Impregnation Of Carbon Research Articles

Adsorption of cadmium from wastewater with activated carbons derived from pig fur biowaste: A comparative study of in-situ and ex-situ activation routes

The environmental challenges associated with cadmium contamination in wastewater have necessitated the development of high-performing activated carbons (ACs) for effective wastewater treatment. Adsorption capacity depends on both the surface area and the adsorption-active functional groups developed on the adsorbent's surface during activation. Proper manipulation of key process variables using the appropriate activation route produces highly efficient and economically viable ACs. This research investigates the viability of pig fur biowaste as a novel precursor for activated carbons using two distinct activation methods—in-situ and ex-situ. Using a central composite design (CCD) of the Response Surface Methodology (RSM), the study systematically examines the effects of impregnation ratio, carbonization temperature, and carbonization time on the cadmium adsorption capacities of the resulting ACs. The optimal conditions for in-situ activation were found to be 691 °C, 175.11 min, and an impregnation ratio of 1.784 g/g, resulting in a cadmium adsorption capacity of 91.57 %. For ex-situ activation, the optimal conditions were 468.8 °C, 80.81 min, and an impregnation ratio of 2.915 g/g, which achieved a higher cadmium adsorption capacity of 91.21 %. Both types of activated carbons maintained high efficiency after five regeneration cycles, indicating they are suitable for long-term applications requiring repeated regeneration. Although both methods produced ACs with comparable cadmium removal efficiency, the ex-situ activation route proved to be more economically viable due to its lower temperature and shorter processing time. This study demonstrates the potential of pig fur biowaste as a sustainable and underutilized resource for AC production and highlights the ex-situ activation route as the more cost-effective approach for producing high-performance adsorbents.

Characterization and Adsorption Capacity Evaluation of ZnCl2 Impregnated Cassava Peel Carbon for Removal of Fe, Ca, Mg and Zn ions in Wastewater from Cassava processing Industry

The objective of this paper was to prepare, characterize and evaluate the adsorption capacity of cassava peel carbon (CPC) impregnation with ZnCl2 salt for the removal of Fe, Ca, Mg and Zn ions in wastewater derived from cassava processing which has been noted to be problematic in terms of management. CPC and cassava peel activated carbon (CPAC) at 1:3, 2:3, and 1:1 impregnation levels were placed in fixed bed adsorption columns to determine metal ion adsorption capacities of the carbon materials after 120, 240, 360 and 480-minute contact times. Langmuir and Freundlich isotherm models were used in assessment of adsorption of the carbon materials, while pseudo-first and second order models were used to validate the adsorption kinetics of Fe, Ca, Mg and Zn. Pore space development was also monitored using scanning electron microscope (SEM) imagery. Results SEM images revealed hexagonal honeycomb surface structure at 2:3 impregnation level and spongy configuration at 1:1 ZnCl2 impregnation level. The correlation coefficient of Langmuir isotherm was observed to be between 0.86 to 1, indicating that the adsorbent is very good in adsorption of the metals, however, Freundlich isotherm is found to be unfavorable in describing CPAC’s capacity in adsorbing zinc ion contaminant. The pH of the carbon materials was observed to have increased while the bulk density reduced with increasing level of impregnation. Conclusively, CPC and CPAC materials are well suited to Langmuir isotherm as well as pseudo-second order model, implying that adsorption occurs well in a monolayer form on the surface material surface.

Cd2+ removal efficiency of activated carbon from Prosopis juliflora: Optimization of preparation parameters by the Box-Behnken Design of Response Surface Methodology

