Hydrogeochemical Characterization Research Articles

Hydrogeochemical Characterization of Aquifer Systems and Surface Water/Groundwater Relations in the Lower Senegal River Valley

Hydrogeochemical Characterization of Aquifer Systems and Surface Water/Groundwater Relations in the Lower Senegal River Valley

Hydrogeochemical Characterization of Groundwater of Field Y, Offshore Niger Delta

Hydrogeochemical analyses were carried out on groundwater samples in order to understand the hydrochemistry of the water. The results revealed that groundwater has a high electrical conductivity, which could be as a result of more chemicals dissolved in the water and total hardness observed in all samples shows that the water isn’t hard water. Major cations and anions were identified using Piper Trilinear diagram Durov diagrams and Stiff diagrams. The parameters studied include; Ph, Electrical conductivity, Temperature, Total Suspended Solid, Salinity as Chloride, Sulphate, Total Hardness, Total Hydrocarbon Content, Nitrate, Phosphate, Alkalinity, Calcium, Sodium, Magnesium, Potassium, Iron, Zinc. The major cations are: Sodium (Na+), Potassium(K+), Calcium (Ca2+), while the major anions are: Bicarbonate (HCO3–), Carbonate(C03–), Sulfate (SO4–), and Chloride (Cl–). TDS is the major physical parameter that is dominant in the Durov diagram, although the analysis in the Durov, Piper and Stiff diagram shows that Ca2+ and HCO3–, are the major cation and anion respectively which implies that the groundwater in the study area are Ca2+ and HCO3–. It was also observed that the quality of groundwater was suitable for domestic purpose and agricultural purpose.

Hydrogeochemical Characterization of Groundwater from Fissured Aquifers in the Angovia Mine Operating Permit Area (Central-West Côte d’Ivoire)

Hydrogeochemical Characterization of Groundwater from Fissured Aquifers in the Angovia Mine Operating Permit Area (Central-West Côte d’Ivoire)

Using Clustering, Geochemical Modeling, and a Decision Tree for the Hydrogeochemical Characterization of Groundwater in an In Situ Leaching Uranium Deposit in Bayan-Uul, Northern China

Uranium extraction through the in situ leaching method stands as a pivotal approach in uranium mining. In an effort to comprehensively assess the repercussions of in situ uranium leaching on groundwater quality, this study collected 12 representative groundwater samples within the Bayan-Uul mining area. The basic statistical characteristics of the water samples showed that the concentrations of SO42− and total dissolved solids (TDS) were relatively high. Through the use of cluster analysis, the water samples were categorized into two distinct clusters. Seven samples from wells W-d, W-u, N01, W10-2, W08-1, W10-1, and W13-1, situated at a considerable distance from the mining area, were grouped together. Conversely, five samples from wells W08-2, W13-2, W01-1, W02-2, and the pumping well located in closer proximity to the mining area, formed a separate cluster. A decision tree-based machine learning approach was employed to discern the influence of various hydrochemical indicators in forming these clusters, with results indicating that SO42− exerts the most substantial influence, followed by Ca2+. The mineral saturation indices from geochemical modeling indicated that, as the distance from the mining area increased, the trend of calcium minerals changed from dissolution to precipitation; iron minerals were in a precipitation state, and the precipitation trend was gradually weakening. In light of these findings, it is clear that in situ uranium leaching significantly impacted the groundwater in the vicinity of the mining area. The prolonged consumption of groundwater sourced near the study area, or its use for animal husbandry, poses potential health risks that demand heightened attention.

