Increase In Strength Research Articles

Bioinspired surface modification of mussel shells and their application as a biogenic filler in polypropylene composites

This study explores the potential of mussel shells (MS) as biogenic fillers in polymer composites. The chemical composition and crystal structures of MS were characterised. To improve MS filler dispersion and adhesion within a polypropylene (PP) matrix, three surface modification methods were evaluated: polydopamine (PDA) coating, maleic anhydride-grafted polypropylene (MAPP) modification, and PDA/MAPP co-modification. The PDA coating, inspired by the adhesive properties of mussel foot proteins, successfully functionalized the MS surface, as confirmed by X-ray photoelectron spectroscopy (XPS). Thermodynamic analysis, based on contact angle measurements, revealed that MAPP and PDA/MAPP modifications reduced surface energies and potential energy differences. These changes enhanced filler dispersion and interfacial bonding by increasing hydrophobicity and reducing agglomeration in the PP matrix. Consequently, PP composites with 20% PDA/MAPP-modified MS fillers exhibited a 2.9% increase in tensile strength and a 7.5% increase in flexural strength compared to neat PP. Scanning electron microscopy (SEM) also showed reduced filler-matrix debonding and fewer voids. The proposed mechanism attributes these macroscopic property enhancements to the ability of the PDA coating to facilitate chemical and hydrogen bonding between MS fillers and MAPP.

Penerapan Range Of Mation (ROM) terhadap Peningkatan Kekuatan Otot dengan Kasus Stroke Non Hemoragik pada Ny. A Di UPT PSTW Jember

Background: Stroke remains a major health issue both in Indonesia and globally. Non-hemorrhagic stroke is a leading cause of physical disability, resulting in decreased muscle strength and motor function. Physical rehabilitation, including Range of Motion (ROM) exercises, plays a crucial role in the recovery of stroke patients by restoring muscle function and improving muscle strength. Objective: This study aims to evaluate the effectiveness of ROM exercises in improving muscle strength in non-hemorrhagic stroke patients with physical mobility impairment. Methods: A descriptive study with a case study approach was conducted on one non-hemorrhagic stroke patient who was given passive ROM exercises for 7 days, with a frequency of twice a day (morning and evening). The instruments used included Standard Operating Procedures (SOP) and a Manual Muscle Testing (MMT) observation sheet to assess muscle strength before and after the passive ROM intervention. Results: The study showed a significant increase in muscle strength after ROM exercises. Muscle strength consistently improved throughout the intervention, indicating that ROM exercises are effective in enhancing muscle strength in non-hemorrhagic stroke patients. Conclusion: Regular ROM exercises can increase muscle strength in non-hemorrhagic stroke patients. Initially, the patient's left extremity muscle strength was at a scale of 3, and after 7 days of ROM exercises, it improved to a scale of 4. This study provides evidence that ROM exercises are effective for stroke patients

Effects of burnt sawdust ashes from timber species on the strength properties of laterite-interlocking blocks

The most basic problem facing man is shelter, apart from food. This problem is acute in Ghana and other developing countries due mainly to the high growth rate of the population, inflation, unemployment and poor economic resources. Today in Ghana both middle and low income earners can hardly afford their own houses. From one point of view one can see that some of the materials used in building are of good quality and can last. The study aimed to partially replace ordinary Portland cement (oPc) with burnt sawdust ash (BSDA) from different timber species (Wawa, Mansonia, Teak, Odum, Ceiba, Essah and Mahogany) in making interlocking laterite blocks by replacing 0–30 wt %. Mix proportion was 1:8 (cement + BSDA: laterite) with a 0.60 water-to-cement ratio. 528 specimens of size 185 mm × 220 mm × 120 mm were produced and cured at normal temperature and humidity under shady and sunny conditions for 7, 14, 21 and 28 days. Compressive and tensile strengths were subsequently evaluated. However, an initial strength increase was observed with curing time for specific wood species (Wawa, Mansonia, Teak, Odum, Essah, Ceiba, and Mahogany). Notably,Wawa, Mansonia and Odum ash exhibited superior strength performance at 10–20% replacement levels, potentially satisfying relevant standards for load-bearing wall construction. This research suggests that up to 10% replacement with Wawa, Mansonia or Odum BSDA presents a promising eco-friendly approach for partially substituting oPc in LIB production.

