Hydrostatic Conditions Research Articles

Structural and Electronic Phase Transitions in Three Stable Tin-Sulfur Metallic Chalcogenides under High Pressure.

As a representative homologous series, tin-bearing metallic chalcogenides (SnxSy) have sparked considerable attention because of their stoichiometric compositions and structural diversities. In this work, three stable compounds, SnS, Sn2S3, and SnS2, were screened from SnxSy and a comprehensive investigation on their structural and electrical transport properties was performed up to 60.1 GPa using a diamond anvil cell (DAC) under different hydrostatic environments. Upon nonhydrostatic compression, SnS underwent the Pnma-to-Cmcm transition accompanied by metallization at 7.6 GPa, followed by the Cmcm-to-Pm3̅m transformation at 17.8 GPa. For SnS2, the pressure-induced metallization and isostructural phase transition (IPT) occurred successively at 31.2 and 46.6 GPa, respectively. As an intermediate composition, Sn2S3 first experienced an IPT at 10.8 GPa, and then, the Pnma-to-Cmcm transition concomitantly with metallization occurred at 16.9 GPa, analogous to the high-pressure structural transformation routes of SnS and SnS2. The 0.6-5.4 GPa pressure hysteresis was detectable for the phase transitions of SnxSy under quasi-hydrostatic and hydrostatic conditions owing to the influence of deviatoric stress. In comprehensive consideration of our high-pressure Raman scattering and electrical conductivity results, the systematic construction of a pressure-phase state diagram on SnxSy not only unveils its composition-structure-property relation but also advances the in-depth exploration for other IVA-VIA metallic chalcogenides.

Performance of Recycled Opaque PET Modified by Reactive Extrusion

A comparative study of the structural integrity of an opaque recycled poly(ethylene terephthalate) (rPET-O) has been carried out with two types of modified rPET-O by applying reactive extrusion techniques, namely (a) using a multi-epoxide reactive agent (REx-rPET-O) and (b) a 90/10 (wt/wt) rPET-O/polycarbonate (PC) blend. The chemical modifications introduced during reactive extrusion were confirmed using differential scanning calorimetry (DSC) and rheological dynamic analysis (RDA). For the quantification of the fracture parameters, an instrumented pendulum impact testing machine was used using specimens in SENB configuration. The structural modifications generated during reactive extrusion promote an increase of between 16 (REx-rPET-O) and 20% (rPET-O/PC) in the stress-intensity factor (KQ) compared to unmodified rPET-O. The most significant differences between both modifications are registered in the “specific work of fracture” (wf) (alternative parameter to the standardized impact strength), where an increase of 61% is reached for the case of rPET-O/PC and only 11% for REx-rPET-O. This trend can be attributed to the type of reactive modification that is generated, namely chain branching (REx-rPET-O) vs. the generation of a random copolymer “in situ” (rPET-O/PC). This copolymer decreases the crystallization capacity and degree of crystalline perfection of rPET-O, promoting an increase in the critical hydrostatic stress conditions for the generation of crazing and crack propagation.

Lateral Heterostructures Fabricated via Artificial Pressure Gradient.

Hydrostatic conditions are generally pursued in high-pressure research, maintained to prevent the intrinsic pressure gradient on the culets of diamond anvil cells (DACs) from introducing heterogeneity to the structure and physical properties of the regulated materials. Here, a pioneering route to fabricate lateral heterostructures is proposed via artificial pressure gradients intentionally designed in DACs. Under the tailored pressure gradients, different structural phases emerge in distinct parts of the material, resulting in the formation of heterostructures. Harnessing the polymorphic transition nature of violet phosphorus under high pressure, violet/blue and violet/black phosphorus lateral heterostructures with different electrical properties have been successfully prepared by the pressure gradient method. This achievement highlights the potential of artificial pressure gradients as a portable and universal strategy for the fabrication of lateral heterostructures, shedding new light on the preparation and regulation of lateral heterostructures across a wider range of materials.

