This paper focuses on the influence mechanism of process parameters on the geometry morphology and microstructure characteristic of single-track and multi-track 316L/CuSn10 multiple materials manufactured by laser powder bed fusion (LPBF). The width of single-track increases with the increase of laser power and layer thickness, and decreases with the increase of scanning speed. Both variations in the copper content and wetting angle of the molten pool were investigated. In addition, the comparison of defect characteristics shows that the scanning speed and layer thickness have a greater influence on the formation of single cracks. The traces of Marangoni convection are observed directly in the centre of the molten pool due to the difference in microstructure between 316L and CuSn10 alloys. It is found that the copper penetration cracks appear on the steel side at the molten pool bottom. Moreover, fine grains appear in the copper-rich region, and the large-angle grain boundary distribution seems to be the reason for the concentration of dislocations. Four types of crack formation mechanisms are found in the cross section of the multi-track: crack formation inside the molten pool, passing through the track boundary, extending to the steel substrate, and copper penetration cracks.