In-plane Direction Research Articles

Effects of microstructure on hydraulic fracturing and gas–water production in coal reservoirs: A case study of the Dahebian coalbed methane block in Western Guizhou, China

AbstractThe development of coalbed methane (CBM) in China is susceptible to the influence of microstructure. Therefore, it is crucial to understand the extension laws of hydraulic fractures and engineering responses in coal reservoirs affected by microstructure development. Utilizing the Dahebian block in western Guizhou as the study area, this investigation examines the coal reservoir characteristics, fracturing, and drainage engineering analysis of the well DC1 group in the region. The aim is to discuss the spatial distribution characteristics of hydraulic fractures, geological controlling factors influenced by microstructure, and their corresponding engineering responses. The results indicate that, for coal reservoirs unaffected by microstructure, the extension laws of the fracture network in both longitudinal and planar directions are influenced by burial depth and the regional stress field. In the microstructural belt, tectonic stress dominates, causing changes in the ground stress field. Consequently, the hydraulic fracture network deviates from the direction of the maximum principal stress during the extension process. When a secondary fracture is nearby, the hydraulic fracture network extends towards the shortest path radial secondary fracture direction, leading to a rapid increase in fracture width per unit length until it intersects with the secondary fracture. Additionally, the presence of secondary joints near the microfault structure decreases fracturing pressure and results in a dense distribution of the fracture network. This promotes the formation of a complex fracture network, favorable for fracturing. The extension of the fracture network in complex structural development areas is influenced by the microfault structure between wells, which is reflected in the fracturing construction pressure and fluid output. This accounts for the significant variations in the early drainage performance of CBM wells.

Fast 3D fMRI acquisition with high spatial resolutions over a reduced FOV.

To develop and demonstrate a fast 3D fMRI acquisition technique with high spatial resolution over a reduced FOV, named k-t 3D reduced FOV imaging (3D-rFOVI). Based on 3D gradient-echo EPI, k-t 3D-rFOVI used a 2D RF pulse to reduce the FOV in the in-plane phase-encoding direction, boosting spatial resolution without increasing echo train length. For image acceleration, full sampling was applied in the central k-space region along the through-slab direction (kz) for all time frames, while randomized undersampling was used in outer kz regions at different time frames. Images were acquired at 3T and reconstructed using a method based on partial separability. fMRI detection sensitivity of k-t 3D-rFOVI was quantitively analyzed with simulation data. Human visual fMRI experiments were performed to evaluate k-t 3D-rFOVI and compare it with a commercial multiband EPI sequence. The simulation data showed that k-t 3D-rFOVI can detect 100% of fMRI activations with an acceleration factor (R) of 2 and ˜80% with R = 6. In the human fMRI data acquired with 1.5-mm spatial resolution and 800-ms volume TR (TRvol), k-t 3D-rFOVI with R = 4 detected 46% more activated voxels in the visual cortex than the multiband EPI. Additional fMRI experiments showed that k-t 3D-rFOVI can achieve TRvol of 480 ms with R = 6, while reliably detecting visual activation. k-t 3D-rFOVI can simultaneously achieve a high spatial resolution (1.5-mm isotropically) and short TRvol (480-ms) at 3T. It offers a robust acquisition technique for fast fMRI studies over a focused brain volume.

Anisotropic Thermal Conductivity Enhancement of the Aligned Metal-Organic Framework under Water Vapor Adsorption.

Metal-organic frameworks (MOFs) exhibit high adsorption and catalytic activities for various gas species. Because gas adsorption can cause a temperature increase in the MOF, which decreases the capacity and adsorption rate, a strict evaluation of its effect on the thermal conductivity of MOFs is essential. In this study, the thermal conductivity measurement of the MOF under water vapor adsorption was performed using an oriented film of copper tetrakis(4-carboxyphenyl)porphyrin (Cu-TCPP) MOF. A recently developed bidirectional 3ω method enabled the anisotropic thermal conductivity measurement of layered Cu-TCPP while maintaining its ordered structure. The water adsorption was found to increase the thermal conductivity in both in-plane and cross-plane directions with different trends and magnitudes, owing to the structural anisotropy. Molecular dynamics simulations suggest that additional vibrational modes provided by the adsorbed water molecules were the reason for the thermal conductivity enhancement.

