Igneous Samples Research Articles

The mid-Variscan suture in the Morais complex of Trás-os-Montes (Portugal): insights from geochemistry and geochronology of oceanic rocks

ABSTRACT The Middle Allochthon of the Galicia-Trás-os-Montes Zone (GTMZ) in NW Iberia is an assemblage of oceanic units representing the Variscan suture of one or more peri-Gondwanan oceans. This contribution brings new geochronological and geochemical data from the Middle Allochthon of the Morais Complex, in northern Portugal. There, the oceanic ensemble consists of a stack of five tectonic units which from bottom to top are the Junqueira, Pombais and Izeda oceanic supracrustals and the Remondes and Morais-Talhinhas ophiolitic units. The Junqueira and Pombais units consist of greenschists and metapelites. No age data are available for these two units, but a correlation is established with a Cambro-Ordovician unit in the Órdenes Complex of Galicia (NW Spain) dated at 500 Ma. The Izeda Unit consists of fine-grained, low-grade amphibolites transitional to epidote-amphibolites and greenschists, for which an age of 484 ± 3 Ma has been obtained for a metabasic tuff. In the ophiolitic ensemble, the Remondes and Morais-Talhinhas units consist of fine-grained amphibolites associated with deformed metagabbros, mafic cumulates and serpentinized ultramafics. In this study, two plagiogranite samples from the Remondes Unit yielded a complex spread of age data with Silurian ages representing the dominant population. This suggests that the newly defined Remondes Unit is younger than the Izeda Unit but older than the previously published age for these rocks, which are considered part of the overlying Morais-Talhinhas Unit, dated as Devonian (406–395 Ma) in a previous study. The geochemistry of the basic rocks in the five units is that of NMORB with a subduction-derived component that varies from weak to null. The ages, together with new and previously published whole rock geochemical data obtained from basic igneous samples, are interpreted to date and reflect the formation of igneous protoliths in oceanic ridge settings associated with the Mid-Variscan Ocean, a part of the Rheic oceanic realm that registered magmatic activity between the late Cambrian and the Lower Devonian.

Mapping paleoelevations along active continental margins with igneous geochemistry: A case study from South America

Mountains and mountain ranges, often situated at convergent plate margins, play a pivotal role in many fields of the Earth, climate, and biological sciences. Reconstructing past episodes of mountain building from the geological rock record is one of the main challenges for unravelling the ancient physical geography of Earth’s surface. Established methods for quantifying past elevations traditionally relied on sedimentary rocks, but in recent years, alternative approaches have emerged on the basis that geochemical signatures of magmatic rocks formed in convergent settings correlate with crustal thickness or elevation. Consequently, methods based on igneous samples have the potential to allow quantitative mapping of past topographic change for large spans of space and time where existing maps are largely based on a qualitative approach. Here, we investigate the application of paleoelevation estimates derived from geochemistry using the western margin of South America as a case study. We investigate their consistency with independent indicators of past elevations such as stratigraphy, stable isotopes, fossils etc. for Cenozoic samples along the Andean margin. For older times, we compare the estimated paleoelevations with more general aspects of the geological record, as well as paleoelevations from global paleogeography models widely used in climate modelling studies, to evaluate the extent to which these models are consistent with the igneous geochemical proxies. We find that estimates based on multiple geochemical proxies, and which account for variations in elevation as a function of MgO, are preferable to those based on individual proxies. The multi-mohometer estimates yield estimates of elevation that better match both present-day topography and Cenozoic paleoelevations, and retain more samples during the data filtering stage. In deeper time, we show that igneous geochemistry quantifies changes in elevation related to documented phases of crustal thickening and thinning, and is thus likely to allow improvements to existing maps of paleotopography.