Effect of the Addition of Manganese Dioxide Nanoparticles on the Mechanical Properties of Concrete against Carbonation and Sulfate Attack

This study evaluates the impact of the addition of nanoparticles of anodic manganese dioxide (NAMD) on the mechanical properties and resistance to chemical attack of concrete. The research focused on nine concrete mixtures with water/cement ratios of 0.40, 0.45, and 0.50 and NAMD contents of 0, 5, and 10%. The properties of NAMD were analyzed, and fresh concrete properties such as temperature, unit weight, and consistency were measured. The compressive strength was determined at different ages (7, 14, 28, 56, and 90 days). The tensile and flexural strength were evaluated at 28 days, and the longitudinal change generated by the SO4Mg attack was monitored until 90 days. In addition, an accelerated carbonation test was performed on concrete samples with 28 days of curing exposed to an atmosphere of 6% CO2 for one week. The addition of NAMD did not significantly affect the temperature or unit weight of the fresh concrete, but it did influence the consistency. An increase in compressive, tensile, and flexural strength was observed, especially at early ages and for low w/c ratios. The addition of NAMD reduced the expansion of concrete exposed to magnesium sulfate, with 5% being the most effective dose, and reduced the carbonation rate of concrete by up to 40% in mixes with w/c ratios of 0.40 and 0.50. It was shown that the addition of 5% as an effective dose of NAMD improves the mechanical and durability properties of concrete, especially in mixtures with a low water/cement ratio, contributing to the improvement of the quality and strength of concrete.

Optimization of mechanical properties of small diameter artificial blood vessels based on alginate/chitosan/gelatin

Due to the rise in cardiovascular disease and the problem of autologous transplant limitation, the emergence of 3D bioprinted blood vessels using natural polymer materials as ink is becoming increasingly important in the field of small-diameter artificial blood vessels (φ ≤ 6 mm). In this paper, gelatin was firstly adopted to explore alginate/chitosan composite hydrogel properties and solve the current issues of poor mechanical performance and suboptimal printability of small-diameter blood vessels, which indicated that the modification caused a 17.7 % increase in compressive strength and a 63.2 % enhancement in tensile properties. The material microstructure evaluation showed that the samples with gelatin(4 %) presented the excellent water absorption rate(>90 %) significantly increasing their porosities. A self-developed 3D bioprinter was utilized to clarify the controllable mechanism of small-diameter artificial blood vessel, which has superior performance and excellent printability. This study provides a new reference solution to the current challenges in the bio-ink performance and printability of small-diameter artificial blood vessels.

Effect of bioceramic inclusions on gel-cast aliphatic polymer membranes for bone tissue engineering applications: An in vitro study.

Polylactic acid (PLA) has been extensively used in tissue engineering. However, poor mechanical properties and low cell affinity have limited its pertinence in load bearing bone tissue regeneration (BTR) devices. Augmenting PLA with β-Tricalcium Phosphate (β-TCP), a calcium phosphate-based ceramic, could potentially improve its mechanical properties and enhance its osteogenic potential. Gels of PLA and β-TCP were prepared of different % w/w ratios through polymer dissolution in acetone, after which polymer-ceramic membranes were synthesized using the gel casting workflow and subjected to characterization. Gel-cast polymer-ceramic constructs were associated with significantly higher osteogenic capacity and calcium deposition in differentiated osteoblasts compared to pure polymer counterparts. Immunocytochemistry revealed cell spreading over the gel-cast membrane surfaces, characterized by trapezoidal morphology, distinct rounded nuclei, and well-aligned actin filaments. However, groups with higher ceramic loading expressed significantly higher levels of osteogenic markers relative to pure PLA membranes. Rule of mixtures and finite element models indicated an increase in theoretical mechanical strength with an increase in β-TCP concentration. This study potentiates the use of PLA/β-TCP composites in load bearing BTR applications and the ability to be used as customized patient-specific shape memory membranes in guided bone regeneration.