New charged anisotropic solution in f(Q)-gravity and effect of non-metricity and electric charge parameters on constraining maximum mass of self-gravitating objects

In the present article, A new class of singularity-free charged anisotropic stars is derived in f(Q)-gravity regime. To solve the field equations, we assume a particular form of anisotropy along with an electric field and obtain a new exact solution in f(Q)-gravity. The explicit mathematical expression for the model parameters is derived by the smooth joining of the obtained solutions with the exterior Reissner–Nordstrom de-Sitter solution across the bounding surface of a compact star along with the requirement that the radial pressure vanishes at the boundary. We have modeled four self-gravitating pulsar objects such as LMC X-4, PSR J1903+327, PSR J1614-2230, and GW190814 in our current study and predict the radii of these objects that fall between 8 and 10 km. Furthermore, the physical validity of the solution is performed for self-gravitating object PSR J1614-2230 with mass 1.97±0.04M⊙\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$1.97\\pm 0.04~M_{\\odot }$$\\end{document} with radius 10 km. The solution successfully fulfills all the physical requirements along with the stability and hydrostatic equilibrium conditions for a well-behaved model. The non-metricity f(Q)-parameter χ1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\chi _{_1}$$\\end{document} and electric charge parameter η\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\eta $$\\end{document} play an important role in the maximum mass of the objects. The maximum mass increases when χ1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\chi _{_1}$$\\end{document} and η\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\eta $$\\end{document} increase but a non-collapsing stable object can be obtained when χ1≤0.0205\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\chi _{_1}\\le 0.0205$$\\end{document} and η≤0.0006\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\eta \\le 0.0006$$\\end{document}.

Stress-Induced Martensitic Transformation in Na3YCl6.

Martensitic transformation with volume expansion plays a crucial role in enhancing the mechanical properties of steel and partially stabilized zirconia. We believe that a similar concept could be applied to unexplored nonoxide materials. Herein, we report the stress-induced martensitic transformation of monoclinic Na3YCl6 with an ∼3.4% expansion. In situ synchrotron X-ray diffraction and atomistic simulations showed that anisotropic crystallographic transformation from monoclinic to rhombohedral Na3YCl6 occurs exclusively under uniaxial pressure; no effect is observed under hydrostatic pressure conditions. The uniaxially pressed powder compact of monoclinic Na3YCl6 showed a large indentation impression and low Young's modulus, in contrast to its high bulk modulus, suggesting that these unique mechanical properties are induced by the martensitic transformation.

Unusual plastic strain-induced phase transformation phenomena in silicon

Pressure-induced phase transformations (PTs) in Si, the most important electronic material, have been broadly studied, whereas strain-induced PTs have never been studied in situ. Here, we reveal in situ various important plastic strain-induced PT phenomena. A correlation between the direct and inverse Hall-Petch effect of particle size on yield strength and pressure for strain-induced PT is predicted theoretically and confirmed experimentally for Si-I→Si-II PT. For 100 nm particles, the strain-induced PT Si-I→Si-II initiates at 0.3 GPa under both compression and shear while it starts at 16.2 GPa under hydrostatic conditions. The Si-I→Si-III PT starts at 0.6 GPa but does not occur under hydrostatic pressure. Pressure in small Si-II and Si-III regions of micron and 100 nm particles is ∼5–7 GPa higher than in Si-I. For 100 nm Si, a sequence of Si-I → I + II → I + II + III PT is observed, and the coexistence of four phases, Si-I, II, III, and XI, is found under torsion. Retaining Si-II and single-phase Si-III at ambient pressure and obtaining reverse Si-II→Si-I PT demonstrates the possibilities of manipulating different synthetic paths. The obtained results corroborate the elaborated dislocation pileup-based mechanism and have numerous applications for developing economic defect-induced synthesis of nanostructured materials, surface treatment (polishing, turning, etc.), and friction.

Study on the Turning Characteristics and Influencing Factors of the Unmanned Sailboat

Unmanned sailboats can convert wind energy with sails to provide power for navigation, which can independently plan routes and collect data without human intervention. They have received increasing attention in recent years due to their low power consumption and strong self-sustainability. Due to the greater difficulty of manipulation, the unmanned sailboats have a weaker maneuverability than the propeller-driven vessels in the complex and variable marine environment. Typically, the turning motion is evaluated to characterize the maneuverability of a vessel, which has rarely been investigated in the existing research on unmanned sailboats. Therefore, this study builds a motion simulation platform for unmanned sailboats based on the 3 m class Petrel Sail to investigate the turning characteristics. The index of the approximate turning circle is introduced based on the turning motion trajectory, which is used to obtain the effect of rudder angle, wind angle, wind speed, and current speed on the turning performance of the sailboat in ideal hydrostatic conditions and under flow disturbance, respectively. Finally, a harbor pool test is conducted with an unmanned sailboat to verify the analysis results, and the errors in maximum transverse distance and maximum advance distance are in the reasonable range, proving the correctness of the theoretical results. The current study also provides theoretical guidance for subsequent research on sailboat manipulation and maneuverability.

