Recently a number of articles concerning subjects related to limitation of greenhouse gasses emission or neutralization of greenhouse gasses present in atmosphere significantly increased. Global warming negatively influences on non-failure operation of ecosystem and due to glaciers melting resulting in water volume increase causing raising of water level in seas and oceans. Large number of negative factors resulting from global warming effect creating necessity of performance of intensified investigations going to development of technologies enabling limitation of emission or neutralization of greenhouses gasses through its conversion to chemical compounds which can be applied in synthesis of other useful chemical compounds or functional materials. Other important problem beyond limitation of CO2 amount in atmosphere is related to possibilities of its conversion to chemical compounds which can be used as energy carriers. It creates possibilities for its applications in renewable energy storage oriented systems. The proposed project is focused on photoelectrochemical conversion of one of main greenhouse gas, CO2 to ethylene. The main scientific objective of performed studies was the development of methodology for electrochemical synthesis of binary composite Cu-Cu2O material. Copper is the only metal that exhibits very high selectivity for electrochemical conversion of CO2 to ethylene (1). Ren et al. observed similar effect in case of p-type Cu2O (2). Reported effects allow assumption that combination of both materials can be great solution in the frame of light supported electrochemical conversion of carbon dioxide to ethylene. Authors describe optimization of electrochemical synthesis process towards synthesis of composite coatings of wide composition range. Synthesis conditions were investigated starting from the thermodynamic analysis of the electrolyte. Conditions for synthesis were determined based on the results of voltammetric tests and electrochemical quartz crystal microbalance analyses. Synthesized coatings were characterized towards their composition, structure, morphology and catalytic properties towards electrochemical reduction of CO2 to ethylene. References Y. Kwon, Y. Lum, E. L. Clark, J. W. Ager and A. T. Bell, ChemElectroChem, 3, 1012 (2016).D. Ren, Y. Deng, A. D. Handoko, C. S. Chen, S. Malkhandi and B. S. Yeo, ACS Catalysis, 5, 2814 (2015).P. D. Tran, S. K. Batabyal, S. S. Pramana, J. Barber, L. H. Wong and S. C. J. Loo, Nanoscale, 4, 3875 (2012).
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