The application of amorphous alloys in tribology is constrained by their inherent brittleness. An alkaline treatment (AT) can address this limitation by hydrogen generated rejuvenation. Following AT in a 3 mol/L NaOH solution for 3 days, the hardness of as-cast Ti-based amorphous alloys decreased by about 10 %, while the relaxation enthalpy increased approximately 2.2 times. Concurrently, the average coefficient of friction (COF) decreased by more than 15 % under all test loads except at 10 N. Additionally, the wear rate significantly decreased by over 20 %, with a notable reduction of about 25 % under a 7 N load. The improvements in tribological properties are primarily attributed to increased plasticity and surface oxidative ability, resulting from the hydrogen absorption during chemical reactions. Thus, AT offers a practical and effective way to significantly enhance the tribological performance of amorphous alloys.
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