Ice Mantles Research Articles

Infrared complex refractive index of astrophysical ices exposed to cosmic rays simulated in the laboratory

In the dense and cold regions of the interstellar medium, molecules can be adsorbed on to dust grains to form ice mantles. Once formed, these can be processed by ionizing radiation coming from the stellar or interstellar medium, leading to the formation of several new molecules in the ice. Among the different types of ionizing radiation, cosmic rays play an important role in solid-phase chemistry because of the large amount of energy deposited in the ices. The physicochemical changes induced by the energetic processing of astrophysical ices are recorded in a intrinsic parameter of the matter called the complex refractive index. In this paper, for the first time, we present a catalogue containing 39 complex refractive indices (n, k) in the infrared from 5000 to 600 cm−1 (2.0–16.6 μm) for 13 different water-containing ices processed in the laboratory by cosmic ray analogues. The calculation was performed using the nkabs – an acronym of the determination of N and K from absorbance data – code,which employs the Lambert–Beer and Kramers–Kronig equations to calculate the values of n and k. The results are also available at the following web site: http://www1.univap.br/gaa/nkabs-database/data.htm. As a test case, H2O:NH3:CO2:CH4 ice was employed in a radiative transfer simulation of a protoplanetary disc to show that these data are indispensable to reproduce the spectrum of ices containing young stellar objects.

Negligible photodesorption of methanol ice and active photon-induced desorption of its irradiation products

Methanol is a common component of interstellar and circumstellar ice mantles and is often used as an evolution indicator in star-forming regions. The observations of gas-phase methanol in the interiors of dense molecular clouds at temperatures as low as 10 K suggests that a non-thermal ice desorption must be active. Ice photodesorption was proposed to explain the abundances of gas-phase molecules toward the coldest regions. Laboratory experiments were performed to investigate the potential photodesorption of methanol toward the coldest regions. Solid methanol was deposited at 8 K and UV-irradiated at various temperatures starting from 8 K. The irradiation of the ice was monitored by means of infrared spectroscopy and the molecules in the gas phase were detected using quadrupole mass spectroscopy. Fully deuterated methanol was used for confirmation of the results. The photodesorption of methanol to the gas phase was not observed in the mass spectra at different irradiation temperatures. We estimate an upper limit of 3x10e-5 molecules per incident photon. On the other hand, photon-induced desorption of the main photoproducts was clearly observed. The negligible photodesorption of methanol could be explained by the ability of UV-photons in the 114 - 180 nm (10.87 - 6.88 eV) range to dissociate this molecule efficiently. Therefore, the presence of gas-phase methanol in the absence of thermal desorption remains unexplained. On the other hand, we find CH_4 to desorb from irradiated methanol ice, which was not found to desorb in the pure CH_4 ice irradiation experiments.

Present and past glaciation on Pluto

Modern N2 ice glaciers flow from highlands to the east of the 750×1400km2 lowland of Sputnik Planum [SP] and merge with the ices of similar composition on SP. We explore the possibility that glaciation may be fed by N2 sublimation from SP followed by redeposition on the highlands. The uplands to the northeast, north, and west of SP have been erosionally sculpted into a variety of dissected terrains that feature linear depressions (valleys), locally in dendritic networks. We interpret these dissected terrains to have been carved by N2 glaciers formerly covering the uplands. Depositional glacial landforms (moraines, eskers, outwash) have not been identified, however. N2 glaciation would have a different erosional manifestation because the substrate (porous water ice and CH4-rich mantles) probably has lower density than N2, and also because of the lack of freeze-thaw weathering. If sufficiently thick (1–4km), N2 glaciers might have experienced basal melting. Past flow of N2 glaciers from the highlands into SP may have detached and transported the prominent mountainous water ice mountains along the western border of SP.

Laboratory measurements and astronomical search for the HSO radical.

