Hydrodynamic Measurements Research Articles

Measurements of groundwater, hydrodynamics, and sand characteristics at a dissipative sea turtle nesting beach

Beach groundwater and nearshore hydrodynamic data were collected during a field experiment along two dissipative beach transects on Galveston Island, Texas, in the fall of 2023. The monitored beaches serve as nesting habitat for the critically endangered Kemp’s ridley sea turtle. Conditions ranged from calm to stormy, with two storms occurring during the experiment, inundating the entire beach up to the dune toe. Collected hydrodynamic data include readings from pressure loggers submerged in the foreshore and mounted in groundwater wells in the backshore, data from two wave buoys about 1.5 km offshore, and GoPro timestacks of the instantaneous waterline (wave runup). Other collected data include bathymetry and topography surveys, subsurface temperature and moisture content readings, and sediment characteristics. This comprehensive dataset can be used to (1) study relevant beach inundation and groundwater processes, including their effect on the local ecosystem (e.g., repeated flooding of sea turtle nests), (2) study the propagation of nearshore hydrodynamic processes into the beach matrix and groundwater table, and (3) validate existing beach groundwater models.

Interactive toxicity effects of metronidazole, diclofenac, ibuprofen, and differently functionalized nanoplastics on marine algae Chlorella sp.

Pharmaceutical products (PPs) and nanoplastics (NPs) are prominent emerging contaminants that pose serious threats to marine ecosystems. The present study aimed to investigate both pristine and combined toxicity of PPs (metronidazole, diclofenac, and ibuprofen) and polystyrene nanoplastics (PSNPs) with amine (NH2-PSNPs) and carboxyl (COOH-PSNPs) surface functionalization on marine microalgae Chlorella variabilis. Toxicity assessment included the evaluation of growth inhibition, total reactive oxygen species production, malondialdehyde content, antioxidant activity, and photosynthetic activity. Furthermore, changes in the surface functional groups of the algae after exposure to contaminants were examined. The correlation among the toxicity endpoints was assessed using Pearson correlation and cluster heatmap analysis. Zeta potential analysis and hydrodynamic size measurements revealed that the PSNPs became unstable in the presence of PPs. This instability facilitated the aggregation and rapid settlement of PSNPs, consequently impeding their direct interaction with algal cells. Growth inhibition results indicated that Chlorella variabilis exhibited minimal growth inhibition when exposed to pristine PPs (1 mg L-1), whereas PSNPs (1 mg L-1) caused substantial growth inhibition. Notably, the combined toxicity of PSNPs and PPs was lower compared to pristine PSNPs. The independent action model revealed that the combination of PPs and PSNPs showed an antagonistic mode of interaction. The potential reasons for the decreased toxicity observed in the mixture of PSNPs and PPs compared to pristine PSNPs can be attributed to diminished oxidative stress and enhanced photosynthetic activity. These findings provide valuable insights into the role of PPs in modulating the toxicity of PSNPs towards microalgae.

Nearshore Migration of Munitions and Canonical Objects Under Large-Scale Laboratory Forcing

A quantitative understanding of the migration of munitions and canonical objects in the nearshore is needed for the effective management of contaminated sites. Migrations of munitions with a density range of 2000 kg/m3 to 5720 kg/m3 were quantified in a large-scale wave flume. The forcing consisted of six cases of varying wave heights, periods, still water depths, and durations. The cross-shore profile, typical of natural sandy beaches, was sub-divided into swash, surf, and offshore zones. Overall, 2228 migration measurements were recorded with 16% and 84% of the migration observations classified as “motion” (net distance > 0.5 m) and “no motion” (net distance ≤ 0.5 m), respectively. The probability of munitions migration increased with proximity to the shoreline. There was a nearly equal probability of onshore or offshore migration in the swash zone. Migration in the surf zone tended to be offshore-directed (65%), while migration was onshore-dominant (65%) in the offshore zone. