Incompatible Minor Elements Research Articles

Subduction-related mantle accretion and makeover revealed by mantle xenoliths at the Pacific margin of NE Eurasia

Subduction is thought to be a major factor in the origin and makeover of continental lithospheric mantle, but essential aspects of these processes continue to be debated. Here, we report textural, chemical and Re Os isotope data on mantle xenoliths from far eastern Russia located at different distances from the Asian Pacific coast to examine how the proximity to subduction zones affects lithospheric mantle compositions. The xenoliths come from the Khanka block close to the border with China and several sites in the Sikhote-Alin orogenic belt (SAOB) near the Japan Sea coast. The inboard Khanka xenoliths are spinel lherzolites with chemical compositions, suggesting that they are residues of low- to moderate-degrees of melt extraction from fertile mantle and essentially unaffected by later events for 1.9 Ga. Such rocks are also common among peridotites in the SAOB, located closer to the subduction margins, but the SAOB suite also includes: a) heterogeneous rocks with veins and patches of pyroxenites or hydrous minerals, and b) rocks enriched in iron (8.8–13.5 wt%), Al 2 O 3 and incompatible minor elements. The positive correlation between elevated 187 Os/ 188 Os ratios (>0.135) and FeO contents in some Fe-rich SAOB xenoliths is interpreted to indicate that the metasomatic melts were derived from the asthenosphere hybridized with recycled materials from the Pacific slab. The lack of correlation between Re -depletion Os model ages (T RD ) and depletion indices, as well as the similarity of Os isotopic compositions between the SAOB peridotites and abyssal peridotites are interpreted to show that the SAOB mantle possibly formed and accreted to Eurasia from the asthenosphere during eastward migration of the Paleo-Pacific subduction trench. Based these results, we infer that the SAOB lithospheric mantle experienced multi-stage metasomatism after its formation, the most significant of which is localized infiltration of subduction-related basaltic melts with recycled characteristics induced by the extension of Japan Sea and release of volatiles from the slab. By contrast, the inboard Khanka lithospheric mantle shows little, if any, evidence for metasomatism. Such contrasting metasomatic modification implies different degrees and styles of makeover processes at different distances relative to the subduction margins. • The Khanka mantle was little affected by metasomatism since it was formed at ~1.9 Ga. • The Sikhote-Alin lithospheric mantle was formed by subduction and accretion. • Mantle metasomatism beneath Sikhote-Alin was caused by melts with recycled signature. • The nature and degrees of metasomatism are related to the distance from subduction front.

Geochemistry and Petrogenesis of Basaltic Rocks and Enclosed Xenoliths from the Ghab Pliocene Volcanic Field in Northwestern Syria

Basaltic rocks and their content of ultramafic xenoliths are common in the Ghab Pliocene Volcanic Field in northwestern Syria in the form of lava flows, cinder cones and pyroclastic deposits. The rocks occur within the Ghab pull- apart graben that formed by sinister strike slip faults within the zone that defines the boundary between the African and the Arabian plates. Three petrographic types occur: basanite, olivine basalt and more commonly alkali olivine basalt. The peridotite xenoliths are spinel lherzolite and harzburgite. Geochemical analysis indicates that the basalts are mostly alkaline to subalkaline. A distinctive feature of these rocks is the narrow compositional variations in the content of most major oxides and minor elements, SiO2 (44.33 - 46.43 wt%) and MgO (4.01 - 8.28 wt%). Some of the refractory and high field strength elements and incompatible minor elements in the basalts are relatively high (Cr average = 303 ppm and Ni average = 185 ppm) compared with their content in average basalts. These geochemical characteristics reflect crystallization of the Ghab basalts from pristine and primary magmas that have experienced minimal fractional crystallization and crustal contamination. Similarly, chemical compositions of the ultramafic xenoliths vary within a restricted geochemical range. They are compatible with the generation of these rocks from partial melting of a primitive mantle pyrolite to yield the xenoliths. These magmatic processes operated during the Pliocene in a regional transtensional stress environment attending the development of the Dead Sea Rift.