Despite the fact that many sulfur-bearing molecules, ranging from simple diatomic species up to astronomical complex molecules, have been detected in the interstellar medium, the sulfur chemistry in space is largely unknown and a depletion in the abundance of S-containing species has been observed in the cold, dense interstellar medium (ISM). The chemical form of the missing sulfur has yet to be identified. For these reasons, in view of the fact that there is a large abundance of triatomic species harbouring sulfur, oxygen, and hydrogen, we decided to investigate the HSO radical in the laboratory to try its astronomical detection. High-resolution measurements of the rotational spectrum of the HSO radical were carried out within a frequency range well up into the THz region. Subsequently, a rigorous search for HSO in the two most studied high-mass star-forming regions, Orion KL and Sagittarius (Sgr) B2, and in the cold dark cloud Barnard 1 (B1-b) was performed. The frequency coverage and the spectral resolution of our measurements allowed us to improve and extend the existing dataset of spectroscopic parameters, thus enabling accurate frequency predictions up to the THz range. These were used to derive the synthetic spectrum of HSO, by means of the MADEX code, according to the physical parameters of the astronomical source under consideration. For all sources investigated, the lack of HSO lines above the confusion limit of the data is evident. The derived upper limit to the abundance of HSO clearly indicates that this molecule does not achieve significant abundances in either the gas phase or in the ice mantles of dust grains.

INFALLING–ROTATING MOTION AND ASSOCIATED CHEMICAL CHANGE IN THE ENVELOPE OF IRAS 16293–2422 SOURCE A STUDIED WITH ALMA

ABSTRACT We have analyzed rotational spectral line emission of OCS, CH3OH, HCOOCH3, and H2CS observed toward the low-mass Class 0 protostellar source IRAS 16293–2422 Source A at a sub-arcsecond resolution (∼0.″6 × 0.″5) with ALMA. Significant chemical differentiation is found on a scale of 50 au. The OCS line is found to trace well the infalling–rotating envelope in this source. On the other hand, the distributions of CH3OH and HCOOCH3 are found to be concentrated around the inner part of the infalling–rotating envelope. With a simple ballistic model of the infalling–rotating envelope, the radius of the centrifugal barrier (a half of the centrifugal radius) and the protostellar mass are evaluated from the OCS data to be from 40 to 60 au and from 0.5 to 1.0 M ⊙, respectively, assuming the inclination angle of the envelope/disk structure to be 60° (90° for the edge-on configuration). Although the protostellar mass is correlated with the inclination angle, the radius of the centrifugal barrier is not. This is the first indication of the centrifugal barrier of the infalling–rotating envelope in a hot corino source. CH3OH and HCOOCH3 may be liberated from ice mantles by weak accretion shocks around the centrifugal barrier and/or by protostellar heating. The H2CS emission seems to come from the disk component inside the centrifugal barrier in addition to the envelope component. The centrifugal barrier plays a central role not only in the formation of a rotationally supported disk but also in the chemical evolution from the envelope to the protoplanetary disk.

TEMPERATURE SPECTRA OF INTERSTELLAR DUST GRAINS HEATED BY COSMIC RAYS. I. TRANSLUCENT CLOUDS

ABSTRACT Heating of whole interstellar dust grains by cosmic-ray (CR) particles affects the gas–grain chemistry in molecular clouds by promoting molecule desorption, diffusion, and chemical reactions on grain surfaces. The frequency of such heating, f T , s−1, determines how often a certain temperature T CR, K, is reached for grains hit by CR particles. This study aims to provide astrochemists with a comprehensive and updated data set on CR-induced whole-grain heating. We present calculations of f T and T CR spectra for bare olivine grains with radius a of 0.05, 0.1, and 0.2 μm and such grains covered with ice mantles of thickness 0.1a and 0.3a. Grain shape and structure effects are considered, as well as 30 CR elemental constituents with an updated energy spectrum corresponding to a translucent cloud with A V = 2 mag. Energy deposition by CRs in grain material was calculated with the srim program. We report full T CR spectra for all nine grain types and consider initial grain temperatures of 10 K and 20 K. We also provide frequencies for a range of minimum T CR values. The calculated data set can be simply and flexibly implemented in astrochemical models. The results show that, in the case of translucent clouds, the currently adopted rate for heating of whole grains to temperatures in excess of 70 K is underestimated by approximately two orders of magnitude in astrochemical numerical simulations. Additionally, grains are heated by CRs to modest temperatures (20–30 K) with intervals of a few years, which reduces the possibility of ice chemical explosions.