Constraints on the spin-state transition of siderite from laboratory-based Raman spectroscopy and electrical conductivity under high temperature and high pressure

The vibrational and electrical transport properties of natural siderite are systematically investigated by means of in-situ Raman spectroscopy and alternating current impedance spectroscopy under conditions of 0.6–55.6 GPa, 298–873 K and different hydrostatic environments using a diamond anvil cell (DAC). Upon non-hydrostatic compression, all of these observable characteristic variations of siderite including the appearance of three absolutely new Raman peaks (L’, v4′ and v1′), the disappearance of Raman peaks (T, L and v4) and the discontinuity in the pressure-dependent electrical conductivity can provide robust evidence of electronic spin transitions of Fe2+ from high-spin to mixed-spin to low-spin states at the respective pressures of 42.5 GPa and 48.5 GPa. As far as hydrostatic condition, the electronic spin states from high-spin to mixed-spin to low-spin states occurred at the higher pressures of 45.7 GPa and 50.4 GPa, respectively, which implied the highly sensitive hydrostaticity of electronic spin transition pressures. Upon decompression, the reverse electronic spin transitions from low-spin to mixed-spin to high-spin states were detected at the respective pressures of 47.2 GPa and 28.7 GPa under non-hydrostatic condition, and as well as at the pressures of 49.4 GPa and 25.1 GPa under hydrostatic condition, respectively. The huge pressure hysteresis of 13.8 GPa and 20.6 GPa for the electronic spin state transition was revealed under non-hydrostatic and hydrostatic environments, respectively. In order to explore the effect of temperature on the electronic spin transition, a series of electrical conductivity experiments on siderite were performed over the temperature range of 323–873 K under conditions of three typical pressures of 47.7, 49.8 and 51.6 GPa. Furthermore, the functional relationships between the temperature and pressure describing the high-spin to mixed-spin to low-spin transitions for siderite were successfully established: P1 (GPa) = 39.318 + 0.015 T (K) and P2 (GPa) = 41.277 + 0.018 T (K), respectively. In conclusion, our acquired phase diagram of the electronic spin transition on siderite is beneficial to deep insight into the electronic spin behavior for those of iron-bearing carbonate minerals under high-temperature and high-pressure conditions.

Compaction and Permeability Evolution of Tuffs From Krafla Volcano (Iceland)

AbstractPressure and stress perturbations associated with volcanic activity and geothermal production can modify the porosity and permeability of volcanic rock, influencing hydrothermal convection, the distribution of pore fluids and pressures, and the ease of magma outgassing. However, porosity and permeability data for volcanic rock as a function of pressure and stress are rare. We focus here on three porous tuffs from Krafla volcano (Iceland). Triaxial deformation experiments showed that, despite their very similar porosities, the mechanical behavior of the three tuffs differs. Tuffs with a greater abundance of phyllosilicates and zeolites require lower stresses for inelastic behavior. Under hydrostatic conditions, porosity and permeability decrease as a function of increasing effective pressure, with larger decreases measured at pressures above that required for cataclastic pore collapse. During differential loading in the ductile regime, permeability evolution depends on initial microstructure, particularly the initial void space tortuosity. Cataclastic pore collapse can disrupt the low‐tortuosity porosity structure of high‐permeability tuffs, reducing permeability, but does not particularly influence the already tortuous porosity structure of low‐permeability tuffs, for which permeability can even increase. Increases in permeability during compaction, not observed for other porous rocks, are interpreted as a result of a decrease in void space tortuosity as microcracks surrounding collapsed pores connect adjacent pores. Our data underscore the importance of initial microstructure on permeability evolution in volcanic rock. Our data can be used to better understand and model fluid flow at geothermal reservoirs and volcanoes, important to optimize geothermal exploitation and understand and mitigate volcanic hazards.

