Improvement Of Wettability Research Articles

Effect of oxidation of End-of-Life Tire Rubber as Aggregate Substitute in Cement Mortars.

In this paper the possible use of end-of-life tire rubber as a substitute for aggregate in cement mortars was explored. The aim of this paper was to investigate the effect of rubber surface modification by acidic treatment on the final properties of mortars. In fact, through treatment with sulfuric acid at moderate concentrations, a significant improvement in rubber wettability and interaction with cement has been observed. The compressive strength of mortars containing 15%w treated rubber as a replacement of natural aggregate is comparable to those of standard mortars. This suggests that surface modification of rubber plays a very important role in the possible integration of end-of-life tire rubber in mortar and concrete. The results presented in this paper confirm that recycling in mortar and concrete is a promising way for improving rubber waste management and sustainable innovation in the construction industry.

Synergy of chelating agents and surfactants on the wettability and pore structure of coal dust: Experimental study and molecular simulation

To reduce the hazards of coal dust pollution to miner health and the environment, and to realize efficient wetting and settling of coal dust, this paper evaluates the wettability of tetrasodium glutamate diacetate (GLDA)–aliphatic alcohol polyoxyethylene ether sodium sulfate (AES), hereafter termed G–A, by selecting the surfactant through macroscopic experiments and microscopic simulations. With the help of molecular simulation to study the synergistic mechanism of the surfactants and chelating agents, the functional group changes and mesoscopic modification of coal dust particles were evaluated in combination with characterization experiments. Comprehensive analysis showed that the G-A solution had the best wettability with a low surface tension of 22.77 mN/m, the diffusion rate of the solution increased to 1.25°/s, and the contact angle with the coal dust decreased to 18° within 12 s. After infiltration, the median particle size of coal dust reached 38.140 μm, which increased by 148 %. The pores and slits on the surface of the coal dust particles are further increased, providing surfactants with more extensive adsorption sites, and the proportion of hydrophilic groups on the surface of coal increased by 8.42 %, with the consequent improvement of wettability. This study provides a theoretical basis for the research and development of more environmentally friendly and efficient dust reducing agents in the field of spray dust reduction.

Electrohydrodynamic effect within CFRP laminates by bipolar nsPDC electric field during the curing process

In this paper, a new method based on bipolar nanosecond pulsed superimposed direct current (nsPDC) electric field assisted curing technique was developed to fabricate modified fiber-reinforced composites to enhance their mechanical properties. It was found that the mode I interlaminar fracture toughness of the electric field-modified CFRP laminates reached 1014.2 MPa, which increased by 80.4 %. The average tensile strength and tensile modulus were 2180 MPa and 100780 MPa, respectively, which were 20.7 % and 3.5 % higher than the blank control group. The enhancement mechanism was explored by COMSOL simulation, curing temperature inspection, and microscopic characterization by electron microscopy. The results show that the presence of electric field and electric field force inside the laminate, which affects the flow of resin and the weak migration of fibers, enables the elimination of larger air bubbles present in the material, the reduction of resin-rich zones in the interlayer as well as the improvement of the fiber-resin wettability without significantly altering the curing temperature. The proposed simple, convenient, and environmentally friendly strategy can effectively regulate some of the deficiencies in the conventional manufacturing methods and thus is suitable for the optimal design of fiber-reinforced composites.

Recent Patents on Particle Wettability Measurement and Improvement

Background: As the coal mining industry becomes more mechanized, it leads to a large number of coal dust particles suspended in the air, polluting the surrounding environment, accompanied by an increase in fine-grained low-rank coal particles and a low recovery rate of a large amount of organic matter in the particles, wasting resources. Objective: The study of particle wettability can have an impact on spray dust reduction and particle flotation efficiency. By adjusting the hydrophilicity of coal powder particles, the generation of suspended coal dust can be effectively suppressed. By adding surfactants, the flotation separation efficiency of coal particles can be improved. Method: This article introduces the measurement method of particle wetting properties and methods to improve the wetting properties of particles, providing a reference for studying the wetting properties of particles Results: The measurement of particle wetting properties is more accurate, simple, and convenient. Improving the wetting properties of particles by adding additives has significant implications for later dust reduction and particle flotation. Conclusion: This thesis provides an important basis for studying the wettability of particles, modifying the wettability and hydrophilicity of particles, providing specific guidance for improving the wettability of particles for spray dust reduction and particle flotation, and greatly improving industrial production efficiency.