Mechanical property and corrosion performance in the as-rolled Mg-8Li-4Gd-1.5Ni alloy

As for the magnesium-lithium (Mg-Li) alloys for the applications of rapid corrosion material, enhancing their mechanical properties while maintaining the degradation rate poses a significant challenge. Simultaneously, it is crucial to elucidate the behavior of the long period stacking ordered (LPSO) phase in the corrosion process of as-rolled Mg-Li alloys. This study prepared the as-rolled Mg-8Li-4Gd-1.5Ni alloy with rolling reductions of 30 %, 50 %, 70 %, and 90 % at room temperature. Results indicate that, during the rolling process, the reticular LPSO gradually transitions to a fibrous LPSO and the GdNi3 particles are refined. Additionally, the amounts of twin increases. The alloy with 30 % reduction exhibits the highest corrosion rate, with a weight loss rate of 0.50 mg·cm−2·min−1 in a solute of 3 % KCl. The tensile strength reaches a maximum of 247 MPa. The increase in tensile strength is achieved at the expense of plasticity. The bending of the LPSO phase, the fracture of the secondary phases, and the increase in dislocations and twins increase the chemical reactivity of the alloy, leading to a higher corrosion rate. Rolling brings about the increase in dislocation density, dislocation entanglement, and the reduction in grain size, which indicate that the strengthening mechanisms of the alloy after rolling include work hardening and grain refinement strengthening.

Effect of Hybrid Nanofillers on the Mechanical Characteristics of Polymethyl Methacrylate Denture Base Composite

The research study focused on enhancing the mechanical characteristics of polymethyl methacrylate (PMMA) denture bases. PMMA is commonly used in dentistry due to its easy fabrication, cost-effectiveness, and favourable physical properties. However, its limitations include low wear resistance, hardness, and mechanical strength, making it less suitable for long-term dental applications. To address these limitations, the study employed a combination of hybrid nano-fillers, specifically HNTs (halloysite nanotubes) and MWCNTs (multi-walled carbon nanotubes), at varying loading levels to improve the mechanical characteristics of the PMMA composite. These nano-fillers underwent treatment by using a coupling agent to enhance their compatibility with PMMA. Key findings of the research include that introducing HNTs/MWCNTs into the PMMA matrix led to a substantial increase in flexural strength, with a significant improvement of 109.1 MPa compared to unfilled PMMA. This indicates that the composite material became more resistant to bending or deformation. There was a substantial rise in flexural modulus values, suggesting improved stiffness in the nanocomposite compared to unfilled PMMA. In addition, the tensile strength of the PMMA composite increased by 64.4 MPa with the addition of the hybrid nano-fillers, indicating enhanced resistance to stretching or pulling forces. The study found that the improvement in flexural and tensile strength was dependent on the concentration of MWCNTs. Increasing the MWCNT concentration up to 0.75 wt.% led to improved mechanical properties, but further increases resulted in a reduction in PMMA properties. Although there was a modest improvement in Vickers hardness (approximately 18.93 kg/mm<sup>2</sup>), the addition of HNTs/MWCNTs as hybrid nano-fillers effectively enhanced the properties of the PMMA nanocomposite. The study concludes that incorporating hybrid nano-fillers into PMMA could contribute to the longevity and durability of dental composites, addressing some of the material's inherent limitations. The specific combination and concentration of nano-fillers played a crucial role in determining the mechanical properties of the resulting nanocomposite.

Magnetomechanical Behaviors of Hard-Magnetic Elastomer Membranes Placed in Uniform Magnetic Field.