Application of microwave digestion for complete dissolution of igneous silicate rock samples: A simple and quick sample preparation procedure

In the area of geochemical analyses of rock solutions, achieving a complete sample dissolution is a fundamental prerequisite for obtaining accurate, precise and reliable analytical results. The challenge posed by the presence of resistant minerals such as zircon, rutile, corundum, spinel, tourmaline, beryl, chromite, and cassiterite in different silicate rocks is a well-recognized challenge in geological studies. These minerals, due to their resilient nature, demand additional efforts to ensure complete dissolution during sample preparation. The prevailing conventional sample digestion methods require several days of laboratory work and the handling of large amounts of multiple types of acids, which also increase sample blanks. Until recently, there was a widely held belief that microwave-assisted digestion, where microwave radiation is transformed to heat, faced limitations in achieving complete dissolution of refractory minerals. This prevailing opinion led to skepticism about the applicability of microwave-assisted digestion for sample preparation of e.g. igneous rock samples containing these minerals. This study introduces a novel, universal and quick closed-vessel (pressurized) high-temperature microwave-assisted digestion method appropriate for dissolution of all major types of igneous silicate rock samples, including rocks containing refractory minerals. This streamlined and expeditious procedure, comprising three steps, requires only a total time of ∼9 h. The method proves its versatility by successfully dissolving both, mafic igneous samples (e.g., basalt) with low-content of resistant minerals, and felsic igneous samples (e.g., granite) with relatively high-content of resistant minerals. To validate the reliability of this procedure, 36 trace elements were analyzed: Li, Be, Sc, V, Cr, Co, Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, Pb, Th and U in several geological Certified Reference Materials (CRMs). The CRMs including basalts JB-3, BCR-2, BHVO-2; andesites JA-2, AGV-2; granodiorite GSP-2; granite JG-2 and alkaline granite MGL-OShBO, were digested and analyzed using triple quadrupole Inductively Coupled-Plasma-Mass Spectrometer (ICP-QQQ). The results of the analysis demonstrate remarkable consistency, closely aligning with both certified and literature values.

Complementarity of Hf isotopes from detrital and igneous zircon: an example from the Central Gneiss Belt, Grenville Province, Ontario

Combined U–Pb and Hf isotopic analysis of detrital and igneous zircon provides information about variations in crustal addition versus reworking through time. However, whereas detrital zircon data from only a few samples can provide information about extended periods of orogenic activity, this approach lacks the geological context that comes with studying igneous zircon and may not record mid- and deep-crustal sources or sources isolated from sites of deposition. Conversely, igneous zircon is likely to miss sources that were removed by later tectonic activity, but which may be preserved in the detrital record. The Central Gneiss Belt of the southwest Grenville Province in Ontario has a relatively well-understood orogenic architecture and records active-margin growth and reworking between ca. 1900 and 1200 Ma. We present U–Pb and Hf isotope data of zircon from 30 orthogneiss samples ranging in age from ca. 1750 to 1250 Ma, covering all tectonostratigraphic levels of the Central Gneiss Belt. As expected, the detrital and igneous datasets display many of the same overall features, such as crustal growth along the southwest Laurentian active margin; however, there are also some distinct differences. In particular, sedimentation appears to have taken place near the active margin, with little or no input from distal inboard sources, thus missing this significant component of reworked crust. This study highlights the need for a combination of detrital and igneous samples to provide the most complete picture of long-lived accretionary orogenic systems.

Middle Jurassic to Early Cretaceous orogenesis in the Klamath Mountains Province (Northern California–southern Oregon, USA) occurred by tectonic switching: Insights from detrital zircon U-Pb geochronology of the Condrey Mountain schist

