The operation of building-integrated photovoltaic (BIPV) systems gives rise to a significant proportion of the solar radiation absorbed by the cells being unable to be converted into electricity. This phenomenon consequently increases the temperature. This temperature increase impacts the cells' electrical efficiency, leading to a reduction in their performance and accelerating their degradation. The combination of phase-change materials with insulating fluid blades, situated behind photovoltaic cells, represents a passive cooling solution that optimizes the performance of hybrid photovoltaic systems when incorporated into facades. The present study assesses a system that incorporates paraffin as a PCM and an argon layer in a PV-PCM-argon layer physical model (PVT/ArPCM), in comparison with a PV-PCM system (PVT/PCM), to enhance the thermoelectric performance of photovoltaic systems mounted on façades while ensuring optimal thermal comfort within buildings. The discrete heat transfer equations were solved using the Thomas algorithm and the iterative Gauss-Seidel method in conjunction with the implicit finite difference method. The findings illustrate that the electrical efficiency experienced only a slight increase, estimated at 0.01%, while there was a notable enhancement in the indoor thermal comfort experienced by occupants, with a 65% improvement observed due to the incorporation of an argon-filled thermal screen. The incorporation of an argon layer led to a minor reduction in temperature of 0.01°C in the photovoltaic cells, resulting in a minimal improvement of 0.014% in electrical power production. The phase-changing material incorporated into PVT/ArPCM demonstrated superior thermal management capabilities in comparison to the same material employed in PVT/PCM.