also decreased with increasing the torrefaction temperature. However, the red/green chromaticity (a*) increased at 200℃ but decreased at 240℃ and 280℃. Moisture content and pellet density decreased with increasing torrefaction temperature. The pellets’ water adsorption decreased as the torrefaction temperatures increased at 200℃, 240℃, and 280℃. The results also showed that the torrefied pellets were more resistant to water immersion than the control pellet as they could maintain their original form even after 24 h immersion test. The compressive strength decreased as increasing the temperature. The torrefaction temperature affected and improved the properties of Andong bamboo pellets.

Effect of Biomass Particle Size on the Torrefaction Characteristics in a Fixed-Bed Reactor

The aim of this study is to investigate the influence of biomass particle size on the torrefaction characteristics under different torrefaction temperatures and times. Paulownia wood with particle sizes ranging from 12 to <0.3 mm was selected. It was torrefied at 260 and 290 °C in a fixed-bed reactor for 30–90 min. The results showed that biomass particle size did affect the product’s evolution during biomass torrefaction. With the decrease in particle size from 12 to <0.3 mm, the yield of the solid product decreased by 5.41 and 3.54 wt.%, the yield of the liquid product increased by 5.87 and 3.25 wt.%, and the yield of the gas product changed insignificantly, at 260 and 290 °C, respectively. Comparatively, torrefaction temperature had a more significant effect on the composition of gas products than particle size and torrefaction time. At lower temperatures, decarboxylation reactions dominated in the torrefaction process with more CO2 produced. However, at higher temperatures, decarbonylation reactions were significantly strengthened with more CO generated. The contents of CO2 and CO could account for more than 98 vol% of the product gas. The influence of particle size on the chemical composition of the solid product was much smaller than that of torrefaction temperature and time, but the energy yield of the solid product decreased with the decrease in particle size. The increase in torrefaction temperature and time could significantly increase the C content in the solid product while reducing its O content. It is recommended to use a relatively higher temperature (e.g., 290 °C) for the torrefaction of large particle biomass, as it could significantly reduce the impact of particle size on the torrefaction process and reduce the torrefaction time.

Elucidating on Time and Temperature Effects on Torrified Moldy Bread

Waste-to-energy is the preferred solution, according to the waste management hierarchy considering landfill waste disposal may not be the most effective method of waste usage. Torrefaction of kitchen waste to produce higher-quality solid fuels is an effective option with lower temperature requirements than pyrolysis and gasification. By addressing the problems, the fuel quality in terms of high heating value can be investigated. Also, the torrefaction parameters, temperature and time, can be examined on the fuel performance. The moldy bread undergoes torrefaction by torrefying it in the furnace with temperatures of 200, 250 and 300°C, respectively, with 15, 30, 45 and 60 mins of processing times. With increased torrefaction temperature, the mass dropped while the higher heating value (HHV) increased. The rise in carbon content also enhanced the torrefied moldy bread's fuel properties. Also, this is because the primary components of the moldy bread, particularly hemicellulose, have significantly decomposed. Therefore, processed temperature of 300°C at elevation time of 45 min produced tremendous gain than other parameters observed.

Evaluation of Pyrolysis Reactivity, Kinetics, and Gasification Reactivity of Corn Cobs after Torrefaction Pretreatment

To reveal the effect of torrefaction pretreatment on pyrolysis and gasification reactivity of biomass, corn cob was first subjected to torrefaction pretreatment in a fixed-bed reactor at various reaction temperatures. The pyrolysis reactivity, kinetics, and gasification reactivity of torrefied corn cob were systematically assessed by various methods, proving that torrefaction pretreatment has a substantial influence on the physicochemical properties of corn cobs. The O/C and H/C molar ratios of corn cobs considerably drop with the increasing torrefaction temperature, and their higher heat-ing value (HHV) and energy density rise as well. It is found that torrefaction improves the pyrolysis reactivity of corn cobs because hemicellulose degradation is more severe than cellulose degradation during torrefaction, resulting in an increase in the percentage of cellulose in torrefied corn cobs. However, the severe depolymerization, polycondensation, and carbonization reaction during torre-faction of corn cobs at 280–300 °C can lead to a significant decline in the pyrolysis reactivity of corn cobs. Torrefaction pretreatment increases the pyrolysis activation energy of corn cobs, in addition to decreasing the char gasification reactivity of corn cob. The average char gasification reactivity of corn cobs drops when torrefaction severity increases. The passivation of active sites on the char surface may cause condensation and carbonation reactions of corn cobs during torrefaction. These findings provide new sights into the reasonable design of efficient torrefaction methods for appli-cation prior to pyrolysis and gasification of biomass.