The Klamath Mountains Province of Northern California and southern Oregon, USA, consists of generally east-dipping terranes assembled via Paleozoic to Mesozoic subduction along the western margin of North America. The Klamath Mountains Province more than doubled in mass from Middle Jurassic to Early Cretaceous time, due to alternating episodes of extension (e.g., rifting and formation of the Josephine ophiolite) and shortening (e.g., Siskiyou and Nevadan events). However, the tectonic mechanisms driving this profound Mesozoic growth of the Klamath Mountains Province are poorly understood. In this paper, we show that formation of the Condrey Mountain schist (CMS) of the central Klamath Mountains Province spanned this critical time period and use the archive contained within the CMS as a key to deciphering the Mesozoic tectonics of the Klamath Mountains Province. Igneous samples from the outer CMS subunit yield U-Pb zircon ages of ca. 175–170 Ma, which reflect volcanic protolith eruptive timing. One detrital sample from the same subunit contains abundant (~54% of zircon grains analyzed) Middle Jurassic ages with Paleozoic and Proterozoic grains comprising the remainder and yields a maximum depositional age (MDA) of ca. 170 Ma. These ages, in the context of lithologic and thermochronologic relations, suggest that outer CMS protoliths accumulated in an outboard rift basin and subsequently underthrust the Klamath Mountains Province during the Late Jurassic Nevadan orogeny. Five samples of the chiefly metasedimentary inner CMS yield MDAs ranging from 160 Ma to 130 Ma, with younger ages corresponding to deeper structural levels. Such inverted age zonation is common in subduction complexes and, considering existing K-Ar ages, suggests that the inner CMS was assembled by progressive underplating over a >10 m.y. timespan. Despite this age zonation, age spectra derived from structurally shallow and deep portions of the inner CMS closely overlap those derived from the oldest section of the Franciscan subduction complex (South Fork Mountain schist). These relations suggest that the inner CMS is a composite of South Fork Mountain schist slices that were sequentially underplated beneath the Klamath Mountains Province. The age, inboard position, and structural position (i.e., the CMS resides directly beneath Jurassic arc assemblages with no intervening mantle) of the CMS suggest that these rocks were emplaced during one or more previously unrecognized episodes of shallow-angle subduction restricted to the Klamath Mountains Province. Furthermore, emplacement of the deepest portions of the CMS corresponds with the ca. 136 Ma termination of magmatism in the Klamath Mountains Province, which we relate to the disruption of asthenospheric flow during slab shallowing. The timing of shallow-angle subduction shortly precedes that of the westward translation of the Klamath Mountains Province relative to correlative rocks in the northern Sierra Nevada Range, which suggests that subduction dynamics were responsible for relocating the Klamath Mountains Province from the arc to the forearc. In aggregate, the above relations require at least three distinct phases of extension and/or rifting, each followed by an episode of shallow-angle underthrusting. The dynamic upper-plate deformation envisioned here is best interpreted in the context of tectonic switching, whereby slab steepening and trench retreat alternate with slab shallowing due to recurrent subduction of buoyant oceanic features.

Petrologic relationship between lamprophyres, carbonatites, and heavy rare‐earth element enriched breccias at Hicks Dome

AbstractNew petrological, geochemical, and P–T modelling results from igneous samples clarify how carbonatite‐lamprophyre magmatism, fluorite and rare earth element (REE) enrichment are petrogenetically related in southern Illinois. P–T modelling reveals that igneous rocks derive from a deep mantle carbonated source, that is consistent with trace element signatures for a fluorine‐rich transition zone origin. Major element systematics suggests liquid‐immiscibility with lamprophyric melts as the origin for Ca‐carbonatites. Heavy REE (HREE) enrichments in Hicks Dome breccias likely formed through preferential partitioning and transport of HREE by brine‐melts, exsolved from a deep carbonatite body. Brine‐melts redistributed HREEs throughout the system along brecciated pathways where they reprecipitated as HREE‐rich phosphate/fluorcarbonate minerals (e.g. xenotime, florencite, synchesite) in host bedrock. The diversity of igneous rocks in southern Illinois highlights the area as an excellent natural laboratory to study carbonated melt petrogenesis and evolution.

Modeling apparent Pb loss in zircon U–Pb geochronology

Abstract. The loss of radiogenic Pb from zircon is known to be a major factor that can cause inaccuracy in the U–Pb geochronological system; hence, there is a need to better characterize the distribution of Pb loss in natural samples. Treatment of zircon by chemical abrasion (CA) has become standard practice in isotope dilution–thermal ionization mass spectrometry (ID-TIMS), but CA is much less commonly employed prior to in situ analysis via laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) or secondary ionization mass spectrometry (SIMS). Differentiating the effects of low levels of Pb loss in Phanerozoic zircon with relatively low-precision in situ U–Pb dates, where the degree of Pb loss is insufficient to cause discernible discordance, is challenging. We show that U–Pb isotopic ratios that have been perturbed by Pb loss may be modeled by convolving a Gaussian distribution that represents random variations from the true isotopic value stemming from analytical uncertainty with a distribution that characterizes Pb loss. We apply this mathematical framework to model the distribution of apparent Pb loss in 10 igneous samples that have both non-CA LA-ICP-MS or SIMS U–Pb dates and an estimate of the crystallization age, either through CA U–Pb or 40Ar/39Ar geochronology. All but one sample showed negative age offsets that were unlikely to have been drawn from an unperturbed U–Pb date distribution. Modeling apparent Pb loss using the logit–normal distribution produced good fits with all 10 samples and showed two contrasting patterns in apparent Pb loss; samples where most zircon U–Pb dates undergo a bulk shift and samples where most zircon U–Pb dates exhibited a low age offset but fewer dates had more significant offset. Our modeling framework allows comparison of relative degrees of apparent Pb loss between samples of different age, with the first and second Wasserstein distances providing useful estimates of the total magnitude of apparent Pb loss. Given that the large majority of in situ U–Pb dates are acquired without the CA treatment, this study highlights a pressing need for improved characterization of apparent Pb-loss distributions in natural samples to aid in interpreting non-CA in situ U–Pb data and to guide future data collection strategies.

