Impact Flash Research Articles

N-Benzylidene-2-nitrobenzenesulfenamide and 1-Nitro-2-(phenylthio)benzene: Comparison of Their Behavior on Flash Vacuum Pyrolysis and Under Electron Impact

The molecular ion of N-benzylidene-2-nitrobenzenesulfenamide (1) loses SO2 and N2 and gives a base peak at m/z 165, C13H9, and another abundant peak at m/z 166, C13H10. Analysis, by gas chromatography/mass spectrometry and by preparative thin-layer chromatography, of the products of flash vacuum pyrolysis at 500-800°C of (1) showed no detectable hydrocarbon, but dibenzothiophen (mol. wt 184) was isolated and identified. The abundance of m/z 184 in the positive-ion mass spectrum of (1) is about 1%. In the mass spectrum of 1-nitro-2-( phenylthio )benzene (2a) the base peak is at m/z 167, C12H9N, and there is a fragment ion at m/z 184, C12H8S (35%). However, carbazole (3) could not be isolated from the flash vacuum pyrolysis products, but dibenzothiophen (4) was obtained in increasing yield as the pyrolysis temperature was raised from 500 to 800°C. It is clear from these results that drawing analogies between electron impact mass spectra and flash vacuum pyrolysis results is somewhat hazardous.

Analysis of the hypervelocity impact process from impact flash measurements

Hypervelocity microparticle impact experiments were performed with a 2 MV Van De Graaff dust accelerator. From measurements of the light intensity I and the total light energy E, the relations I= c 1 mv 4.1 and E= c 2 mv 3.2 were obtained, where m is the projectile mass, ν the projectile velocity and c 1, c 2 are constants, depending on projectile and target material. Using the measured values of the spectral distribution of the light emitted during impact, the temperature of the radiating material was estimated to be between 2500 and 5000 K depending on the projectile velocity. From an analysis of these measurements the angular distribution of secondary particle velocities as well as the relative mass distribution of these particles was determined. Approximately 90% of the detected ejecta mass ( ν≳1 km/sec) is found between 50° and 70° ejection angle. For ejection angles smaller than 20°, ejecta velocities of up to 30 km/sec were detected when the primary particle velocity was 4.8 km/sec. Using the dependence of the light intensity on pressure in the target chamber, an estimate of the total amount of material vaporized during impact could be derived. It was concluded that at 7.4 km/sec particle impact velocity at least 1.6% of the displaced projectile and crater material was vaporized.

Measurements of the light flash produced by high velocity particle impact

The impact light flash produced by electrostatically accelerated iron particles with diameters meters ranging from 5 to 0.05 μm and velocities lying between 1 km/sec and 30 km/sec has been investigated by means of photomultipliers. As target materials mainly gold and tungsten were used. The pulse of the multiplier was registered directly and after electronic integration. The pulse height of the multiplier signal, the amplitude of the integrated signal as well as its rise time were found to be unique functions of the mass and velocity of the impacting particle. For the pulse height of the differential signal the relation I = c 1 × m 1.25 × v 5 was obtained, and for the integrated signal the relation I = c 2 × m 1.25 × v 3.8, with only c 1 and C 2 depending on the target material. The rise time of the integrated signal follows the relation T = 2.2 × 10 2 × v −0.4 using gold as target, and in the case of tungsten material follows the relation T = 9.8 × 10 2 × v −1.2, where v is expressed in km/sec and T in μsec. Using the spectral distribution of the light intensity, measured by means of calibrated photomultipliers, the total amount of light energy emitted in the visible range could be calculated. As a result we obtained that for v = 4 km/sec and m = 10 −11 g about 3 × 10 −4 of the kinetic energy of the particle was converted into light energy. The variation of the impact flash intensity with the target material and the measured spectral distribution allowed the temperature of the crater after the impact to be estimated as between 2000 and 3000 K.

Radiation from hypervelocity impact generated plasma

Hypervelocity impact flash resolved into submicrosecond continuum radiation pulse succeeded by slow rising long duration light pulse from neutral atomic line emission

Impact Flash at High Speed Water Entry

Impact Flash at High Speed Water Entry