The combined effect of solar assisted torrefaction and pyrolysis on the production of valuable chemicals obtained from water hyacinth biomass

In this study, both the torrefaction and pyrolysis of water hyacinth biomass samples were accomplished by using concentrated solar radiation. The first attempt was to prepare torrefied samples and then used those in the following pyrolysis process. The aim of preparing pretreated torrefied samples was to reduce moisture from the feedstock and make it perfect for the pyrolysis process besides improving product quality. Three different torrefied samples were prepared by pretreating at 200, 250, and 300℃. The pyrolysis operation was done by maintaining a reactor temperature of 440±10℃. Torrefaction severity had a greater influence on char yields. The char yield was found to be 27.4 wt.% for the non-torrefied sample (ST-Raw) while 42.3, 51.2, and 59.4 wt.% for torrefied samples of ST-200, ST-250, and ST-300 respectively. However, an increase in torrefaction temperature had negative consequences on bio-oil and syngas yields. The acidity of the bio-oils was greatly reduced with an increase in torrefaction temperature. The lowest acid content in ST-300 bio-oil sample was confirmed by the FTIR, and GC-MS analysis. This ensures that the torrefied bio-oils are more non-corrosive than non-torrefied bio-oils. The heating values of ST-300 bio-oils were found to be about 75% of diesel fuel. The char obtained in the pyrolysis process for all torrefied samples was of high quality and graded as peat or brown coal. Considering the characteristics of biomass, products, and method used in this study, solar pyrolysis is a promising technique to produce high-quality chemical intermediates. • The combined effect of solar torrefaction and pyrolysis on the products was investigated. • Torrefaction severity significantly increased char (27.4 to 59.4 wt.%) content. • Torrefaction severity improved the product's heating values. • Torrefaction reduced the acidity of bio-oils obtained in solar pyrolysis.

Improving Lignocellulosic and Non-Lignocellulosic Biomass Characteristics through Torrefaction Process

In this study, three locally available biomasses, namely miscanthus, hops, sewage sludge, and additionally, their mixtures, were subjected to the torrefaction process to improve their fuel properties. The torrefaction process was conducted at 250–350 °C and 10–60 min in a nitrogen (N2) environment. The torrefaction temperature and time were studied to evaluate the selected biomass materials; furthermore, heating values, mass and energy yields, enhancement factors, torrefaction severity indexes (TSI), and energy-mass co-benefit indexes (EMCI) were calculated. In addition, thermogravimetric (TGA) and Fourier transform infrared analyses (FTIR) were performed to characterize raw and torrefied biomass under the most stringent conditions (350 °C and 60 min). The results showed that with increasing torrefaction temperature and duration, mass and energy yields decreased, and heating values (HHVs) increased for all studied biomasses. The results of the TSI and EMCI indexes showed that the optimum torrefaction conditions were as follows: 260 °C and 10 min for pure miscanthus and hops, whilst this could not be confirmed for the sewage sludge. Furthermore, the combination of sewage sludge and the above-mentioned types of lignocellulosic biomass exhibited better fuel properties than sewage sludge alone.

Investigation of the Effects of Torrefaction Temperature and Residence Time on the Fuel Quality of Corncobs in a Fixed-Bed Reactor

Biomass from agriculture is a promising alternative fuel due to its carbon-neutral feature. However, raw biomass does not have properties required for its direct utilization for energy generation. Torrefaction is considered as a pretreatment method to improve the properties of biomass for energy applications. This study was aimed at investigating the effects of torrefaction temperature and residence time on some physical and chemical properties of torrefied corncobs. Therefore, a fixed-bed torrefaction reactor was developed and used in the torrefaction of corncobs. The torrefaction process parameters investigated were the torrefaction temperature (200, 240, and 280 °C) and the residence time (30, 60, and 90 min). The effects of these parameters on the mass loss, grindability, chemical composition, and calorific value of biomass were investigated. It was shown that the mass loss increased with increasing torrefaction temperature and residence time. The grinding throughput of the biomass was improved by increasing both the torrefaction temperature and the residence time. Torrefaction at higher temperatures and longer residence times had greater effects on the reduction in particle size of the milled corncobs. The calorific value was highest at a torrefaction temperature of 280 °C and a residence time of 90 min. The energy yield for all treatments ranged between 92.8 and 99.2%. The results obtained in this study could be useful in the operation and design of torrefaction reactors. They also provided insight into parameters to be investigated for optimization of the torrefaction reactor.