This paper aims to develop a theoretical model for a viscoelastic hard-magnetic elastomer membrane (HMEM) actuated by pressure and uniform magnetic field. The HMEM is initially a flat, circular film with a fixed boundary. The HMEM undergoes nonlinear large deformations in the transverse direction. The viscoelastic behaviors are characterized by using a rheological model composed of a spring in parallel with a Maxwell unit. The governing equations for magneto-visco-hyperelastic membrane under the axisymmetric large deformation are constructed. The Zeeman energy, which is related to the magnetization of the HMEM and the magnetic flux density, is employed. The governing equations are solved by the shooting method and the improved Euler method. Several numerical examples are implemented by varying the magnitude of the pre-stretch, pressure, and applied magnetic field. Under different magnetic fields, field variables such as latitudinal stress exhibit distinct curves in the radial direction. It is observed that these varying curves intersect at a point. The position of the intersection point is independent of the applied magnetic field and only controlled by pressure and pre-stretch. On the left side of the intersection point, the field variables increase as magnetic field strength increases. However, on the other side, this trend is reversed. During viscoelastic evolution, one can find that the magnetic field can be used to modulate the instability behaviors of the HMEM. These findings may provide valuable insights into the design of the hard-magnetic elastomer membrane structures and actuators.

Effect of Zn amount on AlZn-based composite material produced by high speed mechanical alloying method

Purpose The purpose of this study is AlZn-based produced by high speed mechanical alloying method to investigate the effect of Zn amount on the composite material, Al-Zn-Mg-Cu-SiC composite material billets are obtained by sintering. Design/methodology/approach Mechanical alloying, X-ray diffraction analysis (XRD) graphics, sintering, polishing, scanning electron microscopy and energy dispersive X-ray analyzer (EDX) images and micro hardness tests were applied, respectively. Findings In the XRD analysis results, it was observed that the Al peak height decreased as the alloying time increased. When the samples sintered for 90 min are examined, it can be clearly seen that the hardness increases as the Zn ratio increases. EDX analysis results also support XRD results. Originality/value Increase in strength will require the use of thinner sheet metal and smaller rivets to achieve the same strength. This will reduce the weight of the aircraft. Weight reduction also means less fuel consumption and more economical flight. This increase in strength is a very important scientific achievement.

Long-term mechanical performance of fly ash-incorporated reactive magnesia cements

In this research, after producing reactive magnesia directly from calcination of magnesite, reactive magnesia specimens with fly ash were prepared and cured in two different environments to investigate their long-term mechanical performance by carbonation. To investigate the effect on their microstructures of carbonation, the XRD profiles of the samples were also obtained and investigated. It is found that the strength of reactive magnesia samples is highly affected by the addition rate of reactive magnesia and the curing regime. In spite of the presence of the nesquehonite (MgCO3.3H2O) in the reactive magnesia cements having no portland cement, any type of magnesium carbonate crystal was not found for the cements with portland cement in carbon dioxide curing. The strength increase in reactive magnesia cements can be due to the incorporation of Mg2+ ions to the calcite crystals.

Experimental study on progressive collapse behavior of frame structures triggered by impact column removal

In the research field investigating the progressive collapse of building structures, event-dependent collapse processes have gained increasing attention in analytical and numerical studies. Different events could cause varying effects on progressive collapse resistance. The alternate load path could be related to events that could also lead to variations in load actions. However, experimental studies on reinforced concrete (RC) frame structures triggering structural column removal by the low-velocity impact have not been reported. Therefore, this paper performed an initial experimental study employing impact loading as the extreme event to investigate subsequent progressive collapse behavior of structures. Tests were conducted on six RC substructures consisting of a two-span beam and a structural column. Gravity loads were applied to the top of substructures, and a pendulum impact setup was utilized to remove RC columns by low-velocity impact. When the column underwent lateral failures, the downward force exerted by longitudinal steel bars of the column, before they fractured, pulled the two-span beam beyond the compressive arch action (CAA) stage, leading to a collapse process entirely different from their event-independent counterparts. The parametric study based on experimental results indicated that low-elevation impact and increase of column longitudinal bars detrimentally affected the performance of two-span beams resisting progressive collapse, while the increase in concrete strength partially improved the residual bearing capacity after impact column removal (ICR). Based on a dynamic model, a simplified calculation method is proposed for quantifying the downward force.