The study focuses on the preparation of activated carbon from Prosopis juliflora (PJAC) wood by pyrolysis and chemical activation. The objective is to assess its effectiveness as an adsorbent for synthesizing a composite adsorbent coating (CAC) for Cadmium (Cd2+) removal from aqueous solution. The effect of preparation factors related to Cd2+ removal efficiency was assessed. The Design of Experiments (DoE) for the adsorption of Cd2+ on the PJAC were done using the Box-Behnken Design (BBD) of the Response Surface Methodology (RSM) (Design Expert software version 11). The influence of impregnation ratio (IR), carbonization time (t), and carbonization temperature (T) on the Cd (II) percent (%) removal was evaluated. The response surface graphs in 3D were also generated for the response variable, and the higher R2 coefficient values were fitted into the polynomial quadric model. The results indicated that all the variable preparation factors were significant in the Cd2+ removal by PJAC with carbonization temperature being the most significant. At the optimum conditions i.e. impregnation ratio (1.8), carbonization temperature (595 °C) and carbonization time (174 min), the model predicted a 99.9 % Cd2+ removal efficiency while the adsorption experiment obtained a 96.7 % removal efficiency, respectively. Later, the morphological and chemical properties of the PJAC prepared with optimal parameters were analyzed using different characterization techniques including SBET, SEM-EDX, pHPZC, FTIR and XRD. The SEM images revealed a rough and porous morphological surface with an SBET of 600.4 m2/g and a near neutral pHPZC of 6.92. The XRD pattern indicated the crystalline nature of the prepared adsorbent. The pre and post adsorption FTIR spectrum of the PJAC demonstrated a distinct difference with the latter showing a reduction in peak intensity and height. These results underpin the potential of utilizing invasive plants like Prosopis Juliflora as adsorbents for heavy metal removal.

1 nm Tin Oxide Cluster for the Electrochemical Conversion of Carbon Dioxide to Formate at Low Overpotential

Due to its cost-effectiveness and high product selectivity, tin oxide has been regarded as a promising catalyst for the electrochemical conversion of CO2 to formate. However, formate production is hindered by the high overpotential; there is a need to reduce the overpotential to enhance energy efficiency and lower electricity cost for the implementation of carbon utilization technology. Here, we report a facile synthesis method for 1 nm-sized SnO2 cluster catalysts, which can be used for CO2-to-formate conversion. SnO2 clusters were prepared through impregnation of porous carbon with a tin precursor solution. The SnO2 clusters showed a low overpotential, generating a current density of 10 mA cm-2 at a potential of -0.34 V vs. RHE in 1 M KOH. They also achieved high Faradaic efficiencies of 90.5% and 81.5% at 200 and 300 mA cm−2, respectively. Their electrocatalytic performance was strongly dependent on the annealing conditions, which affected the particle size, electrochemical active surface area, and metal oxidation state. This paper presents a versatile method for synthesizing metal oxide cluster catalysts, apart from providing insights into the catalytic activity for the electrochemical conversion of CO2 to formate.

Tannin Industry Waste-Derived Porous Carbon: An Effective Adsorbent from Black Wattle Bark for Organic Pollutant Removal

In Brazil, a significant part of the biomass is unused, contributing to environmental pollution. The tannin industry commonly extracts tannins from the bark of Acacia mearnsii or black wattle, leaving a significant residue of 70% (w w−1). This study investigates the conversion of black wattle bark into a porous carbonaceous material to efficiently remove organic pollutants. Using ZnCl2 as a chemical activation reagent, the experiments varied the impregnation time, carbonization rates, and temperatures. Additional experiments aimed to increase the specific surface area (SSA). X-ray diffraction (XRD) analysis showed the formation and removal of ZnO, which increased porosity. Scanning electron microscopy (SEM) showed an irregular morphology with pores. Fourier-transform infrared (FTIR) spectroscopy indicated characteristic bands, and electron paramagnetic resonance (EPR) detected organic free radicals. The SSAs exceeded 1000 m2 g−1, averaging 1360 m2 g−1, with a maximum of 1525 m2 g−1. Micropores (1.4 nm) were consistent. The structure of the material and the high SSA suggest a potential for efficient removal of aromatic impurities by π–π interactions. This approach addresses the issue of biomass waste, provides a solution for environmental remediation, and represents a transformative strategy for biomass utilization.

First record of Colpodidium caudatum (Ciliophora, Colpodidiidae) in Europe

The present study documents the discovery of the first European population of Colpodidium caudatum (Ciliophora, Colpodidiidae) in a water drain in a school playground in Manzanares (Ciudad Real, Spain). This species has been documented on every continent except Antarctica and Europe, until now. The ciliate was isolated from wet run-off soil collected from the water drain and was grown in semi-permanent cultures in the laboratory. The infraciliature of the ciliate was revealed using silver carbonate impregnation and cell measurements were taken from living and silver-impregnated specimens. A comparative analysis of published data from various populations of C. caudatum across the globe showed high intraspecific morphological variability in this species. To differentiate between species within the Colpodidium genus, a dichotomous key is presented. This investigation shows that C. caudatum is a ciliate that is found all over the world and is particularly associated with terrestrial habitats that are periodically flooded.