Mantle formation, coagulation, and the origin of cloud/core shine

Many dense interstellar clouds are observable in emission in the near-IR, commonly referred to as "Cloudshine", and in the mid-IR, the so-called "Coreshine". These C-shine observations have usually been explained with grain growth but no model has yet been able to self-consistently explain the dust spectral energy distribution from the near-IR to the submm. We want to demonstrate the ability of our new core/mantle evolutionary dust model THEMIS (The Heterogeneous dust Evolution Model at the IaS), which has been shown to be valid in the far-IR and submm, to reproduce the C-shine observations. Our starting point is a physically motivated core/mantle dust model. It consists of 3 dust populations: small aromatic-rich carbon grains; bigger core/mantle grains with mantles of aromatic-rich carbon and cores either made of amorphous aliphatic-rich carbon or amorphous silicate. We assume an evolutionary path where these grains, when entering denser regions, may first form a second aliphatic-rich carbon mantle (coagulation of small grains, accretion of carbon from the gas phase), second coagulate together to form large aggregates, and third accrete gas phase molecules coating them with an ice mantle. To compute the corresponding dust emission and scattering, we use a 3D Monte-Carlo radiative transfer code. We show that our global evolutionary dust modelling approach THEMIS allows us to reproduce C-shine observations towards dense starless clouds. Dust scattering and emission is most sensitive to the cloud central density and to the steepness of the cloud density profile. Varying these two parameters leads to changes, which are stronger in the near-IR, in both the C-shine intensity and profile. With a combination of aliphatic-rich mantle formation and low-level coagulation into aggregates, we can self-consistently explain the observed C-shine and far-IR/submm emission towards dense starless clouds.

Herschel-HIFI view of mid-IR quiet massive protostellar objects

We present Herschel/HIFI observations (WISH KP) of 14 water lines in a small sample of galactic massive protostellar objects: NGC6334I(N), DR21(OH), IRAS16272-4837, and IRAS05358+3543. We analyze the gas dynamics from the line profiles. Through modeling of the observations using RATRAN, we estimate outflow, infall, turbulent velocities, molecular abundances, and investigate any correlation with the evolutionary status of each source. The molecular line profiles exhibit a broad component coming from the shocks along the cavity walls associated with the protostars, and an infalling (or expansion for IRAS05358+3543) and passively heated envelope component, with highly supersonic turbulence likely increasing with the distance from the center. Accretion rates between 6.3 10^{-5} and 5.6 10^{-4} \msun yr^{-1} are derived from the infall observed in three of our sources. The outer water abundance is estimated to be at the typical value of a few 10^{-8} while the inner abundance varies from 1.7 10^{-6} to 1.4 10^{-4} with respect to H2 depending on the source. We confirm that regions of massive star formation are highly turbulent and that the turbulence likely increases in the envelope with the distance to the star. The inner abundances are lower than the expected 10^{-4} perhaps because our observed lines do not probe deep enough into the inner envelope, or because photodissociation through protostellar UV photons is more efficient than expected. We show that the higher the infall/expansion velocity in the protostellar envelope, the higher is the inner abundance, maybe indicating that larger infall/expansion velocities generate shocks that will sputter water from the ice mantles of dust grains in the inner region. High-velocity water must be formed in the gas-phase from shocked material.

Detection of CH3SH in protostar IRAS 16293-2422

The nature of the main sulphur reservoir in star forming regions is a long standing mystery. The observed abundance of sulphur-bearing species in dense clouds is only about 0.1 per cent of the same quantity in diffuse clouds. Therefore, the main sulphur species in star forming regions of the interstellar medium are still unknown. IRAS 16293-2422 is one of the regions where production of S-bearing species is favourable due to its conditions which allows the evaporation of ice mantles. We carried out observations in the 3 mm band towards the solar type protostar IRAS 16293-2422 with the IRAM 30m telescope. We observed a single frequency setup with the EMIR heterodyne 3 mm receiver with an Lower Inner (LI) tuning frequency of 89.98 GHz. Several lines of the complex sulphur species CH3SH were detected. Observed abundances are compared with simulations using the NAUTILUS gas-grain chemical model. Modelling results suggest that CH3SH has the constant abundance of 4e-9 (compared to H2) for radii lower than 200 AU and is mostly formed on the surfaces. Detection of CH3SH indicates that there may be several new families of S-bearing molecules (which could form starting from CH3SH) which have not been detected or looked for yet.

