Increase In Resistance Research Articles

Prevention of weld decay in TIG welded AISI 304 steel pipes

Weld decay due to chromium carbide precipitation at grain boundaries in the heat affected zone (HAZ) during TIG welding of austenitic stainless steels. This issue is particularly significant concerning the welding of AISI 304 steels, commonly used in the food industry. Although this problem can be overcome with different methods, there are some restrictions. A novel technique for welding AISI 304 steel pipes is introduced to reduce weld decay and improve the mechanical properties. The use of this technique, which includes faster cooling after welding, significantly minimizes the time of precipitation of chromium carbide. Temperature measurements and microstructural analyses monitor precipitation and the impact of the technique on the mechanical characteristics of AISI 304 steel pipes was assessed through hardness and hoop tensile tests. There was a 6% increase in hardness values observed in the HAZ region. Furthermore, a 16.7% increase in maximum load and a 127.4% increase in elongation. The reduction in chromium carbide precipitation observed in the microstructural analysis was confirmed through the double loop electropotentiokinetic reactivation (DLEPR) test, specifically for assessing intergranular corrosion. With the novel method, there was a 25% increase in corrosion resistance in the HAZ and a 40% increase in the weld zone.

Numerical study on the forced convective flow and heat transfer mechanism with macro-patterned hydrophilic-hydrophobic hybrid surfaces

Hydrophilic-hydrophobic hybrid surfaces can be used to harmonize the drag and heat transfer. However, the hybrid surfaces are almost microscopic scale and hardly used for forced convection at present. In this study, six macro-patterned hydrophilic-hydrophobic hybrid surfaces (square, diamond, circle, ellipse, triangle, and sector) and a no-slip surface are built. The performances are studied with the k-ε turbulent model by COMSOL, and the mechanism of performance change is analyzed with large eddy simulation (LES). The results show that macro-patterned hybrid surfaces can all reduce the flow drag but have different influences on heat transfer. With the increasing Reynolds number, the drag reduction rate (DR) declines. The largest DRs are 14.57% with the ellipse-patterned at lower Reynolds numbers, and 13.18% with the triangle-patterned at higher Reynolds numbers. For heat transfer capability, although adding hydrophobic parts, the square-patterned and diamond-patterned hybrid surfaces can raise Nusselt numbers. Combined above, the largest goodness factor (φ) enlarged rates are 16.43% (square-patterned) and 16.35% (diamond-patterned). Meanwhile, the influencing mechanism with the macro-patterned hybrid surface concludes four factors: the velocity slip, thermal resistance increases of air cavities, eddies of hydrophilic-hydrophobic interfaces, and the guiding effect of hydrophobic patterns' edges.

Analysis of heating defects in extension rods of extra-high voltage direct current overhead transmission lines

This paper studies the overheating defect of an extension rod in a ± 800 kV extra-high voltage direct current overhead transmission line, and proposes various factors that affect the overheating of the extension rod. Establish an equivalent model of an extra high voltage DC transmission line based on equipotential point and line parameter analysis, and calculate the model parameters. The proposed model can also be applied to ultra-high voltage DC overhead transmission lines such as ± 500 kV, and has strong universality. Simulation experiments show that if the equivalent resistance value of the split wire side is reduced by 0.01Ω, the power loss on the extension tie rod can be increased to 380.951 W; if the equivalent resistance value of the jumper side is increased by 0.01Ω, the power loss on the extension tie rod can be increased to 273.41 W. Combined with theoretical analysis and simulation verification, it is concluded that the main factor affecting the overheating of the extension rod is the change in the resistance value on the jumper side caused by the increase in contact resistance. A systematic troubleshooting plan for related defect problems is proposed, which has important reference and guidance significance for such line fault problems.

