Increase In Transition Temperature Research Articles

Analyzing Frequency Spectra of Dielectric Loss to Clarify Influence of L,α-alanine Doping on Phase Transition in Triglycine Sulfate

As reported in the literature, the doping of L,α-alanine (LA) led to increasing the phase transition temperature in triglycine sulfate (TGS) – a bio-ferroelectric material that has been widely applied in industry. The nature of this anomaly is commonly investigated by considerably complicated theoretical and experimental techniques. Unlike previous studies, the present work proposes a simple physical method of analyzing frequency spectra for dielectric loss to clarify the relationship between the movement of phase transition positions and the shift of relaxation frequencies observed in the spectra. The experimental results obtained for LA-doped TGS samples synthesized at different LA contents (0, 5, 10, 20, and 30 wt.%) were used for the analysis. It was indicated that the increase in phase transition temperature was accompanied by the decrease in relaxation frequencies due to the enhanced viscosity created by strong hydrogen bonds formed between amino acids of alanine and TGS structure.

Immobilization of Conjugated Polymer Domains for Highly Stable Non-Fullerene-Based Organic Solar Cells.

To commercialize organic solar cells (OSCs), changes in the optimized morphology of the photoactive layer caused by external stimuli that cause degradation must be addressed. This work improves OSC stability by utilizing the cross-linking additive 1,8-dibromooctane (DBO) and a sequential deposition process (XSqD) to fabricate the photoactive layer. The cross-linking additive in the donor polymer (PTB7-Th) improves polymer crystallinity and immobilizes the crystalline morphology by partial photo-cross-linking. Ellipsometry experiments confirm the increase in the glass transition temperature of cross-linked PTB7-Th. The polymer crystallinity is further improved after removal of non-cross-linked polymer and residual additive by chlorobenzene. The cross-linked polymer layer forms an efficient and stable heterojunction with a nonfullerene acceptor (IEICO-4F) layer via an XSqD process. The OSC based on the immobilized PTB7-Th exhibits excellent stability against light soaking and thermal aging.

Synthesis, characterization, conductivity, and gas‐sensing performance of copolymer nanocomposites based on copper alumina and poly(aniline‐co‐pyrrole)

AbstractA series of copolymer nanocomposites based on poly(aniline‐co‐pyrrole) (PANI‐co‐PPy) with different contents of copper alumina (Cu‐Al2O3) nanoparticles were synthesized by benign in situ chemical oxidation polymerization. The structural, thermal transition, and morphological interpretations were carried out by Fourier‐transform infrared spectroscopy (FTIR), x‐ray diffraction (XRD), differential scanning calorimetry (DSC), and high‐resolution transmission electron microscope (HR‐TEM). The electrical properties such as alternating current (AC) conductivity and dielectric measurements were performed at room temperature to verify their application in developing new electronic devices. The presence of nanoparticles in the copolymer and the synergistic interaction in the copolymer matrix was confirmed by FTIR and XRD. HR‐TEM indicates the nanosized uniform dispersion of nanofiller in the copolymer matrix. DSC revealed a reduction in the flexibility of polymer with an increase in glass transition temperature of copolymer composites. AC conductivity measurement manifested an increased hopping of charge carriers in nanocomposites when compared with pristine PANI‐co‐PPy. Dielectric properties were maximum for copolymer with 5 wt% Cu‐Al2O3. Excellent gas sensing traits were observed for copolymer nanocomposites due to the electron transfers existing between PANI‐co‐PPy and ammonia gas. The maximum gas‐sensing properties and electrical conductivity were observed for 5 wt% copolymer composites. The magnificent material properties make PANI‐co‐PPy/Cu‐Al2O3 nanocomposites, a promising contender for developing nano‐electronic devices.

Ferroelectric Switching and Phase Transition in Composites from Ferroelectric Metal–Organic Framework of [ND4][Zn(DCOO)3] and Silicon Dioxides

A composite from a ferroelectric metal–organic framework of [ND4][Zn(DCOO)3] and nano-dispersed silicon dioxides nanoparticles (nSiO2) has been synthesized. The study investigates the influence of nSiO2 on ferroelectric switching and phase transition properties in [ND4][Zn(DCOO)3]. It was indicated that the addition of nSiO2 led to the increase in phase transition temperatures and the inhibition of repolarization in ferroelectric parts. When the nSiO2 amount increased, the saturated dielectric hysteresis loops were more difficult to obtain and transformed into unsaturated ones with the rise of coercive field. The residual water molecules kept on nSiO2 were found to be responsible for the above anomalies.