Does Zircon Shape Retain Petrogenetic Information?

AbstractZircon shape is commonly reported during geochronology and geochemistry analyses of igneous, metamorphic, and sedimentary rocks, but the relationship of zircon shape to primary growth environmental conditions remains poorly constrained. Current models for the control on igneous zircon shape focus on the relative growth of crystal prisms and pyramids, which are not discernible in the imaging techniques used for rapid quantification of zircon shape in geochronology sample mounts. We model the relationship between whole‐rock composition and zircon 2D shape in mineral separates from 45 mafic to felsic igneous samples, representative of Archean and Proterozoic crust in Western Australia. Shape parameters are derived from semi‐automated measurement of photomicrographs of polished zircon crystals in epoxy resin mounts. Whole‐rock composition shows a statistically significant relationship to median magmatic zircon crystal area and mathematically defined “roundness.” Zircon populations show reduced median area and increased median roundness as whole‐rock silica decreases. Phase equilibrium modeling based on whole‐rock composition, and automated electron microscopy mineral maps, indicates that the compositional predisposition of zircon shape is influenced by fundamentally different physical growth environments in mafic versus felsic melts. Specifically, influential factors that differ between mafic and felsic liquids include crystallization sequence and duration—which influence unconstrained growth space—and the potential for absorption/exsolution of zirconium from the accompanying mineral assemblage. We present quantitative, explanatory models for the relationship between zircon 2D shape and whole‐rock silica and demonstrate that the relationships are adhered to across a broad spectrum of whole‐rock compositions.

Multi-method dating constrains the diversification of early eukaryotes in the Proterozoic Mbuji-Mayi Supergroup of the D.R.Congo and the geological evolution of the Congo Basin

We present a petrological and geochronological study of the Proterozoic Mbuji-Mayi sedimentary Supergroup (Sankuru-Mbuji-Mayi-Lomami-Lovoy basin, Democratic Republic of the Congo) and of the overlying subvolcanic doleritic rocks. Dating this Supergroup in Central Africa is crucial to reconstruct the geological history and evolution of the Congo Basin and because it contains a large diversity of organic-walled microfossils including early eukaryotes. For this study, we use the Re–Os dating method on kerogen from shales from the top of the lower Group BI (which contains the microfossils) and Ar–Ar, Sm–Nd and U–Pb methods on the dolerites emplaced near the top of the succession, defining the end of the sedimentation in the basin. The 187Re/187Os dating yield an age of 1041 ± 58 Ma. For the dolerites, 40Ar/39Ar dating provide a similar minimum age from 1006 ± 13 to 1009 ± 32 Ma in the whole basin. 147Sm/143Nd dating confirms a less precise but overlapping age of 926 ± 170 Ma for sample from the Western part of the basin. Some 40Ar/39Ar dating and U–Pb dating provide also inherited Archean ages. The weighted average age for igneous samples from the basin is 1006 ± 12 Ma. This confirms that the upper Group BII was deposited from 1030 to 1040 to 1006 Ma, consistent with previous U–Pb dating on diagenetic minerals and with biostratigraphy. This new dating provides constraints on the late Mesoproterozoic – early Neoproterozoic diversification of early eukaryotes in Central Africa.We also compare the petrology, geochemistry and geochronology of dolerites from different locations of the basin. Our new data evidence a common origin for all the subvolcanic rocks, emplaced in an intraplate setting and intruding the Archean basement, and indirectly date the end of the extensional stage that initiated the development of the Congo Basin.