Effect of noninertial acceleration on heat transfer by Rayleigh–Bénard magnetoconvection: Exploring nonlinear dynamics

AbstractBuoyancy‐driven Rayleigh–Bénard convection in the presence of a magnetic field, rotation, and temperature‐dependent viscosity has applications in the field of crystal growth, space laboratory experiments, and atmospheric convection. It also has potential applications in heat transfer and magnetohydrodynamics, which can occur in planetary and stellar interiors. The present work aims to study the combined effect of magnetic fields and rotation on the onset of Rayleigh–Bénard convection in temperature‐dependent viscosity Newtonian liquids with internal heat sources/sinks. Both linear and weak nonlinear stability analyses of convection are performed in the problem. The minimal representation of the Fourier series for the stream function and the magnetic potential allows us to derive the analytical expression for the thermal Rayleigh number () and the generalized Lorenz model. In linear theory, the critical Rayleigh number and the wave number are tabulated for different values of the Chandrasekhar number (), the Taylor number (), and the thermorheological parameter (), and the onset of stability is analyzed. It is found that the instability manifests at when for stress‐free and isothermal boundaries. In nonlinear theory, the generalized Lorenz model obtained is not amenable to analytical treatment; therefore, the classical fourth‐order Runge–Kutta method is applied to solve the Lorenz model. It is found that the internal Rayleigh number, the thermorheological parameter, and the Taylor number influence the onset of convection and heat transfer coefficient. It is also demonstrated that the joint increase in rotational force and magnetic field strength stabilizes the system strongly, thereby reducing heat transfer. However, increasing the heat source and the variable viscosity parameter have antagonistic influences.

Grafting of maleic anhydride onto waste acrylonitrile butadiene styrene (ABS) and its application for compatibilization of ABS blends

AbstractIncorporating recycled plastics into the manufacturing process is an essential way to establish a sustainable plastics economy. However, current processes are limited by the degradation of mechanical properties, high cost, and inconsistent product quality compared with their virgin counterparts. Here, we present an upcycling strategy for waste plastics where waste acrylonitrile‐butadiene‐styrene (reABS) is first grafted with maleic anhydride (MAH), then utilized to compatibilize nylon 6(PA6)/ABS and PA6/ABS/CaCO3 blends. The reABS‐g‐MAH exhibits improved Young's modulus and tensile strength, but lower strain at break and impact strength compared with reABS. As an additive, reABS‐g‐MAH effectively compatibilizes PA6/ABS and PA6/ABS/CaCO3 blends, indicated by greatly decreased PA6 domain size, homogeneous dispersion of fillers, and narrowed glass transition temperature regions between PA6 and ABS. Adding only 5 wt% reABS‐g‐MAH increases the Young's modulus, strain at break, and impact strength of PA6/ABS blends by 26%, 180%, and 110%, respectively, compared with uncompatibilized samples. Similarly, for PA6/ABS/CaCO3 blends, the strain at break and impact strength increase by 370% and 150%, respectively, while the Young's modulus and tensile strength show increases of 5% and 10%. The results show that this strategy of using polar groups to functionalize waste plastics as compatibilizers may open numerous opportunities for upcycling waste plastics.

Seismic behavior of prefabricated lightweight steel composite frame-sandwich wall with enhanced border structure

An innovative prefabricated lightweight steel composite frame-sandwich wall with an enhanced border structure (LSCF-SW), suitable for low-energy consumption low-rise residences, is proposed. Low cyclic loading experiment were conducted to study its seismic behavior. The main parameters include wallboard border type (composite border, mixed border) and steel reinforcement strength (HRB450, HRB500). One full-scale LSCF specimen and four full-scale LSCF-SW specimens are prepared, and their seismic behavior is investigated in terms of failure mode, hysteretic characteristics, ultimate bearing capacity, stiffness degradation, deformation capacity, energy dissipation, and strain characteristics. The results revealed that the sandwich wall (SW) with an enhanced border and lightweight steel composite frame (LSCF) is the primary and secondary seismic fortification lines of the structure, respectively. The LSCF-SW structure exhibited a damage evolution process with four stages. The failure mode involving concrete crushing at the bolted connection area is observed in the specimens with composite bordered sandwich walls (LSCF-SWC), and dense diagonal cracks are discovered in the specimens with mixed bordered sandwich walls (LSCF-SWM). Compared to LSCF-SWC specimens, the ultimate load of LSCF-SWM specimens increases by 23.0 %–50.3 %, and the initial stiffness improves by 16.3 %–42.3 %. The deformation capacity of LSCF-SWC specimens is superior to that of LSCF-SWM specimens. As the steel reinforcement strength increases, the ultimate bearing capacity and initial stiffness of the LSCF-SW also rise. A shear model for the bolt group and a local bending model for the wallboard border are proposed, establishing an ultimate bearing capacity calculation method for LSCF-SW. The calculation results closely align with the experimental results.

