Removal Of Hydrogen Sulfide Research Articles

Novel Porous Organic Polymer for the Concurrent and Selective Removal of Hydrogen Sulfide and Carbon Dioxide from Natural Gas Streams.

Natural gas sweetening currently requires multistep, complex separation processes to remove the acid gas contaminants, carbon dioxide and hydrogen sulfide. In addition to being widely recognized as energy inefficient and cost-intensive, the effectiveness of this conventional process also suffers considerably because of limitations of the sorbent materials it employs. Herein, we report a new porous organic polymer, termed KFUPM-5, that is demonstrated to be effective in the concurrent separation of both hydrogen sulfide and carbon dioxide from a mixed gas stream at ambient conditions. To understand the ability of KFUPM-5 to selectively capture these gas molecules, we performed both pure-component thermodynamic and mixed gas kinetic adsorption studies and correlated these results with theoretical molecular simulations. Our results show that the underlying polar backbone of KFUPM-5 provides favorable adsorption sites for the selective capture of these gas molecules. The outcome of this work lends credence to the prospect that, for the first time, porous organic polymers can serve as sorbents for industrial natural gas sweetening processes.

Electrolytic cell–assisted polyoxometalate based redox mediator for H2S conversion to elemental sulphur and hydrogen

This study proposed a novel electrolytic cell–assisted redox system based on lacunary-type polyoxometalate, which can simultaneously remove hydrogen sulphide (H2S), recover elemental sulphur, and produce hydrogen. In this redox system, H2S is oxidised into elemental sulphur by using polyoxometalate ([Sm(PMo(VI)11O39)2]−11), which is reduced to corresponding heteropoly blue (reduced polyoxometalates [Sm(PMo(IV)11O39)2]−55). Furthermore, heteropoly blue is electrochemically oxidised back into polyoxometalate on the anode surface, and hydrogen is produced on the surface of the cathode in an electrolytic cell. The experimental results indicated that a 94.8% H2S removal efficiency, and 77.9% sulphur recovery efficiency were achieved under optimum conditions. H2S was effectively converted to elemental sulphur in the proposed system. Moreover, Optical and electrochemical characterisations demonstrated that the structures of the lacunary-type polyoxometalate could be well-maintained at pH 5, which was most favourable for H2S removal. Notably, clean energy hydrogen could be produced in polyoxometalate regeneration process. This innovative system—combining H2S waste conversion to elemental sulphur, electrochemical regeneration of redox mediators, and hydrogen production and thus providing environmental benefits and significant economic value—may have future applications in commercial technology.

Impact of increased instream heterogeneity by deflectors on the removal of hydrogen sulfide of regulated urban waterways-A laboratory study.

Laboratory experiments were conducted to test the hypothesis that increase in physical heterogeneity by deflectors would improve the water quality of urban regulated (straight and prismatic) waterways. Deflectors changed the near-uniform flow to a rapidly varied flow, as such the depth, velocity, and Froude number (Fr) variations were four, 10, and 14 times more than the without deflector scenario, respectively. Removal of hydrogen sulfide (H2 S), the main focus of the study, was significantly high when deflectors were placed in the laboratory urban waterway. Introduction of a sediment bed further improved H2 S removal; however, in this case turbidity and color were significantly high too. These observations endorse the fact that attenuation induced by deflectors and assimilation promoted by the sediment bed aids the H2 S removal. These facts were further strengthened by the significant strong negative correlations H2 S made with DO and pH for all experiments. Further studies are recommended for different deflector orientations and modified sediment beds (e.g., mixture of sediment and gravel), identification of localized water quality hot spots to capture spatial variation of water quality, and impact of increased heterogeneity on flood safety. PRACTITIONER POINTS: Increase in physical heterogeneity (by deflectors) on water quality improvement was studied in a laboratory set up. Deflectors changed the near-uniform flow to rapidly varied flow with several mesoscale physical habitats. Hydrogen sulfide (H2 S) removal was greatest with deflectors and the sediment bed, but was characterized by high turbidity. H2 S removal showed strong negative correlations with dissolved oxygen and pH.