DUST AND POLYCYCLIC AROMATIC HYDROCARBON IN THE PRE-TRANSITIONAL DISK AROUND HD 169142

ABSTRACT The pre-transitional disk around the Herbig Ae star HD 169142 shows a complex structure of possible ongoing planet formation in dust thermal emission from the near-infrared (IR) to millimeter wavelength range. Also, a distinct set of broad emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 &mgr; m ?> , commonly attributed to polycyclic aromatic hydrocarbons (PAHs), is detected prominently in the HD 169142 disk. We model the spectral energy distribution (SED) as well as the PAH emission features of the HD 169142 disk simultaneously with porous dust and astronomical-PAHs, taking into account the spatially resolved disk structure. Our porous dust model, consisting of three distinct components that are primarily concentrated in the inner ring, middle ring, and outer disk, provides an excellent fit to the entire SED, and the PAH model closely reproduces the observed PAH features. The accretion of ice mantles onto porous dust aggregates occurs between ∼16 and 60 AU ?> , which overlaps with the spatial extent (∼ 50 AU ?> ) of the observed PAH emission features. Finally, we discuss the role of PAHs in the formation of planets possibly taking place in the HD 169142 system.

A 1-D evolutionary model for icy satellites, applied to Enceladus

We develop a long-term 1-D evolution model for icy satellites that couples multiple processes: water migration and differentiation, geochemical reactions and silicate phase transitions, compaction by self-gravity, and ablation. The model further considers the following energy sources and sinks: tidal heating, radiogenic heating, geochemical energy released by serpentinization or absorbed by mineral dehydration, gravitational energy and insolation, and heat transport by conduction, convection, and advection. We apply the model to Enceladus, by guessing the initial conditions that would render a structure compatible with present-day observations, assuming the initial structure to have been homogeneous. Assuming the satellite has been losing water continually along its evolution, we postulate that it was formed as a more massive, more icy and more porous satellite, and gradually transformed into its present day state due to sustained long-term tidal heating. We consider several initial compositions and evolution scenarios and follow the evolution for the age of the Solar System, testing the present day model results against the available observational constraints. Our model shows the present configuration to be differentiated into a pure icy mantle, several tens of km thick, overlying a rocky core, composed of dehydrated rock at the center and hydrated rock in the outer part. For Enceladus, it predicts a higher rock/ice mass ratio than previously assumed and a thinner ice mantle, compatible with recent estimates based on gravity field measurements. Although, obviously, the model cannot be used to explain local phenomena, it sheds light on the internal structure invoked in explanations of localized features and activities.

The sulfur depletion problem: upper limits on the H2S2, HS·2, and S2gas-phase abundances toward the low-mass warm core IRAS 16293-2422

A fraction of the missing sulfur in dense clouds and circumstellar regions could be in the form of three species not yet de- tected in the interstellar medium: H2S2, HS2, and S2 according to experimental simulations performed under astrophysically relevant conditions. These S-S bonded molecules can be formed by the energetic processing of H2S-bearing ice mantles on dust grains, and subsequently desorb to the gas phase. The detection of these species could partially solve the sulfur depletion problem, and would help to improve our knowledge of the poorly known chemistry of sulfur in the interstellar medium. To this purpose we performed dedicated ground-based observations toward the low-mass warm core IRAS16293-2422. Observations in the submillimeter regime were obtained with the APEX 12 m telescope during 15 hours of observation, targeting a wide selection of the predicted rotational transitions of the three molecules. The 1{\sigma} noise rms values were extracted in the spectral regions where the targeted species should have been detected. These values were a factor of 2-7 lower than those reached by previous observations toward the same source, and allowed us to estimate a 1{\sigma} upper limit to their molecular abundances of 8.1E-9 , 1.1E-8 , and 2.9E-7 relative to H2, for H2S2, HS2, and S2, respectively. The upper limit abundances of the three molecules containing the S2 unit are up to two orders of magnitude lower than the H2S abundance in the source, and one order of magnitude lower than the expected abundances from the experimental simulations using ice analogs. Subsequent gas-phase chemistry after desorption could lower the abundances of the three species to undetectable levels in our observations.

Geochemistry, thermal evolution, and cryovolcanism on Ceres with a muddy ice mantle

AbstractWe present a model of the internal evolution of Ceres consistent with pre‐Dawn observations and preliminary data returned by Dawn. We assume that Ceres accreted ice and both micron‐ and millimeter‐sized rock particles and that micron‐sized fines stayed suspended in liquid during differentiation. We conclude that aqueously altered grains were emplaced on Ceres's surface during the first tens of megayears of its evolution. Our geochemical simulations suggest that Ceres's unusual surface mineralogy is consistent with aqueous alteration of CM material, possibly by NH3‐bearing fluid. Thermal evolution simulations including insulating fines yield present‐day liquid at depth if Ceres has a small core or no core at all; otherwise, they yield temperatures at the core‐mantle boundary of 240–250 K, just warm enough for chloride brines to persist and be freezing today. We hypothesize that ongoing freezing may overpressurize liquid or briny reservoirs, driving cryovolcanic outflow whose surface expression may have been observed by Dawn at Ceres's “bright spots.” These outflows may contribute to the water vapor being produced at Ceres.