Preparation of cellulose nanocrystals coated with polymer crystals and their application in composite films

AbstractIncreasing the dispersibility of cellulose nanocrystals (CNCs) as a reinforcing material is highly desirable to obtain composites with enhanced mechanical properties. To this aim, nanocomposite fibers (NCF(CNC/polymer)) were fabricated by coating CNCs with polymer crystals. Poly(vinyl alcohol) (PVA) and poly(vinyl alcohol‐co‐ethylene) (EVOH) were crystallized from a dilute solution in the presence of CNCs, which acted as nucleating agents for polymer crystal growth on the CNC surface. NCF consisting of CNCs coated with PVA crystals (NCF(CNC/PVA)) and CNCs coated with EVOH crystals (NCF(CNC/EVOH)) were successfully obtained. Both NCF(CNC/polymer) showed good dispersibility in water, even after drying, and were used to prepare composite films with improved mechanical properties. The reinforcement effect of NCF(CNC/PVA) was greater than that of pure CNCs and NCF(CNC/EVOH). The PVA composite films exhibited optical transmittance above 99% compared with additive‐free PVA films. No agglomerates appeared even under the optical microscopic observation of the PVA composite film, and NCF(CNC/PVA) dispersibility was extremely good. NCF(CNC/PVA)‐added PVA composite films exhibited increased glass transition temperature compared with additive‐free PVA films, and the crystallinity of the PVA film increased. The highly dispersed CNCs in the PVA matrix and the increase in the glass transition temperature and crystallinity caused an increase in the mechanical modulus of the PVA composite film at low NCF(CNC/PVA) content. Furthermore, the effect of the morphologies of cellulose nanofibers and CNCs on the mechanical properties of the composite films prepared using the respective NCFs was investigated.

ANALYSIS OF STRUCTURAL CHANGES OF MODIFIED POLYETHYLENE FILMS BY DIFFERENTIAL SCANNING CALORIMETRY

The article presents the results of studies of the effect of high-frequency capacitive (HF) plasma modification on the change in the structure of polyethylene (PE) films. To analyse structural changes by differential scanning calometry (DSC), the temperature and specific heat of melting, as well as the glass transition temperature of PE film samples before and after plasma modification in plasma-forming gases argon and air were determined. A temperature programme has been selected to determine the glass transition temperature, which can serve as a qualitative characteristic of structural changes in polymer macromolecules. It is shown that the modified samples have an increase in the glass transition temperature, while the maximum effect is observed for samples modified in the HE plasma of air, which may be due to the formation of functional groups, multiple bonds and crosslinking, which contributes to a decrease in molecular mobility and difficulty of conformational transitions in PE macromolecules.

Epoxy Composites Reinforced with ZnO from Waste Alkaline Batteries.

The zinc alkaline battery is one of the most popular sources of portable electrical energy, with more than 300,000 tons being consumed per year. Accordingly, it is critical to recycle its components. In this work, we propose the use of zinc oxide (ZnO) microparticles recovered from worn-out batteries as fillers of epoxy resins. These nanocomposites can be used as protective coatings or pigments and as structural composites with high thermal stability. The addition of ceramic nanofillers, such as ZnO or/and TiO2, could enhance the thermal and mechanical properties, and the hardness and hydrophobicity, of the epoxy resins, depending on several factors. Accordingly, different nanocomposites reinforced with recycled ZnO and commercial ZnO and TiO2 nanoparticles have been manufactured with different nanofiller contents. In addition to the different ceramic oxides, the morphology and size of fillers are different. Recycled ZnO are“desert roses” such as microparticles, commercial ZnO are rectangular parallelepipeds nanoparticles, and commercial TiO2 are smaller spherical nanoparticles. The addition of ceramic fillers produces a small increase of the glass transition temperature (<2%), together with an enhancement of the barrier effect of the epoxy resin, reducing the water diffusion coefficient (<21%), although the maximum water uptake remains constant. The nanocomposite water absorption is fully reversible by subsequent thermal treatment, recovering its initial thermomechanical behavior. The water angle contact (WCA) also increases (~12%) with the presence of ceramic particles, although the highest hydrophobicity (35%) is obtained when the epoxy resin reinforced with recycled flowerlike ZnO microparticles is etched with acid stearic and acetic acid, inducing the corrosion of the ZnO on the surface and therefore the increment of the surface roughness. The presence of desert rose ZnO particles enhances the de lotus effect.