Numerical simulation of mechanical properties and damage process of carbon nanotube concrete under triaxial compression and splitting conditions

To investigate the mechanical properties and failure processes of carbon nanotube concrete, a three-dimensional meso-scale finite element model of concrete was constructed. Using ABAQUS software, numerical simulations were conducted on concrete samples with different carbon nanotube concentrations under triaxial compression and splitting conditions. The results indicate that under splitting conditions, the failure of the specimens initially occurs along the loading direction from both ends, with few cracks and slow propagation. Subsequently, the cracks rapidly expand, penetrating the entire specimen, leading to the formation of a macro-fracture surface with a crack aligned with the loading direction. This failure mode manifests as a straight crack. At the same loading rate, the tensile strength of the specimens with different carbon nanotube concentrations increases to varying degrees during splitting failure, with a maximum increase of 45.10% to 4.15 MPa. nder triaxial compression conditions, the main failure mode of the specimens exhibits shear failure characteristics. As the confining pressure gradually increases, the failure angle of the specimens enlarges. Under low confining pressure, there are fewer wing-shaped tensile cracks at the shear failure surface of the specimens. As the confining pressure increases, irregular shear failures and multiple shear planes appear in the specimens, resulting in more complex failure modes. For specimens with the same carbon nanotube concentration, the triaxial compressive strength of carbon nanotube concrete specimens increases with increasing confining pressure. The triaxial compressive strengths of the specimens under confining pressures of 5 MPa, 10 MPa, 15 MPa, and 20 MPa are 90.48 MPa, 122.72 MPa, 137.22 MPa, and 172.65 MPa, with strength increases of 35.63%, 51.66%, and 90.81%, respectively.

Microstructure Evolution and Mechanical Properties of In Situ TiB2/Al–Zn–Mg–Cu Composites by Electropulsing‐Assisted Solution Treatment

The traditional solution treatment is not completely applicable for in situ TiB2/Al–Zn–Mg–Cu composite due to the influence of TiB2 particles. This study investigates the impact of the electropulsing‐assisted solution (EAS) process on the microstructure evolution and mechanical properties of TiB2/Al–Zn–Mg–Cu composites. The nonuniform microstructure evolution related to the difference in temperature and current density is supported by simulative and experimental results. EAS treatment significantly enhances the degree of supersaturation, allowing phases surrounding TiB2 particles to dissolve without extensive overburning, unlike traditional solution treatments. This improvement is attributed to the reduced thermodynamic barrier and accelerated atomic diffusion, facilitated by both localized and average Joule heating effects and enhanced thermal electron/phonon scattering. Meanwhile, grain size remains stable during the temperature rise induced by EAS treatment. Furthermore, the mechanical properties of composites increase, among which the increase in strength is mainly ascribed to solid–solution strengthening, and the increase in elongation is related to multiple factors referring to TiB2 particles fracture and interface crack between the undissolved phases and matrix. This study provides an approach to achieve an efficient dissolution of phases aggregated with particles and without widespread overburning in particle‐reinforced Al matrix composites via electropulsing techniques.