Along-strike variability of primitive magmas (major and volatile elements) inferred from olivine-hosted melt inclusions, southernmost Andean Southern Volcanic Zone, Chile

Glass compositions of melt inclusions in olivine phenocrysts found in tephras derived from explosive eruptions of the four volcanoes along the volcanic front of the southernmost Andean Southern Volcanic Zone (SSVZ) are used to constrain primitive magma compositions and melt generation parameters. Primitive magmas from Hudson, Macá, and Melimoyu have similar compositions and are formed by low degrees (8–18%) of partial melting. Compared to these other three centers, primitive magmas from Mentolat have higher Al2O3 and lower MgO, TiO2 and other incompatible minor elements, and are generated by somewhat higher degrees (12–20%) of partial melting. The differences in the estimated primitive parental magma compositions between Mentolat and the other three volcanic centers are consistent with difference in the more evolved magmas erupted from these centers, Mentolat magmas having higher Al2O3 and lower MgO, TiO2 and other incompatible minor element contents, suggesting that these differences are controlled by melting processes in the mantle source region above the subducted oceanic plate. Parental magma S=1430–594 and Cl=777–125 (μg/g) contents of Hudson, Macá, and Melimoyu are similar to other volcanoes further north in the SVZ. However, Mentolat primitive magmas have notably higher concentrations of S=2656–1227 and Cl=1078–704 (μg/g). The observed along-arc changes in parental magma chemistry may be due to the close proximity below Mentolat of the subducted Guamblin Fracture Zone that could efficiently transport hydrous mineral phases, seawater, and sediment into the mantle, driving enhanced volatile fluxed melting beneath this center compared to the others.

Calcium-rich melt inclusions in Cr-spinels from Borgarhraun, northern Iceland

Two groups of primitive melts are observed as inclusions in Cr-spinels in a picrite (Fo 88–92.4) from northern Iceland. Group I inclusions have 12.2–13.8 wt% MgO, high CaO (14.6–15.8 wt%), low Al 2O 3 (10.1–11.8 wt%) and very high CaO/Al 2O 3 (1.3–1.5); they occur in spinels with a cr# between 0.63 and 0.70. Group II inclusions occur in spinels with slightly lower cr# (0.55–0.60) and they have 13.3–15.8 wt% MgO, 12.0–13.8 wt% CaO, 11.2–13.4 wt% Al 2O 3 and CaO/Al 2O 3 0.9–1.1. Both groups have low concentrations of the incompatible minor elements (TiO 2, K 2O and P 2O 5) and relatively high SiO 2. The two groups converge at MgO approximately 10 wt%. A single inclusion in a low cr# spinel could represent a more evolved member (9.00 wt% MgO) of either group. Group I inclusions are on a clinopyroxene control line while Group II inclusions are close to being on an olivine control line. Groups I and II cannot be derived one from the other. They require high degree of melting from a refractory mantle source which probably is pyroxenitic to account for the high CaO. Melts with such high CaO/Al 2O 3 cannot be generated by melting commonly assumed lherzolites, so that pyroxenite or wehrlite mantle component is the suggested source.

Fluorine in basalts from Iceland

The fluorine content of Icelandic tholeiitic and alkaline basalts matches values found in similar rocks from other areas. Covariation between fluorine and incompatible minor elements such as potassium or phosphorus is found in evolved tholeiites and alkali basalts. Lack of such covariation in primitive olivine tholeiites indicates that fluorine and other incompatible minor and trace elements are not controlled by minerals such as amphibole, mica or apatite in the mantle residue, and that the covariation between these elements in the evolved basalts cannot be inherited from the mantle. Model calculations on rocks from the Langjokull area show that olivine tholeiite suites are, if derived by simple fractional crystallization, enriched in incompatible elements much in excess of the increase due to crystal removal. These observations are taken to indicate that the well documented covariation between fluorine and other incompatible elements is not established until evolution of the basaltic magma has started in crustal holding chambers. The constancy of element ratios and enrichment in excess of what can be accounted for by crystal fractionation or incremental addition of new batches of primitive magmas does indicate (1) mineral control involving amphibole, mica or apatite and (2) addition of fluorine, potassium and phosphorous from an external source. It is argued that this source is the crustal envelope of the holding chamber.