Pressure-induced structural phase transitions and metallization in cuprous oxide under different hydrostatic environments up to 25.3 GPa

High-pressure vibrational and electrical transport behaviors of cuprous oxide were systematically investigated in a diamond anvil cell through in-situ Raman spectroscopy and electrical conductivity measurements under different hydrostatic environments up to 25.3 GPa. Upon compression, Cu2O undergoes a series of structural transformations from Cu2O–I to Cu2O–Ia to Cu2O–Ib to Cu2O–II to Cu2O–III phases at the respective pressures of 1.7(2), 10.3(2), 12.9(3) and 21.0(2) GPa under non-hydrostatic condition. Meanwhile, the metallization of Cu2O at 19.5(3) GPa is well characterized by the variable-temperature electrical conductivity experiments. Under hydrostatic condition, the pressure delay of 0.6–1.6 GPa is detected in the phase transitions from Cu2O–Ia to Cu2O–Ib to Cu2O–II to Cu2O–III phases. Upon decompression, one huge discrepancy is observed in the Raman spectra and electrical conductivity before and after the metallization, which indicates the irreversibility of phase transitions under different hydrostatic environments.

Electrochemical Dissolution Behavior of ZCuPb10Sn10 Alloy in NaNO3 Solution

Copper alloys, such as ZCuPb10Sn10, have been widely applied to friction pairs in various products. Surface texture, such as micro-dimple array has attracted significant attention from researchers worldwide to improve tribological performance. To generate micro-dimple array on ZCuPb10Sn10 alloy by electrochemical machining, it is essential to investigate the electrochemical dissolution behavior of ZCuPb10Sn10 in NaNO3 solution. In this paper, the electrochemical dissolution behavior of ZCuPb10Sn10 alloy in NaNO3 solution is investigated through experimental tests. Anodic polarization, Tafel polarization, and electrochemical impedance spectroscopy were conducted to investigate its passive and corrosion behavior. The microstructure and composition of the dissolved surfaces were analyzed under various conditions. Additionally, a model was proposed to explain the electrochemical dissolution process of ZCuPb10Sn10 alloy in NaNO3 solution under high pressure hydrostatic conditions. Ultimately, a NaNO3 solution with 10% in concentration and 20 °C in temperature was selected as the electrolyte and a micro-dimple array with an average diameter of 119.7 μm and a depth of 7.4 μm was successfully generated with through-mask electrochemical micromachining on the surface of ZCuPb10Sn10 alloy.

Transcriptomic responses and evolutionary insights of deep-sea and shallow-water mussels under high hydrostatic pressure condition

Marine mussels inhabit a wide range of ocean depths, necessitating unique adaptations to cope with varying hydrostatic pressures. This study investigates the transcriptomic responses and evolutionary adaptations of the deep-sea mussel Gigantidas platifrons and the shallow-water mussel Mytilus galloprovincialis to high hydrostatic pressure (HHP) conditions. By exposing atmospheric pressure (AP) acclimated G. platifrons and M. galloprovincialis to HHP, we aim to simulate extreme environmental challenges and assess their adaptive mechanisms. Through comparative transcriptomic analysis, we identified both conserved and species-specific mechanisms of adaptation, with a notable change in gene expression associated with immune system, substance transport, protein ubiquitination, apoptosis, lipid metabolism and antioxidant processes in both species. G. platifrons demonstrated an augmented lipid metabolism, whereas M. galloprovincialis exhibited a dampened immune function. Additionally, the expressed pattern of deep-sea mussel G. platifrons were more consistent than shallow-water mussel M. galloprovincialis under hydrostatic pressures changed conditions which corresponding the long-term living stable deep-sea environment. Moreover, evolutionary analysis pinpointed positively selected genes in G. platifrons that are linked to transmembrane transporters, DNA repair and replication, apoptosis, ubiquitination which are important to cell structural integrity, substances transport, and cellular growth regulation. This indicates a specialized adaptation strategy in G. platifrons to cope with the persistent HHP conditions of the deep sea. These results offer significant insights into the molecular underpinnings of mussel adaptation to varied hydrostatic conditions and enhance our comprehension of the evolutionary forces driving their depth-specific adaptations.