Comparing Hydrogen Sulfide Removal Efficiency in a Field-Scale Digester Using Microaeration and Iron Filters

Biological desulfurization of biogas from a field-scale anaerobic digester in Peru was tested using air injection (microaeration) in separate duplicate vessels and chemical desulfurization using duplicate iron filters to compare hydrogen sulfide (H2S) reduction, feasibility, and cost. Microaeration was tested after biogas retention times of 2 and 4 h after a single injection of ambient air at 2 L/min. The microaeration vessels contained digester sludge to seed sulfur-oxidizing bacteria and facilitate H2S removal. The average H2S removal efficiency using iron filters was 32.91%, with a maximum of 70.21%. The average H2S removal efficiency by iron filters was significantly lower than microaeration after 2 and 4 h retention times (91.5% and 99.8%, respectively). The longer retention time (4 h) resulted in a higher average removal efficiency (99.8%) compared to 2 h (91.5%). The sulfur concentration in the microaeration treatment vessel was 493% higher after 50 days of treatments, indicating that the bacterial community present in the liquid phase of the vessels effectively sequestered the sulfur compounds from the biogas. The H2S removal cost for microaeration (2 h: $29/m3 H2S removed; and 4 h: $27/m3 H2S removed) was an order of magnitude lower than for the iron filter ($382/m3 H2S removed). In the small-scale anaerobic digestion system in Peru, microaeration was more efficient and cost effective for desulfurizing the biogas than the use of iron filters.

Chars from wood gasification for removing H2S from biogas

Biomass gasification is a mature thermochemical process used to produce a gaseous fuel to run burners, engines, and gas turbines. One of the byproducts of biomass gasification is char, which is a residue with low value and sometimes this material is even considered waste. Therefore, options for using gasification chars are required. On the other hand, there is a necessity of making biogas production and use more attractive by employing cheap materials for the biogas cleaning process. One of the promising options for using gasification chars is for cleaning biogas produced via anaerobic digestion (AD). The objective of this work was to assess the use of residual gasification chars from fast growing wood species (Eucalyptus Grandis-EG and Pinus Patula-PP) to remove hydrogen sulfide (H2S) from biogas produced via AD. Gasification chars were produced employing a laboratory scale downdraft gasifier. EG char (EG-C30) was produced by gasification of EG using a 30 L min−1 airflow, whereas the PP chars (PP–C20 and PP-C40) were produced from PP using 20 and 40 L min−1 airflow. Results show that these three chars offer potential for biogas cleaning, although PP-derived chars produced at higher airflow rates are more effective. The H2S removal capacity of the chars is ascribed to their large apparent surface area (up to 517 m2 g−1) and the presence of minerals and metals (e.g., Ca, K, and Fe) in the chars’ ash.

Sulfur from biogas desulfurization: Fate of S during storage in manure and after application to plants

Residues from hydrogen sulfide (H2S) removal in biogas filters contain sulfur (S) in various forms (sulfate, sulfide, elemental S) that, if properly stored, is potentially valuable as crop fertilizer. We investigated 1) the turnover of the S compounds from filter materials during storage in untreated and digested cattle manure (CM), and 2) the S fertilizer replacement value (SFRV) of the filter materials applied in pure form or mixed manure with and without storage. The S filter materials from four H2S removal processes (biological and physical-chemical) containing mostly sulfate and/or elemental S were added to untreated CM or digested CM and stored at 10 °C for six months. Afterwards, a pot experiment was established to assess the S availability in an oil-seed rape (Brassica napus) crop. Microbial reduction of sulfate into sulfide took place rapidly after 69 days storage of untreated CM. A lower reduction rate was observed in digested CM mixtures. After six months, 68% and 32% of the initial sulfate content were still present in mixtures containing the S filter materials from biological desulfurization with digested CM and untreated CM, respectively. Sulfate reduction was inhibited for 120 days when digested CM was mixed with S saturated solution from an ash filter, probably due to high pH (≥8.2) and redox potential (>−100 mV) levels. Oppositely, elemental S was immediately and simultaneously both reduced and oxidized. Relatively low losses of total S were observed during the present storage conditions. Despite S turnover, the SFRV of CM and digested CM significantly increased from 15–19% (of total S applied) to 56–90% when S filter materials were added. The storage of S filter materials in digested manure reduced the risk of sulfide production and potential S volatilization. The S filter materials were a valuable source of plant-available S.

