Hydrogen Equivalence Research Articles

Prediction and optimization of combustion performance and emissions for lean methane-hydrogen non-premixed flame using RSM-PSO methodology

To reduce carbon emissions, hydrogen is a clean energy as fuel to co-combustion with natural gas. This experimental work focuses on studying the effects of hydrogen addition to methane on combustion performance and emissions in non-premixed coaxial burners, establishing performance prediction models and optimizing operation conditions involving fuel velocity, hydrogen blending ratio and equivalence ratio. The global sensitivity and analysis of variance were adopted to quantify the contributions of independent variables on the output responses of temperature, O2, NO, CO and CO2 emissions. The hydrogen blending ratio is the most influential parameter, whose total effects of NO and CO2 emissions are 64.6% and 83.5%, respectively. The equivalence ratio is not significant to NO and CO2 emissions, and the adjusted determination coefficient of the reduced prediction model is 0.9707 and 0.9360, demonstrating a better goodness of fit. Based on the response surface model and particle swarm optimization algorithm, a Pareto was solved showing NO and CO2 emissions decrease by 42.0%–73.6% and 60.8%–89.5%, and peak temperature in the chamber centerline increases by 1.02%–3.61%. The research results provide a profound guide to predict and optimize combustion performance and emissions for methane-hydrogen non-premixed flame.

Thermodynamic and entropy generation analyses of Telsa-valve structured meso-scale combustors fuelled with hydrogen for thermophotovoltaic applications

The present work numerically examed the effects of hydrogen volume flow rates (Qv) and equivalence ratios (Φ) on thermal performances of meso-scale combustors structured with Tesla-vale type flow channels. Four distinct Tesla-valve configurations are implemented and then subsequently compared. The reverse-flow Tesla valve with counter-flow combustor (RC) structure shows a remarkable improvement of 72.6 % to the combustor wall temperature at Qv = 100 mL/min. The diodicity (Di) of the Tesla valve is found to be increased with a higher Qv, and a lower Φ contributes to a higher Di. Besides, Di is decreased when Φ goes up, stabilizing at Φ = 0.9. The reverse-flow Tesla valve exhibits a more uniform pressure distribution and entropy production than the forward-flow Tesla valve. At Φ = 0.9, the hydrogen-to-air ratio maximized heat release, producing the highest entropy. Tesla-valve structured combustors demonstrate near complete combustion before Φ reaching 0.9, the combustion efficiency (ηcombustion) is gradually decreased after Φ getting to 1.0. The RC construction achieved maximum combustion efficiency under conditions of insufficient oxygen. This present study demonstrates the feasibility of enhancing thermal and overall performances of meso-scale combustors structured with Tesla-valve channels, and revealing the key parameters effects on the combustion characteristics in these combustors.

Impacts of hydrogen fraction and equivalence ratio on the explosion characteristics of ethanol/hydrogen mixtures

With the anticipated widespread integration of biofuels and hydrogen fuels within the future energy landscape, the potential explosion hazards after their release within confined spaces under the atmospheric are deserving of heightened attention. The present work takes the mixtures of ethanol and hydrogen as the objects and experimentally studies the impacts of hydrogen fraction and equivalence ratio on the explosion characteristics in a constant-volume explosion vessel at 0.10 MPa and 400 K. The data reveals that an increase in the hydrogen fraction leads to a rise in the maximum explosion pressure during lean explosions but causes a decrease during rich explosions. Nonetheless, the duration of the explosion decreases with the increase of hydrogen fraction in all the explosions. In consideration of explosion pressure, the maximum pressure rise is found to be exponential in relation to the maximum explosion pressure. However, the confidence level diminishes significantly with an increase in the hydrogen fraction. Conversely, the maximum rate of pressure rise during an explosion appears to be a function of the duration of the explosion, suggesting that the reaction rate plays a more pivotal role in determining the hazardous level. Meanwhile, the duration of fast combustion steadily occupies approximately 83 % of the explosion duration. Furthermore, the deflagration index is no more than 30 MPa*m/s, namely, ethanol/hydrogen mixture is a promising fuel with mild hazardous potential.