Rifted margin with localized detachment and polyphase magmatism: A new model of the northern South China Sea

Continental passive margins are commonly classified into volcanic (or magma-rich) and non-volcanic (or magma-poor) types based on the magmatic budget. It is difficult, however, to use either of these models to define the northern margin of the South China Sea (SCS). Based on 2-D/3-D time/depth-migrated seismic data and borehole data from the Pearl River Mouth Basin in the northern SCS, we examine the detachment fault systems and syn-rift magmatism in the Baiyun and Liwan Sags. The detachment fault systems and related tilted blocks of the northern SCS established in the Baiyun and Liwan Sags in previous studies may be mainly constrained to the Baiyun Sag. The Liwan Sag, however, acts as a “sag-type” basin accompanied by magmatic domes. Radiometric age of igneous samples from wells, coupled with multi-horizon onlapping terminations within syn-rift layers, reveal four-phase rift-related magmatism in the northern SCS. The crustal thinning in the Baiyun Sag is controlled by a detachment fault, but in the Liwan Sag, it is mainly controlled by a preferential thinning of the lower crust. High thermal conditions and intense syn-rift magmatism weakened the lower crust, which contributes to the depth-dependent thinning in the Liwan Sag.

Off-sequence plume magmatism near Ninetyeast Ridge in the Indian Ocean: evidence for extensive lateral flow of the Kerguelen plume

One of the fundamental questions about Earth processes that is still outstanding is how far a moving plate can drag plume material at its base after its initial impact with the plume. The IODP-362 Expedition recovered igneous samples from drilled sites near Ninetyeast Ridge (NER) in the Indian Ocean. A detailed geochemical and isotopic (Sr–Nd) investigation of these samples found that the basement basalts of the core are typical N-MORB tholeiites, but the igneous sills intruding the upper layer of sediments are highly alkaline, with a composition equivalent to the Kerguelen plume magma. Based on biostratigraphy, the minimum age of the alkaline samples was calculated as c. 58 Ma, which is younger than the adjacent NER crust ( c. 82–78 Ma). The existence of such young plume magma amidst the older blocks of the NER is unusual and contrary to its southwards-younging age pattern. We propose that the fast-moving Indian plate dragged a considerable amount of Kerguelen plume material underneath the Indian Ocean lithosphere northwards during the Cretaceous–Paleocene, covering a longitudinal distance of c. 2220 km. The reactivation of deep fractures triggered decompression melting of the underlying plume material and emplaced this as magmatic sills and lava flows near the NER at c. 58 Ma.

Advances in in-situ Rb-Sr dating using LA-ICP-MS/MS: applications to igneous rocks of all ages and to the identification of unrecognized metamorphic events

Age determinations of rocks by in-situ Rb-Sr dating of minerals has the advantage of providing spatially resolved analysis without time-consuming preparation, but is hampered by isobaric and polyatomic interferences on Sr isotopes, especially 87Rb. LA-ICP-MS/MS using N2O as a reaction gas allows online chemical separation of 87Rb from 87Sr by measuring SrO+. Here, the method for in-situ Rb-Sr is optimized and applicability demonstrated for geological samples ranging from late Archean to 20 Ma in age.Rb-Sr isotopes of multiple reference materials and geological samples have been analyzed by LA-ICP-MS/MS to evaluate the method for dating rocks throughout the geological record. The quality of Sr isotopic data can be greatly improved by external calibration of mass bias. For internal calibration, better accuracy is obtained with the addition of H2 as a trace molecular gas. The elemental fractionation of Rb and Sr during LA-ICP-MS/MS analysis varies for different reference materials. We find that the matrix of NIST SRM 610 renders it unsuitable for correction of 87Rb/86Sr. The Mica-Mg reference material is preferred for calibration of 87Rb/86Sr of micas despite showing significant Rb-Sr fractionation.In-situ Rb-Sr ages were determined for igneous samples ranging in age from 20 Ma to Mesoproterozoic, confirming accurate application of the method to samples of widely differing ages. The most accurate isochron ages were obtained with 87Rb/86Sr calibrated against Mica-Mg. Application to two metamorphic gneisses with late Archean protoliths from Labrador and Finland reveal thermal events at 1.66–1.70 Ga when they were part of a large Paleoproterozic active margin along the southern edge of Laurentia-Baltica. Data collected for minerals with differing closure temperatures for the Rb-Sr system allow detection of thermal events not recorded by other geochronological systems, indicating a huge potential of this technique not only for accurately dating samples, but also for providing previously inaccessible information on metamorphic histories.

