In models with colored particle mathcal {Q} that can decay into a dark matter candidate X, the relevant collider process pprightarrow mathcal {Q}bar{mathcal {Q}}rightarrow Xbar{X},+,jets gives rise to events with significant transverse momentum imbalance. When the masses of mathcal {Q} and X are very close, the relevant signature becomes monojet-like, and Large Hadron Collider (LHC) search limits become much less constraining. In this paper, we study the current and anticipated experimental sensitivity to such particles at the High-Luminosity LHC at sqrt{s}=14 TeV with mathcal {L}=3 ab^{-1} of data and the proposed High-Energy LHC at sqrt{s}=27 TeV with mathcal {L}=15 ab^{-1} of data. We estimate the reach for various Lorentz and QCD color representations of mathcal {Q}. Identifying the nature of mathcal {Q} is very important to understanding the physics behind the monojet signature. Therefore, we also study the dependence of the observables built from the pprightarrow mathcal {Q}bar{mathcal {Q}} + j process on mathcal {Q} itself. Using the state-of-the-art Monte Carlo suites MadGraph5_aMC@NLO+Pythia8 and Sherpa, we find that when these observables are calculated at NLO in QCD with parton shower matching and multijet merging, the residual theoretical uncertainties are comparable to differences observed when varying the quantum numbers of mathcal {Q} itself. We find, however, that the precision achievable with NNLO calculations, where available, can resolve this dilemma.
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