Catalytic pyrolysis of torrefied olive stone for production of potential petrochemical alternatives

AbstractBench‐scale fluidized bed fast pyrolysis of as‐received and torrefied residual olive stone (OS) was carried out at 500 °C in the presence or absence of a solid acid catalytic bed. Light to mild torrefaction conditions were investigated, with temperatures of 200, 225, and 250 °C, set in a bench‐scale fluidized bed torrefier. Light torrefaction temperatures (200 and 225 °C) did not yield appreciable differences in the thermogravimetric pyrolysis studies, despite notable changes in mass and energy yield resulting from the influence of temperature difference. The mass and energy yields decreased from 91.1 to 74.0% and from 92.0 to 80.9%, respectively, moving from light to mild torrefaction. The higher heating value (HHV) increased linearly with an increase in torrefaction temperature, reaching a maximum of 22.1 MJ/kg at 250 °C, which was 9.7% greater than the as‐received OS sample. A comparison was made between the influence of light and mild torrefaction on subsequent bench‐scale pyrolysis experiments. In particular, the quality of bio‐liquids for torrefaction coupled to fast pyrolysis shifted signifcantly towards the production of higher phenolic and aromatic derivatives that may find applications as potentaila drop‐in alternative hydrocarbons. © 2022 The Authors. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.

Effects of Torrefaction Temperature on the Characteristics of Betung (Dendrocalamus asper) Bamboo Pellets

The objective of this study was to evaluate the effects of torrefaction temperature on the physical and mechanical properties of betung bamboo (Dendrocalamus asper) pellets. Torrefaction was conducted in an electric furnace at 200°C, 240°C, and 280°C for 50 minutes. The physical properties evaluated included color change, density, moisture content, water resistance, and water adsorption. The mechanical properties were also investigated by compressive strength test. The result showed that torrefaction affected the color properties of betung bamboo pellets with ∆E values of more than 12 or totally changed. The density and moisture content of torrefaction bamboo betung pellets decreased with increasing torrefaction temperature. The results also showed that the hydrophobic properties of the bamboo betung pellets improved with the increased of torrefaction temperature. The highest compressive strength value was obtained by bamboo betung pellets torrefied at 200°C and the values decreased with the increase of temperature. In conclusion, there were differences in the physical and mechanical properties of bamboo betung pellets that were torrefied at different temperatures. Torrefaction with an electric furnace effectively improved the quality of betung bamboo pellets. Keywords: Bamboo betung, pellets, temperature, torrefaction

Effect of gas-pressurized torrefaction on the upgrading and pyrolysis characteristics of corn stalk

Corn straw was torrefied under different temperatures and pressures to verify the influence of gas pressure on the torrefaction of biofuel. The torrefied products were characterized by proximate analysis, ultimate analysis, FT-IR, TGA and pyrolysis experiments. The results indicate that the deoxidation efficiency and energy density of torrefied products under both atmospheric pressure (AP) and gas pressured (GP) conditions increase with the increase of torrefaction temperature. The temperature required for GP torrefaction is almost 40 °C lower than that for AP torrefaction to obtain the same mass yield. The energy yield, carbon yield, deoxidation efficiency and the energy density of GP-torrefied corn straw are 1.125, 1.142, 1.539 and 1.131 times higher than those of AP-torrefied one, respectively. The GP-torrefied samples show better hydrophobicity and are easier to dehydrate. In addition, the pyrolysis of GP-torrefied corn straw produces significantly higher fractions of CH4 and H2 in the gaseous product than the pyrolysis of AP-torrefied one. Meanwhile, the relative content of phenols in the liquid products for the pyrolysis of GP-torrefied samples increases up to 51.11%, whereas the contents of furans and acids decrease considerably. The results suggest that GP torrefaction performs better in biofuel upgrading than AP torrefaction under the same temperature.

Effect of torrefaction on thermal oxidative degradation kinetics of lignite using multi-distributed activation energy model

Torrefaction treatment is a promising method for lignite upgrading. However, its effect on the combustion characteristics has not been fully evaluated. In this study, the combustion characteristics of lignite and its upgrading samples by torrefaction were studied via non-isothermal thermogravimetric analysis. Results show that increasing the torrefication temperature decreases the volatile content while increasing the fixed-carbon in the fuels. The mole ratios of both H/C and O/C in the samples decreases as the torrefaction temperature increases. Torrefaction treatment significantly improves the combustion performance of lignite with a higher reactivity index S, and the optimum torrefaction temperature was determined to be 200 °C. The upgrading lignite by torrefaction at 200 °C has the lowest temperatures of Tf and Tp as well as the maximum corresponding DTG value. Furthermore, the results of three-parallel-DAEM model analysis results show that the activation energies corresponding to the three peaks are 176.1 kJ/mol, 186.5 kJ/mol and 221.7 kJ/mol, respectively, and that increasing torrefaction temperature had no significant effects on activation energies. With the torrefaction temperature increasing, the first standard deviation decreased while the third standard deviation increased.