Hydrogen sulfide removal from biogas using ion-exchanged nanostructured NaA zeolite for fueling solid oxide fuel cells

Hydrogen sulfide is the most abundant sulfur compound in the biogas, and in order to use for fueling the solid oxide fuel cells, its content should be less than 1 ppm. In this work, NaA nano zeolite is synthesized hydrothermally and modified by Ag+ ions, and its breakthrough capacity for hydrogen sulfide adsorption was measured using dynamic lab-scale adsorption tests on the experimental set-up for the first time. The results are compared to those of unmodified NaA nano zeolite and micron-sized commercial 4A zeolite. AgNaA nano zeolite showed the highest adsorption capacity (33.24 mg H2S/g of Sorbent) and the longest breakthrough time (310 min). The regeneration performance of AgNaA nano zeolite and its structural stability are also investigated after five cycles. The results revealed that the AgNaA nano zeolite could be used promisingly for removing hydrogen sulfide from biogas for cleaner energy production.

Hydrothermal synthesis of V2O5 nanospheres as catalyst for hydrogen sulfide removal from sour water

Vanadium pentoxide (V2O5) nanospheres were synthesized hydrothermally for the first time with high specific surface area. The effect of different parameters including pH level, H2O2/H2O volume ratio and reaction temperature on the precipitate yield was investigated, and the highest yield was attained at the pH level of 3, H2O2/H2O volume ratio of 0.01 and the reaction temperature of 160 °C. Freeze drying, oven drying and vacuum drying methods along with auxiliary processes were employed to improve the drying process and minimize the aggregation of the synthesized nanoparticles (NPs). Two auxiliary processes were used prior to drying in the oven to improve the performance of drying. Firstly, precipitates were immersed in ethanol to get replaced in place of water molecules in a week. The precipitates were then dried at room temperature for a week to evaporate their moisture. In vacuum drying method, only the second auxiliary process was employed. In freeze drying technique, the segregate and uniform nanospheres of V2O5 were produced with an average diameter of 37 nm. Generally, the employed additional treatments cause the drying techniques to enhance and the extent of particles aggregation to reduce. Finally, the application of the synthesized NPs as catalyst was investigated for the elimination of H2S from sour water with the initial concentration of 1300 ppm. The sour water was provided from Shiraz Oil Refinery Company. Results revealed that the synthesized NPs enable to completely eliminate hydrogen sulfide from sour water with 20% greater conversion at early contact seconds as compared to commercial V2O5 powder.

N-Rich Carbon Catalysts with Economic Feasibility for the Selective Oxidation of Hydrogen Sulfide to Sulfur.

The efficient removal of hydrogen sulfide (H2S) from exhaust emissions is a great challenge to chemical industries. Selective catalytic oxidation of H2S into elemental sulfur is regarded as one of the most promising approaches to alleviate environmental pollution, while recycling sulfur resources. It is therefore highly desirable to develop efficient catalysts for the conversion of H2S to sulfur under mild reaction conditions. Here we present a nitrogen-rich carbon obtained by the direct thermal treatment of commercial polyaniline (PANI) for the selective oxidation of H2S in a continuous way at relatively low temperature (180 °C). The efficient conversion of H2S over the N-rich carbon catalysts was attributed to the in situ generation of pyridine-N on the carbon matrix, which served as the active sites to promote the absorption and dissociation of H2S molecules, achieving a superior catalytic conversion rate of 99% and selectivity up to 95% at 180 °C.

Hydrogen sulfide removal from biogas on ZIF-derived nitrogen-doped carbons

This work studied the H2S removal from biogas, a CO2-containing gas mixture, over nitrogen-doped carbon materials deriving from the carbonization of ZIF-8. The H2S sorption performance on a series of N-doped porous carbon materials was investigated, in which the N-doping composition and textural properties of adsorbents were turned by varying the carbonization temperatures. By changing the carbonization temperatures from 750 to 950 ℃, the N contents vary in the range of 17.75−5.46 wt.%, and the BET surface area in the range of 373-757 cm2/g, while the H2S sorption capacity vary from 28.4–48.2 mg-H2S/g-sorb accordingly. Detailed characterization results (XPS, XRD, FTIR, and TGA/DTA) reveal the correlation of H2S sorption capacity with doped N species and porosity, in which the N surface area/volumetric density is crucial. This observation is corroborated by the kinetic studies by fitting H2S adsorption isotherms with Langmuir and Dubinin-Radushkevich isotherm (DR) isotherms. The H2S sorption capacity is independent of CO2 concentrations examined (up to 40 vol%) on ZIF-8-derived sorbents, making them promising candidates for H2S removal from biogas.

