Hysteresis Coefficient Research Articles

Evaluation study for phosphorus mobilisation-release behaviour on different marine sediments: focus on phosphate sorption characteristics

Environmental contextPhosphorus is a key nutrient element associated with eutrophication in aquatic ecosystems. We studied phosphate sorption processes, which play a key role in phosphorus cycling, in sediments collected from 23 sites including estuary, coastal sea and aquaculture areas in China. The results show the influence of sediment type on phosphorus buffering capacity and allow better interpretation of phosphorus migration in aquatic ecosystems. AbstractPhosphorus is well known as an important nutrient element associated with eutrophication in the marine ecosystem, and its sorption on sediments plays a key role in its immobilisation in the bio-geochemical cycle. In this paper, the sorption behaviour of phosphorus onto sediments collected from 23 different sites in estuary, coastal sea and aquaculture areas of China was studied. The main aim is to determine the phosphorus sorption characteristics of these sediments thereby assessing their phosphorus buffering capacities. Both kinetic and equilibrium isotherms of the sorption and desorption of phosphorus were assessed. The resultant sorption and desorption kinetic curves fit well to a two-compartment first-order equation. The equilibration time was considered as 48h. The isotherms agreed well with the Freundlich and Langmuir equations. The hysteresis coefficient values showed an obvious sorption-desorption hysteresis. Decreasing salinity was favourable for the sorption ability in the range from 30 to 3. The mean values of the phosphorus sorption-desorption equilibrium concentration and the maximum phosphorus sorption capacity were 0.098mgL−1 and 0.086mgg−1 for sediments in the Changjiang Estuary and East China Sea shelf, and 0.138mgL−1 and 0.067mgg−1 for the sediments in the aquaculture area. The fractions of clay, calcite and organic matter influenced the sorption and retention abilities and the effects were different for sediments obtained from different origins.

Adsorption and Desorption Behaviors of Spirotetramat in Various Soils and Its Interaction Mechanism.

Spirotetramat is a pesticide with bidirectional systemicity and can effectively control pests by inhibiting the biosynthesis of fatty acids. In this study, adsorption and desorption behaviors of spirotetramat in six soils and its interaction mechanism were studied using the batch equilibrium method and infrared radiation. The results showed that the adsorption and desorption behaviors of spirotetramat conformed to the Freundlich isotherm model. The values of adsorption capacities KF-ads ranged from 2.11 to 12.40, and the values of desorption capacities KF-des varied from 2.97 to 32.90. From the hysteresis coefficient, spirotetramat was easily desorbed from the test soils. The adsorption capacity of the soil to spirotetramat enhanced with an increasing temperature. Moreover, the changes in pH values and exogenous addition of humic acid and surfactant could also affect soil adsorption capacity, but for desorption, there was no correlation.

An investigation of fretting behavior of thermoplastic polyurethane for mechanical seal application

For seals in dynamic applications, fretting is one of the most common types of failure. In this study, the fretting behavior of thermoplastic polyurethane (TPU) was investigated. The hysteresis behavior, wear scar and coefficient of friction were analyzed in detail. Various wear mechanisms and their influences on the fretting behavior were examined. A new method was introduced to calculate the coefficient of friction for late cycles in gross slip regime. It takes the surface damage and the dynamic influence of the test system into consideration. Besides, the dependency of fretting behavior on displacement amplitudes, normal loads were investigated.