Numerical Simulation and Field Experimental Study of Combustion Characteristics of Hydrogen-Enriched Natural Gas

For the safe and efficient utilization of hydrogen-enriched natural gas combustion in industrial gas-fired boilers, the present study adopted a combination of numerical simulation and field tests to investigate its adaptability. Firstly, the combustion characteristics of hydrogen-enriched natural gas with different hydrogen blending ratios and equivalence ratios were evaluated by using the Chemkin Pro platform. Secondly, a field experimental study was carried out based on the WNS2-1.25-Q gas-fired boiler to investigate the boiler’s thermal efficiency, heat loss, and pollutant emissions after hydrogen addition. The results show that at the same equivalence ratio, with the hydrogen blending ratio increasing from 0% to 25%, the laminar flame propagation speed of the fuel increases, the extinction strain rate rises, and the combustion limit expands. The laminar flame propagation speed of premixed methane/air gas reaches the maximum value when the equivalence ratio is 1.0, and the combustion intensity of the flame is the highest at this time. In the field tests, as the hydrogen blending ratio increases from 0% to nearly 10% with the increasing excess air ratio, the boiler’s thermal efficiency decreases as well as the NOx emission. This indicates that there exists a tradeoff between the boiler thermal efficiency and NOx emission in practice.

Structures of Laminar Lean Premixed H2/CH4/Air Polyhedral Flames: Effects of Flow Velocity, H2 Content and Equivalence Ratio

AbstractPolyhedral Bunsen flames, induced by hydrodynamic and thermo-diffusive instabilities, are characterized by periodic trough and cusp cellular structures along the conical flame front. In this study, the effects of flow velocity, hydrogen content, and equivalence ratio on the internal cellular structure of premixed fuel-lean hydrogen/methane/air polyhedral flames are experimentally investigated. A high-spatial-resolution one-dimensional Raman/Rayleigh scattering system is employed to measure the internal scalar structures of polyhedral flames in troughs and cusps. Planar laser-induced fluorescence of hydroxyl radicals and chemiluminescence imaging measurements are used to quantify the flame front morphology. In the experiments, stationary polyhedral flames with varying flow velocities from 1.65 to 2.50 m/s, hydrogen contents from 50 to 83%, and equivalence ratios from 0.53 to 0.64 are selected and measured. The results indicate that the positively curved troughs exhibit significantly higher hydrogen mole fractions and local equivalence ratios compared to the negatively curved cusps, due to the respective focusing/defocusing effect of trough/cusp structure on highly diffusive hydrogen. The hydrogen mole fraction and local equivalence ratio differences between troughs and cusps are first increased and then decreased with increasing measurement height from 5 to 13 mm, due to the three-dimensional effect of the flame front. With increasing flow velocity from 1.65 to 2.50 m/s, the hydrogen mole fraction and local equivalence ratio differences between troughs and cusps decrease, which is attributed to the overall decreasing curvatures in troughs and cusps due to the decreased residence time and increased velocity-induced strain. With increasing hydrogen content from 50 to 83%, the hydrogen mole fraction and local equivalence ratio differences between troughs and cusps are amplified, due to the enhanced effects of the flame front curvature and the differential diffusion of hydrogen. With increasing equivalence ratio from 0.53 to 0.64, a clear increasing trend in hydrogen mole fraction and equivalence ratio differences between troughs and cusps is observed at constant flow velocity condition, which is a trade-off result between increasing effective Lewis number and increasing curvatures in troughs and cusps.