Hydro-geochemical characterization and modeling of groundwater in Chikun Local Government Area of Kaduna state, Nigeria

Abstract This study assessed groundwater quality in Chikun Local Government Area of Kaduna State and how it can be harnessed as a useful resource for water supply and to improve the management of water resources. The field survey methods adopted with the collection of water samples in the field were employed in collecting data. The study randomly collected fifty water samples from wells and boreholes in the peak of wet and dry seasons for 2 years (2021–2022) in the five selected wards within the Chikun Local Government Area and a range of water quality parameters were measured and compared with WHO standards for drinking water. The laboratory analysis results revealed that with the exception of magnesium, mercury, iron, lead and calcium, all other physicochemical parameters measured fell within the maximum permissible limit. The presence of some of these pollutants at varying degrees was found. Groundwater models showed groundwater flow in the North-Western direction and significant vertical movement of contaminants up to depths of about 60 m. This calls for regulations on the handling of wastes and pollutants that affect groundwater, which is best done through strict enforcement of laws and advocacy through all the appropriate institutions involved in water management.

Hydrogeochemical Characterization of Groundwater at the Boundaries of Three Aquifers in Central México

This study investigates the natural hydrogeochemical mechanisms that govern groundwater chemistry at the margins of the Silao-Romita, Valle de León, and La Muralla aquifers in Mexico’s “Bajío Guanajuatense”. The wells of the La Muralla aquifer have temperatures ranging from 25 to 45 °C, while in the valleys, the temperatures range from 25 to 29 °C. In the Sierra de Guanajuato recharge zone, the thermal spring registers 95 °C. High Na concentrations (125 to 178 mg/L) are measured due to thermalism. One sample includes 316 mg/L of SO4, which is related to a potential gypsum zone. Three hydrogeochemical facies are identified (Ca-Mg HCO3, Na-Ca-HCO3, and Na-HCO3). The hydrogeochemical characterization and processes imply hydraulic linkage via regional thermal flows enhanced by faults and the mixing of local flow waters with intermediate flows. The isotopic results indicate that part of the groundwater volume has been exposed to local evaporation processes due to the presence of surface water bodies and irrigation returns. The highest isotopic enrichment is observed near or in the recharge regions. In contrast, the most depleted zones are in the valleys, where there is a more significant interaction with the rock and a longer residence time, implying a mixture of local water flows with deeper or intermediate flows, which, when combined with water geochemistry, indicates a connection between the aquifers studied. The Kruskal–Wallis variance tests, used to compare the differences between aquifers, show that the Valle de León aquifer has more significant differences with respect to the Silao-Romita and La Muralla aquifers. This study’s findings are essential for one of central Mexico’s most populous and economically active areas.

Hydrogeochemical characterization and precursor anomalies of hot springs in the North Tianshan orogen

The North Tianshan orogen consists of a series of thrust faults and is the most seismic region in China. In this paper, the characteristics of hot springs in the North Tianshan orogen are analyzed. Hydrochemical analysis of 13 hot springs and four mud volcanoes reveals that the cations of most hot springs are mainly Na+, while the anions are mainly Cl−.Atmospheric precipitation is the main recharge source for the hot springs in the study area, with recharge heights ranging from −9 to 2344 m. Heat storage analysis and trace element results showed deep fluid characteristics, which is consistent with deep circulation processes and regional extrusion pressure background. In addition, continuous measurements of six hot springs were conducted once every three days. The results showed that Cl− and SO42− concentration anomalies occurred before several earthquakes of ML4.0 in the North Tianshan orogen. The hot springs SWQ, HTB, and WS, which have deeper circulation depths, show better responsiveness than X10, which has a shallow circulation depth. The deep circulation of hot springs increases fault sliding friction, which contributes to energy accumulation and strong seismogenesis, and participates in the seismogenesis process. Therefore, continuous monitoring of ion concentrations of deep-circulation hot springs can help identify effective precursor anomalies in the North Tianshan orogen.