High electric field-induced strain with ultra-low hysteresis and giant electrostrictive coefficient in barium strontium titanate lead-free ferroelectrics

Ferroelectrics with high electrostrictive properties are of great interest in fundamental researches and industrial applications. In this work, the phase structural evolution, dielectric properties as well as electrostrictive properties in barium strontium titanate [(Ba1-xSrx)TiO3, BST] lead-free ferroelectrics with x from 0.05 to 0.4 were investigated in details. High electric field-induced strain (∼0.2%) at 60 kV/cm are obtained in x = 0.05 and 0.1 compositions. More importantly, almost purely positive strains with ultra-low hysteresis (<8%) determined from bipolar strain-electric field curves are observed in compositions with x from 0.05 to 0.3, suggesting the dominating role of electrostrictive effect. Temperature-insensitive and composition-insensitive longitudinal electrostrictive coefficient Q33 for BST ceramics with giant values from 0.0409 m4/C2 to 0.0479 m4/C2 is identified. These features suggest that BST ceramics not only possess high electric field-induced strain with ultra-low hysteresis and giant Q33, but also are good candidates for potential application in high-precision actuator devices.

The numerical study of the effect of design parameters on EWOD actuation in microchannels of rectangular cross section

Electrowetting on Dielectric (EWOD) method is widely used to actuate microdroplets sandwiched between parallel plates in microfluidic chips. However, utilization of this method to transport liquid plugs in conduits has not been comprehensively studied to date. In this paper, the EWOD actuation of a liquid plug confined in a microchannel of rectangular cross section is numerically studied using OpenFoam. The effect of various parameters including electrowetting dimensionless number ( $$\eta $$ ), contact angle hysteresis (CAH), dynamic viscosity and surface tension coefficient on transport velocity is investigated by employing an interactive simulation approach. The transport velocity can be considered a gauge to evaluate the actuation efficiency. The results show that, increasing $$\eta $$ has a greater impact on velocity for larger values of CAH. In addition, it is shown that the average velocity increases linearly by increasing the surface tension coefficient. An inverse relationship between velocity and dynamic viscosity is also observed. These trends are in accordance with the theoretical model developed for a similar case in the literature. To estimate the maximum possible gap size between electrodes (MPGS), non-actuated distance travelled before the liquid plug comes to stop is evaluated. The results show that by decreasing the values of $$\eta $$ , the effect of changing CAH on MPGS becomes more substantial.

Time and temperature dependent adsorption-desorption behaviour of pretilachlor in soil

Understanding and quantifying the adsorption-desorption behaviour of herbicide in soil is imperative for predicting their fate and transport in the environment. In the present study, the effect of time and temperature on the adsorption–desorption behaviour of pretilachlor in soils was investigated using batch equilibration technique. The adsorption–desorption kinetics of pretilachlor in soils was two step process and was well described by pseudo-second-order kinetic model. Freundlich model accurately predicted the sorption behaviour of pretilachlor. The adsorption–desorption of pretilachlor varied significantly with the concentration, temperature and properties of soil viz. organic matter and clay content. All the studied soils had non-linear slopes (n < 1) and degree of nonlinearity increased with increase in clay, organic matter content and temperature (p < 0.05). Desorption of pretilachlor was hysteretic in studied soils and hysteresis coefficient varied from 0.023 to 0.275. Thermodynamic analysis showed that pretilachlor adsorption onto soils was a feasible, spontaneous and endothermic process which becomes more favourable at high temperature. It could be inferred that the adsorption of pretilachlor on soils was physical in nature.

Sorption and desorption of glyphosate in Mollisols and Ultisols soils of Argentina.

In Argentina, glyphosate use has increased exponentially in recent years as a result of the widespread adoption of no-till management combined with genetically modified glyphosate-resistant crops. This massive use of glyphosate has created concern about its potential environmental impact. Sorption-desorption of glyphosate was studied in 3 Argentinean soils with contrasting characteristics. Glyphosate sorption isotherms were modeled using the Freundlich equation to estimate the sorption coefficient (Kf ). Glyphosate sorption was high, and the Kf varied from 115.6 to 1612 mg1-1/n L1/n /kg. Cerro Azul soil had the highest glyphosate sorption capacity as a result of a combination of factors such as higher clay content, cation exchange capacity, total iron, and aluminum oxides, and lower available phosphorus and pH. Desorption isotherms were also modeled using the Freundlich equation. In general, desorption was very low (<12%). The low values of hysteresis coefficient confirm that glyphosate strongly sorbs to the soils and that it is almost an irreversible process. Anguil soil had a significantly higher desorption coefficient (Kfd ) than the other soils, associated with its lower clay content and higher pH and phosphorus. Glyphosate high sorption and low desorption to the studied soils may prevent groundwater contamination. However, it may also affect its bioavailability, increasing its persistence and favoring its accumulation in the environment. The results of the present study contribute to the knowledge and characterization of glyphosate retention in different soils. Environ Toxicol Chem 2017;36:2587-2592. © 2017 SETAC.