The impact of magnesium content on lithium-magnesium alloy electrode performance with argyrodite solid electrolyte

Solid-state lithium-based batteries offer higher energy density than their Li-ion counterparts. Yet they are limited in terms of negative electrode discharge performance and require high stack pressure during operation. To circumvent these issues, we propose the use of lithium-rich magnesium alloys as suitable negative electrodes in combination with Li6PS5Cl solid-state electrolyte. We synthesise and characterise lithium-rich magnesium alloys, quantifying the changes in mechanical properties, transport, and surface chemistry that impact electrochemical performance. Increases in hardness, stiffness, adhesion, and resistance to creep are quantified by nanoindentation as a function of magnesium content. A decrease in diffusivity is quantified with 6Li pulsed field gradient nuclear magnetic resonance, and only a small increase in interfacial impedance due to the presence of magnesium is identified by electrochemical impedance spectroscopy which is correlated with x-ray photoelectron spectroscopy. The addition of magnesium aids contact retention on discharge, but this must be balanced against a decrease in lithium diffusivity. We demonstrate via electrochemical testing of symmetric cells at 2.5 MPa and 30∘C that 1% magnesium content in the alloy increases the stripping capacity compared to both pure lithium and higher magnesium content alloys by balancing these effects.

HULL REDESIGN AND ITS EFFECT ON THE RESISTANCE OF MANADO PROTOTYPE SMALL PURSE SEINER

This research aims to determine the effect of redesigning the hull of a small purse seine ship on its motion resistance. The research was carried out using a small purse seine ship prototype in Manado by changing the length-breath-depth ratio based on the main dimensions of the ship, resulting in three new hull designs coded K-0 (prototype), K-1, K-2, and K- 3. Maxsurf modeler and Maxsurf resistance were used to run a simulation set of three loading conditions (light, half, full) and speed (low, medium, high). The research results show that changes in ship hull design affect the resistance and thrust of the ship. There is a difference in resistance between the ship with the redesigned hull and the prototype, where the smallest difference is shown by K-3. In addition to changes in hull design, changes in ship loading conditions, Froude number, and ship speed lead to increases in ship resistance and thrust. Based on the average allowance (sea margin or service margin) in shipping lanes, the need for propulsion power and the number of propulsion power vessels K-0 (prototype) and K-3 are still better than K-1 and K-2. Keywords: purse-seiner, resistance, speed, propulsion

Formation of Corrosion‐Resistant Nitride Coatings Based on Ti–Al–Cr–Fe–Ni High‐Entropy Alloy

The purpose of the work is to study the features of the phase and structure formation of coatings (Ti–Al–Cr–Fe–Ni)N formed by vacuum arc deposition and to study the influence of technological parameters of the deposition process on their corrosive properties. It is established that on the basis of the selected elements, it is possible to form a high‐entropy compound in the form of a solid solution. The structure of nitride coatings based on high‐entropy compounds formed by vacuum arc deposition is studied. It is established that the phase composition of coatings largely depends on the ratio of titanium and aluminum, which is determined by the technological parameters of deposition. An analysis of the results of the electrochemical behavior of coatings (Al,Ti,Fe,Cr,Ni)N shows that an increase in the corrosion resistance of these coatings is due to the synergistic effect of the formation of a solid substitution solution with a dense nanoscale structure and an increased relative aluminum content in them.

Serotype epidemiology and antibiotic resistance of pneumococcal isolates colonizing infants in Botswana (2016-2019).