Preparation and property modulation of three-dimensional bicontinuous graphite/aluminum alloy composites

In this paper, porous graphite skeletons were rapidly prepared using selective laser sintering (SLS) molding technique. After several vacuum impregnation reinforcements, carbonization, graphitization and surface modification, the porous graphite skeleton has good compressive strength and thermal-physical properties. A356 aluminum alloy was compounded with porous graphite skeleton by vacuum extrusion casting method to obtain three-dimensional bicontinuous graphite/aluminum alloy composites. The effects of vacuum impregnation reinforcement on the comprehensive properties of the porous graphite skeleton were investigated, and the bending strength, thermal conductivity (TC) and coefficient of thermal expansion (CTE) of the three-dimensional bicontinuous graphite/aluminum alloy composites were regulated by changing the volume fraction of the porous graphite skeleton. In the composites, the porous graphite skeleton bonded well with the aluminum alloy interface. The various properties of the composites showed significant anisotropy of each by the influence of the porous graphite skeleton. When the volume fraction of porous graphite skeleton is 55 %, the bending strength of three-dimensional bicontinuous graphite/aluminum alloy composite reaches 75.8 MPa, TC reaches 116.84 W/m K, and CTE reaches 6.11 × 10-6 K−1, which is expected to be a potential thermal management material.

Non-solvent displacement nonaqueous precipitation method for core-shell materials preparation: Synthesis of C@ZrSiO4 black pigment

A novel non-solvent displacement-nonaqueous precipitation method was developed for the preparation of core-shell materials by considering C@ZrSiO4 black pigments synthesis as the case. The effects of the impregnation time, precursor concentration, and carbon content on the synthesis and coloration of the C@ZrSiO4 pigment and the mechanism of this method were investigated via X-ray diffraction, transmission electron microscopy, field-emission scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and CIELAB colorimetry. The results showed that the optimal impregnation time, precursor concentration, and carbon content were 24 h, 1.5 mol/L, and 9 wt%, respectively. C@ZrSiO4-encapsulated pigments prepared by a non-solvent displacement-nonaqueous precipitation method have a uniform and dense shell-encapsulated zircon layer with a thickness of 10–20 nm. The size of C@ZrSiO4 encapsulated pigments was 50–210 nm, without particle agglomeration. This uniform and dense encapsulation facilitated an excellent color-rendering effect in the high-temperature glaze, and the chromaticity values of the glaze were L* = 35.05, a* = 0.34, and b* = 1.08. The alkyl halide elimination non-hydrolytic heterocondensation reaction ensured the formation of a uniform precipitate along the surface of the carbon particles with Si–O–Zr bonds as the skeleton. The introduction of the non-solvent kerosene ensured the complete, uniform, and dense progress of the precipitation process to form a C@ZrSiO4 pigment with a high-quality core-shell structure. The non-solvent displacement-nonaqueous precipitation method might be an extremely promising method for preparing core-shell structural materials.

Potassium carbonate impregnation and torrefaction of wood block for thermal properties improvement: Prediction of torrefaction performance using artificial neural network

Catalytic torrefaction using potassium carbonate (K2CO3) impregnation is a pretreatment method demonstrated to catalyze wood powder's thermal degradation for energy use. In this study, beech wood boards were impregnated with K2CO3, with the aim to scale up from the studies on wood powder found in the literature. The beech boards were impregnated with five different concentrations and torrefied at 300°C for four durations (5–60 min). The impregnation procedure was successful with a linear increase of K content in wood from 0.103 wt% for raw to 0.207 wt% for the 0.012 M sample. The weight loss during torrefaction increased with the increasing potassium (K) content in wood, reaching a maximum increase of 27.17% between 0.012 M and washed (no K2CO3) after 30 min. For the longest duration, the extent of the catalytic action of K decreased, similar to what is observed in wood powder. After 60 min torrefaction, potassium increased the torrefaction severity index by up to 10% and the higher heating value (HHV) by up to 55%. Potassium efficiently increased the fixed carbon and decreased the volatile matter to values comparable to coal by catalyzing the devolatilization during torrefaction. The atomic H/C and O/C ratios shifted to similar ratios as coal. The energy yield (EY) was above 80% for the shorter durations but dropped drastically at 30 and 60 min torrefaction. The prediction of the solid yield (SY), energy yield (EY), and enhancement factor of the HHV (EF) through an artificial neural network was robust with a fit quality R2≥0.999. The proposed method for catalytic torrefaction on wood boards was efficient and could be used prior to grinding and transportation for bioenergy production. This process could decrease the production costs of biomass fuel to compete with fossil fuels.