Pressure-induced optical anisotropy of HfS2

The effect of pressure on Raman scattering (RS) in bulk HfS2 is investigated under hydrostatic and non-hydrostatic pressure conditions. The RS line shape does not change significantly in the hydrostatic regime up to P = 9.6 GPa, showing a systematic blueshift of the spectral features. In a non-hydrostatic environment, seven peaks appear in the spectrum at P = 7 GPa, which dominate the RS line shape up to P = 10.5 GPa. The change in the RS line shape manifests a pressure-induced phase transition in HfS2. The simultaneous observation of both low-pressure (LP) and high-pressure (HP) related RS peaks suggests the coexistence of two different phases over a wide pressure range. It is found that the HP-related phase is metastable and persists during the decompression cycle down to P = 1.2 GPa, while the LP-related features eventually recover at even lower pressure. The angle-resolved polarized RS performed under P = 7.4 GPa revealed a strong in-plane anisotropy of both the LP-related A1g mode and the HP peaks. The anisotropy is related to the possible distortion of the structure induced by the non-hydrostatic component of the pressure. The results are explained in terms of a distorted Pnma phase as a possible pressure-induced phase of HfS2.

Noncommutative wormhole in de Rham-Gabadadze-Tolley like massive gravity

The wormhole solution in dRGT massive gravity is examined in this paper in the background of non-commutative geometry. In order to derive the wormhole model, along with the zero tidal force, we assume that the matter distribution is given by the Gaussian and Lorentzian distributions. The shape function in both models involves the massive gravity parameters m2c1 and m2c2. But the spacetime loses its asymptotic flatness due to the action of the massive gravity parameter. It is noticed that the asymptotic flatness is affected by the repulsive effect induced in the massive gravitons that push the spacetime geometry very strongly. We observed that each model violates the null energy criteria, indicating the presence of exotic matter which is necessary to sustain the wormholes. The exotic matter is measured using the volume integral quantifier. Moreover, it is discovered that the model is stable under the hydrostatic equilibrium condition by utilizing the TOV equation. Finally, our research encompassed an exploration of the repulsive influence exerted by gravity. Our findings demonstrated that the presence of repulsive gravity results in a negative deflection angle for photons following null geodesics. Remarkably, we consistently observed negative values for the deflection angle across all values of r0 in the two scenarios examined. This consistent negativity unequivocally signifies the manifestation of the repulsive gravity effect.

MINERAL PARAGENESIS OF EARLY BIOTITE VEINS AT THE KUH-E JANJA Cu-Au PORPHYRY DEPOSIT, SOUTHEASTERN IRAN: IMPORTANCE OF MICROTEXTURAL OBSERVATIONS IN STUDIES CONSTRAINING THE RELATIVE TIMING OF HYPOGENE Cu MINERALIZATION

Abstract Veins consisting primarily of biotite are the earliest stockwork vein type recognized at the Kuh-e Janja Cu-Au porphyry deposit in southeastern Iran. These early biotite veins may contain quartz and minor amounts of sulfide minerals such as chalcopyrite and pyrite. Observations at the hand-specimen scale do not provide reliable constraints on the paragenetic relationships, as the early biotite veins have been repeatedly overprinted during the evolution of the magmatic-hydrothermal system. Microscopic investigations show that the sulfide minerals in the early biotite veins are texturally late, providing evidence that sulfide deposition did not occur at the high temperatures of biotite formation and potassic alteration of the host rocks. Chalcopyrite primarily occurs along hairline fractures that crosscut or refracture the earlier biotite veins. Biotite in contact with the chalcopyrite can be apparently unaltered or is replaced by chlorite, depending on the degree of wall-rock buffering of the magmatic-hydrothermal fluids that caused hypogene Cu mineralization. The findings add to the growing body of evidence that Cu mineralization in this deposit type occurs at temperatures close to the transition from ductile to brittle conditions (<450°C) following a drop in the pressure regime from lithostatic to hydrostatic conditions.