Molecular Dynamics Study of Phosphorus Migration in Σ3(111) and Σ5(0-13) Grain Boundaries of α-Iron

Phosphorus atoms in steels accumulate at grain boundaries via thermal and irradiation effects and induce grain boundary embrittlement, which is experimentally confirmed by an increase in the ductile-brittle transition temperature. Quantitative prediction of phosphorus segregation at grain boundaries under various temperature and irradiation conditions is essential for preventing embrittlement. To develop a model of grain boundary phosphorus segregation in α-iron, we studied the migration of a phosphorus atom in two types of symmetrical tilt grain boundaries (Σ3[1-10](111) and Σ5[100](0-13) grain boundaries) using molecular dynamics simulations with an embedded atom method potential. The results revealed that, in the Σ3 grain boundary, phosphorus atoms migrate three-dimensionally mainly in the form of interstitial atoms, whereas in the Σ5 grain boundary, these atoms migrate one-dimensionally mainly via vacancy-atom exchanges. Moreover, de-trapping of phosphorus atoms and vacancies was investigated.

Salt-induced stability and modified interfacial energetics in self-faceting emulsion droplets

HypothesisThe counterintuitive temperature-controlled self-faceting of water-suspended, surfactant-stabilized, liquid oil droplets provides new opportunities in engineering of smart liquids, the properties of which are controllable by external stimuli. However, many emulsions exhibiting self-faceting phenomena have limited stability due to surfactant precipitation. The emulsions’ stability may be enhanced, and their inter-droplet electrostatic repulsion tuned, through controlled charge screening driven by varying-concentration added salts. Moreover, in many technologically-relevant situations, salts may already exist in the emulsion’s aqueous phase. Yet, salts’ impact on self-faceting effects has never been explored. We hypothesize that the self-faceting transitions’ temperatures, and stability against surfactant precipitation, of ionic-surfactants-stabilized emulsions are significantly modified by salt introduction. ExperimentsWe explore the temperature-dependent impact of NaCl and CsCl salt concentration on the emulsions’ phase diagrams, employing optical microscopy of emulsion droplet shapes and interfacial tension measurements, both sensitive to interfacial phase transitions. FindingsA salt concentration dependent increase in the self-faceting transition temperatures is found, and its mechanism elucidated. Our findings allow for a significant enhancement of the emulsions’ stability, and provide the physical understanding necessary for future progress in research and applications of self-faceting phenomena in salt-containing emulsions.

Investigation of Structural and Thermal Properties of Graphene Oxide Reinforced Epoxy Nanocomposites

The nanocomposites thin film was prepared by adding exfoliated GO in epoxy-hardner solution in different weight ratio. We investigate the thermal and surface properties of epoxy-graphene oxide (GO) nanocomposites using differential scanning calorimetry (DSC), fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and contact angle measurement method. AFM and contact angle results are supporting that graphene oxide provides the best reinforcement in epoxy. AFM is investigated the dispersion of GO and structural morphology of epoxy nanocomposites. The FTIR results show that exfoliated GO of two-dimensional (2D) shape favors the hardening process of the epoxy matrix, increasing its reaction rate by observing an epoxy stretching frequency at 907 cm−1. The GO modified with amino group of epoxy lead to the increase of crosslinking density. FTIR absorption peak in 1700–1500 cm−1 regions is due to amino group. This attributes the significant increase of glass transition temperature of epoxy/GO nanocomposites . The contact angle and surface roughness increases with increase in concentration of GO in epoxy shows roughness induced hydrophobic surface. The solid surface energy was calculated by contact angle favors the good dispersion of GO in epoxy matrix.