Titanium Isotope Analysis of Igneous Reference Materials using a Double‐spike MC‐ICP‐MS Method

AbstractTi separation was achieved by ion‐exchange chromatography using Bio‐Rad AG 1‐X8 anion‐exchange and DGA resins. For high‐Fe/Ti and high‐Mg/Ti igneous samples, a three‐column procedure was required, whereas a two‐column procedure was used for low‐Fe/Ti and low‐Mg/Ti igneous samples. The Ti isotopes were analysed by MC‐ICP‐MS, and instrumental mass bias was corrected using a 47Ti‐49Ti double‐spike technique. The 47Ti‐49Ti double‐spike and SRM 3162a were calibrated using SRM 979‐Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa‐Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR‐2, BHVO‐2, GBW07105, AGV‐1, AGV‐2, W‐2, GBW07123, GBW07126, GBW07127, GBW07101, JP‐1, and DTS‐2b. Samples yield δ49/47Ti (‰) of −0.035 ± 0.022, −0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, −0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and −0.047 ± 0.025 (relative to OL‐Ti, ±2SD), respectively; of which isotopic compositions of DTS‐2b, JP‐1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa‐Ti was analysed repeatedly over a ten‐month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.

S-type like granites and felsic volcanic rocks in the Mahabad area, NW Iran: Late Neoproterozoic extensional tectonics follow collision on the northern boundary of Gondwana

The Late Neoproterozoic basement is exposed in the Mahabad area of northwest Iran, and it is classified into three main groups. The first is metamorphic rocks that include gneiss, schist, phyllite, and slate. The second is sedimentary rocks, which comprise shale, sandstone, and dolomite and the third is igneous rocks including granite, rhyolite, felsic tuff, and ignimbrite, which are the subject of this research. Zircon UPb ages for three igneous samples show that crystallization occurred at 558–552 Ma in the late Neoproterozoic (Ediacaran). The felsic magmatic rocks have SiO2 contents of 64.3 to 78.9 wt%, Al2O3 contents of 12.0 to 16.8 wt%, low TiO2 contents (0.08 to 0.69 wt%), and large variations in K2O (0.05 to 5.46 wt%) and Na2O (1.17 to 6.70 wt%). The felsic magmatic rocks are enriched in light rare earth elements (REEs) such as La and Sm, have flat heavy REE patterns, and strong negative Eu anomalies. They are mainly weakly to strongly peraluminous and calc-alkalic to alkali-calcic rocks. A wide range of initial 87Sr/86Sr(556Ma) ratios (0.7056 to 0.7203) and negative εNd(t) values (−6.0 to −2.9) do not show clear trends of mixing/contamination among mantle, slab fluids, and/or altered oceanic crust. The Mahabad magmatic rocks were produced mainly by partial melting of graywacke, psammite, and shale at high temperatures (~800 °C), based on the zircon saturation index. S-type like granites usually form in syn- to post-collisional systems, but the Mahabad felsic rocks, which have almost the same ages as the associated sedimentary rocks, were generated in an extensional regime according to geochemical discrimination diagrams. This can be explained as follows: sediments were deeply buried during the late Neoproterozoic amalgamation of microcontinents at a subduction zone along the northern boundary of Gondwana, and then erosion of the roof and/or thinning owing to extension led to upwelling of the asthenosphere and intrusion of mafic magma, which was responsible for partially melting the buried metasedimentary rocks to generate S-type like granites and felsic volcanic rocks.