In 2012, Botswana introduced 13-valent pneumococcal conjugate vaccine (PCV-13) to its childhood immunization program in a 3+0 schedule, achieving coverage rates of above 90% by 2014. In other settings, PCV introduction has been followed by an increase in carriage or disease caused by non-vaccine serotypes, including some serotypes with a high prevalence of antibiotic resistance. We characterized the serotype epidemiology and antibiotic resistance of pneumococcal isolates cultured from nasopharyngeal samples collected from infants (≤12 months) in southeastern Botswana between 2016 and 2019. Capsular serotyping was performed using the Quellung reaction. E-tests were used to determine minimum inhibitory concentrations for common antibiotics. We cultured 264 pneumococcal isolates from samples collected from 150 infants. At the time of sample collection, 81% of infants had received at least one dose of PCV-13 and 53% had completed the three-dose series. PCV-13 serotypes accounted for 27% of isolates, with the most prevalent vaccine serotypes being 19F (n = 20, 8%), 19A (n = 16, 6%), and 6A (n = 10, 4%). The most frequently identified non-vaccine serotypes were 23B (n = 29, 11%), 21 (n = 12, 5%), and 16F (n = 11, 4%). Only three (1%) pneumococcal isolates were resistant to amoxicillin; however, we observed an increasing prevalence of penicillin resistance using the meningitis breakpoint (2016: 41%, 2019: 71%; Cochran-Armitage test for trend, p = 0.0003) and non-susceptibility to trimethoprim-sulfamethoxazole (2016: 55%, 2019: 79%; p = 0.04). Three (1%) isolates were multi-drug resistant. PCV-13 serotypes accounted for a substantial proportion of isolates colonizing infants in Botswana during a four-year period starting four years after vaccine introduction. A low prevalence of amoxicillin resistance supports its continued use as the first-line agent for non-meningeal pneumococcal infections. The observed increase in penicillin resistance at the meningitis breakpoint and the low prevalence of resistance to ceftriaxone supports use of third-generation cephalosporins for empirical treatment of suspected bacterial meningitis.

Simulation investigation of effects of substrate and thermal boundary resistance on performances of AlGaN/GaN HEMTs

The temperature distributions and thermal resistances of the GaN HEMTs fabricated on different substrates (sapphire, Si, SiC and diamond) with Mo/Au interlayers were calculated and analyzed by numerical simulation. The results show that the GaN HEMT on the diamond substrate exhibits the lowest channel temperature and thermal resistance, and the thermal resistance rises with the increase of the thermal boundary resistance (TBR) for all the GaN HEMTs with the different substrate materials. Meanwhile, the high TBR (2 × 10−7 m2·K/W) severely hinders the heat exchange between the GaN layer and the substrate, which makes it difficult for the heat flux to pass through the barrier. Even diamond with high thermal conductivity can hardly reduce the channel temperature of the device. Therefore, TBR must be reduced so that the heat flux can be dissipated through a high thermal conductivity substrate. In addition, the Mo/Au interlayer generates a lower thermal boundary resistance, which has little effect on the channel temperature, thermal resistance and interfacial temperature discontinuity of GaN HEMTs.

Bioactive peptides as alternative treatment for Helicobacter pylori infection

The infection and chronic inflammatory response generated by Helicobacter pylori is a global health concern. This pathogen is characterized as a major risk factor in the development of gastric cancer and other diseases. Conventional eradication therapies are based on antibiotic regimens and as a consequence there is an increase in antimicrobial resistance of the pathogen strains, besides other potential side effects for the host. Therefore, it is necessary to explore new alternatives. This review delves into the realm of antimicrobial peptides, exploring their efficacy against H. pylori sourced from diverse origins. Furthermore, it sheds light on food-derived peptides exhibiting remarkable biological activity. These peptides exhibit promising effects on biomarkers associated with H. pylori infection, demonstrating anti-inflammatory and antioxidant properties validated through rigorous testing in both cell and animal models. Regarding the anti-inflammatory activity, the peptide VPY derived from soybean and the peptides derived from animal sources such as meat (β-Ala-His), egg (DEDTQAMPFR, DEDTQAMPF, MLGATSL, MSYSAGF, CR, FL, HC, LL, MK) and milk (IPAV) have reported a reduction of the cytokine IL-8, biomarker directly related to H. infection. For the antioxidant activity, peptides derived from milk (EAMAPK, AVPYPQ) and from Spirulina maxima (LDAVNR, MMLDF) have reduced ROS levels and could have a positive effect on the control of H. infection. Food-derived bioactive peptides with an anti-adhesive effect were also discussed. They derive from vegetable sources (corn, pea and wheat) and are capable of interacting with the host cells, interfering the adherence of H. pylori. Food-derived bioactive peptides have potential to avoid and/or mitigate undesired outcomes of infectious diseases due to the possibility of its application in nutraceuticals and food products, resulting in a preventive approach. Keywords: Helicobacter pylori, antibiotic resistance, bioactive peptides, antimicrobial peptides

Site-Specific Antimicrobial Activity of a Dual-Responsive Ciprofloxacin Prodrug.