Exceptionally High Piezoelectric Coefficient and Low Strain Hysteresis in Grain-Oriented (Ba, Ca)(Ti, Zr)O3 through Integrating Crystallographic Texture and Domain Engineering.

Both low strain hysteresis and high piezoelectric performance are required for practical applications in precisely controlled piezoelectric devices and systems. Unfortunately, enhanced piezoelectric properties were usually obtained with the presence of a large strain hysteresis in BaTiO3 (BT)-based piezoceramics. In this work, we propose to integrate crystallographic texturing and domain engineering strategies into BT-based ceramics to resolve this challenge. [001]c grain-oriented (Ba0.94Ca0.06)(Ti0.95Zr0.05)O3 (BCTZ) ceramics with a texture degree as high as 98.6% were synthesized by templated grain growth. A very high piezoelectric coefficient (d33) of 755 pC/N, and an extremely large piezoelectric strain coefficient (d33* = 2027 pm/V) along with an ultralow strain hysteresis (Hs) of 4.1% were simultaneously achieved in BT-based systems for the first time, which are among the best values ever reported on both lead-free and lead-based piezoceramics. The exceptionally high piezoelectric response is mainly from the reversible contribution, and can be ascribed to the piezoelectric anisotropy, the favorable domain configuration, and the formation of smaller sized domains in the BCTZ textured ceramics. This study paves a new pathway to develop lead-free piezoelectrics with both low strain hysteresis and high piezoelectric coefficient. More importantly, it represents a very exciting discovery with potential application of BT-based ceramics in high-precision piezoelectric actuators.

First principle study: parametric investigation of the mechanics of elastic and inelastic textile materials for the determination of compression therapy efficacy

Vascular diseases are among the most common diseases in the world. Whether acute or chronic cases, compression therapy by bandaging is a well-known treatment for the majority of these diseases. In the textile processing of bandages, the influence of material chemistry (e.g. viscosity), the laws of physics (e.g. resiliency), and the medical requirements in the therapy must be taken into account. Furthermore, knowledge of the textile material helps us to understand why bandages do or do not have the desired effect. This paper provides a study of the Dynamic Hysteresis Coefficient (DHC) and lengthening, allowing the examination of compression bandage systems used in phlebology and lymphology using a novel measurement parameter. Compression bandage systems were subjected to a dynamic hysteresis test on a dynamometer, enabling estimation of the DHC and the lengthening (Δ L2) after five consecutive cycles. Evaluation of the findings indicates that the therapeutical stiffness index of the compression bandages can be reliably estimated using this new method. These findings show that inelastic compression bandage systems with elastomers can achieve a sustainable compression therapy over several days. DHC and Δ L2 are proven to be highly reliable parameters for comparing different compression bandage systems.

Analyzing Hysteresis and Thermal Expansion Coefficient of M40/AZ91D during Thermal Cycling

In this work, AZ91D composite reinforced with M40 fiber was prepared by pressure impregnation method. Expansion behaviors of M40/AZ91D composite were studied with thermal expansion instrument in 25-150 °C and 25-150 °C temperature ranges of internal heat circulation, and then analyzed the influence law of hysteresis, residual strain and coefficient of thermal expansion (CTE) by different temperature change rate. The results revealed that residual stress and strain in process of pressure impregnation would lead to strain hysteresis and residual strain of composite in thermal cycling. At the same time, the CTE of the composites decreased with the increase of cycle times. Residual strain of the composite went up with the rise of temperature changed rate of the thermal cycling and CTE decreased with temperature change rate ascending in the 25-150°C temperature range. The CTE of the composites decreased with the increase of temperature during the heating process, which cut down with the increase of temperature in process of heating and cooling in the 25-495°C temperature range.