Revisiting the Bøggild Intergrowth in Iridescent Labradorite Feldspars: Ordering, Kinetics, and Phase Equilibria

The enigmatic Bøggild intergrowth in iridescent labradorite crystals was revisited in light of recent work on the incommensurately modulated structures in the intermediated plagioclase. Five igneous samples and one metamorphic labradorite sample with various compositions and lamellar thicknesses were studied in this paper. The lamellar textures were characterized with conventional transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM). The compositions of individual lamellae were analyzed with high-resolution energy-dispersive X-ray spectroscopy (EDS) mapping and atom probe tomography (APT). The average structure states of the studied samples were also compared with single-crystal X-ray diffraction data (SC-XRD). The Na-rich lamellae have a composition of An44–48, and the Ca-rich lamellae range from An56 to An63. Significant differences between the lamellar compositions of different samples were observed. The compositions of the Bøggild intergrowth do not only depend on the bulk compositions, but also on the thermal history of the host rock. The implications on the subsolidus phase relationships of the plagioclase feldspar solid solution are discussed. The results cannot be explained by a regular symmetrical solvus such as the Bøggild gap, but they support an inclined two-phase region that closes at low temperature.

Inherited structure as a control on late Paleozoic and Mesozoic exhumation of the Tarbagatai Mountains, southeastern Kazakhstan

Central Asia hosts the Tianshan, the largest intracontinental mountain belt in the world, which experienced major reactivation and uplift since the Oligocene in response to the collision of India with Asia. This reactivation was focused around pre-existing structures inherited from the Paleozoic tectonic history of the region. The significant Cenozoic tectonic reworking of Central Asia complicates efforts to understand earlier phases of intracontinental tectonics during the late Paleozoic and Mesozoic. The Tarbagatai Mountains of eastern Kazakhstan record a thermotectonic history that provides insight into the timing and distribution of intracontinental tectonic activity in Central Asia prior to the India–Eurasia collision. Apatite fission-track and (U–Th–Sm)/He analysis of igneous samples from the Tarbagatai Mountains reveals two episodes of cooling as a result of exhumation following Paleozoic amalgamation. Initial intracontinental deformation during the Late Permian drove exhumation synchronous with activity along newly formed strike-slip faults spanning the Central Asian Orogenic Belt. The major Chingiz–Tarbagatai Fault was reactivated during the Early Cretaceous, driving localized exhumation along the fault. The relative lack of Cenozoic tectonic activity in the Tarbagatai Mountains means that they provide unique insight into the broader thermotectonic evolution of Central Asia during the late Paleozoic and Mesozoic. Supplementary material: Detailed thermochronological data, including plots and tables, are available at https://doi.org/10.6084/m9.figshare.c.5414555

Comparison Between the Classical Classification and Digital Classification for Selected Samples of Igneous and Carbonate Rocks

As igneous rocks have widely chemical and mineralogical compositions, there are many ways to classify these rocks. These ways are classical approved methods to give a reliable classification and nomenclature of rocks. Some igneous rocks may be classified by digital image processing to assist in classical methods. Five igneous samples were cut, prepared of thin sections, and polished to classify them by classical methods and digital image processing by ENVI software. Moreover, part of these samples crushed an analysis of major oxides. The current igneous samples have referred to the basic and mesocratic rocks based on the classical methods and this has corresponded to ENVI software. The igneous samples have reflected the leucogabbros when classify them by classical and ENVI classifications, except the G5 sample, which has been referred to as gabbro by ENVI. There is a clear similarity between the classical and ENVI classifications. ENVI classification is a reliable classification to assist the classical methods in the nomenclature of igneous rocks, especially, plutonic rocks, it can be also applied to thin sections of volcanic rocks to classify and nomenclature classification by ENVI has been applied on fifty thin sections of limestones to identify microfacies which are classified beforehand by classical (optical) classification. According to optical classification, microfacies have classified as mudstone, wackestone, packstone, and grainstone. When the digital classification is applied to them, there is no grainstone texture found in these them. Digital thin sections, where the true name of these microfacies is packstone. Therefore, the positive sides of the digital image processing by ENVI software appeared and contrasted to the optical classification which contained some mistakes when applied to the nomenclature of these microfacies.

Probing Venus Surface Iron Contents With Six‐Band Visible Near‐Infrared Spectroscopy From Orbit

AbstractMachine learning models enable interpretation of orbital spectral measurements of Venus using laboratory calibration data collected at Venus surface temperatures. Partial least squares models show that total iron content can be accurately predicted using data from the six bands (two in the 1.02 μm window). Prediction errors on total wt% FeO are ±0.50 for common subalkaline volcanic rocks. Accuracy is ±0.42 for wt% FeO in alkaline rocks, and ±2.47 for all 18 igneous samples studied to date. These robust capabilities will allow discrimination of basalt versus rhyolite/granite and elucidate the rock type of the enigmatic tessera terrain on Venus.