Bacterial infections create distinctive microenvironments with a unique mix of metabolites and enzymes compared with healthy tissues that can be used to trigger the activation of antibiotic prodrugs. Here, a single and dual prodrug masking the C3 carboxylate and C7 piperazine of the fluoroquinolone, ciprofloxacin, responsive to nitroreductase (NTR) and/or hydrogen sulfide (H2S), was developed. Masking both functional groups reduced the activity of the prodrug against Staphylococcus aureus and Escherichia coli, increasing its minimum inhibitory concentration (MIC) by ∼512-fold (S. aureus) and ∼8000-fold (E. coli strains), while masking a single group only increased the MIC by ∼128-fold. Bacteria subjected to prolonged prodrug exposure did not show any increase in resistance. Triggering assays demonstrated the conversion of prodrugs to ciprofloxacin, and in a murine infection model, responsive prodrugs showed antibacterial activity comparable to that of ciprofloxacin, suggesting in vivo activation of prodrugs. Thus, the potential for site-specific antibiotic treatment with reduced threat of resistance is demonstrated.

Post-service analysis of the degradation and protective mechanisms of chromate-based structural aircraft coatings

The substitution of chromate-containing structural coating systems in aviation with alternatives complying with nowadays strict environmental, health and safety regulations remains a formidable challenge. This complexity is partly due to the absence of a standardized from-test-to-market methodology, including a performance comparison between chromate-containing and alternative coating systems. To address this gap, the present study delves into the identification of crucial degradation factors that merit inclusion in such a methodology. Concurrently, it investigates the protective mechanisms inherent in chromate-containing coating systems and proposes improvements that can be applied to alternative coating systems. This study entails a comprehensive post-service examination of the degradation of paint applied to an aircraft component with over 35 years of service, employing electrochemical, microscopic and spectroscopic techniques. The findings underscore the role of thermo-oxidation as a significant degradation factor in the aging process of such coatings. Furthermore, the investigation elucidates a notable phenomenon in which aluminium ions within the coating pores form an aluminium hydroxide gel onto which chromate adsorbs. This process contributes to an increase in pore resistance upon exposure to electrolyte, leading to a self-healing barrier effect within the coating. Remarkably, this self-healing mechanism continues to offer long-term protection even when the coating matrix is sub-optimally cured due to application errors. Furthermore, this study reveals that the significant changes in capacitance during immersion testing result primarily from inhibitor leaching, emphasizing the effectiveness of combining Electrochemical Impedance Spectroscopy (EIS) with Scanning Electron Microscopy (SEM) analysis for studying coating degradation.

#3050 Hemodynamic study of hypertensive disorders in pregnancy using cardiothoracic bioimpedance