Evaluating the effect of torrefaction on the pyrolysis of biomass and the biochar catalytic performance on dry reforming of methane

The torrefaction and pyrolysis experiments on hawthorn seed (HS) were carried out, and biochar obtained was utilized as a catalyst in dry reforming of methane (DRM) under microwave field. The product was characterized and analyzed to explore the influence of torrefaction on HS, subsequent pyrolysis process and catalytic performance of biochar. Results reveal that increasing torrefaction temperature enhanced deoxygenation and dehydration of solid product, thus increase gas and liquid product. And the yield of tar increases significantly with pyrolysis temperature. The carbon content of biochar with potential as carbon-based catalyst can exceed 80%. As torrefaction was implement before pyrolysis, not only was smokey flavor of tar improved, but also carbonization of biochar was further enhanced. As torrefaction temperature and pyrolysis temperature was respectively set at 300 °C and 600 °C, the biochar acquired could make the conversion rate of CH4 and CO2 reach 75% and 85% in the DRM reaction, respectively.

Solar pyrolysis of cotton stalks: Combined effects of torrefaction pretreatment and HZSM-5 zeolite on the bio-fuels upgradation

Solar pyrolysis of biomass is a novel method for bio-fuels production. In this study, cotton stalks were first subjected to solar torrefaction at 200–300 °C, and then subjected to solar catalytic pyrolysis at 550 °C. The effects of torrefaction deoxygenation pretreatment and HZSM-5 zeolite on the bio-fuels (gas, biochar, and bio-oil) upgradation was investigated. Results showed that the elements of cotton stalks removed via torrefaction follow the order of deoxygenation > dehydrogenation > decarbonization. Torrefaction pretreatment has a remarkably influence on the subsequent catalytic pyrolysis. The bio-oil and gas yields were considerably reduced while the biochar yield increased with increasing torrefaction temperature. The primary pyrolytic volatiles cracked under the HZSM-5 catalyst, followed by a series of deoxygenation and aromatization reactions to form H2O, CO2, CO, alkanes, olefins, and aromatic hydrocarbons. Consequently, the oxygen-containing functional groups were removed to generate hydrocarbons that were rich in bio-oil, meanwhile the selective yield of benzene, toluene, and xylene (BTX) increased remarkably. Moreover, the torrefaction pretreatment inhibited the formation of coke deposited on the catalyst and promoted the carbon yield in the biochar. Considering the benefits of electricity savings, the approach proposed herein is a potential way to improve the competitiveness of biomass-derived products.

A study on torrefaction of spent coffee ground to improve its fuel properties

Excessive use of fossil fuels has contributed significantly to global warming and the impending energy crisis, necessitating the promotion and development of alternative energy sources to achieve green energy or energy neutrality. Converting waste biomass into energy has a significance impact in solid waste management. Spent coffee grounds (SCG) are the primary residue from the coffee industry generated during the coffee brewing process. This study, therefore, aims to improve the fuel properties of SCG via torrefaction and investigates the characteristics of torrefied products. A horizontal tubular reactor, at temperatures ranging from 250 °C to 350 °C at 20 °C intervals, and residence times ranging from 0 to 30 min with 10-min intervals, were utilized for torrefaction. The associated physical and chemical transformations in SCG torrefaction were investigated using proximate and ultimate analysis, gas composition, thermogravimetric and derivative analyses along with Fourier Transform Infrared Spectroscopy (FTIR). The mass and energy yields decreased while the higher heating value increased with the increase in torrefaction temperature. Additionally, the decrease in the oxygen content and increase in the fixed carbon content helped to improve the fuel properties of the SCG. A torrefaction temperature of 290 °C and a residence time of 10 min was found to be the optimal conditions for SCG torrefaction.

Increasing the bio-aromatics yield in the biomass pyrolysis oils by the integration of torrefaction deoxygenation pretreatment and catalytic fast pyrolysis with a dual catalyst system

The integration of Torrefaction Deoxygenation Pretreatment (TDP) and Catalytic Fast Pyrolysis (CFP) with dual catalysts was employed to improve the yield of bio-aromatics (BTX) derived from Miscanthus. Results showed that the TDP could effectively remove the oxygen content up to 38.16% at 280 °C. This resulted in a remarkable reduction of undesired oxygenate compounds in the pyrolysis oil. With ZSM-5 catalyst, the dominant components in pyrolysis oil became aromatic hydrocarbons (up to 66.29%) instead of oxygenates. The selectivity of bio-BTX increased with the increase of torrefaction temperature up to 56.63%. For the pyrolysis process, the highest yield (37.54%) and selectivity (56.63%) of bio-BTX were obtained at 600 °C. Compared with ZSM-5, the addition of CaO and MoO3 promoted bio-BTX yield due to the enhanced deoxygenation and olefins aromatization. The integrated TDP and CFP with ZSM-5 and MoO3 significantly improved the selectivity of bio-BTX, reaching the highest selectivity of 70.69% and a yield of 51.07%. Combining these two processes can enhance bio-aromatics yields from biomass, thus considerably improving the quality and value of the liquid product.