Tailoring a Two-Dimensional Halide Perovskite Composed of the Secondary Amine Cation for Anisotropic X-ray Responses.

Two-dimensional (2D) metal-halide perovskites have shown broad application prospects in the field of optoelectronic detection. The presence of the natural quantum-well structure results in strong anisotropy of physical properties, while studies on anisotropic X-ray responses remain insufficient. Here, we present an intriguing anisotropy of X-ray-responsive behaviors in a 2D halide perovskite, (t-ACH)2(DMA)Pb2Br7 (1, where t-ACH is trans-4-(aminomethyl)cyclohexanecarboxylate and DMA is dimethylamine), in which the secondary amine DMA+ cation with a large ionic radius locates inside the perovskite cage to form inorganic frameworks. The alternative alignment of inorganic slabs and organic bilayers creates a typical quantum-well architecture, which accounts for the generation of photoelectronic anisotropy. High-quality crystals of 1 exhibit notable semiconducting properties with a large μτ product (1.9 × 10-4 cm2 V-1). Intriguingly, 1 has better X-ray detection sensitivity (∼569.9 μC Gyair-1 cm-2) along the in-plane direction, which is attributed to its excellent charge carrier transport performance in this direction. Conversely, the higher resistance stemming from the organic barrier results in a lower detection limit along the out-of-plane direction (∼78.1 nGyair s-1), much lower than the medical diagnostic criteria (∼5.5 μGyair s-1). This work might open up new possibilities for the creative use of hybrid perovskites in direct X-ray detection.

A gradient electrospinning electrode structure both in the in/through-plane directions for non-aqueous iron-vanadium redox flow battery

To boost the performance of non-aqueous redox flow batteries (RFBs), it is important to synergistically improve the flow/mass transfer efficiencies and the uniformity of overpotential distribution into the porous electrode. In this work, electrostatic spinning technology is developed to propose a novel porous electrode with gradient pore distribution both in the in-plane and through-plane directions, and applied in deep eutectic solvent (DES) electrolyte-based iron-vanadium RFB. On the one hand, the new in-plane gradient design modifies the distribution of reactive species of electrode near the membrane side, resulting in the decreasing polarization loss. On the other hand, the increasing porosity of electrodes from the flow field side to the membrane side attains a trade-off between the charge transfer and the electrolyte flow resistances. According to the experimental results, compared to the graphite felt electrode, the energy efficiency of this RFB with three-dimensional gradient electrode improves by 74.2 % at a current density of 10 mA·cm−2. Moreover, the numerical simulation reveals the reactive transfer behaviors of three-dimensional gradient porous electrode. The results show that the proposed three-dimensional gradient design can enhance the uniformity of overpotential distribution and achieve the decrease of polarization resistance, thus improving the performance of DES electrolyte-based iron-vanadium RFB effectively.

Global quark spin correlations in relativistic heavy ion collisions

The observation of the vector meson’s global spin alignment by the STAR Collaboration reveals that strong spin correlations may exist for quarks and antiquarks in relativistic heavy-ion collisions in the normal direction of the reaction plane. We propose a systematic method to describe such correlations in the quark matter. We classify them as local and long range quark spin correlations in the system. We show in particular that the effective quark spin correlations contain the genuine spin correlations originated directly from the dynamical process as well as those induced by averaging over other degrees of freedom. We also show that such correlations can be studied by measuring the vector meson’s spin density matrix and hyperon-hyperon and hyperon-anti-hyperon spin correlations. We present the relationships between these measurable quantities and spin correlations of quarks and antiquarks. Published by the American Physical Society 2024

Response of the orthogonal corrugated sandwich panel under low-velocity impact with different shaped impactors

This study aims at investigating the low-velocity impact resistance of the composite orthogonal corrugated sandwich panel through experimental and simulation methods, considering different shaped impactors. To that scope, the progressive damage model with the sandwich panel is developed and numerical investigations are carried out in ABAQUS / Explicit. The results show that as the impactor changes from flat to hemispherical and then to conical shape, the first peak load gradually decreases, and the maximum displacement of the impactor and total energy absorption gradually increase. The high impact energy makes the sandwich panel more compliant. Furthermore, the expansion area of fiber damage, matrix damage and delamination in the top face sheet, core and bottom face sheet depends on the impactor shape and impact energy. Under high impact energy, the damage under the conical impactor mainly expands along the thickness direction of the sandwich panel rather than in the in-plane direction, while the flat impactor causes large damage area in the in-plane direction as well.