Experimental study on the combustion characteristics of hydrogen/ammonia blends in oxygen

Carbon-free ammonia and hydrogen have various disadvantages when used individually, which limits their application as clean energies. These disadvantages can be effectively overcome by combining them as ammonia/hydrogen mixtures in a rational manner. In this paper, the combustion of ammonia/hydrogen in oxygen (the basic form of combustion) is experimentally investigated at various experimental conditions. The results display that the laminar burning velocities of ammonia/hydrogen/oxygen mixtures increase with increasing fuel ratios. At P0 = 0.5 atm and φ = 1.0, the laminar burning velocity proliferated from 1.91 m/s to 4.7 m/s with the increase of fuel ratio from 0.5 to 2.0. As the equivalence ratio increases, the laminar burning velocity rises first and then decreases, with the highest point appearing at φ = 0.8. The initial pressure has minimal impact on the laminar burning velocity. At x = 0.5 and φ = 1.0, the laminar burning velocity decreased slightly from 3.16 m/s to 2.96 m/s with the initial pressure increased from 0.1 atm to 1.0 atm. The empirical correlation among the laminar burning velocity versus the equivalence ratio and hydrogen ratio is given, and the laminar burning velocity of ammonia/hydrogen/oxygen under varying hydrogen ratios (0 %–100 %) and equivalence ratios (0.5–1.5) at atmospheric pressure can be well predicted by the empirical equations. NO is the most emitted NOx substance from hydrogen/ammonia combustion. The amount of NO produced decreases gradually with the growing equivalence ratio. The results of this research can be utilized to renew the basic flame data of ammonia/hydrogen mixture and are important for the development and application of ammonia/hydrogen mixtures.

Effects of Hydrogen Blending Ratio and Equivalence Ratio on the Dynamic Characteristics of Deflagration Shock Waves of CH4/H2 Mixtures

Effects of Hydrogen Blending Ratio and Equivalence Ratio on the Dynamic Characteristics of Deflagration Shock Waves of CH₄/H₂ Mixtures

Effect of NH3/H2/O2 premixed combustion on energy conversion enhancement and NOx emission reduction of the segmented nozzle micro-combustor in thermophotovoltaic system

In the context of international carbon neutrality, ammonia as a carbon-free energy has attracted extensive attention and research, and its renewability is the most prominent advantage. However, ammonia combustion is unstable, and harmful nitrogen oxides will be generated at the same time. In order to enhance the combustion stability of ammonia and control the emission of nitrogen oxides, the premixed combustion of NH3/H2/O2 in a segmented nozzle micro-combustor is studied in this paper. The mean wall temperature of segmented micro-combustor is 11.5 K higher than that of non-segmented micro combustor, and NO emission is reduced by 7.91 % at most. When mass fraction of hydrogen in the gas mixture XH2 increases from 10 % to 30 %, radiation efficiency increases by 13.5 %, but NO emission also increases. Considering that fuel-rich combustion can reduce NO emission, when hydrogen equivalence ratio ΦH2 = 1.0 and ammonia equivalence ratio ΦNH3 = 1.2, NO emission is reduced by 13.3 %, while radiation efficiency remains above 60 %. In addition, the radiation efficiency of the combustor increases by up to 4.15 % when the dimensionless length of segmented channel L6 is 7.5 mm and the dimensionless width of segmented channel D4 is 2.5 mm, and NO emission is reduced by 5.14 %.

Numerical simulation on combustion characteristics of methane/hydrogen blended fuel for non-premixed conical bluff body burner

Blending hydrogen into methane impacts flame stability, morphology, and pollutant emissions. This study, set against the backdrop of hydrogen-enriched natural gas combustion technology, employs a non-premixed coaxial burner with conical bluff body to create recirculation zones for flame stabilization. Combining EDC and GRI-Mech 3.0, the research fills in the gap of effects of hydrogen blending ratio (0–100%) and equivalence ratio vary (0.4–1.4) within a wide range. Keeping equivalence ratio and fuel volume flow rate as constants, as increasing hydrogen blending ratio, the mean velocity in the chamber decreases, the size of vortex structure located in outer recirculation zones reduces, and the flame length is shortened, illustrating the reaction zone shifts to chamber inlet. Furthermore, when Ф = 1.4, average temperature and temperature uniformity are averagely larger 59.82% and 4.21% than that under Ф = 0.4. The CO2 emission at XH2 = 80% is 54.70% averagely lower than that at XH2 = 0%, but peak concentration of NO increases.