Abstract Background and Aims Hypertensive disorders in pregnancy (HDP) are a major cause of maternal and perinatal morbidity and mortality. There is still a need for the development of biomarkers for early diagnosis of the severity of the condition. Thoracic electrical bioimpedance (TEB) is a non-invasive hemodynamic technique based on the resistance to the flow of electrical current. We investigated hemodynamic changes in pregnant/postpartum women with HDP using TEB. Method A retrospective observational study was conducted in pregnant and postpartum women with hypertension monitored by TEB. Indirect changes were analyzed in: cardiac work, left cardiac work index (LCWI kg⋅m/m2) and calculated cardiac output (CO ml/min=systolic volume -SV ml- × heart rate -HR bpm-); fluid status, thoracic fluid content index (TFCI l/kOhm/m2); and resistances, systemic vascular resistance index (SVRI dyn.s.cm-5.m2). Normality of variables was assessed by Shapiro-Wilk test and correlation analysis was performed by Pearson/Spearman tests. Statistical inference between the hypertension-preeclampsia and pregnancy-postpartum groups was performed using Student's/Mann-Whitney U tests. Analysis was performed using STATA 12. Results Fifty-five patients were included with a mean age of 36.5 years (SD 4.54), 69% were older than 35 years. Pregnant women accounted for 86% of the TEB evaluations, the majority (93.6%) in the third trimester. There was chronic hypertension in 7.27% and pre-eclampsia in 18.18% of previous pregnancies. The diagnoses were: pre-eclampsia (56.36%), gestational hypertension (40%) and HELLP syndrome (3.64%). The mean blood pressure was 144/89 (SD 16/11) mmHg. Mean proteinuria was 363.2 (range: 10.3-23220) mg/g. The median values were as follow: LCWI: 5.05 (IQR: 1.4) kg⋅m/m2; CO: 6352 (IQR: 2345) ml/min; TFCI: 17.9 (IQR: 6.3) l/kOhm/m2; SVRI: 2167.63 (SD: 462.87) dyn.s.cm-5.m2. LCWI showed a weak positive correlation with systolic blood pressure (SBP) and a strong correlation with diastolic blood pressure (DBP) (Rho 0.2899 and 0.5176, respectively). There was also a positive and moderate correlation between SVRI and SBP and DBP (r 0.4265 and 0.4019, respectively). There was no correlation between CO or TFCI and SBP or DBP. No statistically significant differences in hemodynamic parameters were found between gestational hypertension and pre-eclampsia, nor between pregnant and postpartum women. Conclusion Increased blood pressure in the setting of HDP correlates with increased LCWI and systemic resistance independent of fluid retention. An increase in systemic vascular resistance measured by TEB (which decreases in normal pregnancy) may be an early diagnostic marker of HDP. These findings require further validation in a larger cohort, including a control group of pregnant women without hypertension.

Modern trends in the application of thermoelectric method in non-destructive testing (review)

The article provides an overview of the main directions of using the thermoelectric testing method in various spheres of the national economy. The thermoelectric method is most widely used in industry. There are publications on the application of the thermoelectric method for quality monitoring of turning and friction stir welding. It is shown that the thermoelectric method makes it possible to increase the reliability of testing and, based on testing data, ensure optimal modes of the technological process of metalworking and welding. A number of articles are devoted to the application of the thermoelectric method to plastic deformation testing, the dependence of thermal EMF on the degree of plastic deformation is revealed. Recently, publications have appeared on the application of the thermoelectric method to testing the thermal resistance of the design “housing of a power semiconductor device-thermal interface-cooling radiator”. This design is very widespread in electronic equipment. In addition, there are articles on the use of the thermoelectric method to testing the transient resistance of contacts in the power supply network. It is shown that with an increase in contact resistance, the value of thermal EMF increases proportionally, which can be used to prevent emergencies in the power supply network. The thermoelectric method has also been successfully applied to diagnose the degree of titanium flooding. The dependence of the thermal EMF value on the degree of hydrogenation has been revealed. The use of the thermoelectric method is not limited to the field of industrial production. The thermoelectric method is successfully used in medicine for the undetectable detection of nucleic acid sequences, for the temperature diagnosis of human teeth, as well as for the diagnosis of inflammatory processes in the human body.

The female urethral closure mechanism during physical stress.

The closure of the urethra under the condition of stress is the result of a reflex contraction of the urethral rhabdosphincter and pelvic floor muscles. This is likely induced by activity of the abdominal muscles due to a sudden increase in abdominal pressure. This reflex contraction with an increase of urethral pressure occurs a few milliseconds before an increase in intraabdominal pressure. The urethral pressure increase during stress is only possible with fixation of the urethra by the pubourethral ligaments (PUL), facilitating urethral kinking. The highest and most important increase in pressure and resistance occurs in the distal urethra due to this kinking of the urethra.

Cardiovascular and cerebrovascular effects of caffeine maintenance in preterm infants during the transitional period.