Sorption potential of different biomass fly ashes for the removal of diuron and 3,4-dichloroaniline from water

Hazardous contaminants in water and biomass fly ash spillage are causes for environmental and health concern. We selected five fly ashes generated from olive-mill (O,P, G and H) and greenhouse vegetable (I) waste used as biomass fuel in order to quantify their capacity to remove diuron and 3,4-dichloroaniline (DCA) from water. To understand the sorption processes involved, four kinetic models and two adsorption isotherms were assayed. The pseudo second-order kinetic showed the best fit (R2>0.99). The initial adsorption rate constant was found to be faster for DCA than for diuron. The Freundlich adsorption constants of ashes O, P, G and H for diuron were more than 2-fold higher than for DCA (Kf=109–16μg1−1/ng−1mL−1). The alkaline pH of these fly ashes plays an important role in the adsorption process. Sorption/desorption processes were significantly affected by iron oxide content. DCA sorption was also influenced by particle size and carbon content. Low hysteresis coefficient values (H=0.01–0.26) revealed an irreversible sorption process. The study presents novel information on the immobilization of hazardous chemicals in water by biomass fly ashes generated from olive-oil industry and greenhouse crop waste.

A Numerical Study of Two-Phase Flow Models with Dynamic Capillary Pressure and Hysteresis

Saturation overshoot and pressure overshoot are studied by incorporating dynamic capillary pressure, capillary pressure hysteresis and hysteretic dynamic coefficient with a traditional fractional flow equation in one-dimensional space. Using the method of lines, the discretizations are constructed by applying the Castillo–Grone’s mimetic operators in the space direction and a semi-implicit integrator in the time direction. Convergence tests and conservation properties of the schemes are presented. Computed profiles capture both the saturation overshoot and pressure overshoot phenomena. Comparisons between numerical results and experiments illustrate the effectiveness and different features of the models.

Research on strip hysteretic behavior and mill vertical vibration system nonlinear dynamics

Rolling mill vibration is a technical problem in the iron and steel industry for many years and has serious impact and harm on production. There were serious vibrations in the middle mills when rolling thin container strip for the compact strip production (CSP) strip hot rolling process. This paper studied the hysteretic characteristic of rolled strip and established the vertical vibration system single-degree-of-freedom dynamics model of the F3 mill rollers. The influence of parameters on the system characteristics was studied, such as the linear damping coefficient, linear stiffness coefficient, nonlinear displacement coefficient, nonlinear velocity coefficient and exciting force, and then, the vibration source and vibration-restraining measure were studied from the roll gap. The results show that with increasing linear stiffness, damping and hysteresis coefficient, it can reduce the possibility of chaotic system; the linear stiffness coefficient had the greatest influence, and hysteresis damping coefficient had minimal influence on chaotic threshold. In order to reduce rolling mill vibration amplitude, we should reduce the external excitation force firstly, and in order to improve the dynamic performance of the system, we should control the speed of nonlinear coefficient values. The contrast experiments were carried out at the production scene finally.