Effect of growth temperature on properties of β-Ga2O3 films grown on AlN by low-pressure chemical vapor deposition

In this work, thin films of β-Ga2O3 were prepared on AlN substrates using low-pressure chemical vapor deposition (LPCVD). The effects of growth temperature on the crystal structure, surface morphology, chemical composition, and photoluminescence properties of the synthesized β-Ga2O3 thin films were then systematically investigated. The results indicated that various films grown at different temperatures in the range of 550–850 °C had a preferred growth orientation in the planar direction (−201). The surface roughness was seen to reduce gradually as the growth temperature was raised. However, excessive temperature (850 °C) led to a reduction in the densification of the prepared films. The surface chemistry of the films was analyzed using X-ray photoelectron spectroscopy (XPS) and the O/Ga ratio of the optimal film was calculated to be 1.49, which is quite close to the optimal stoichiometric ratio of 1.5. Multiple luminescence bands were obtained in the photoluminescence spectra of the films taken at room temperature, where the blue emission formed the dominant bands. The results of the study suggest that the growth temperature has a significant impact on the film properties and that appropriately increasing the growth temperature leads to substantial improvement in the overall quality of the β-Ga2O3 thin films.

Hygrothermomechanical loading-induced vibration study of multilayer piezoelectric nanoplates with functionally graded porous cores resting on a variable viscoelastic substrate

Harnessing vibrations in multifunctional nanostructured plates is pivotal to next-gen microsystems but necessitates understanding scale effects under multifield loading. Investigated in this work are the forced and unforced vibrations of multilayered piezoelectric nanoplates supported on a variable viscoelastic medium and loaded hygrothermo-electromechanically with functionally graded porous (FGP) cores. The viscoelastic foundation is supposed to demonstrate non-linear changes in both stiffness and damping characteristics in the x-coordinate direction. The goal is to improve the accuracy of the results by using the nonlocal strain gradient theory (NSGT) and the third-order shear deformation assumption (TSDA), which include the effects of hardening and softening materials. The FGP core layer considers four states of porosity distribution patterns. These porosity distributions are expected to change in both the in-plane and thickness directions. The governing partial differential equations resulting from Hamilton's principle can be reduced to a system of algebraic equations by applying the Galerkin method. The parametric studies evaluate the effects of several factors, such as the initial electric voltage, viscoelastic medium parameters, moisture rise, temperature changes, porosity distributions, FG index, nonlocal and strain gradient features, and boundary conditions, on the vibration response. The novelty lies in the incorporation of advanced theories, such as the NSGT and TSDT, which capture size-dependent effects and material hardening/softening phenomena. Additionally, the consideration of four distinct porosity distribution patterns in the FGP core layer provides insights into the influence of porosity gradients on the dynamic response. The proposed model can guide the design and optimization of multifunctional nanostructured plates for applications in next-generation microsystems, energy harvesting devices, and smart structures.

Molecular Packing Topology and Interactions to Decipher Mechanical Compliances in Dicyano-Distyrylbenzene Derivatives.

Flexible optoelectronics is the need of the hour as the market moves toward wearable and conformable devices. Crystalline π-conjugated materials offer high performance as active materials compared to their amorphous counterpart, but they are typically brittle. This poses a significant challenge that needs to be overcome to unfold their potential in optoelectronic devices. Unveiling the molecular packing topology and identifying interaction descriptors that can accommodate strain offers essential guiding principles for developing conjugated materials as active components in flexible optoelectronics. The molecular packing and interaction topology of eight crystal systems of dicyano-distyrylbenzene derivatives are investigated. Face-to-face π-stacks in an inclined orientation relative to the bending surface can accommodate expansion and compression with minimal molecular motion from their equilibrium positions. This configuration exhibits good compliance towards mechanical strain, while a similar structure with a criss-cross arrangement capable of distributing applied strain equally in opposite directions enhances the flexibility. Molecular arrangements that cannot reversibly undergo expansion and compression exhibit brittleness. In the isometric CT crystals, the disproportionate strength of the interactions along the bending plane and orthogonal directions makes these materials sustain a moderate bending strain. These results provide an updated explanation for the elastic bending in semiconducting π-conjugated crystals.