Caffeine is routinely used for the prophylaxis of prematurity-related apnoeas. We aimed to evaluate the effect of caffeine maintenance on cardiovascular and cerebrovascular haemodynamics using a non-invasive multimodal monitoring in preterm infants during the transitional period. Infants <32 weeks' gestational age (GA) were enrolled in this observational prospective study. The following parameters were recorded before and after the administration of caffeine citrate 5 mg/kg using near-infrared spectroscopy, pulse oximetry and electrical velocimetry: heart rate, cardiac output, stroke volume, cardiac contractility, systemic vascular resistance (SVR), perfusion index, peripheral and cerebral oxygenation, cerebral fractional oxygen extraction, correlation index between cerebral oxygenation and heart rate (TOHRx, marker of cerebrovascular reactivity). Multilevel mixed-effects linear models were used to assess the impact of caffeine and of relevant clinical covariates on each parameter. Seventy-seven infants (mean GA 29.3 ± 2.5 weeks, mean birthweight 1148 ± 353 g) were included. Caffeine administration was associated with increased SVR (B = 0.623, p = 0.004) and more negative TOHRx values (B = -0.036, p = 0.022), which suggest improved cerebrovascular reactivity. Caffeine administration at maintenance dosage during postnatal transition is associated with increased systemic vascular tone and improved cerebrovascular reactivity. A possible role for caffeine-mediated inhibition of adenosine receptors may be hypothesized. This study provides a thorough and comprehensive overview of multiple cerebrovascular and cardiovascular parameters, monitored non-invasively by combining near-infrared spectroscopy, electrical velocimetry and pulse oximetry, before and after the administration of caffeine at maintenance dosage in preterm infants during postnatal transition. Caffeine was associated with an improvement in cerebrovascular reactivity and with a slight but significant increase in systemic vascular resistance, with no additional effects on other cardiovascular and cerebrovascular parameters. Our results support the safety of caffeine treatment even during a phase at risk for haemodynamic instability such as postnatal transition and suggest potential beneficial effects on cerebral haemodynamics.

IMPROVING THE PLANTS EFFICIENCY OF THERMAL INCINERATION HOUSEHOLD WASTE BY RECOVERING WASTE HEAT

The work is devoted to research on the creation of recovery exchanger for waste heat exhaust gases of household waste incineration plants. The purpose of the work is to develop a technical solution for the heat recovery exchanger of waste incineration plants (WIP) and determine its thermal efficiency indicators. The main objectives of the study were to analysis of the modern experience of using the WIP and establish requirements for the creation of a exhaust gas heat recovery exchanger, develop a new technical solution for the heat recovery exchanger, and determine the change patterns in its main thermal indicators in different operating modes of the WIP. The known methods of thermal calculation of heat exchangers and the results of previous studies on the development and implementation of heat recovery equipment operating on dusty gases were used. The results of work on the creation of a new technical solution for an air-heating heat recovery exchanger with the ability to clean working surfaces from dust deposits are presented. The heat exchange surface of the heat recovery exchanger is composed of steel panels formed by tubes with membranes. The tubes applied have circular flow turbulizators on their internal surfaces. Turbulizators provide heat transfer intensification by 1.4 to 1.8 times with a moderate increase in aerodynamic resistance compared to other methods of heat transfer intensification. The regularities of changes in the main indicators of the heat recovery unit in different operating modes during the year in the practical range of changes in its input parameters were established. The research results show that, depending on the initial temperatures of gases and air, the excess air ratio in exhaust gases and the dust level of the working surface, the heat recovery exchanger provides heating capacity of 72-263 kW; cooling of exhaust gases to a temperature of 107-245 °C; heating of air to 96-220 °C. It was also established that the deposition of dust on the heat exchange surface of the heat recovery unit under the considered conditions leads to a decrease in the heating air temperature by 1.3-1.4 times and an increase in the final exhaust gas temperature by 1.1-1.2 times. At the same time, the heating capacity of the heat recovery exchanger is reduced by half. To increase heat recovery efficiency, it is necessary to periodically clean the working surfaces of the heat recovery unit with compressed air.