The effect of heat-treatment temperature (HTT) on the carbon matrix development of both polyarylacetylene-and phenolic-derived carbon–Carbon (C/C) composites

Phenolic resins have been successfully used in the manufacture of C/C Composite hardware. However, they require costly, multiple impregnation–carbonization cycles due to their low char yield. Polyarylacetylene (PAA) resin is a promising alternative carbon precursor that possesses numerous advantages due to its higher char yield and low mass loss. In addition, both thermoset-derived carbons are non-graphitizable and rely on stress graphitization for matrix development, which ultimately dictates composite mechanical performance. The stress graphitization behavior of both composite systems was investigated and related to their mechanical behavior. PAA and phenolic-derived/T50 C/C composites were processed to a series of heat-treatment temperatures (HTTs), (1100°, 1800°, 2800°C) and compared. Increases in localized graphitization as verified by image analysis, AFM, and Raman were observed with increasing HT for both systems, though notably to a much higher degree for the phenolic system. We believe this to be a result of the larger degree of matrix pyrolysis shrinkage experienced at the fiber-matrix interface promoting molecular alignment. The mechanical properties of both composites were strongly affected by the HTT, primarily due to a weakening of the fiber-matrix interface. However, the phenolic-derived composite exhibited a 40% greater increase in fiber strength utilization over the PAA-derived composites after 2800°C, which is attributed to this highly oriented microstructure which contributes favorably to intra-matrix failure and crack deflection. Although there are benefits in utilizing high char yield carbon precursors that reduce manufacturing timelines, one must also account for possible differences in microstructure development when designing these composites for next generation systems.

Additive manufacturing of continuous carbon fiber–reinforced silicon carbide ceramic composites

AbstractA material extrusion (MEX) technology has been developed for the additive manufacturing of continuous carbon fiber–reinforced silicon carbide ceramic (Cf/SiC) composites. By comparing and analyzing the rheological properties of the slurries with different compositions, a slurry with a high solid loading of 48.1 vol% and high viscosity was proposed. Furthermore, several complex structures of Cf/SiC ceramic composites were printed by this MEX additive manufacturing technique. Phenolic resin impregnation–carbonization process reduces the apparent porosity of the green body and protects the Cf. Finally, the reactive melting infiltration (RMI) process was used to prepare samples with different Cf contents from 0 to 2 K (a bundle of carbon fibers consisting of 1000 fibers). Samples with Cf content of 1 K show the highest bending strength (161.6 ± 10.5 MPa) and fracture toughness (3.72 ± 0.11 MPa·m1/2) while the thermal conductivity of the samples with the Cf content of 1 K reached 11.0 W/(m·K). This study provides a strategy to prepare Cf/SiC composites via MEX additive manufacturing and RMI.

Partially carbonized wastepaper with excellent mechanical strength for oil-water and emulsion separation

BackgroundTaking the treatment of oily sewage and the recycling of wastepaper as the starting point, the idea of using waste to treat waste was used to treat the swage with aerogels made of wastepaper. MethodsPorous ultralight Fe-functionalized cellulose carbon aerogels (CPFe) were synthesized using wastepaper as raw material through FeCl3 impregnation and low-temperature carbonization. FindingsCPFe aerogels exhibit excellent physicochemical properties, such as: low density (0.0284 g/cm3), high porosity (97.32%), and selective absorption capacity for various oil products. The absorption capacity of chloroform reached 62.8 g/g. In addition, it exhibits excellent capacity in emulsion separation for both o/w and w/o types. Droplet size of w/o emulsion reduced by two orders of magnitude. CPFe aerogel is a low-cost, renewable, environmentally friendly material and suitable for large-scale production. It is expected to have broad applications in pollution remediation.