Hydrogen sulfide removal from geothermal fluids by Fe(III)-based additives

A new method to remove hydrogen sulfide from geothermal fluids during well operation was tested in situ at a geothermal site in Vienna (Austria). For this purpose, ferric iron was added either as granulated iron hydroxide or as FeCl3 solution into a reaction vessel containing the thermal water directly removed from the wells. From the container, the water would be pumped through a particle filter. Physicochemical parameters as well as sulfide were measured constantly over time before and after the filter. It was found that the sulfide was fully removed from the water by both iron additives. While the addition of FeCl3 led first to the formation of black iron(II) sulfide (FeS), which subsequently oxidized in presence of oxygen to Fe(III) hydroxide, no visible change of the granulated iron hydroxide was observed. The reaction time was longer when using the Fe(III) hydroxide additive as compared to the FeCl3 (completed in less than 20 min) but could be enhanced by increasing the amount of added particles. In all experiments the pH was constantly rising during the reaction from about 6.3 to 7.5, which was explained by loss of protons due to purging out of the gaseous H2S. The redox value, which was measured over time, remained rather constant after addition of granulated iron hydroxide (about −350 mV), but strongly increased from −350 mV to −50 mV after adding the FeCl3 suggesting a strong electron-consuming reaction. This can be explained by a two-step reaction: first, the Fe(III) was reduced to Fe(II) by oxidation of either sulfide or thiosulfate to sulfate. Afterward, the Fe(II) oxidized again by dissolved oxygen forming orange Fe(III) hydroxides. The application of the investigated method during operation of geothermal wells could prevent H2S-induced corrosion and would eliminate the toxic effects of this gas.

Removing hydrogen sulfide from a feed stream using suitable adsorbent materials

A series of materials, including sand (S) silica blue (SB), iron-exchanged sand (IES), zeolite 13X (Z), iron-exchanged zeolites (IEZ), and the waste material acid mine drainage sludge (AMDS), were used as adsorbents for the removal of hydrogen sulfide (H2S) from a feed stream in a pilot (bench)-scale study. Artificially polluted H2S gas streams were created using a gas cylinder with 10,000 ppmv of H2S in nitrogen (N2), which was used for further dilution. The adsorption performance of each sorbent material was assessed by dynamic breakthrough analysis. The sorbents were analyzed via Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-Ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. The efficiency of H2S removal was observed and compared between adsorbents under various operating conditions, such as different contact times and initial concentrations. The AMDS was discovered to have highest adsorption efficiency for H2S, of all adsorbents studied here. The Yoon-Nelson, Thomas and Adam-Bohart models were applied to study the effects of H2S concentration and flow rate on adsorption of H2S on AMDS, and the maximum adsorption capacity of 312.73 g g−1 was attained at 1000 ppmv and 0.5 L min−1 of H2S concentration and flow rate, respectively. This study found that all tested adsorbent materials have appreciable H2S adsorption capacity and AMDS in particular is an appropriate adsorbent for treatment of H2S-contaminated steam. Moreover, AMDS is a waste material and is available in abundance; hence, AMDS could be a practical choice for the adsorption of H2S from biogas.

Comprehensive Computational Analysis Exploring the Formation of Caprolactam-Based Deep Eutectic Solvents and Their Applications in Natural Gas Desulfurization