Defect dipole induced large recoverable strain and high energy-storage density in lead-free Na0.5Bi0.5TiO3-based systems

In this letter, we propose an effective route to obtain large recoverable strain, purely electrostrictive effects and high energy-storage density by inducing defect dipoles into Na0.5Bi0.5TiO3 (NBT)-based relaxor ferroelectrics. It has been found that pinched and double polarization hysteresis loops with high maximum polarization (Pmax) and negligible remanent polarization (Pr) can be observed due to the presence of acceptor-induced defect dipoles. A large recoverable strain of 0.24% with very little hysteresis and high electrostriction coefficient of 0.022 m4 C2 with purely electrostrictive characteristics were acquired when 11 mol. ‰ Mn-doped. Meanwhile, a high recoverable energy density of 1.06 J/cm3 with excellent temperature stability was obtained at the same composition owing to the enlarged value of Pmax-Pr (36.8 μC/cm2) and relatively high electric field (95 kV/cm). Our achievement can open up the exciting opportunities for ferroelectric materials in high-precision positioning devices and high electric power pulse energy storage applications.

Effect of soil type and organic manure on adsorption-desorption of flubendiamide.

Laboratory study on adsorption-desorption of flubendiamide was conducted in two soil types, varying in their physical and chemical properties, by batch equilibrium method. After 4 h of equilibrium time, adsorption of flubendiamide on soil matrix exhibited moderately low rate of accumulation with 4.52 ± 0.21% in red soil and low rate with 3.55 ± 0.21% in black soil. After amending soils with organic manure, adsorption percentage increased to 6.42 ± 0.21% in red soil and (4.18 ± 0.21%) in black soil indicating that amendment significantly increased sorption. Variation in sorption affinities of the soils as indicated by distribution coefficient (K d) for sorption was in the range of 2.98-4.32, 4.91-6.64, 1.04-1.45 and 1.92-2.81 ml/g for red soil, organic manure-treated red soil, black soil and organic manure-treated black soil, respectively. Desorption was slightly slower than adsorption indicating a hysteresis effect having hysteresis coefficient ranges between 0.023 and 0.149 in two test soils. The adsorption data for the insecticide fitted well the Freundlich equation. Results revealed that adsorption-desorption was influenced by soil types and showed that the maximum sorption and minimum desorption of the insecticide was observed in soils with higher organic carbon and clay content. It can be inferred that crystal lattice of the clay soil plays a significant role in flubendiamide adsorption and desorption. Adsorption was lower at acidic pH and gradually increased towards alkaline pH. As this insecticide is poorly sorbed in the two Indian soil types, there may be a possibility of their leaching to lower soil profiles.

PET, Tencel, Cotton MVS 혼방사의 섬도와 혼용률에 따른 물성 특성

This study investigates the physical properties of Murata Vortex Spinning (MVS) blended yarn with yarn count(20's, 30's, 40's) and blend ratio(Polyester 100, Polyester70:Cotton30, Polyester50:Cotton50, Polyester30:Cotton70, and Polyester50:Tencel40:Cotton10). This study evaluated tenacity, elongation, bending rigidity, bending hysteresis, hairiness coefficient, irregularity and twist number. The structure of MVS blended yarn influenced stress, strain, bending rigidity, bending hysteresis and the hairiness coefficient of MVS blended yarn decreased as the yarn count increased. MVS blended yarn consists of core and sheath. The core of MVS blended yarn is composed of a parallel fiber with a wrapping fiber that covers thecore fiber. This special structure of the MVS blended yarn effects the physical properties of the yarn; in addition, the mechanical properties of the component fibers influenced the stress, strain, bending rigidity, bending hysteresis and hairiness coefficient of MVS blended yarn with the blend ratio. Polyester decreases and cotton increases resulted in decreased physical properties. A similar polyester content increased the tencel and physical properties. Appropriate physical properties and a variety of touch expression can be realized through a correct blend ratio.

Effect of Reactive Monomer Concentration on Electro-Optical Properties in Polymer-Stabilized Blue Phase Liquid Crystals with Identical Chiral Dopant Concentrations

The effects of reactive monomer concentration on electro-optical properties were investigated using polymer-stabilized blue phase (PS-BP) liquid crystals (LCs) with different reactive monomer concentrations but identical chiral dopant concentrations. We found that the driving voltage was increased with increase in the reactive monomer concentration, whereas the switching hysteresis and Kerr coefficient were decreased with increase in the reactive monomer concentration in PS-BP LCs with identical chiral dopant concentrations. In addition, we found that the activation energy of electro-optical rising time was increased with increase in the reactive monomer concentration, whereas that of electro-optical decay, time was slightly decreased with increase in the reactive monomer concentration in PS-BP LCs.