Hydro-geochemical characterization and groundwater modelling of the subsurface around Ughelli West Engineered Dumpsite in the Western Niger Delta, Nigeria

Geoelectric, geochemical investigation, and groundwater modelling were integrated in areas surrounding the Ughelli West Engineered dumpsite in the Western Niger Delta. The study focused on assessing the environmental impact of the dumpsite on its surrounding groundwater. The geochemical analyses revealed that the leachates generated from the dumpsite have significant potential to contaminate the surrounding environment. The BOD5/COD ratio was less than 0.1, indicating that the dumpsite is old with stabilized leachate of low biodegradability and in the methanogenic phase of anaerobic degradation. The groundwater chemistry in monitoring wells outside the dumpsite and at other control sites showed no significant impact of the dumpsite on groundwater quality. Groundwater models showed groundwater flow in the north-western direction and significant vertical movement of contaminants up to depths of about 60 m beneath the dumpsite after a period of 3 years. The contaminant plume, however, had not moved considerably laterally away from the dumpsite. The location of the dumpsite within areas of low vulnerability due to the presence of clay/sandy clay between 1.3 and 6 m thick around the dumpsite limited the lateral migration of leachate in groundwater.

Hydrogeochemical characterization of groundwater and critical assessment of its quality in a coastal basin

Hydrogeochemical characterization of groundwater and critical assessment of its quality in a coastal basin

Coupled Geophysical and Hydrogeochemical Characterization of a Coastal Aquifer as Tool for a More Efficient Management (Torredembarra, Spain)

The aquifers of the Spanish Mediterranean coast are generally subjected to intense exploitation to meet the growing water supply demands. The result of the exploitation is salinization due to the marine saltwater intrusion, causing a deterioration in the quality of the water pumped, limiting its use for community needs, and not always being well delimited. To prevent deterioration, a groundwater control network usually allows precise knowledge of the areas affected by saltwater intrusion but not the extent of the saline plumes. Moreover, the characterization of aquifer systems requires a model that defines the geometry of aquifer formations. For this objective, we integrated hydrogeological, hydrogeochemical, and electrical resistivity subsoil data to establish a hydrogeological model of the coastal aquifer of Torredembarra (Tarragona, NE Spain). In this research, we have carried out a regional and local-scale study of the aquifer system to define the areas prone to being affected by saline intrusion (electrical resistivity values below 10 Ω·m). The obtained results could be used as a support tool for the assessment of the most favorable areas for groundwater withdrawal, as well as enabling the control and protection of the most susceptible areas to be affected by saltwater intrusion.

Ground water quality evaluation using hydrogeochemical characterization and novel machine learning in the Chikun Local Government Area of Kaduna State, Nigeria.

The investigation collected 50 random water samples from wells and bore holes in the five wards. In the meantime, the Water Quality Index (WQI) in this region was assessed using a novel machine learning model. In this sphere of science, the Emotional Artificial Neural Network (EANN) was used as an innovative technique. The training dataset comprised 80% of the available data, while the remaining 20% was used to assess the performance of the network. The laboratory analysis revealed that the levels of magnesium (0.581 mg/L), mercury (0.0143 mg/L), iron (0.82 mg/L), lead (0.69 mg/L), calcium (2.03 mg/L), and total dissolved solid (105 mg/L) in the water sample were quite high and exceeded the maximum permissible limits established by the National Standard Water Quality (NSWQ) and Water Quality Association (WQA). Except for magnesium, mercury, iron, and lead, all physicochemical parameters are below the utmost permissible limit. Results showed that hydrogeological effects and anthropogenic activities, such as waste management and land use, impact groundwater pollution in the Chikun Local Government Area of Kaduna State up to 60 m deep. The results of the EANN showed that R2 index and normalized root mean square error (RMSENormalized) values for the training and test stages are 0.89 and 0.18, and 0.83 and 0.23, respectively.