Numerical Study on Effect of Flow Field Configuration on Air-Breathing Proton Exchange Membrane Fuel Stacks

Air-breathing proton exchange membrane fuel cells (PEMFCs) show enormous potential in small and portable applications because of their brief construction time without the need for gas supply, humidification and cooling devices. In the current work, a 3D multiphase model of single air-breathing PEMFCs is developed by considering the contact resistance between the gas diffusion layer and bipolar plate and the anisotropic thermal conduction and electric conductive in the through-plane and in-plane directions. The 3D model presents good grid independence and agreement with the experimental polarization curve. The single PEMFC with the best open area ratio of 55% achieves the maximum peak power density of 179.3 mW cm−2. For the fuel cell stack with 10 single fuel cells, the application of the anode window flow field is beneficial to improve the stack peak power density compared to the anode serpentine flow field. The developed model is capable of providing assistance in designing high-performance air-breathing PEMFC stacks.

In-plane thermal conductivity of hexagonal boron nitride from 2D to 3D

The in-plane thermal conductivity of hexagonal boron nitride (h-BN) with varying thicknesses is a key property that affects the performance of various applications from electronics to optoelectronics. However, the transition of the thermal conductivity from two-dimensional (2D) to three-dimensional (3D) h-BN remains elusive. To answer this question, we have developed a machine learning interatomic potential within the neuroevolution potential (NEP) framework for h-BN, achieving a high accuracy akin to ab initio calculations in predicting its thermal conductivity and phonon transport from monolayer to multilayers and bulk. Utilizing molecular dynamics simulations based on the NEP, we predict the thermal conductivity of h-BN with a thickness up to ∼100 nm, demonstrating that its thermal conductivity quickly decreases from the monolayer and saturates to the bulk value above four layers. The saturation of its thermal conductivity is attributed to the little change in phonon group velocity and lifetime as the thickness increases beyond four layers. In particular, the weak thickness dependence of phonon lifetime in h-BN with a nanoscale thickness results from its extremely high phonon focusing along the in-plane direction. This research bridges the knowledge gap of phonon transport between 2D and 3D h-BN and will benefit the thermal design and performance optimization of relevant applications.

Aircraft Wing Morphing Using Auxetic Structures

Cellular materials exhibit two key properties: structures and mechanisms. This allows for the design of structures using cellular materials while effectively controlling both stiffness and flexibility, based on the connectivity of the struts. This study aims to explore the in-plane flexible properties of cellular materials dominated by bending under macroscopic deformation. Additionally, it seeks to establish a method for designing a passive morphing airfoil with flexible cellular cores. The investigation focuses on airfoils featuring re-entrant and S-shaped cellular cores, analyzing their behavior under static loads by examining the deformation of the cellular cores subjected to aerostatic loads. In the context of the airfoil's deformation with flexible cellular cores under aerostatic loading, shear emerges as the predominant deformation mode for the cores of the airfoil. Wings of conventional aircraft are optimized for only a few conditions, not for the entire flight envelope. Therefore, it is necessary to develop the morphing airfoil with smart structures for the next generation of excellent aircraft. In this project, this was made possible using, re-entrant and S-shaped auxetic structures as a member of the meta- material family, with negative Poisson's ratio to enable an effortless passive morphing mechanism as it has high flexibility along in-plane direction (chord-wise). The 3D CAD Models of Re-entrant and S-shaped auxetic airframes were designed and analyzed. Initially, Static Structural analysis is performed on both airframes to observe the structure’s behavior, and design modification and optimization are performed in different iterations. With a reduction in maximum equivalent stress by 20%, the Re-entrant airframe exhibits lower stress and hence more flexibility. The wings were modeled with a span of 1m using auxetic airframes, air pressure was generated using CFD analysis with MACH 0.45. Finally, the fluid-structure interaction was done by importing the air pressure and performing static structural analysis for the structural performance of wings using auxetic airframes. It was found that Re-entrant auxetic wing showed an increase of 9.99% in load carrying capacity, accompanied by a decrease of 389 grams of weight when compared to S-shaped auxetic wing. Considering the deformation of the airframe with flexible cellular cores under a load, the re-entrant honeycomb core shows the highest flexibility in shear and causes lower stress than the S-auxetic cores. This implies that the re-entrant honeycomb core has the potential for passive morphing.

