The state of atmospheric pollution is determined by the growth of the population, the amount of transport and the generated volumes of emissions. The object is the process of analyzing passenger transportation in the city. The subject is passenger transport analysis methods. Purpose: analysis of passenger transportation and approaches to optimization of public transport based on the concept of a smart city. Tasks: analysis of passenger transportation, classification of existing conceptual approaches to optimization of public transport with low carbon emissions, systematization of existing methods, means and types of neural networks in smart cities, analysis of successful implementation projects. Methods of statistical analysis, linear and non-linear interpolation, logical generalization, comparison, grouping, analysis and synthesis. Results: the analysis of passenger transportation in the city revealed that statistical data sets indicate a decrease in the main indicators of passenger traffic and an increase in the volume of emissions of carbon-containing compounds. The classification of existing approaches to the optimization of public transport is carried out according to the priority of public transport, hybridization and electrification of vehicles and the implementation of IT monitoring. During the systematization of methods and means in smart cities, the following are highlighted: smart transport systems; electric vehicles; transport sharing networks; smart applications and information systems; innovative payment systems; unmanned vehicles; information boards and announcement systems; networks of bicycle paths and equipped sidewalks; environmental monitoring systems. Among neural networks, recurrent, convolutional, and deep neural networks have been proposed as those that contribute to route optimization and traffic prediction. Conclusions: the statistical analysis of passenger transportation established that reducing carbon dioxide emissions is an unresolved task for both public transport and the transportation system. It is proposed to include methods and means that optimize public transport, reducing the carbon footprint of the initiatives of implementing the concept of a smart city, which are successful all over the world. It is proposed to use recurrent, convolutional and deep neural networks to optimize passenger transportation in smart cities.