Several deep eutectic solvents (DESs) have been recently developed for extraction of hydrogen sulfide from natural gas. Among these newly designed DESs, a combination of caprolactam and tetrabutylammonium halides at a molar ratio of 1:1, as the DESs, has the highest desulfurization efficiencies. In this work, we explored the formation of caprolactam-based DESs using molecular dynamics (MD) simulations and ab initio computations. The results, based on the time average of the equilibrated production run of MD simulations, revealed ∼15% decrease in the ionic interactions of tetrabutylammonium halides and, more interestingly, ∼92% decrease in the hydrogen bonds between caprolactam, thereby explaining the strong depression in the melting point observed in experiments during the formation of the DES. Next, simulations of the DES with mixtures of methane and hydrogen sulfide were performed to mimic the natural gas desulfurization process. Efficient absorption of hydrogen sulfide from natural gas under different operating conditions (5000 and 10,000 ppm H2S, at 25 and 60 °C, and at 1 and 10 bar) can be observed from the simulations. The results further unveiled strong interactions between the anions of the DESs and hydrogen sulfide, with interaction energies 10-fold higher than those of methane/hydrogen sulfide, explaining the mechanism of desulfurization by these DESs. Additionally, two different DESs composed of monoethanolamines/methyltriphenylphosphonium bromide and urea/choline chloride were used to evaluate and compare their capacity to absorb hydrogen sulfide; however, we observed that the caprolactam-based DESs are highly efficient, particularly at low temperatures, low pressures, and low fuel/DES mole ratios. As the existing literature covers only experiments on the removal of hydrogen sulfide via the DESs, the simulations presented herein provide insights into the mechanism of absorption, thereby paving a way forward for better design of the DESs.

Preparation of activated red mud and its application for removal of hydrogen sulfide in air

Red mud is a highly alkaline solid waste from the Bayer process for aluminum production. Red mud reservoirs are usually considered as a potential environmental risk. The treatment of red mud is costly due to the lack of an effective and economical treatment technology. On the other hand, the main components of red mud are Fe2O3, Al2O3, SiO2, and Na2O, which could be employed as a promising precursor for the preparation of various nanomaterials. In this study, we prepared activated red mud by thermal and acid treatment method and applied it for adsorption of H2S in air. The red mud was activated under different temperatures (i.e., 200, 400, 600, and 800 oC for 4 h), types of acid (i.e., H2SO4 and HCl), and acid concentrations (i.e., 0.5, 1.5, and 2.5 M). The produced materials were then applied for H2S removal in air with concentration of 90 – 110 mg/m3 using a fix-bed adsorption column test. Results showed that red mud activated at 800 oC and with 1.5 M H2SO4 solution had the highest adsorption capacity of 29.38 mg/g with an average removal efficiency of 80.2%. The effects of gas flow rate and initial H2S concentration were also investigated, and the highest removal capacity was achieved at an inlet concentration of 100 mg/m3 and flow rate of 1 L/min. Both Langmuir and Freundlich adsorption isotherms were employed for modelling the H2S adsorption by this material and the experimental result was more fitted with the Langmuir isotherm. The thermal desorption and recyclability test were also conducted for evaluating the practical application of activated red mud material and 200 oC was the suggested desorption temperature with 81.7% adsorption capacity recovery.

Removal of H2S by vermicompost biofilter and analysis on bacterial community

AbstractThe vermicompost collected from dewatered domestic sludge as packing material in biofilter was investigated for hydrogen sulfide (H2S) removal. No nutrients or microbial inoculation was added throughout the experiment. The corresponding bacterial community characteristics in the vermicompost biofilter of different spatial levels were evaluated by Miseq high-throughput sequencing technique. The results showed that the vermicompost biofilter performed well during operation. The H2S removal efficiency reached nearly 100% under condition of the inlet concentration <350 mg m−3 and 0.25−0.35 m3 h−1 gas flow rate. The maximum elimination capacity of 20.2 g m−3 h−1 was observed at a flow rate of 0.35 m3 h−1. Furthermore, the amounts of biodegraded products and pH varied accordingly. In addition, the results from high-throughput sequencing revealed pronouncedly spatial variation of the vermicompost, and the Rhodanobacter, Halothiobacillus, Mizugakiibacter as well as Thiobacillus, which can play an important role in removing H2S, were predominant in the final vermicompost. These results imply that the vermicompost with diverse microbial communities has a good potential for eliminating H2S.

Liquid-Phase Oxidation of n-Propyl Mercaptan with Molecular Oxygen in the Presence of an Ammoniac Solution of Cobalt Phthalocyanine

The main kinetic features of the oxidation of n-propyl mercaptan with molecular oxygen in a model mixture with diesel fuel in the presence of an ammoniac solution of cobalt phthalocyanine have been studied. The rate equation of the reaction has been derived based on the experimental data, and optimum conditions of a waste-free process for removing hydrogen sulfide and mercaptans from crude petroleum have been selected.