The effect of changing constituents on tensile mechanical properties of HfNbTaTiZr high entropy alloy: A molecular dynamics study

The recent trend of high-entropy alloys (HEAs) was studied extensively for their promising mechanical properties, but individual constituents' effects have remained unexplored. In this work, the effects of changing the percentage of elements of HfNbTaTiZr-HEA on the mechanical properties were analyzed during uniaxial tension using molecular dynamics simulation. The tensile strength and modulus of elastic properties of the samples were analyzed. It was found that adding Nb or Ta up to 10 % (i.e. Nb10/Ta10) in the high entropy alloys increased the ultimate tensile strength (UTS) from 2.9 GPa in the base alloy to 3.8/3.9 GPa (Nb10/Ta10) respectively, but further increment of these elements to 30 % resulted in a downgrade of UTS to 2.7 GPa. Similarly, the modulus of elasticity increased from 117.7 (±3) GPa in the base alloy to 137.7/129 (±3) GPa (Nb10/Ta10) respectively, but fell to 112–115 GPa upon further increment. The initial increase in strength could be due to the solid solution strengthening mechanism. However, further increases in these elements might hinder the development of a homogeneous solid solution because of differences in atomic size and crystal structure, which could ultimately reduce the alloy's strength. However, the effect of Ti and Zr follows an opposite trend as compared to Nb and Ta. Furthermore, the optimum composition of HEAs alloys was analyzed using a surface-contour plot and suggests minimizing the inclusion of Ta for maximizing the UTS, E, and %Elongation. Also, the high-temperature behavior of the optimized HEA's alloy was analyzed which showed a deterioration in properties at elevated temperature. The fracture evolution of the samples showed cup and cone-type fractures propagating under strain, the linear thermal expansion coefficient of HfNbTaTiZr-HEA was also calculated and found closer to the literature value.

A comparative study on corrosion and mechanical properties of laser-cladded X2CrNiMoN22-5-3 duplex stainless steel on 42CrMo4 steel substrate

Duplex stainless steel is an alloy that combines the advantages of austenitic stainless steel and ferritic stainless steel. It has excellent corrosion resistance, high strength, and good weldability. One of the main problems in marine shafts using X2CrNiMoN22-5-3 Duplex Stainless Steel (2205) is bending and warping over time. In this study, 42CrMO4 (MO40) steel was clad with 2205 dual-phase steel using direct metal deposition with wire to simultaneously utilize the mechanical properties, and corrosion resistance. Perform metallographic imaging, corrosion test, and tensile test, to maintain the quality of the cladding. The results show that the corrosion potential of 2205 cladding layer is −0.65 (including semi-passive zone), while the control sample of 2205 had a corrosion potential of −0.26, and the MO40 substrate had a corrosion potential of −0.1 (highlighting the advantage of the cladding in thermodynamics term). EIS results showed that the REISMO40=2325Ω, REIS2205=24315Ω, and REIS2205cladded=216133Ω. The corrosion rate for the substrate, control sample, and laser-clad sample were 0.33, 0.15, and 0.00095 mm/year, respectively, without significant loss in tensile properties. The final strength for MO40(with 2205 clad) reaches 672 MPa with a 14 % decrease from 788 for MO40. In this case, we still have a 36 % increase in strength compared to the 2205 sample. It seems that the bent problem of the pure 2205 marine shaft can be solved completely in this case and continues to be solved in our ongoing work.

Green hybrid materials from biomass waste: Distiller’s grains/epoxy vitrimer—Green synthesis, superior properties, and potential application in solar-thermal-electric generator

Distiller’s grains (DG) are a major biomass waste product in the ethanol and brewing industries, and have shown great potential as fillers for polymer composites. However, combining DG with polymer matrixes using traditional method often involves tedious pre-modification of DG and/or the use of costly coupling agents, significantly increasing the preparation cost of the final composite materials. In this study, we present an environmentally friendly approach for preparing a new type of green composite, termed distiller’s grains/epoxy vitrimer hybrid materials (EV@DG). This method eliminates the need for laborious pre-modifications of DG, as well as the use of solvents and coupling agents. The resulting EV@DG hybrid materials exhibit superior mechanical properties—approximately 90 % increase in tensile strength and 400 % increase in Young’s modulus—along with high thermal stability (Td,max of 357.63°C) and excellent reprocessability. Moreover, the EV@DGs demonstrate impressive photothermal conversion capabilities, positioning them as promising candidates for the fabrication of solar-thermal-electric generator.