The deformation characteristics of WC–Co cemented carbide composites, with emphasis on the binder phase, were investigated. The binder, which is present mainly in the fcc modification in the as-sintered condition, was found to deform through the formation of hcp lamellae. This initially gives the binder the ability to deform in full compatibility with the carbide skeleton. Ultimately the partially transformed binder is unable to fulfil the compatibility requirements and loses its ability to impede crack propagation. Simultaneously the carbide skeleton, which deforms plastically by a glide mechanismin each WC grain, starts to break up and fracture of the composite occurs.
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