This article formulates the daily economic/environmental hydrothermal scheduling problem as a multi-objective optimization problem. By introducing non-dominated sorting and crowding distance, the multi-objective artificial physical optimization algorithm is proposed to solve the daily economic/environmental hydrothermal scheduling problem. To enhance the performance of the proposed algorithm, new velocity update equation, which takes advantage of the individual memory and population information, is utilized. To overcome the drawback of premature convergence, a chaotic mutation is adopted in the multi-objective artificial physical optimization algorithm. Especially for handling the equality constraints of daily economic/environmental hydrothermal scheduling, novel heuristic strategies are developed to repair the infeasible solutions. To demonstrate the effectiveness of the multi-objective artificial physical optimization algorithm for solving daily economic/environmental hydrothermal scheduling, the proposed method is implemented on a hydrothermal system and the numerical results are compared with several optimization approaches. It demonstrates that the proposed multi-objective artificial physical optimization algorithm is competent as an alternative for the daily economic/environmental hydrothermal scheduling problem.