Nanotechnology-enhanced castability of wrought aluminum alloys 2024 and 6063

In the realm of high-performance applications, wrought aluminum alloys are esteemed for their high mechanical properties and excellent strength-to-weight ratio. However, their limited castability poses challenges in economically producing intricate structures through casting processes. To address this issue, a small proportion of TiC nanoparticles is introduced into the melts of AA 2024 and AA 6063 for nano-treating. This nano-treatment imparts several beneficial effects, including the delayed release of latent heat, inhibition of grain growth, and improvement of wettability. These effects enhance the fluidity of the melt, eliminate hot cracking, and elevate the surface quality of the castings. The outcomes underscore the promising potential of emerging nano-treatment technology in rendering traditionally non-castable wrought aluminum alloys suitable for cost-effective casting processes, ultimately delivering high-performance products for a wide range of applications.

Designing the regularity of biodegradable copolyester for sustainable hot-melt adhesives: Adhesion, removability, and biodegradability

Recent research has increased in eco-friendly hot-melt adhesives as alternatives to conventional commercial hot-melt adhesives. However, there have been limitations in terms of removability and biodegradability. This study addresses these issues by designing a novel molecular structure for a single polymer, resulting in a sustainable hot-melt adhesive that offers strong adhesion, clear removability, and high biodegradability without additional additives. By varying the ratio of alcohol monomers 1,4-butanediol (BD) and ethylene glycol (EG) during polymerization, we synthesized poly(butylene adipate-co-butylene terephthalate-co-ethylene adipate-co-ethylene terephthalate) (PBEAT) with four block segments. We increased the open time by reducing the regularity of the molecular structure, controlling crystallization behavior, and inhibiting polymer chain packing. This improvement in wettability with the adherend allowed us to achieve a lap shear adhesion strength of 3.18 MPa. Additionally, we proposed a debonding mechanism based on the correlation between the crystallization temperature (Tc) block copolymer's and shear adhesion failure temperature (SAFT), demonstrating the removability of the prepared hot-melt adhesive. Finally, analyses of hydrolysis, enzymatic degradation, and biodegradation in compost confirmed that reduced crystallinity enhances biodegradability. PBE30AT, exhibiting the strongest adhesion strength, achieves complete degradation in compost within 20 days, faster than neat poly(butylene adipate-co-terephthalate) (PBAT). This research offers a novel and practical approach to enhancing the potential and expandability of sustainable adhesives by tailoring the molecular structure of the polymer.

Effects of transition elements additions on interfacial properties of Al (111)/B4C (0001) interface based on first-principles study

In this study, the structural stability and adhesion performance of the Al (111)/B4C (0001) interface are explored by performing first-principles calculations, as well as the effects of the additions of the transition elements Sc, Zr, and V on the interfacial adhesion work and electron structures are further investigated. The results of interfacial structure calculations demonstrate that the B-terminated interface with FCC site stacking modality is the optimal configuration of the Al (111)/B4C (0001) interface. The results of adhesion work and electronic properties indicate that the d orbitals of Sc, Zr, and V elements are hybridized with the p orbital of B to form Sc-B, Zr-B, and V-B bonds, respectively, at the interface, which are more covalent than the Al-B bond. In particular, the hybridization between the d orbital of the V element and the p-orbital of B is more intense. Therefore, the best improvement of the interfacial wettability is obtained by the V element, in which the interfacial adhesion work is enhanced by 41.18% compared to the undoped interface. A theoretical guide to enhance the wettability and interfacial properties of the Al/B4C system by adding transition elements can be provided by our calculations.