Design and characterization of carbon fiber-reinforced PEEK/PEI blends for Fused Filament Fabrication additive manufacturing

We formulated high temperature-resistant thermoplastic composite materials featuring high thermal and mechanical properties for the Fused Filament Fabrication (FFF) additive manufacturing process. The composite materials were blends of poly(ether ether ketone) (PEEK) and poly(ether imide) (PEI) with weight ratios of 100/0, 90/10, 80/20, 70/30, 60/40, 50/50 and 40/60 and all mixed using an extrusion process with 30 wt% chopped carbon fibers (CFs). Differential Scanning Calorimetry measurements on the blends showed a significant increase of the single glass transition temperature, Tg, (up to 37 °C for PEEK/PEI 40/60 formulation), when compared to the neat PEEK, indicating a good miscibility of PEEK and PEI. Microscopy observations using Scanning Electron Microscopy and X-ray microtomography revealed a good dispersion of CFs in the PEEK/PEI blend matrix and also the presence of some voids. Tensile mechanical testing results showed that the highest value of the Young’s Modulus (13 GPa), among all the formulations, is obtained for the composition of reinforced PEEK/PEI (80/20) which also exhibited the lowest degree of porosity (2.90%), and high printability in the FFF process (i.e., high visual quality of the printed parts with no major printing issues). The materials developed here will help move towards manufacturing of functional prototypes made of high-performance composites (e.g., high mechanical properties and high service temperature) using FFF additive manufacturing process for various aerospace applications.

Highly efficient extraction of Eucommia ulmoides gum by IL-organic solvent biphasic system

A biphasic solvent system consisting of ionic liquids (IL) and petroleum ethers was applied in the extraction of Eucommia ulmoides gum (EUG) from pericarp. Effects of IL and extraction parameters on the yield and purity of EUG were investigated. The results showed that the addition of IL could enhance the yield and purity of EUG extracted from pericarp comparing with the traditional alike pretreatment method. FTIR, XRD and 1H NMR characterization conformed the chemical structure of EUG. DSC analysis reviewed the partial destruction of crystal structure and the disappearance of β-crystal phase of EUG extracted by biphasic solvent system, resulting in the decrease of the melting point and increase of glass transition temperature. Moreover, the extracted EUG exhibited high tensile strength of 27.68 MPa, excellent elongation at break of 1069%, and thus high toughness of 181.45 MJ∙m−3. Additionally, the excellent reusability of IL and petroleum ethers showed the extraction method of the biphasic solvent system promise as a feasible method to replace the traditional alkali pretreatment.

Strength, Water Absorption, Thermal and Antimicrobial Properties of a Biopolymer Composite Wound Dressing

Conventional wound material allows bacterial invasions, trauma and discomfort associated with the changing of the dressing material, and the accumulation of body fluid for wounds with high exudate. However, there is a shift from conventional wound dressing materials to polymeric nanofibers due to their high surface area to volume ratio, high porosity, good pore size distribution, which allows for cell adhesion and proliferation. There is an urgent need to synthesis a biodegradable composite that is resistant to bacterial infection. In this study, an electrospun polylactide (PLA) composite suitable for wound dressing, with enhanced antimicrobial and mechanical properties, was produced. The neat PLA, PLA/CH (10 wt.%), PLA/CH (5 wt.%), PLA/CHS (10 wt.%), PLA/CHS (5 wt.%), PLA/CH (2.5 wt.%) /CHS (2.5 wt.%) and PLA/CH (5 wt.%)/CHS (5 wt.%), were electrospun using 0.14 g/ml solution. Results show that crystallinity (67.6%) of neat PLA declined by 3.8% on the addition of 2.5 wt.% chitin/chitosan with improved hydrophilicity of the composite. The tensile strength of neat PLA (0.3 MPa) increased (0.6 MPa) with 2.5 wt.% chitin/chitosan addition. The slight increase in the glass transition temperature from 75°C for neat PLA to 78°C of the composite fibre, showed improved ductility. The fibres showed little beads, hence suitable for wound dressing. The electrospun mats have good water absorption capacity and strong resistance against Staphylococcus aureus. Good performance was attained at 5 wt.% of chitin, chitosan and hybrid reinforcements. Therefore, a PLA/chitin/chitosan composite is recommended as a wound dressing material.