Numerical investigation of artificial ground freezing–thawing processes in tunnel construction

Artificial ground freezing is a frequently used method for temporary support of the soil in geotechnical interventions, such as tunneling. Besides the time required to form a supporting frozen soil structure during freezing, the prediction of temperature evolution during the thawing process and the final thawing time are also relevant, since settlements induced by thawing of the frozen soil can pose a risk to sensitive structures in urban tunneling. The freezing and thawing process of soils depends strongly on the unfrozen liquid content. The unfrozen liquid content during the freezing and thawing cycles is known to have a pronounced hysteresis response, whose effect on the temperature distribution and groundwater flow, especially at the structural level has not been extensively studied. In this work, we present a thermo-hydraulic finite element model for freezing soils and incorporate the hysteresis behavior of soil. We aim to investigate the suitability of the presented numerical model for tunnel construction on the one hand, and quantify the extent of the influence of the hysteresis response of the unfrozen liquid content at the structural level on the other. To this end, the model is first validated with the help of experimental data from a soil test subjected to a freezing–thawing cycle and subsequently used to analyze three problems of artificial ground freezing in tunnel construction during the freezing phase or freezing–thawing phases. The results show a good agreement with the experimental measurements. We show that the computational model is capable of providing accurate prognosis of the temperature profile as well as broader metrics such as the thickness and shape of the frozen body for tunneling applications under hydrostatic and seepage flow conditions. The hysteresis response is shown to have a significant influence on the coupled thermo-hydraulic process, with thawing times differing depending on whether hysteresis is considered. It is concluded, that the inclusion of the hysteresis response is crucial for obtaining an accurate representation of the freezing process.

Revisiting the Serçe Limanı Sail Plan

The reconstruction of the Serçe Limanı ship proposed a double-masted rig consisting of two sails with a total combined area of 100 m2. That proposal considered provenance evidence and appraised hydrodynamic and hydrostatic conditions. The current paper proposes an alternative rig consisting of a single sail. By applying computational fluid analysis and hydrostatic stability software to evaluate hull resistance, sail propulsion, and heeling moments, it has been demonstrated that a sail of no less than 150 m2 was suited to propel the Serçe Limanı. One of the two suitable alternative sails tested has been selected.

Design of fuzzy controller for dynamic positioning based on improved particle swarm algorithm

Abstract The traditional PID controller commonly used in ship dynamic positioning has the defects of difficult online adjustment and weak anti-interference ability. Combining fuzzy control with PID can be a good way to improve the adaptability and accuracy of the controller. However, the parameters of fuzzy PID need to be adjusted by human beings, and there exists a certain uncertainty, which has a great influence on the robustness of the controller. Therefore, the fuzzy PID is optimized using an improved particle swarm algorithm to parameterize the quantized scale factor and rules of the fuzzy PID. Particle swarm optimized fuzzy PID was simulated, and the control of PID and fuzzy PID controllers was compared under different operating conditions, as shown by the experimental results: Under the hydrostatic condition, the convergence speed of the control system is faster; under the load condition, the overshooting amount of the control system is smaller, and the robustness and adaptability have been significantly improved.

Optoelectronic properties of mechanically stable cubic Niobate compounds under hydrostatic pressure: A systematic DFT investigation

Perovskite oxides, particularly cubic Niobate compounds, have been studied for their potential application in the development of optoelectronic devices. The mechanical stability of these compounds has been verified by determining their elastic constants. Based on an analysis of their electronic band structures and densities of states, it has been found that both compounds exhibit non-magnetic behavior and possess properties typical of indirect bandgap semiconductors. The bandgap energies of the compounds are 1.524 eV and 1.392 eV, respectively. The optical properties of the compounds are analyzed under varying hydrostatic pressure conditions. Bandgap modulation results in a shift in absorption spectra from ultraviolet to visible wavelengths, rendering the materials appropriate for use in optoelectronic devices. Perovskites with (K,Rb)NbO3 exhibit potential as non-magnetic indirect bandgap semiconductors for the advancement of optoelectronic devices.

Raman Spectroscopy on Free-Base Meso-tetra(4-pyridyl) Porphyrin under Conditions of Low Temperature and High Hydrostatic Pressure

We present a Raman spectroscopy study of the vibrational properties of free-base meso-tetra(4-pyridyl) porphyrin polycrystals under various temperature and hydrostatic pressure conditions. The combination of experimental results and Density Functional Theory (DFT) calculations allows us to assign most of the observed Raman bands. The modifications in the Raman spectra when excited with 488 nm and 532 nm laser lights indicate that a resonance effect in the Qy band is taking place. The pressure-dependent results show that the resonance conditions change with increasing pressure, probably due to the shift of the electronic transitions. The temperature-dependent results show that the relative intensities of the Raman modes change at low temperatures, while no frequency shifts are observed. The experimental and theoretical analysis presented here suggest that these molecules are well represented by the C2v point symmetry group.