A tunnel and a traffic jam: How transition disks maintain a detectable warm dust component despite the presence of a large planet-carved gap

We combined hydrodynamical simulations of planet-disk interactions with dust evolution models that include coagulation and fragmentation of dust grains over a large range of radii and derived observational properties using radiative transfer calculations. We studied the role of the snow line in the survival of the inner disk of transition disks. Inside the snow line, the lack of ice mantles in dust particles decreases the sticking efficiency between grains. As a consequence, particles fragment at lower collision velocities than in regions beyond the snow line. This effect allows small particles to be maintained for up to a few Myrs within the first astronomical unit. These particles are closely coupled to the gas and do not drift significantly with respect to the gas. For lower mass planets (1$M_{\rm{Jup}}$), the pre-transition appearance can be maintained even longer because dust still trickles through the gap created by the planet, moves invisibly and quickly in the form of relatively large grains through the gap, and becomes visible again as it fragments and gets slowed down inside of the snow line. The global study of dust evolution of a disk with an embedded planet, including the changes of the dust aerodynamics near the snow line, can explain the concentration of millimetre-sized particles in the outer disk and the survival of the dust in the inner disk if a large dust trap is present in the outer disk. This behaviour solves the conundrum of the combination of both near-infrared excess and ring-like millimetre emission observed in several transition disks.

H-atom addition and abstraction reactions in mixed CO, H2CO and CH3OH ices – an extended view on complex organic molecule formation

Complex organic molecules (COMs) have been observed not only in the hot cores surrounding low- and high- mass protostars, but also in cold dark clouds. Therefore, it is interesting to understand how such species can be formed without the presence of embedded energy sources. We present new laboratory experiments on the low-temperature solid state formation of three complex molecules: methyl formate (HC(O)OCH3), glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH), through recombination of free radicals formed via H-atom addition and abstraction reactions at different stages in the CO-H2CO-CH3OH hydrogenation network at 15 K. The experiments extend previous CO hydrogenation studies and aim at resembling the physical&chemical conditions typical of the CO freeze-out stage in dark molecular clouds, when H2CO and CH3OH form by recombination of accreting CO molecules and H-atoms on ice grains. We confirm that H2CO, once formed through CO hydrogenation, not only yields CH3OH through ongoing H-atom addition reactions, but is also subject to H-atom-induced abstraction reactions, yielding CO again. In a similar way, H2CO is also formed in abstraction reactions involving CH3OH. The dominant methanol H-atom abstraction product is expected to be CH2OH, while H-atom additions to H2CO should at least partially proceed through CH3O intermediate radicals. The occurrence of H-atom abstraction reactions in ice mantles leads to more reactive intermediates (HCO, CH3O and CH2OH) than previously thought, when assuming sequential H-atom addition reactions only. This enhances the probability to form COMs through radical-radical recombination without the need of UV photolysis or cosmic rays as external triggers.

SPECTROSCOPIC INFRARED EXTINCTION MAPPING AS A PROBE OF GRAIN GROWTH IN IRDCs

We present spectroscopic tests of MIR to FIR extinction laws in IRDC G028.36+00.07, a potential site of massive star and star cluster formation. Lim & Tan (2014) developed methods of FIR extinction mapping of this source using ${\it Spitzer}$-MIPS ${\rm 24\mu m}$ and ${\it Herschel}$-PACS ${\rm 70\mu m}$ images, and by comparing to MIR ${\it Spitzer}$-IRAC $3$--${\rm 8\mu m}$ extinction maps, found tentative evidence for grain growth in the highest mass surface density regions. Here we present results of spectroscopic infrared extinction (SIREX) mapping using ${\it Spitzer}$-IRS (14 to ${\rm 38\mu m}$) data of the same IRDC. These methods allow us to first measure the SED of the diffuse Galactic ISM that is in the foreground of the IRDC. We then carry out our primary investigation of measuring the MIR to FIR opacity law and searching for potential variations as a function of mass surface density within the IRDC. We find relatively flat, featureless MIR-FIR opacity laws that lack the $\sim{\rm 12\mu m}$ and $\sim{\rm 35\mu m}$ features associated with the thick water ice mantle models of Ossenkopf & Henning (1994). Their thin ice mantle models and the coagulating aggregate dust models of Ormel et al. (2011) are a generally better match to the observed opacity laws. We also find evidence for generally flatter MIR to FIR extinction laws as mass surface density increases, strengthening the evidence for grain and ice mantle growth in higher density regions.