Hydrogen Sulfide Removal from Biogas and Sulfur Production by Autotrophic Denitrification in a Gas-Lift Bioreactor

Biogas biodesulfurization has been successfully performed in biotrickling filters (BTFs). Nevertheless, elemental sulfur (S0) generation and accumulation in the packed bed cause an increase in oper...

Electrospun PU nanofiber composites based on carbon nanotubes decorated with nickel-zinc ferrite particles as an adsorbent for removal of hydrogen sulfide from air.

This study focuses on the synthesis of carbon nanotubes decorated with nickel-zinc ferrites and fabrication of polyurethane (PU) nanofiber containing CNT-ferrite composites as highly efficient adsorbents for removal of hydrogen sulfide. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transformed infrared (FTIR) spectroscopy, and powder X-ray diffraction (PXRD) are used to perform microstructural and morphological characterization of the electrospun nanofibrous composites. To show the efficiency of the composite as an adsorbent, a breakthrough test is carried out. It is shown that the PU-CNT-ferrite composites are fabricated almost uniformly with an average fiber diameter of 320nm and exhibit significant H2S breakthrough capacity (498mgH2S/g) compared to both the pristine PU and PU-CNT nanofibers. These electrospun nanofibers based on CNT-ferrite composites, already studied for H2S adsorption with promising results, open up new and interesting perspective into the design and fabrication of highly efficient membrane for practical application in the processes of air purification.

Investigation of the anticorrosion properties of nanoСЕС in amine environments

It is known that of the methods for purifying gas fraction from hydrogen sulfide is amine treatment. Various types of amines are used to remove hydrogen sulphide, carbon dioxide and carbon dioxide from petroleum gases. The choice of specific amine depends on the needs of the process. Mono-ethanolamine (MEA) (C2H4OH) NH2 and diethanolamine (DEA) (C2H4OH) 2NH are commonly used. Both are ammonia derivatives. The develop recommendations on the choice of material from which to make equipment for amine plants, comparative studies of corrosion resistance of traditionally used low-temperature carbon steel and nano-composite coatings obtained by electrodeposition method. The research has shown, that average corrosion rate on a standard sample (without coatings) is 0.9969 mm/year. Because of this, the frequency of changing equipment for cleaning oil from acidic components (hydrogen, sulfide, carbon dioxide and carbon dioxide) on average is 1 time per two years. During the one year testing period nano-composition coatings showed protective efficacy when exposed to acidic corrosion/erosion. It should be noted that there is a likelihood of damage to the coating during mechanical action. It is established that the use of protective coatings leads to an increase in corrosion resistance 24-56 times, which indicates the expediency of their use in these operating conditions.

The performance of simultaneous denitrification and biogas desulfurization system for the treatment of domestic sewage

This paper proposed a novel simultaneous denitrification and biogas desulfurization (SDBD) process for domestic sewage treatment and biogas upgrading. The process consisted of an expanded granular sludge bed (EGSB) for integrated autotrophic and heterotrophic denitrification (IAHD) and a biological aerated filter (BAF) for nitrification. The experiments were firstly conducted to investigate the performance of the lab-scale SDBD system with real domestic sewage at various hydraulic retention times (HRT). The system successfully achieved 83.0 ± 1.8% chemical oxygen demand (COD), 96.2 ± 1.8% ammonia (NH4+-N) and 67.3 ± 4.1% total nitrogen (TN) removal efficiency without biogas introduction, and the optimal HRT of EGSB and BAF was determined to be 6 h and 4 h, respectively. Then, biogas with three different hydrogen sulfide concentrations (1.5%, 1.2% and 0.9%) was introduced into the system. Almost complete removal of hydrogen sulfide in biogas was achieved in all the tested scenarios and the removal efficiency of COD, NH4+-N and TN maintained at around 86.8%, 98.4% and 83.4%, respectively. Microbial community analysis results showed that biogas introduction notably increased the bacterial diversity and particularly enriched the nitrate-reducing, sulfide-oxidizing bacteria, which forms the major contribution to the hydrogen sulfide removal in the system. Finally, we put the SDBD system in the whole treatment system of domestic sewage and discussed its economics. The results indicated that the total operating cost of sewage treatment plant could be saved to 0.59 RMB/m3, which proved SDBD system to be a promising alternative way in biological nitrogen removal and biogas desulfurization.