Electron beam induced graft polymerized anti oil-fouling biaxial polypropylene membrane with harsh environment tolerance

The intrinsic hydrophobic behavior of biaxial-oriented polypropylene microporous membrane limits its broad application area by leading serious membrane fouling. An environment-friendly, practical, and facile to large-scale prepared surface modification process is designed to enhance the membrane wettability and oil-fouling. By employing electron beam radiation, acrylic acid, and polyvinyl alcohol in the pre-irradiation-induced graft polymerization process, a micro-nano structure was developed and the surface roughness was increased from 66.5 nm to 99.3 nm. Enhancing the grafting ratio further reduces the pore size of the final modified membrane from 54 nm to 25 nm, which is significantly smaller than the size of the emulsified oil droplet. By modifying the morphological and structural characteristics of the grafted membrane, excellent oil-fouling resistance features are attained with UWOCA value 161° and separation efficiency of 99.3 %. Moreover, the theoretical explanations for hydrophilicity and oil-fouling resistance of modified membranes are also developed using DFT calculations and the Hermia model, which shows alignment with experimental data. Consequently, considerable improvements in wettability, thermal and mechanical behavior are obtained by this facial surface modification approach, which could further broaden the modified membrane's applications area in membrane separation technology while lengthening its service life.

Preparation and characterization of pickering emulsions stabilized by zein/quercetin/quaternary ammonium chitosan composite nanoparticles with antibacterial effect

The role of nanoparticles in the stabilizing interface is very important in the preparation of stable Pickering emulsions. In this study, ternary composite nanoparticles (ZQ-HC) were synthesized by complexing zein-quercetin covalent complex (ZQ) with quaternary ammonium chitosan (HTCC) and subsequently stabilized Pickering emulsions (ZQ-HC) with antibacterial activity. Results revealed that HTCC covers the surface of ZQ nanoparticles successfully, which designates an effective improvement in the surface wettability of ZQ effectively. Among them, ZQ-HC2:1 possesses the closest three-phase contact angle of 90° and the highest emulsification activity and emulsion stability. The results of ultra-high resolution microscopy showed that ZQ-HC nanoparticles were adsorbed at the oil-water interface to prevent droplet aggregation and improved the pH, ionic strength, and storage stability of the prepared Pickering emulsions. ZQ-HC nanoparticles construct an antioxidant barrier at the oil-water interface, improving the lipid oxidation stability of the emulsion. The ZQ-HC2:1 stabilized Pickering emulsion exhibits the most superior stability and strongest antibacterial activity against other emulsions. The ZQ-HC stabilized Pickering emulsions prepared in this study exhibit potential for use as carriers of bioactive ingredients in food applications.

First-principle and experimental investigation into the interfacial characters of Ti-doped ZTA and high chromium cast iron

Ti doping can improve the interfacial wettability and bonding condition between ZTA ceramic and high chromium cast iron (HCCI), but the underlying mechanism is still unclear. Therefore, the effects of Ti doping on the interfacial characters between ZTA and HCCI were investigated by experiment and first-principles calculations. Results of XRD, SEM, and high-temperature drop test indicate the presence of Ti at the interface and its effect on the formation of interfacial diffusion layer to improve the interface wettability and bonding obviously. The heat of segregation and work of adhesion obtained by first-principle calculations shows that the improvement in interface wettability and bonding is due to the promotion of dopped Ti atoms on the diffusion of Fe, Al, and Zr elements, but not the diffusion of Ti itself. Further investigation from the electronic level reveals that the doped Ti changes the charge distribution and orbital hybridization, and thus makes the formation or enhancement of strong ionic bonds and covalent bonds at the interface, improving the bonding strength and wettability of interfaces in ZTA/HCCI. The findings of this research can offer new insights into the modification of ceramics and enlarge the application of advanced ceramic materials.