Origin of the Tertiary basaltic volcanism in the northern Hessian Depression

Volcanic activity started about 20 Ma before present with quartz tholeiites (QTh), had a climax with alkali olivine basalts (AOB) 13 to 14 Ma ago and ended 7 Ma ago with nepheline basanites (NB) and olivine nephelinites (ON). AOB covers 73% of the volcanic area. About 250 basalts and peridotite xenoliths were sampled for investigation. An upper mantle layer ranging from about 90 to 60 km depth has been conditioned for a preferential alkali basalt production by advection of H2O-CO2-fluids containing Si, Al, Ca, K, Na, P as major constituents beside numerous incompatible minor elements. At the onset of the geodynamically triggered mantle conditioning locally restricted diapirism into shallow depth has caused formation of olivine tholeiite magmas (OTh) at about 1,300° C by partial melting. All of these OTh primary melts intruded due to a favourable compressibility into granulites of the lower crust. The rare QTh basalts are their derivative magmas which have been slightly contaminated in the crust. Magmas of the subsequent alkali basaltic volcanism (AOB, bAOB, NB, ON, MON) formed by in-situ partial melting at about 75 to 90 km depth after depression of the peridotite solidi by fluids to temperatures ≦1,200° C. Except many AOB these magmas are primary melts as characterized by olivine/melt distribution coefficients of Mg/Fe2+ (KD=0.29 to 0.34), by Ni concentrations (260 to 330 ppm) and the occurrence of peridotite xenoliths. Rapid rise of gas charged melts due to saturation in CO2 prevented separation of olivine etc. and of xenoliths. The sequence of magmas from OTh to ON (or MON) is formed from decreasing proportions of orthopyroxene (opx) and increasing contributions of clinopyroxene (cpx) and phlogopite (ph) at almost equal proportions of spinel (sp). Incongruent melting of opx (and cpx) for OTh, AOB, NB and ON is correlated with precipitation of olivine. The average xenolith composition (73% ol, 18% opx, 7% cpx, 1.1% sp and 1.3/0.5% ph) was used to model the sources of the investigated melts by 9 incompatible elements and to calculate degrees of partial melting. The occurrence of garnet cannot be reliably excluded by modelling on the basis of HREE distribution coefficients. The average xenolith composition was used for modelling because of its resemblance with worldwide sampled depleted mantle inclusions. For avoiding to exhaust at least one mineral of the model mantle in the support of the norm composition of OTh, AOB, NB and MON magmas the degrees of partial melting cannot exceed 12.5%, 6%, 6% and 4% respectively. Mantle containing about 500 ppm K (and the correlated incompatible elements), like the average of 36 xenoliths, allows to explain the formation of OTh magmas. AOB, NB and ON melts require peridotite with slightly less than 1,500 ppm K, 670 ppm P and proportions of the correlated elements LREE, Sr, Ba, Zr, Rb, Cs, Ta, Th, Hf, U, which are higher than their abundance in primitive mantle rocks. About 20% of the xenoliths have this composition. Metasomatism of fluids with these elements must have been an immediate precursor of the alkali basaltic volcanism. Otherwise the preservation of a local disequilibrium in 87Sr/86Sr ratios between cpx cores and total rock at upper mantle temperatures cannot be explained.

DSDP site 334: Magmatic cumulates from oceanic layer 3

Coarse-grained lherzolitic peridotites and two-pyroxene gabbros recovered at Deep Sea Drilling Project site 334 beneath a thin layer of fine-grained basalt are primary magmatic cumulates similar to the upper cumulate portion of ophiolite complexes. Mineral chemistry indicates that they are the crystallization product of oceanic tholeiite magma. Long cooling and annealing times indicated by exsolution and equilibration in pyroxenes indicate emplacement near the Mid-Atlantic Ridge and long residence time in oceanic layer 3, prior to tectonic emplacement at shallow crustal levels. Slow depletion of the anorthite component in cumulate plagioclase relative to increase of Fe/Fe + Mg in coexisting mafic phases indicates more efficient fractionation of sodium into residual liquid than implied by fractionation of plagioclase phenocryst found in oceanic magmas. Strong depletion of incompatible minor elements and lack of intercumulate residual phases may indicate the operation of a diffusion mechanism that would allow interaction of pyroxene and magma prior to the crystallization of pyroxene as a liquidus phase.