Adsorption-desorption of tricyclazole: effect of soil types and organic matter.

Adsorption-desorption of tricyclazole was studied by batch equilibrium method in two soil types, varying in their physical and chemical properties. The adsorption of tricyclazole on the soil matrix exhibited low rate of accumulation with 18.24 ± 0.14 % in Ultisol and moderately high rate with 43.62 ± 0.14 % in Vertisol after 6 h of equilibrium time. For soils amended with farmyard manure (FYM), the adsorption percentage increased to 32.52 ± 0.14 % in Ultisol and 55.14 ± 0.14 % in Vertisol. The Freundlich model was used to describe the adsorption-desorption of the tricyclazole in two soils. The adsorption isotherm suggested a relatively higher affinity of tricyclazole to the adsorption sites at low equilibrium concentrations. Variation in sorption affinities of the soils as indicated by the distribution coefficient (K d) for sorption in the range of 0.78 ± 0.01-1.38 ± 0.03, 1.71 ± 0.03-2.99 ± 0.09, 2.75 ± 0.05-4.69 ± 0.01, and 4.65 ± 0.08-7.64 ± 0.01 mL/g for Ultisol, FYM-amended Ultisol, Vertisol, and FYM-amended Vertisol, respectively. Desorption was slower than adsorption, indicating a hysteresis effect. The hysteresis coefficient varied from 0.023 ± 0.15 to 0.160 ± 0.12 in two test soils. A good fit to the linear and Freundlich isotherms was observed with correlation coefficients >0.96. The results revealed that adsorption-desorption was influenced by soil properties and showed that the maximum sorption and minimum desorption of pesticide were observed in soils with higher organic carbon and clay content. Thus, groundwater contamination may be minimized, on application of tricyclazole in high-sorption soils of rice-growing regions.

Variability in biomechanical properties of the fibrous tunic of the eye in a healthy population

Studying biomechanical properties of the fibrous tunic of the eye meets current clinical demands. Previous studies have proved bidirectional corneal applanation suitable for this purpose. The so called corneal elasticity coefficient is more informative in terms of corneal elastance than the two other parameters measured during bidirectional corneal applanation, namely, corneal resistance factor and corneal hysteresis. All three are known to have wide normal ranges. The aim of the present study was to determine the range of corneal resistance factor, corneal hysteresis, and corneal elasticity coefficient in a normal population. This work summarizes data from 2205 patients (4410 eyes) with no ophthalmic pathology who got their ocular biomechanics examined with an Ocular Response Analyzer. Normal ranges of biomechanical parameters of the fibrous tunic have been determined. Considerable variation has been demonstrated in central corneal thickness (from 448 to 685 µm, with the mean of 563 ± 37 µm). Moreover, the corneal resistance factor, corneal hysteresis, and corneal elasticity coefficient have been shown to have almost equal means and to decrease with age.

Magnetic resonance imaging (MRI) of jet height hysteresis in packed beds

The hysteresis in the jet–spout transition in packed beds was systematically investigated using magnetic resonance imaging (MRI) and pressure measurements. Specifically, the hysteresis in the jet height as a function of the orifice velocity was studied as a function of particle type, bed dimension and fill level. In order to compare the hysteresis of different experimental configurations, a hysteresis coefficient h=(Usf−Ums)/Usf was introduced. It was observed that an increase in the fill level or the bed dimensions resulted in higher values of h. It was also found that the hysteresis is most pronounced for non-spherical particles, whereas no hysteresis was observed for the most spherical particles when placed in the smallest bed. In addition, pressure measurements were used to explore the relationship between the pressure drop and the jet height.