Study of CH4-H2-CO-Air premixed combustion characteristics based on fractal dimension and flame crack method

The laminar combustion characteristics of CH4-H2-CO-Air are studied in a constant volume combustion chamber with different hydrogen content ratios and the initial conditions of 300 K and 0.2 MPa by schlieren technology. The influence laws of flame instability are analyzed through the influence laws of hydrogen content ratio and equivalence ratio (Φ) on the fractal dimensions of the flame contour and the ratio of the total flame face cracks' lengths to the flame radius (L/R), as well as the influence laws of hydrodynamic instability and thermal-diffusive instabilities on the flames. The results show that L/R is more sensitive to flame instabilities than flame front fractal dimensions due to a wider sampling range. After R exceeds a certain value, for lean and rich combustion conditions with the same distance from the stoichiometric ratio, the L/R is greater during lean combustion, and as the equivalence ratio gradually increases from 0.6 to 1.4, the effect of increasing hydrogen content (Hydrogen mole fraction ranges from 60% to 66.67%) on flame instability gradually shifts from promotion to suppression. This study has certain reference value for the combustion application of biomass synthesis gas.

Performance and Emission Optimisation of an Ammonia/Hydrogen Fuelled Linear Joule Engine Generator

This paper presents a Linear Joule Engine Generator (LJEG) powered by ammonia and hydrogen co-combustion to tackle decarbonisation in the electrification of transport propulsion systems. A dynamic model of the LJEG, which integrates mechanics, thermodynamics, and electromagnetics sub-models, as well as detailed combustion chemistry analysis for emissions, is presented. The dynamic model is integrated and validated, and the LJEG performance is optimised for improved performance and reduced emissions. At optimal conditions, the engine could generate 1.96 kWe at a thermal efficiency of 34.3% and an electrical efficiency of 91%. It is found that the electromagnetic force of the linear alternator and heat addition from the external combustor and engine valve timing have the most significant influences on performance, whereas the piston stroke has a lesser impact. The impacts of hydrogen ratio, oxygen concentration, inlet pressure, and equivalence ratio of ammonia-air on nitric oxide (NO) formation and reduction are revealed using a detailed chemical kinetic analysis. Results indicated that rich combustion and elevated pressure are beneficial for NO reduction. The rate of production analysis indicates that the equivalence ratio significantly changes the relative contribution among the critical NO formation and reduction reaction pathways.

Theoretical Evaluation of YSZ and Alumina-YSZ Thermal Barrier Coatings in a Hydrogen Enriched Combustion Environment

Abstract Yttria-stabilized zirconia (YSZ) ((ZrO2)0.93(Y2O3)0.07) and alumina-yttria-stabilized zirconia ((Al2O3)0.853 + (ZrO2)0.93(Y2O3)0.07) thermal barrier coatings (TBCs) were modeled in the presence of hydrogen-enriched combustion product gases to evaluate phase composition and thermal expansivity (coefficient of thermal expansion). Thermal equilibrium simulations for various equivalence ratios (0.5–0.75) and hydrogen enrichment percentages (0−50%) were conducted to determine the product gas composition for various combustor operating conditions. The obtained product gases were then used in a second thermal equilibrium simulation to demonstrate their effect on the defined thermal barrier coatings. The modeling predictions showed that hydrogen enrichment percentage and equivalence ratio were positively correlated to thermal expansivity for both the thermal barrier coatings examined. The alumina-YSZ composite coating exhibited a higher CTE, more closely matching the CTE of a metallic bond coat, for the studied conditions. This closer match of thermal expansivity results in less significant thermal stresses than the YSZ thermal barrier coating. An increase in hydrogen enrichment percentage and equivalence ratio yielded increased percentages of phase transitions from tetragonal zirconia (t-ZrO2) to cubic zirconia (c-ZrO2). The YSZ thermal barrier coating had a larger percentage of phase transitions throughout the operating range examined, which renders concerns for potential failure from thermal cycling and creep. Theoretical examination of the phase composition and thermal expansivity provided further insights into the fate and behavior of the thermal barrier coatings.