In situ growth of silver nanoparticles on carbon fiber by plasma–liquid interaction to improve performance of epoxy composites

Grafting nanomaterials on the carbon fiber (CF) surface is considered an effective strategy for enhancing the interfacial properties of CF-reinforced polymer composites (CFRPs). However, the mechanical properties of the CFs are often compromised during treatment. A new method for in situ growing silver nanoparticles (AgNPs) on the CF surface is proposed in this study. The CFs are first immersed in a low-viscosity silver nitrate solution to form a thin liquid film on the surface. Subsequently, using the abundant active particles in the plasma, the silver ions are reduced to silver atoms and grown into AgNPs on the CF surface. The tensile strength of CF@Ag was 38.74% greater than that of untreated CF, potentially due to the reparative action of AgNPs on defects in CF. The CF showed an evident improvement in surface wettability because of the AgNPs. Furthermore, the interfacial properties were noticeably improved, with the interfacial shear strength of CF@Ag increasing to 91.59 MPa, which was about twice that of pristine CF. Thus, the mechanical properties of composites are significantly improved (flexural strength increased by 190.74%). This study presents a non-destructive and convenient method for growing nanoparticles onto CF to establish a robust interface in CFRPs.

Effect of nano-metallic coating on the wetting of silicon by molten tin at 800 °C

The effects of different nano-metal coatings on the wettability of liquid tin on monocrystalline silicon at 800 °C were discussed, aiming at optimizing the metal bonding technology in high-density chip packaging. Nanometal coatings with different combinations, including silver (Ag), titanium (Ti) and their layered coatings (Ag + Ti), were deposited on monocrystalline silicon by magnetron sputtering, and comparative experiments were carried out. The experimental results show that the metal coating with a thickness of tens of nanometers is enough to completely change the wettability of the system. The improvement of wettability does not follow the idea of active brazing, i.e., there is no need to introduce interfacial active element titanium, and better wettability can be obtained. In the wetting of tin and monocrystalline silicon coated with Ag/Ti or Ti/Ag layered coating, the solid/liquid interface near the triple line forms “pyramid” microstructures, which play a “pinning” role on the triple line. The wettability of monocrystalline silicon coated with a single silver coating with a thickness of 80 nm cannot be significantly improved, and the final wettability is equivalent to the intrinsic wettability of the Sn/Si system (contact angle of 61.2°). When the coating thickness is 160 nm, due to the enrichment of silver at the solid/liquid interface, the locally dissolved silicon precipitates and crystallizes, so that the area of the solid/liquid interface increases, and the triple line cannot be withdrawn. The research results will provide ideas for the optimization and design of metal-substrate bonding in high-density chip packaging.

Improvement of powder properties of milk protein isolate by fluidised bed agglomeration with guar gum binder

A goal of this study was to investigate the influence of fluidised bed agglomeration process with guar gum (GG) binder (0–0.3%) on the physical and rheological properties of agglomerated milk protein isolate (MPI). Larger and more porous particles were formed by the agglomeration process, resulting in an improvement in powder flowability, wettability and solubility. The agglomerate with 0.1% GG binder exhibited higher viscoelastic properties than other agglomerates, with viscoelastic moduli values decreasing as the binder concentration increased (0.1–0.3%). The findings demonstrate that the agglomeration process with GG improved the powder characteristics of MPI and influenced its rheological properties.

Fluorinated Naphthalene Diimides as Buried Electron Transport Materials Achieve Over 23% Efficient Perovskite Solar Cells.