In-situ X-ray Fluorescence Analysis of In-plane Cerium-ion Distribution Under Humidity Gradients in Proton Exchange Membrane

Cerium ions are incorporated into proton exchange membranes (PEMs) of fuel cells to mitigate its chemical degradation caused by radical species. However, under fuel cell operating conditions, cerium ions move in in-plane direction in the cell by humidity gradient. This cerium ion transport results in cerium ion depletion leading to accelerated chemical degradation. This study developed an in-situ and operando measurement technique utilizing synchrotron high-energy X-ray fluorescence spectroscopy to monitor the cerium ion transport across the membrane under the in-plane humidity gradient. This method effectively tracks the dynamic behavior of cerium ions under fuel cell operating conditions.

Formation of texture and twinning at 296 K of “Artificial” polycrystals of an equiatomic Co20Cr20Fe20Ni20Mn20 High-entropy alloy

In the present paper, “artificial” polycrystals of the equiatomic Co20Cr20Fe20Ni20Mn20 high-entropy alloy were obtained for the first time via rolling process of single crystals up to 67 % along the 1¯11 and [001] directions in the rolling plane (011) at 296 K and subsequent annealing at 1423 K for 1 h. It was shown that texture depends on the rolling direction. When rolling along the 1¯11 direction, a 〈012〉{112} texture was formed, and along the [001] direction it was the 〈123〉{111} texture. At 296 K, twinning developed after slip deformation of 30 % in “artificial” polycrystals with the 〈123〉{111} texture and was not observed in samples with the 〈012〉{112} texture.

The long and winding road that leads to homogenisation of Kresling origami

What are the geometrical and mechanical properties ruling bistability of Kresling origami metamaterials? How can we tune the magnitude of their axial-torsional coupling? Complete answers to these compelling questions cannot be found in the scientific literature, as the intertwining between bistability, axial-torsional coupling and an other significant behaviour, namely transverse dilation/contraction, remains mostly uninvestigated. This contribution aims at shedding light on this intertwining, through the use of a discrete model of Kresling origami that takes into account folding resistance. The present study is mostly computational and involves both pre- and post-critical analyses. It is based on displacement controlled tests — shearing and axial shortening/lengthening. Single-storey Kresling origami’s are first considered, preliminarly to multiple-storey tubes, where buckling is observed. Several parameters are taken into account such as the number of storeys, stretching and folding stiffnesses, and – for shearing tests – the prescribed displacement direction in the transversal plane. The ultimate goal of the paper is to provide evidence that can be useful in the construction of homogenised continuum models of Kresling origami metamaterials.

Error correction method based on dual-beam laser for curved rail profile measurement

The current method of dynamic rail profile measurement involves the installation of a line-structured light sensor at the base of the train. The accuracy of this measurement is influenced by the vertical relationship between the laser plane of the light sensor and the longitudinal direction of the rail (LDR). When a train travels in a straight line, the normal of the laser plane aligns with the LDR. However, when the train curves, the angle at which its wheels connect with the rails causes the laser plane’s normal direction to deviate from the LDR, leading to measurement errors. To address this issue, we propose a method for curved rail profile measurement using a dual-beam laser to correct these errors. This method involves generating an auxiliary 3D rail reflecting the LDR and a virtual 3D rail reflecting the normal direction of the laser plane from the cross-section image of the dual-beam laser. An optimization function is then formulated to determine the optimal auxiliary plane (optimal-AP) by analyzing the alignment or intersection between the auxiliary and virtual 3D rails. Distorted contour points are projected onto the optimal-AP to rectify errors. Experiments validate the accuracy and effectiveness of this proposed method. The results show that, regardless of pitch or yaw movement between the laser plane and the LDR, the error in measuring corrected profile wear remains consistently below 0.10 millimeters, thereby meeting the accuracy standard for rail wear measurement. This approach rectifies measurement errors in curved rail profiles from a 3D perspective, ensuring accurate measurements even under complex working conditions. It also provides a valuable reference for error analysis and improving dynamic rail profile measurement accuracy.