Thermal performances and NOx emission studies on an ammonia-hydrogen fueled double-channel outlet micro-combustor for thermophotovoltaic applications

In this work, we propose and examine an ammonia-hydrogen fueled micro-combustor with a single-channel inlet and double-channel outlet (SIDO). The combustion characteristics and nitrogen oxide emission of ammonia/hydrogen-oxygen premixed combustion are explored. Comparison is then made between the conventional and the proposed SIDO combustors. It is found that our proposed new design could lead to an increase of the outer wall temperature and reduced nitrogen oxide emission. The performances of different hydrogen blended ratios (Φb), inlet velocities (Vin), and equivalence ratios (Φ) are evaluated. It is found that increasing Φb reduces the maximum flame temperature and the pressure loss, enabling the flame to move upstream. When Φb is set to 25 %, the convective heat transfer performance reaches its optimal level. The wall temperature and its uniformity can be improved by increasing Vin. However, it is accompanied by increased NO emissions at the outlet. Increasing Φ can significantly reduce nitrogen oxide emission, and such a reduction effect is much more remarkable at a lower Φb. Examining the exergy efficiency is shown to be greatly improved by increasing Φb. Increasing Φ could reduce the combustion efficiency of hydrogen in the mixed fuel and have almost no effect on ammonia. This study demonstrates the feasibility of improving thermal performance and reducing emissions by varying its structure for thermophotovoltaic applications.

Flashback propensity due to hydrogen blending in natural gas: Sensitivity to operating and geometrical parameters

Hydrogen has emerged as a promising option for promoting decarbonization in various sectors by serving as a replacement for natural gas while retaining the combustion-based conversion system. However, its higher reactivity compared to natural gas introduces a significant risk of flashback. This study investigates the impact of operating and geometry parameters on flashback phenomena in multi-slit burners fed with hydrogen-methane-air mixtures. For this purpose, transient numerical simulations, which take into account conjugate heat transfer between the fluid and the solid walls, are coupled with stochastic sensitivity analysis based on Generalized Polynomial Chaos. This allows deriving comprehensive maps of flashback velocities and burner temperatures within the parameter space of hydrogen content, equivalence ratio, and slit width, using a limited number of numerical simulations. Moreover, we assess the influence of different parameters and their interactions on flashback propensity. The ranges we investigate encompass highly H2-enriched lean mixtures, ranging from 80% to 100% H2 by volume, with equivalence ratios ranging from 0.5 to 1.0. We also consider slit widths that are typically encountered in burners for end-user devices, ranging from 0.5mm to 1.2mm. The study highlights the dominant role of preferential diffusion in affecting flashback physics and propensity as parameters vary, including significant enrichment close to the burner plate due to the Soret effect. These findings hold promise for driving the design and optimization of perforated burners, enabling their safe and efficient operation in practical end-user applications.

Techno-economic and environmental assessment of hydrogen production through ammonia decomposition

Hydrogen is one of the potential candidates to replace fossil fuels to meet net zero emissions target. This study reports a detailed techno-economic and environmental assessment of hydrogen production through ammonia decomposition. The case study is based on a multiple catalytic packed bed reactor with intermediate heating system. Aspen plus® and MATLAB® were linked to evaluate economic and environmental impact of the process. The process parameter like furnace temperature, flue gas recirculation, ammonia decomposition temperature, market ammonia supply pressure, ammonia decomposition pressure, hydrogen purification unit's pressure and equivalence ratio, and economic parameters of capital expenditure (CAPEX) and operating expenditure (OPEX) were considered. The overall thermal efficiency of the developed process is found to be 79%. The levelized cost of hydrogen (LCOH) is estimated and found to be 6.05 USD/kg of H2 based on CAPEX and OPEX. A major contribution of up to 62.2% to LCOH comes from the price of feed Ammonia. Based on 25-year plant life with 10% discounted rate the plant is economically viable, with a return on investment of 23.7%, in a payback period of 3.58 years. Global warming potential of the process is also carried out.