Ionic conductivity enhancement of PVA: carboxymethyl cellulose poly-blend electrolyte films through the doping of NaI salt

In this paper, we report the effect of doping sodium iodide (NaI) salt into a polymer blend matrix of sodium carboxymethyl cellulose (NaCMC) and poly(vinyl alcohol) (PVA). Solution casting approach was used to prepare solid polymer electrolyte (SPE) films. The films were characterized by Fourier-transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), electrical impedance spectroscopy, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). XRD showed that NaI incorporation decreased the crystallinity of NaCMC/PVA-based SPE. FTIR technique confirmed the complexation of salt with polymer matrix due to the formation of the coordination bond between Na+ and –OH group and hydrogen bond between I− and –CH group. The sample with 30 wt% NaI showed the highest conductivity of 2.52 × 10–3 S cm−1, strongly influenced by the highest charge concentration (n), not its mobility (μ). DSC analysis revealed an increase in glass transition temperature ({T}_{g}) with increasing salt content. TGA studies showed a decrease in thermal stability with salt inclusion. The transference number was found to be 0.99 for the highest conducting sample showing the primary charge carriers are ions. The highest conducting sample exhibited a mechanical strength of 15.42 MPa at room temperature, and it has been used to fabricate a battery to evaluate its suitability in energy storage devices.Graphical abstractGraphical abstract created with https://biorender.com.

Oxygen defect engineered magnetism of La2NiMnO6 thin films

The double perovskite La2NiMnO6 (LNMO) exhibits complex magnetism due to the competition of magnetic interactions that are strongly affected by structural and magnetic inhomogeneities. In this work, we study the effect of oxygen annealing on the structure and magnetism of epitaxial thin films grown by pulsed laser deposition. The key observations are that a longer annealing time leads to a reduction of saturation magnetization and an enhancement in the ferromagnetic transition temperature. We explain these results based upon epitaxial strain and oxygen defect engineering. The oxygen enrichment by annealing caused a decrease in the volume of the perovskite lattice. This increased the epitaxial strain of the films that are in-plane locked to the SrTiO3 substrate. The enhanced strain caused a reduction in the saturation magnetization due to randomly distributed anti-site defects. The reduced oxygen defects concentration in the films due to the annealing in oxygen improved the ferromagnetic long-range interaction and caused an increase in the magnetic transition temperature.

H/F Substitution Induced Large Increase of Tc in a 3D Hybrid Rare-Earth Double Perovskite Multifunctional Compound.

Invited for the cover of this issue are Le-Ping Miao, Chao Shi, Yi Zhang and co-workers at Jiangxi University of Science and Technology. The image depicts the structure diagrams of the 3D hybrid rare-earth double perovskite compounds. The phase transition temperatures of the two compounds were indicated by the "ice and fire", respectively. It implies the increase of the phase transition temperature of the compounds. Read the full text of the article at 10.1002/chem.202103913.

Influence of microfluidization on physico-chemical, rheological, thermal properties and cholesterol level of cow ghee

Application of microfluidization can influence physicochemical, structural, rheological and functional properties of the food matrix, significantly. In the present research, effect of high pressure microfluidization treatment (50–200 MPa, single pass) on pH, refractive index (RI), free fatty acid (FFA) values, colour measurements, rheology, particle size, structural properties and thermal properties of cow ghee (CG) were investigated. Upon microfluidization, the pH values of CG significantly increased from 4.5 to 4.9. The shear-thinning nature of microfluidized CG was demonstrated by a Rheogram between apparent viscosity and shear rate. At 50 MPa, the apparent viscosity of the sample increased but then decreased as the microfluidization pressure was increased. Thermal analysis revealed an increase in glass transition temperature (Tg) at 50 MPa from 32 to 37 °C and a significant effect was observed on it as the pressure was increased. GC-MS analysis revealed that microfluidization at 150 MPa reduced the cholesterol level in CG by 39.37%. The current research is the first one on microfluidization of CG and can open new channels on the research end.

Comparative Study of Polymeric Laminated Composites Reinforced by Different Fibers of Prosthetic Socket by DSC and FTIR

Prosthetic socket is the device that link artificial limb with the amputee part. This work has been done on seven laminated composite were prepared by vacuum technique from Polyester resin reinforced with (Jute, Carbon, Glass, Perlon) fibers. The interaction between fibers and matrix material was studied using Fourier transform infrared (FTIR) spectroscopy. DSC test also had been studied for different laminated composite materials to make prosthetic socket. The infrared spectra result of the Polyester composite specimens with natural and synthetic fibers indicate that no additional new peak was observed. While DSC results showed the increase in the glass transition temperature (Tg) as the number of Jute layers increased and this may be related to the nature of Jute fibers. As well as Carbon lead to increase Tg but Glass fiber decreased Tg when added to natural fiber (Jute fiber). The composite specimen reinforced with three layers of Jute fibers plus four layers of Carbon fibers (3 Jute + 4 Carbon) had the highest Tg (107°C).