Investigation of crystalline and band alignment properties of NiO/GaN and Ni0.5Co0.5O/GaN heterojunctions using synchrotron radiation based techniques

Epitaxial layers of NiO and Ni0.5Co0.5O have been deposited on GaN templates using RF magnetron sputtering deposition technique. The epitaxial relationship in out-of-plane and in-plane directions for NiO and Ni0.5Co0.5O layers with respect to GaN is [111]NiO(Ni0.5Co0.5O)∥[0001]GaN and [1̅10]NiO(Ni0.5Co0.5O)∥[1̅21̅0]GaN, respectively. The epi-layers are found to have two triangular domain structures oriented along [111] direction with an in-plane rotation of 60° with respect to each other. Photoelectron spectroscopy (PES) has been used to determine the valence band offset (∆EV) and the band alignment at the heterojunctions (HJs). The ∆EV at NiO/GaN and Ni0.5Co0.5O/GaN HJs are 1.2 ± 0.2 eV and 1.8 ± 0.2 eV, respectively. The conduction band offsets (∆EC) have also been estimated using the determined values of optical band gap (NiO: Eg = ∼ 3.5 eV; Ni0.5Co0.5O: Eg = ∼ 3.3 eV) from optical transmission measurements. The values of ∆EC are found to be 1.5 ± 0.2 eV and 1.9 ± 0.2 eV at NiO/GaN and Ni0.5Co0.5O/GaN HJs, respectively. A type-II band alignment is observed at both the HJs. Higher values of valence band and conduction band offsets are observed at Ni0.5Co0.5O/GaN HJ in comparison to NiO/GaN. These experimentally determined values of band offsets can be used to design wide band gap HJ based devices like photodetectors, where higher values of band off-set at the Ni0.5Co0.5O/GaN HJ can be utilized to confine the carriers.

A metaplectic perspective of uncertainty principles in the linear canonical transform domain

We derive Heisenberg uncertainty principles for pairs of Linear Canonical Transforms of a given function, by resorting to the fact that these transforms are just metaplectic operators associated with free symplectic matrices. The results obtained synthesize and generalize previous results found in the literature, because they apply to all signals, in arbitrary dimension and any metaplectic operator (which includes Linear Canonical Transforms as particular cases). Moreover, we also obtain a generalization of the Robertson-Schrödinger uncertainty principle for Linear Canonical Transforms. We also propose a new quadratic phase-space distribution, which represents a signal along two intermediate directions in the time-frequency plane. The marginal distributions are always non-negative and permit a simple interpretation in terms of the Radon transform. We also give a geometric interpretation of this quadratic phase-space representation as a Wigner distribution obtained upon Weyl quantization on a non-standard symplectic vector space. Finally, we derive the multidimensional version of the Hardy uncertainty principle for metaplectic operators and the Paley-Wiener theorem for Linear Canonical Transforms.

Imaging the Magnetic Anisotropy in Ultrathin Fe4GeTe2 with a Nitrogen-Vacancy Magnetometer.

Two-dimensional (2D) FenGeTe2, with n = 3, 4, and 5, has been realized in experiments, showing strong magnetic anisotropy with enhanced critical temperature (Tc). The understanding of its magnetic anisotropy is crucial for the exploration of more stable 2D magnets and its spintronic applications. Here, we report a quantitative reconstruction of the magnetization magnitude and its direction in ultrathin Fe4GeTe2 using nitrogen vacancy centers. Through imaging stray magnetic fields, we identified the spin-flop transition at approximately 80 K, resulting in a change of the easy axis from the out-of-plane direction to the in-plane direction. Moreover, by analyzing the thermally activated escape behavior of the magnetization near Tc in terms of the Ginzburg-Landau model, we observed the in-plane magnetic anisotropy effect and the formation capability of magnetic domains at ∼0.4 μm2 μT-1. Our findings contribute to the quantitative understanding of the magnetic anisotropy effect in a vast range of 2D van der Waals magnets.