Study on lean combustion of ammonia-hydrogen mixtures in a pre-chamber engine

Ammonia holds promise for achieving zero carbon emissions from internal combustion engines. The pre-chamber turbulent jet ignition, characterized by multipoint distributed ignition and rapid combustion, could be applied to ammonia combustion to extend combustion limits and stability. This study investigates the impacts of hydrogen energy fraction (Hfrac), equivalence ratio, and ignition timing on the combustion and emission characteristics of ammonia-hydrogen mixture at lean combustion conditions in a pre-chamber (PC) marine engine by CFD Simulation. In H2-fuel active PC mode, increasing the hydrogen content or achieving stoichiometric combustion within the PC will shorten the cold jet phase and accelerate the formation of a more intense hot jet. As the Hfrac and the equivalence ratio in the main-chamber increase, the combustion pressure, temperature, and heat release rate (HRR) rise, while the combustion duration shortens due to enhanced reactivity, potentially leading to end gas auto-ignition and knock due to lower auto-ignition energy of the mixture. NO primarily forms near the flame front, and both NO concentration and the generation area increase with an increase in hydrogen content and equivalence ratio. Fuel-NO is likely to be the dominant factor in NO generation with lean combustion conditions. N2O, as a product of NH3 low-temperature combustion, is mainly concentrated near the flame front. An increase in unburned NH3 emissions corresponds to an increase in N2O emissions. Delaying the ignition timing to reduce NOx emissions is primarily achieved by controlling NO emissions, even though there is a slight increase in N2O.

Turbulent burning velocity of hydrogen/n-heptane/air propagating spherical flames: Effects of hydrogen content

This study investigated the flame propagation and turbulent burning velocity of hydrogen/n-heptane/air mixtures subjected to differential diffusion and flame stretch induced by turbulence at different hydrogen molar fractions (XH2 = 0–100%), equivalence ratios (ϕ = 0.5–1.0) and turbulence intensities (u’ = 0–3.62 m/s). The experiments were carried out on a medium-scale, fan-stirred cylindrical combustion chamber generating near-isotropic turbulence. Results show that as hydrogen content increases, the turbulent flame propagation speed tends to be affected by stronger differential diffusion and weakened turbulence, characterized by decreasing Lewis number (Le) and Karlovitz number (Ka) within a similar range of turbulence intensity. Among them, the effect of differential diffusion on the normalized turbulent propagation speed (d<r>/dtσSL) appears to be well correlated with ReT,flameLe-2, where ReT,flame represents the turbulent flame Reynolds number. However, inconsistencies in the fitting parameters for this scale are observed at different XH2, highlighting the impact of substantial variations in flame stretch induced by turbulence. Therefore, the normalized turbulent flame propagation velocity under varying hydrogen contents is proposed to be accurately predicted by d<r>/dtσSL-1 = 0.07Ka0.32(ReT,flameLe−2)0.5. The synergistic effects of Le and Ka can also account for the peak phenomenon in the normalized turbulent burning velocity (ST/SL) observed at 85% hydrogen content. Furthermore, the quantitative characterization of turbulence and differential diffusion under extensive experimental data (Ka = 0.03–90) is studied. As evidenced by the Damköhler theoretical hypothesis, the two-stage trend between ST/SL and (u’/SL)Le-1 is identified with a transition near unity Ka. The modified correlations for turbulent burning velocity in terms of (u’/SL)Le-1 and Ka0.2 are obtained with consideration of the differential diffusion and flame stretch rate induced by turbulence, which show good predictive performance for data at different turbulence regime diagrams regardless of fuel type and equipment size.