Naphthalene diimides (NDI) are widely serving as the skeleton to construct electron transport materials (ETMs) for optoelectronic devices. However, most of the reported NDI-based ETMs suffer from poor interfaces with the perovskite which deteriorates the carrier extraction and device stability. Here, a representative design concept for editing the peripheral groups of NDI molecules to achieve multifunctional properties is introduced. The resulting molecule 2,7-bis(2,2,3,3,4,4,4-heptafluorobutyl)benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone (NDI-C4F) incorporated with hydrophobic fluorine units contributes to the prevention of excessive molecular aggregation, the improvement of surface wettability and the formation of strong chemical coordination with perovskite precursors. All these features favor retarding the perovskite crystallization and achieving superior buried interfaces, which subsequently promote charge collection and improve the structural compatibility between perovskite and ETMs. The corresponding PSCs based on low-temperature processed NDI-C4F yield a record efficiency of 23.21%, which is the highest reported value for organic ETMs in n-i-p PSCs. More encouragingly, the unencapsulated devices with NDI-C4F demonstrate extraordinary stability by retaining over 90% of their initial PCEs after 2600 h in air. This work provides an alternative molecular strategy to engineer the buried interfaces and can trigger further development of organic ETMs toward reliable PSCs.

Improving the Interfacial Adhesion of Long Carbon Fiber-Reinforced Polyamide 6 Composites by Electrochemical Oxidation and Polyethylenimine-Carboxymethyl Cellulose Grafting.

Carbon fiber (CF)-reinforced thermoplastic composites have notable ascents in various sectors and applications. For high-performance composites, strong interfacial adhesion between the polymer matrix and the CF is crucial. This is achieved by introducing functional groups on the CF surface. In this paper, a water-based surface treatment was applied to long carbon fibers to enhance the interfacial bonding with the polyamide 6 (PA6) matrix. For that, PEI and CMC were grafted onto the surface of carbon fibers after electrochemical oxidation. The PEI-CMC sizing reduced the carbon fiber/water contact angle to 26.42° from 111.69°. The clear improvement in wettability resulted in a 164.8% increase in the interfacial strength of 26.7 MPa after the application of PEI-CMC sizing on carbon fibers (CFs). The resultant tensile and flexural strength increased by 19.3 and 11.7% from 2009.6 and 378.3 MPa for desized CF/PA6 composites to 250.3 and 422.7 MPa for PEI-CMC-sized CF/PA6 composites, respectively. Moreover, the fractured surface morphologies were also investigated to confirm the enhancement of mechanical properties. The proposed one-step electrochemical oxidation and water-based sizing procedure is found to be promising for the production of high-performance long-fiber-reinforced thermoplastic composites.

Development of a Biopolymer-Based Anti-Fog Coating with Sealing Properties for Applications in the Food Packaging Sector.

The quest for sustainable and functional food packaging materials has led researchers to explore biopolymers such as pullulan, which has emerged as a notable candidate for its excellent film-forming and anti-fogging properties. This study introduces an innovative anti-fog coating by combining pullulan with poly (acrylic acid sodium salt) to enhance the display of packaged food in high humidity environments without impairing the sealing performance of the packaging material-two critical factors in preserving food quality and consumers' acceptance. The research focused on varying the ratios of pullulan to poly (acrylic acid sodium salt) and investigating the performance of this formulation as an anti-fog coating on bioriented polypropylene (BOPP). Contact angle analysis showed a significant improvement in BOPP wettability after coating deposition, with water contact angle values ranging from ~60° to ~17° for formulations consisting only of poly (acrylic acid sodium salt) (P0) or pullulan (P100), respectively. Furthermore, seal strength evaluations demonstrated acceptable performance, with the optimal formulation (P50) achieving the highest sealing force (~2.7 N/2.5 cm) at higher temperatures (130 °C). These results highlight the exceptional potential of a pullulan-based coating as an alternative to conventional packaging materials, significantly enhancing anti-fogging performance.