Mechanical Properties and Density Profile of Ceramics Manufactured from a Board Mixed with Sawdust and Mandarin Peels

In this study, the boards were manufactured according to the mandarin peels addition rate using sawdust and mandarin orange peel. After that, the mechanical properties and density profile of ceramics prepared by conditions through resin impregnation process and carbonization process were investigated. The bending and compression strengths of ceramics tended to increase as the resin impregnation rate increased. When the resin impregnation rate was 70%, the highest values were 8.58 MPa and 14.77 MPa, respectively. Also, the mechanical properties of ceramics according to carbonization temperature showed the highest values at 1,200°C for bending strength of 11.09 MPa and compression strength of 17.20 MPa. The bending strength and compression strength according to the mandarin peels addition rate showed the highest values at 8.62 MPa and 14.16 MPa, respectively, when the mandarin orange peel addition rate was 5%. The mechanical properties tended to decrease when the addition rate of mandarin orange was increased. The density profile of ceramics showed a similar tendency to the mechanical properties. It can be seen that the density distribution from the surface layer to the center layer is more uniform as the resin impregnation rate and carbonization temperature increase and the mandarin peels addition rate decreases.

Improving the Efficiency and Quality of the Impregnation of a Porous Carbon–Graphite Material with the Aluminum Melt by Galvanic Modification of Its Surface

Improving the Efficiency and Quality of the Impregnation of a Porous Carbon–Graphite Material with the Aluminum Melt by Galvanic Modification of Its Surface

Assessment of physical properties and antimicrobial activity of activated charcoal impregnated with silver nanoparticles against Escherichia coli

Activated charcoal possesses small pores that help in the increment of the surface area available for chemical reactions. In this study, coal samples were taken from Kalimati, Dharan, and Eastern Nepal with the goal of determining the antibacterial activity of activated charcoal against Escherichia coli. This study also measured the moisture content, volatile substances, fixed carbon, and pH of coal using proximate analysis. This study was carried out by the activated carbon impregnation with silver nanoparticles by varying with the different AgNO3 concentrations: a) 0.1 mol/liter (mol/L) b) 1 mol/L c) 1.5 mol/L one at a time. By the proximate analysis, it was found that the moisture content was 2.2%, the volatile matter was 15%, the fixed carbon was 53.8%, and the pH was 5.83. The antimicrobial activity was performed by agar well diffusion methods. With 25 mg nanoparticles the zone of inhibition against E. coli was found to be 7 mm, 8 mm and 10 mm respectively and with 50 mg nanoparticles the zone of inhibition against E. coli was found to be 9 mm, 9 mm and 12 mm with concentration 0.1 mol/L, 1 mol/L and 1.5 mol/L of AgNO3 respectively. According to Pearson correlation (r = 0.697) and a simple linear regression (R2 = 0.798), there was a positive relationship between the concentration of AgNO3 and the zone of inhibition observed against E. coli. The highest zone of inhibition (ZOI) of activated charcoal impregnation against E. coli was 12 mm at 1.5 mol/L of AgNO3 with 50 mg silver nanoparticles, which was comparatively less against seven standard antibiotics (13-29 mm ZOI).

Copyrolysis of microalga Chlorella sp. and alkali lignin with potassium carbonate impregnation for synergistic Bisphenol A plasticizer adsorption

Composite functional materials offer promising opportunities for the development of tailored adsorbents with enhanced bioremediation potential towards toxic, carcinogenic endocrine disrupters such as Bisphenol A (BPA). Copyrolysis of microalga Chlorella sp. (CH) alkali lignin (L) with K2CO3 impregnation yielded a carbon-based composite (CHL-AC) with a micro–mesoporous structure of 0.643 cm3/g, surface area of 1414 m2/g, and BPA adsorption capacity of Qmax 316.858 mg/g. Enhanced BPA removal efficiency indicated a positive synergistic effect upon a combination of L and CH, resulting in a 73.24 % removal efficiency compared with the individual carbon components of 52.33 % for L-AC and 67.35 % for CH-AC. The kinetics and equilibrium results were described well by the pseudo second-order kinetic model and Freundlich isotherm, respectively. This paper elucidates the blending of microalgae and lignin into high-value carbon composite material, CHL-AC, with immense potential for the treatment of BPA-contaminated waters to contribute to Goal 6 (clean water and sanitation).