UV photoprocessing of CO2ice: a complete quantification of photochemistry and photon-induced desorption processes

Context. Ice mantles that formed on top of dust grains are photoprocessed by the secondary ultraviolet (UV) field in cold and dense molecular clouds. UV photons induce photochemistry and desorption of ice molecules. Experimental simulations dedicated to ice analogs under astrophysically relevant conditions are needed to understand these processes.Aims. We present UV-irradiation experiments of a pure CO2 ice analog. Calibration of the quadrupole mass spectrometer allowed us to quantify the photodesorption of molecules to the gas phase. This information was added to the data provided by the Fourier transform infrared spectrometer on the solid phase to obtain a complete quantitative study of the UV photoprocessing of an ice analog.Methods. Experimental simulations were performed in an ultra-high vacuum chamber. Ice samples were deposited onto an infrared transparent window at 8K and were subsequently irradiated with a microwave-discharged hydrogen flow lamp. After irradiation, ice samples were warmed up until complete sublimation was attained.Results. Photolysis of CO2 molecules initiates a network of photon-induced chemical reactions leading to the formation of CO, CO3 , O2 , and O3 . During irradiation, photon-induced desorption of CO and, to a lesser extent, O2 and CO2 took place through a process called indirect desorption induced by electronic transitions, with maximum photodesorption yields (Y pd ) of ~1.2 × 10-2 molecules incident photon-1 , ~9.3 × 10-4 molecules incident photon-1 , and ~1.1 × 10-4 molecules incident photon-1 , respectively.Conclusions. Calibration of mass spectrometers allows a direct quantification of photodesorption yields instead of the indirect values that were obtained from infrared spectra in most previous works. Supplementary information provided by infrared spectroscopy leads to a complete quantification, and therefore a better understanding, of the processes taking place in UV-irradiated ice mantles.

Cosmic Rays and the Origin of Volatiles in Protoplanetary Disks

AbstractThe origin of water and other volatiles in protoplanetary disks can be either interstellar or due to chemical processing during the protoplanetary disk phase. Depending on the strength of the ionization field present during this stage, an active chemical evolution in the protoplanetary disk midplane can lead to formation of complex volatiles on timescales shorter than the disk dissipation timescale. For this reason, we investigate the effects of cosmic rays and the usually neglected cosmic ray induced UV ionization field in time dependent chemical models of protoplanetary disks. These results are benchmarked against our current knowledge of the chemical composition of cometary ices. We conclude that water and other, more complex volatiles can be preserved in the ice mantles of dust grains. This ice mantle growth can also have a significant impact on the dust opacity and hence on the temperature profile of the disk midplane. This effect will be observable in the near future with ALMA.

Swift heavy ion modifications of astrophysical water ice

In the relatively shielded environments provided by interstellar dense clouds in our Galaxy, infrared astronomical observations have early revealed the presence of low temperature (10–100K) ice mantles covering tiny grain “cores” composed of more refractory material. These ices are of specific interest because they constitute an interface between a solid phase under complex evolution triggered by energetic processes and surface reactions, with a rich chemistry taking place in the gas phase. The interstellar ice mantles present in these environments are immersed, in addition to other existing radiations fields, in a flux of cosmic ray particles that can produce new species via radiolysis processes, but first affects their structure, which may change and also induces desorption of molecules and radicals from these grains. Theses cosmic rays are simulated by swift ions in the laboratory for a better understanding of astrophysical processes.

Astrochemical models of water

AbstractWe will review the chemical reaction network models of water and its D/H ratio coupled with the dynamics of star formation. Infrared observations show that water ice is abundant even in molecular clouds with relatively low visual extinction (~ 3 mag), which indicates that water ice is formed in early stage of molecular clouds. We thus start from a possible formation site of molecular clouds, i.e. the converging flow of diffuse gas. Then we proceed to dense cloud cores and its gravitational collapse, during which a significant deuterium enrichment occurs. The gas and ice accrete onto the circumstellar disks, which evolve to protoplanetary disks in T Tauri phase. If the disks are turbulent, water could be photodissociated in the disk surface and re-formed in deeper layers. The cycle continues until the dust grains with ice mantle are decoupled from the turbulence and settle to the midplane. The water D/H ratio could thus vary within the disk.