Enhancing surface morphology, mechanical, and wettability properties of PVA/chitosan/HAp nanofiber scaffold through dielectric barrier discharge plasma treatment

Dielectric barrier discharge (DBD) plasma treatment has been widely used for surface functionalization, allowing for precise modification of surface chemistry and morphology. This study investigates the efficacy of DBD plasma treatment in enhancing the surface morphology and wettability of electrospun nanofiber scaffolds composed of polyvinyl alcohol (PVA), chitosan, and hydroxyapatite (HAp), with potential applications in bone tissue engineering. Scanning electron microscopy (SEM) revealed significant alterations in surface morphology after treatment, including a reduction in average fiber diameter and the presence of uneven, damaged, and even broken fibers. Interestingly, the ultimate strength of the nanofibers increased from 1.13 ± 0.05 MPa to 6.99 ± 0.07 MPa despite the decrease in diameter. Contact angle measurements confirmed a remarkable improvement in wettability, with the contact angle decreasing from 39.46° to 7.45° following increasing treatment time. This enhanced wettability suggests improved cell adhesion, potentially leading to more effective bone tissue regeneration.

Soil wettability improvement by plane leaves (Platanus orientalis) biochar in silty clay soil using saline water

Soil wettability improvement by plane leaves (Platanus orientalis) biochar in silty clay soil using saline water

Experimental and simulation studies on the improvement of coal dust pollution by an aqueous solution of sodium α-alkenylsulfonate and amino acid-based surfactants

The use of surfactants is crucial for the prevention and control of coal dust pollution in coal mining operation areas, yet there still exist many challenges in the control of coal dust pollution. In this paper, the green biomass-based amino acid surfactant sodium myristoyl glutamate (SMG) and the anionic surfactant sodium α-alkenyl sulfonate (AOS) were selected to investigate the improvement of coal dust wettability by single and binary solutions from the macroscopic and microscopic perspectives. Molecular simulations were used to reveal the microscopic mechanism of the wettability of coal dust by the different solutions. Experimental measurements showed that the contact angle of the AOS + SMG aqueous solution was as low as 13.8° on a coal surface. Coating the coal dust with the AOS + SMG solution reduced the surface tension by 12.02% compared to coating the coal with a single component solution. Additionally, the use of the binary AOS + SMG solution increased the hydrophilic group content in the coating by 11.77% compared to a single component solution, and the linkage between hydrophilic groups was enhanced, which pulls the water molecules to wet the coal dust. These research results should provide a new way to promote more environmentally friendly coal dust pollution control technology.

Enhancing CFRP laminates with plasma jet arrays: A study of interlaminar mechanical properties

AbstractThis study delves into the efficacy of plasma jet array treatment in bolstering the interlaminar toughness of Carbon Fiber Reinforced Polymer (CFRP) prepregs, a crucial parameter for their deployment in high‐performance domains. Employing high‐frequency pulsed microsecond plasma jet arrays for surface modification, this research not only demonstrated a 19.49% upsurge in peak load capacity but also a remarkable 29.94% enhancement in Mode I interlaminar fracture toughness, as evident from Double Cantilever Beam (DCB) tests. Furthermore, the surface wettability improvements were underscored by a substantial decrease in water contact angle from 108.33° to 31.45° and a total surface energy augmentation from 12.20 to 64.16 mN/m, post a 1‐min plasma treatment. X‐ray Photoelectron Spectroscopy (XPS) results indicated an appreciable rise in oxygen functionalities, suggesting enhanced resin‐fiber bonding. Additionally, Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM) analyses revealed notable decreases in surface roughness and microscale defects, contributing to smoother surfaces conducive to better adhesive bonding and reduced manufacturing defects. These multifaceted improvements, stemming from alterations in surface chemistry and topography, underpin the significant potential of plasma treatment in advancing CFRP laminate applications requiring superior durability and mechanical resilience.Highlights A plasma jet arrays method to enhance CFRP's interlaminar properties was studied. The influence mechanism of plasma modification was revealed in detail. The interlayer toughening mechanism of CFRP after plasma modification is proposed.