A High-Efficiency Technology for Manufacturing Aircraft Carbon Brake Discs with Stable Friction Performance

A binary C/C brake disc (i.e., the test brake disc) was prepared with a C/C (pyrolytic carbon/resin carbon) matrix using modified natural gas as the carbon source through the isothermal chemical vapor infiltration (ICVI) process with a directed flow and the pressure impregnation carbonization (PIC) process with liquid-phase furfural acetone resin. The microstructural, mechanical, thermal, friction and wear properties of the test brake disc were comprehensively analyzed and compared with commercial ones. The results showed that the production efficiency of the test brake disc was 36% higher than that of the commercial ones, which were manufactured through a thermal-gradient chemical vapor infiltration (TCVI) process. The favorable mechanical and thermal properties of the test brake disc were comparable to the commercial ones. While the test brake disc had a more consistently rough laminar microstructure on the worn surface of the brake disc than the commercial ones, this avoided the annular grinding grooves on the worn surface after the braking tests. In addition, the test brake disc had a stable friction coefficient with a low dispersion coefficient of 3.90%, which would improve the friction stability of C/C brake discs used in aircrafts.

Removal of Chromium(VI) by Nanoscale Zero-Valent Iron Supported on Melamine Carbon Foam.

The overuse of chromium (Cr) has significantly negatively impacted human life and environmental sustainability. Recently, the employment of nano zero-valent iron (nZVI) for Cr(VI) removal is becoming an emerging approach. In this study, carbonized melamine foam-supported nZVI composites, prepared by a simple impregnation–carbonization–reduction method, were assessed for efficient Cr(VI) removal. The prepared composites were characterized by XPS, SEM, TEM, BET and XRD. Batch experiments at different conditions revealed that the amount of iron added, the temperature of carbonization and the initial Cr(VI) concentration were critical factors. Fe@MF-12.5-800 exhibited the highest removal efficiency of 99% Cr(VI) (10 mg/L) at neutral pH among the carbonized melamine foam-supported nZVI composites. Its iron particles were effectively soldered onto the carbonaceous surfaces within the pore networks. Moreover, Fe@MF-12.5-800 demonstrated remarkable stability (60%, 7 days) in an open environment compared with nZVI particles.

High performance carbon–carbon composites obtained by a two-step process from phthalonitrile matrix composites

Carbon–carbon composites (C/C) were produced from carbon fiber reinforced phthalonitrile (CFRP) matrix composites in a two-step impregnation–carbonization procedure. After graphitization at 1800 °C, the obtained C/C composites demonstrated highly crystalline structure and properties characteristic of composites derived from phenolic matrix CFRP by the industrial procedure: d = 1.73 g cm−3, interlaminar shear strength was 14.1 MPa, compression strength was 139.8 MPa, and coefficient of friction was in the range 0.32–0.34.

High-efficiency capture of ammonia using hierarchically porous Zr-MOF nanoarchitectures under ambient conditions: Thermodynamics, kinetics, and mechanisms

Zirconium-based metal–organic frameworks (Zr-MOFs) have emerged as a promising candidate for efficiently eliminating toxic chemicals under ambient conditions. Herein, we demonstrate the remarkable ammonia capture capabilities of the hierarchically porous MOF-808 xerogel (G808) macrostructure and its amino-functionalized analogue (G808-NH2), which were constructed through a sol–gel-based strategy combined with convenient ambient pressure drying. Static isotherm measurements and dynamic breakthrough tests using engineered Zr-MOF xerogel granules were conducted to illuminate the thermodynamic and kinetic characteristics for ammonia sorption. The G808 and G808-NH2 xerogels manifest substantially higher ammonia uptake, intensified interfacial interactions, and enhanced irreversible retention toward ammonia compared with the state-of-the-art activated carbon-based materials, particularly at the low-concentration region. Moreover, these hierarchical Zr-MOF nanoarchitectures exhibit extraordinary ammonia removal performance as well as excellent environmental robustness under simulated respirator canister/protection filter circumstances, with the breakthrough capacities of G808-NH2 being individually more than two and one orders of magnitude greater than those for the pristine and metal-amine impregnated carbons. The kinetic ammonia adsorption behaviors can be well delineated by the pseudo-first-order Wheeler-Jonas model. An in-depth discussion on the ammonia sorption regime, detailing five binding patterns besides reversible physisorption with a special focus on the impacts of polar amino groups and humidity, was proposed based on multiple characterizations and Grand Canonical Monte Carlo simulation.