Hydrogeochemical Characterization and Qualitative Evaluation of Major Feeder Rivers/Streams of Loktak Lake, Manipur, India

Hydrogeochemical Characterization and Qualitative Evaluation of Major Feeder Rivers/Streams of Loktak Lake, Manipur, India

Hydro-geochemical characterization of the main European mineral water brands

The history of the mineral water consumption goes back to early legends. Already then, in addition to physiological needs, their beneficial effects were also used in medicine. Mineral water contains a complex of components, the composition of each mineral water varies according to its origin, the minerals, salts, gases and radioactive elements it contains and the quantities of the components. In our research, statistical methods were used to analyze the chemical composition of the macro-parameters indicated on the labels of European bottled and commercial mineral waters. A total of 692 mineral waters from 13 countries were analyzed: Austria (15), Belgium (8), Greece (10), France (33), Poland (34), Portugal (7), Spain (66), Slovakia (11), United Kingdom (9), Hungary (33), Germany (309), Italy (123), Romania (34), United Kingdom (9). Furthermore, mineral waters were classified according to their evaporation residue and ionic content. Correlation coefficients were used to study the relationship between the chemical composition of rocks and mineral waters. Statistical analysis was carried out on the cations Ca2+, Mg2+, Na+, K+, and on the anions HCO3-, Cl-, SO42-. Piper diagrams of the studied mineral waters were prepared at country level, as well as box-plots and Spearman correlations and heat maps.

Hydrogeochemical characterization of groundwater in the Wassa Amenfi East and Prestea-Huni Valley areas of southern Ghana using GIS-based and multivariate statistical techniques

Hydrogeochemical characterization of groundwater in the Wassa Amenfi East and Prestea-Huni Valley areas of southern Ghana using GIS-based and multivariate statistical techniques

Geospatial assessment and hydrogeochemical characterization of groundwater resources of Manipur Valley, India.

Spatio-temporal hydrogeochemical assessments of groundwater resources were carried out for the valley region of Manipur in India to investigate its quality status and suitability criteria for irrigational and potable uses. The assessment was carried out for 140 spatially distributed groundwater samples collected during 2018-2021 for pre- and post-monsoon seasons. To assess and comprehend the hydrogeochemical behavior of underlying aquifers and controlling factors for groundwater quality in the region, groundwater quality indices and statistical tools were used. Assessment of in situ parameters such as pH, TDS, salinity, and EC under field conditions reveal that the values exceed concentration in many locations. Most of the samples fall in the category of hard to very hard water. Moreover, observation of both positive and negative oxidation-reduction potential (ORP) and low dissolved oxygen (DO) concentration in groundwater samples indicates aquifers are of recent unstable geologic formations. Similarly, elevated concentrations of F-, Cl-, HCO3-, and Fe3+ greater than the prescribed standards of the World Health Organization in many samples indicate the unsuitability of the groundwater sources for potable uses. The geochemical interactions were found to be dominated and controlled by the rock-weathering geochemical process that contributes to HCO3--Ca2+-type water, followed by HCO3--Na+, Cl--Ca2+, and mixed-type water in both seasons. Spatio-temporal geospatial vulnerable groundwater zone mapping using interpolation techniques carried out in the ArcGIS platform identifies the aquifers based on the water quality and pollution indices. The study's significant findings can provide baseline information that can supplement the government's planning and management initiatives to deal with the current water security challenges in the region as groundwater uses are increasing due to various hydroclimatic phenomena in the state.

Hydrogeochemical characterization of groundwater under natural and anthropogenically influenced areas located in Upper Ghaggar River Basin, India

Hydrogeochemical characterization of groundwater under natural and anthropogenically influenced areas located in Upper Ghaggar River Basin, India

Hydrogeochemical characterization of ground and surface water in the eastern part of the Adamawa-Yade domain, Bertoua-Cameroon