Numerical research on kerosene/hydrogen/air rotating detonation engines with discrete injection strategies

The two-dimensional simulation of two-phase rotating detonation engines commonly adopts the nozzle–wall configuration, which is inconsistent with the real configurations in experiments. In the annular slot–nozzle structure, the oxidant is completely injected into the annular gap, whereas the fuel is partially injected into the nozzle hole, which is closer to the real operation condition. In this study, a gas–liquid two-dimensional numerical investigation was conducted to explore a more accurate operating condition with a discrete injection configuration. The effects of the kerosene/hydrogen injection area ratio and hydrogen equivalence ratio on the propagation mode and operating performance were investigated. The simulation results show that the kerosene droplet/hydrogen/air gas–liquid two-phase rotating detonation wave exhibits different propagation modes depending on the hydrogen equivalence ratio. When the hydrogen equivalence ratio (φH2) is 0, the detonation wave cannot be successfully initiated. When φH2 is increased to 0.2 and 0.5, a single-wave propagation mode is generated. When φH2 is 1, a double-wave propagation mode is produced initially in the combustion chamber and is subsequently converted into the deflagration mode. The flow field structure, velocity performance, and propulsive performance in the detonation combustion chamber are analyzed. It was found that an appropriate amount of hydrogen addition to the liquid kerosene detonation can aid in stabilizing the propagation of the detonation wave and improving the performance of the detonation engine.

Numerical investigation on the effect of hydrogen share in NH3/H2 blends in a turbulent lean-premixed swirl burner

Climate change and the energy crisis urge the transition from fossil to renewable fuels. Ammonia and hydrogen are the most versatile carbon-free chemical energy carriers. Hydrogen-diluted ammonia combustion can drastically lower the emission of nitrogen oxides. The present paper focuses on the numerical analysis of ammonia/hydrogen combustion in a lean-premixed swirl burner, highlighting the effect of hydrogen share and equivalence ratio. The hydrogen share notably influences the axial position of the heat release maximum due to the higher reactivity, while it marginally influences the global velocity field. Unburned ammonia was observed at lean condition and low hydrogen concentration. At ultra-lean conditions, nitrogen oxide emission increases with hydrogen content, while a maximum can be reached by increasing the equivalence ratio. The values are compared to experimental data from the literature. Dinitrogen oxide emission decreases with both hydrogen concentration and equivalence ratio. Non-reacting flow field was validated by Particle Image Velocimetry measurements.

Study on flame propagation and inherent instability of hydrogen/ammonia/air mixture

To improve the safety and reliability of hydrogen energy, this paper studied the flame propagation and instability characteristics of hydrogen/ammonia/air mixture under different hydrogen contents, equivalence ratios and initial pressures. The results show that three typical phenomena are observed in the premixed hydrogen/ammonia/air flame propagation process under different experimental conditions. In a stable flame, the roughness of the flame surface does not increase, while during unstable flame expansion, the cracking of the flame surface splits and increases. In addition, under the condition of low equivalence ratio and hydrogen content, significant flame uplift is observed. With the increase in hydrogen content, the flame thickness and critical instability radius of the hydrogen/ammonia/air mixture decrease monotonously. The increase of hydrogen content mainly strengthens the hydrodynamic instability, leading to the weakening of flame stability. With the increase of the equivalence ratio, the Markstein length and the critical instability radius increase monotonically. The minimum value of flame thickness appears at the equivalence ratio of 1.0. The Lewis number is always less than 1 for poor combustion and greater than 1 for rich combustion. An increase in the hydrogen content only moves the Lewis number further away from 1. In rich burn, the thermal-diffusion is beneficial to flame stability, and the flame thickness increases with the increasing equivalence ratio. Under the combined effect of thermal-diffusion and hydrodynamic instability, the overall stability of the hydrogen/ammonia/air flame gradually increases with the increasing equivalence ratio. With the increase of initial pressure, the flame thickness decreases gradually. The critical instability radius and Markstein length both decrease rapidly with the increase of initial pressure.