Spectral data are an active tool for mineral exploration, lithological, and structural mapping by spectral classification; due to its accuracy, ease of use, and low cost, especially in inaccessible areas. This study aims to integrate Landsat-8/OLI and ASTER images with extensive field survey and petrographical analysis to discriminate the Neoproterozoic basement rock units in the area east Gabal El-Sibai. In image enhancement techniques, we used the Correlation Coefficient and Optimum Index Factor for choosing the best-colored images to discriminate various rock units based on spectral signature curves. The exposed rock units consist of granitic rocks of variable compositions intruded directly into ophiolitic and island arc associations. The different rock units and structural elements in this study were mapped and discriminated using False Color Composites images (7-6-1 of Landsat-8 and 9-4-3 of ASTER), Minimum Noise Fraction (6-5-1), Principal Component Analysis (4-1-2 for Landsat-8 and 3-1-4 for ASTER), two newly proposed ratios images (3/4, 6/7, 5/6 for Landsat-8 and 4/1, 3/1, 8/9 for ASTER), with the Maximum Likelihood Classification and Support Vector Machine Classification. In conclusion; the overall accuracy and the Kappa coefficient show a good agreement with the Principal Component Analysis and Band Ratio results in the current geological map. Therefore, the suggested methodology shows that optical data have a strong potential for discriminating between lithological units. This approach provides accurate information to geologists, geophysical engineers, and land-use land-cover decision-makers. It can also improve and enhance the accuracy of geological maps in the Nubian Shield in Egypt and other arid environments worldwide.
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