Chondritic mercury isotopic composition of Earth and evidence for evaporative equilibrium degassing during the formation of eucrites

Variations in the abundances of moderately volatile elements (MVE) are one of the most fundamental geochemical differences between the terrestrial planets. Whether these variations are the consequence of nebular processes, planetary volatilization, differentiation or late accretion is still unresolved. The element mercury is the most volatile of the MVE and is a strongly chalcophile element. It is one of the few elements that exhibit large mass-dependent (MDF) and mass-independent (MIF) isotopic fractionations for both odd (odd-MIF, Δ199Hg and Δ201Hg) and even (even-MIF, Δ200Hg) Hg isotopes in nature, which is traditionally used to trace Hg biogeochemical cycling in surface environments. However, the Hg isotopic composition of Earth and meteorites is not well constrained. Here, we present Hg isotopic data for terrestrial basaltic, trachytic and granitic igneous samples. These rocks are isotopically lighter (δ202Hg = −3.3 ± 0.9‰; 1 standard deviation) than sedimentary rocks that have previously been considered to represent the terrestrial Hg isotope composition (δ202Hg=−0.7±0.5‰; 1 standard deviation). We show degassing during magma emplacement induces MIF that are consistent with kinetic fractionation in these samples. Also presented is a more complete dataset for chondritic (carbonaceous, ordinary and enstatite) meteorites, which are consistent with previous work for carbonaceous chondrites (positive odd-MIF) and ordinary chondrites (no MIF), and demonstrate that some enstatite chondrites exhibit positive odd-MIF, similar to carbonaceous chondrites. The terrestrial igneous rocks fall within the range of chondritic compositions for both MIF and MDF. Given the fact that planetary differentiation (core formation, evaporation) would contribute to Hg loss from the silicate portion of Earth and would likely fractionate Hg isotopes from chondritic compositions, we suggest that the budget of the mantle Hg is dominated by late accretion of chondritic materials to Earth, as also suggested for other volatile chalcophile elements (S, Se, Te). Considering the Hg isotopic signatures, materials with compositions similar to CO chondrites or ordinary chondrites are the most likely late accretion source candidates. Finally, eucrite meteorites, which are highly depleted in volatile elements, are isotopically heavier than chondrites and exhibit negative odd-MIF. The origin of volatile depletion in eucrites has been vigorously debated. We show that Δ199Hg versus Δ201Hg relationships point toward an equilibrium nuclear field shift effect, suggesting that volatile loss occurred during a magma ocean phase at the surface of the eucrite parent body, likely the asteroid 4-Vesta.

The zirconium stable isotope compositions of 22 geological reference materials, 4 zircons and 3 standard solutions

We report stable Zr isotope compositions of four common natural zircon grains: Penglai, 91500, GJ-1 and Mud Tank, and 22 whole rock reference materials which include fifteen magmatic rocks, one metamorphic rock, six sediments or sedimentary rocks. In addition, the isotopic calibration of the three Zr standard solutions used in different publications (IPGP-Zr, SRM3169, NIST) has been determined. The data are reported as δ94/90ZrIPGP-Zr, the permille deviation of the 94Zr/90Zr ratio relative to the IPGP-Zr standard solution. The isotopic offsets among the three Zr standard solutions are small (less than 0.033 ± 0.033‰). The isotopic composition of the zircons agrees well with previous in-situ measurements, validating the in-situ measurements. On the other hand, all the samples analyzed in this study show a large range of Zr isotope compositions of 0.602‰. This confirms the fairly large natural Zr isotopic variations. The general variation of δ94/90ZrIPGP-Zr with magmatic evolution of the various igneous samples is in agreement with previous studies, with the most magmatically evolved samples being the isotopically heavier. The two magmatic zircons are isotopically lighter compared to the magmatic rocks, which is in agreement with the enrichment of heavy isotope in the evolved samples. This is ultimately controlled by the crystallization of isotopically light zircons.