Effect of potassium or yttrium introduction in Yb3+-doped germano-gallate glasses on the structural, luminescence properties and fiber processing

Here we report on the effect of potassium or yttrium on the luminescence spectroscopic properties of Yb3+-doped germano-gallate glasses as well as the ability to shape them into optical fibers with the objective of using such glasses to produce near-infrared optical gain medium. Two ytterbium-doped germano-gallate glass systems, (100-x) (28Ga2O3 – 37GeO2 – 23BaO – 12K2O) – xYb2O3 (x = 0, 0.5 and 3 mol.%) and 29.6Ga2O3 – 39.1GeO2 – 24.3BaO – 7 (yY2O3 – zYb2O3) (y = 6.5, 4, 0 and z = 0.5, 3, 7 mol% respectively) have been prepared and the systematic investigation of their thermal, structural, optical and spectroscopic properties have been carried out. The increase in ytterbium oxide content leads to an increase of the glass transition temperature, crystallization temperature and the density of the glasses, as well as induces a red-shift of the cut-off wavelength. Raman spectroscopy analysis shows that both ytterbium oxide addition and potassium substitution by yttrium modify the 3D interconnected germano-gallate glass network. Lifetime diminishes with the increase of Yb3+ concentration but remains higher in the yttrium-containing glasses. We demonstrate that the production of crystal-free light guiding fibers via the preform-to-fiber approach becomes possible only in the yttrium-containing glass system. Cut-back optical attenuation measurements of the produced fibers show minimum losses of 3.3 dB/m at 1310 nm.

Ruddlesden\u2013Popper 2D perovskites of type (C6H9C2H4NH3)2(CH3NH3)n\u22121PbnI3n+1 (n\u2009=\u20091\u20134) for optoelectronic applications

Ruddlesden–Popper (RP) phase metal halide organo perovskites are being extensively studied due to their quasi-two dimensional (2D) nature which makes them an excellent material for several optoelectronic device applications such as solar cells, photo-detectors, light emitting diodes (LEDs), lasers etc. While most of reports show use of linear carbon chain based organic moiety, such as n-Butylamine, as organic spacer in RP perovskite crystal structure, here we report a new series of quasi 2D perovskites with a ring type cyclic carbon group as organic spacer forming RP perovskite of type (CH)2(MA)n−1PbnI3n+1; CH = 2-(1-Cyclohexenyl)ethylamine; MA = Methylamine). This work highlights the synthesis, structural, thermal, optical and optoelectronic characterizations for the new RP perovskite series n = 1–4. The demonstrated RP perovskite of type for n = 1–4 have shown formation of highly crystalline thin films with alternate stacking of organic and inorganic layers, where the order of PbI6 octahedron layering are controlled by n-value, and shown uniform direct bandgap tunable from 2.51 eV (n = 1) to 1.92 eV (n = 4). The PL lifetime measurements supported the fact that lifetime of charge carriers increase with n-value of RP perovskites [154 ps (n = 1) to 336 ps (n = 4)]. Thermogravimetric analysis (TGA) showed highly stable nature of reported RP perovskites with linear increase in phase transition temperatures from 257 °C (n = 1) to 270 °C (n = 4). Scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX) are used to investigate the surface morphology and elemental compositions of thin films. In addition, the photodetectors fabricated for the series using (CH)2(MA)n−1PbnI3n+1 RP perovskite as active absorbing layer and without any charge transport layers, shown sharp photocurrent response from 17 nA/cm2 for n = 1 to 70 nA/cm2 for n = 4, under zero bias and low power illumination conditions (470 nm LED, 1.5 mW/cm2). Furthermore, for lowest bandgap RP perovskite n = 4, (CH)2MA3Pb4I13 the photodetector showed maximum photocurrent density of ~ 508 nA/cm2 at 3 V under similar illumination condition, thus giving fairly large responsivity (46.65 mA/W). Our investigations show that 2-(1-Cyclohexenyl)ethylamine based RP perovskites can be potential solution processed semiconducting materials for optoelectronic applications such as photo-detectors, solar cells, LEDs, photobatteries etc.