Zinc antimonate (ZnSb2O6) nanoparticles were prepared by an inexpensive chemical precipitation method and its structural properties were studied using X-ray diffraction (XRD). Further in electrochemical analysis, Nafion, a per-fluorinated sulfonic acid polymer solution that serves as a binder, wherein the hydrophilic sulfonic acid group provides proton-exchange between electrolyte and active electrode material thereby, it is beneficial in the improvement of the capacitance, chemical and mechanical stability of a material. Considering this key point, the significance of the nafion on the electrochemical characteristics of zinc antimonate nanoparticles were studied through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analysis in 1 M H2SO4 electrolyte. The significant changes in the capacitance, electrochemical behavior and electrochemical stability of the nanostructure with and without the binder were investigated.