Groundwater and surface water are major sources of water supply to the inhabitants of Bertoua. Hydrogeochemical study conducted in the study area aimed at identifying the processes that control the chemistry of groundwater sources and to examine the quality of the water sources for domestic and agricultural purposes. Fifty water samples were collected from boreholes, open wells, springs, and rivers within the study area in January 2022 (the dry season). The samples were analyzed for physicochemical characteristics including pH, electrical conductivity (EC), total dissolved solids (TDS) and major ions. The water samples were acidic with 94% of pH values less than 6.5. The EC varied from 21 to 776 µS/cm and TDS (8.5–388 mg/l). The low EC and TDS indicate low mineralization and fresh water. The relative abundance of major ions (meg/l) was Ca2+> Mg2+> K+>Na+ for cations and {text{H}text{C}text{O}}_{3}^{-}>Cl−>NO3−>SO42− for anions. These major ions concentrations were low and within the WHO guideline values for drinking water. From Piper diagram three water facies were observed; Ca-SO4, Ca-HCO3 and mixed Ca-Mg-Cl. Rock-water interaction, ion exchange, silicate weathering and anthropogenic activities were the processes responsible for the groundwater chemistry with some minor evaporative effects. Based on Sodium Adsorption Ratio and Residual Sodium Bicarbonate all samples fall in the excellent category for agriculture.

Hydrogeochemical characterization and CO2 consumption in the Maqu catchment of the Qinghai-Tibetan Plateau by multiple hydrogeochemical methods

The Qinghai-Tibetan Plateau (TP) is the source of many large Asian rivers and has significant social, ecological and economic importance. However, few hydrogeochemistry and stable isotope studies have been performed in the Maqu catchment of the eastern TP. In this study, the hydrogeochemical composition and stable isotopes (δD and δ18O) of surface water and groundwater samples collected in the Maqu catchment were analysed to characterise the surface water and groundwater, investigate the contributions of different sources, and determine CO2 consumptions. Different techniques were used, including inverse modelling, end member mixing analysis (EMMA), and a forward mass balance model. The results indicated that all water samples are of the HCO3-Ca type. Both the surface water and groundwater are of meteoric origin and there is close contact between them (except wetlands). Water in the wetlands is substantially evaporated (0–45%). Calcite and illite generally precipitate, whereas chlorite and CO2 generally dissolve along groundwater flow paths in the east. The mean contributions of fresh surface waters, mountain-front groundwaters, and anthropogenic inputs to the surface water samples are 56%, 16%, and 28%, respectively. Carbonate and silicate weathering are the dominant sources of major cations. Moreover, high CO2 consumption rates in both the surface runoff and groundwater make the Maqu catchment an important carbon sink in the Yellow River Basin. With many newly-found conclusions on the Maqu catchment, the present study not only provides insight into the catchment but also contributes to a comprehensive understanding of the water cycle and CO2 consumptions on the TP.

Hydrogeochemical characterization of the areas of exploitation of the CBG sites: cas of the plateaus of N'Dangara and Boundou Wandé, Sangarédi sub-prefecture, Prefecture of Boké, Republic of Guinea

Abstract This work aims to analyze the quality of groundwater in the riparian areas of the bauxitic plateaus of N'Dangara and Boundou Wandé in operation by the CBG (Compagnie des Bauxites de Guinée). The geology of the study area consists mainly of sedimentary formations of the Devonian faro, Neogene and Quaternary. Three water measurement and sampling campaigns on the two plateaus were carried out with determination of piezometric measurements and physic-chemical parameters. This study showed that the general flow direction of groundwater is dispersed. The flows at Boundou Wandé are from the center of the plateau to the north and that at N'Dangara is from the center to the south and southwest. It can be seen that the direction of groundwater flow reflects overall the relief of the deposit conditioned by its geomorphological framework. It emerges from the analysis of physical and chemical parameters that well water is consumable. However, the water from wells MW15, MW16, MW17, MW18 and MW21 with a low pH (4.84 to 5.13) may present a certain nuisance for its consumption and because it can be corrosive. Analysis of the Piper diagram showed two hydrogeochemical facies (calcium and magnesium bicarbonate facies and sodium and potassium carbonate facies). However, this study strongly suggests continuous monitoring of groundwater in and around the study area in order to meet the demand for water supply to communities without compromising the ability of future generations to meet water quality requirements.

Pollution status and hydrogeochemical characterization of water resources in Onne industrial layout and environs, Rivers state, Nigeria

Pollution status and hydrogeochemical characterization of water resources in Onne industrial layout and environs, Rivers state, Nigeria