Capacitance-Based Structural Self-Sensing of Stress: Effect of Water/Cement

Abstract The compressive stress self-sensing properties of mortars with different water-cement ratios are investigated without the need for any conductive additives. Mortar specimens are cyclically loaded and the corresponding capacitance and resistance are measured. The aluminum foil that is used as the electrode is wrapped around the prismatic sample. A coplanar configuration of electrodes is used. Capacitance and resistance increase with increasing water/ cement (W/C) ratio. Stress causes decrease in capacitance and increase in resistance. The relationship between stress and fractional capacitance-resistance (except for the sample with 0.30 W/C ratio) change is reasonably consistent. The effectiveness of stress sensing (the fractional change in capacitance-resistance per unit of stress) decreases monotonically as the maximum stress increases, regardless of the W/C ratio. It is found that the dependence of the effectiveness of the stress sensing on the W/C ratio decreases with an increase in the maximum stress.&amp;#xD;

Zinc–cobalt bimetallic metal-organic framework (Zn/Co-MOF) nanoparticles as potent pH stimuli anti-corrosive agent for development of a self-healable epoxy composite coating

The impressive BET-surface area and the design versatility have made Z67(ZIF-67) MOF a potent nanomaterial for anti-corrosion applications. Despite excellent anti-corrosion features the Z67(ZIF-67) suffers poor stability in water media, making it improper for application in polymeric systems. One strategy to enhance the stability of Z67 is its structure modification via a mixed-metal organic framework approach. This study involved the synthesis of a series of Z67 nanoparticles through the incorporation of zinc cation (Zn) at different percentages. Specifically, three different compositions were synthesized: Zn10-Z67, Zn20-Z67, and Zn30-Z67 denoting the addition of 10 %, 20 %, and 30 % molar percent of Zn, respectively. FTIR, FE-SEM, XRD, TEM, ICP-OES, and XPS, as well as BET analyses, were conducted for the Zinc–Cobalt bimetallic MOF structure. Subsequently, the properties attributed to the particles' active and barrier anti-corrosion feature in solution (NaCl) as well as coating (epoxy) phases were investigated. The EIS test performed in the solution phase, after 72h of metal exposure to Zn30-Z67 containing saline media, revealed a 590 % and 30 % increase in total resistance, respectively, compared to the uninhibited sample. Due to the increased stability of Zn10-Z67 in a saline environment, the active corrosion inhibition of the scratched coating containing these particles was increased by approximately 140 % compared to the Z67-containing composite. The incorporation of zinc cations into the structure of Z67 has enhanced the stability and control release features in aqueous environments, thereby enhancing the barrier properties of the epoxy coating. The reduction rate of log|Z|0.01Hz of the Zn10-Z67/EPC was 9 % which was lower than that of the Neat EPC (epoxy coating) (24 %).

In Situ Electrical Resistance Measurement of Pure Titanium During Severe Plastic Deformation by High‐Pressure Sliding

In this study, in situ measurements of electrical resistance in pure Ti during severe plastic deformation (SPD) under high pressures are presented. The process of high‐pressure sliding (HPS) is adopted for the SPD so that straining is feasible under various pressures covering α to ω allotropic phase transformation in pure Ti. Anvil surfaces are coated by a plasma‐sprayed alumina layer to maintain electrical insulation between the sample and the anvils during HPS operation. The electrical resistance increases continuously with straining by the HPS processing but the increase in the electrical resistance is more pronounced as the applied pressure increases, particularly when the ω phase formation occurs. The phase transformation is evidenced by X‐Ray diffraction analysis as well as in situ static heating experiment. The continuous increase in the electrical resistance suggests that there is neither critical strain nor avalanche for the phase transformation to the ω phase.

Transverse resistance variations in helically wound 2G ReBCO high-temperature superconducting tape with core under transverse cycling and bending loads

The variations in normalized transverse resistance of 2G HTS tape in a helically wound configuration with the core were measured at room temperature (RT) and 77 K under transverse cyclic and three-point bending loads. The observed experimental phenomena were explained by considering the differences in gap sizes between the superconducting tape and copper core, as well as between the superconducting tapes when multiple tapes are wound during sample preparation and cooling. By analyzing the impact of winding parameters, we offer engineering recommendations to mitigate the increase in transverse resistance and enhance the bearing ability of superconducting tapes under transverse cyclic and three-point bending loads at 77 K. These recommendations include augmenting pre-tension during the winding process, reducing sample placement time before testing, increasing the copper core radius and winding angle, as well as reducing the number of winding tapes.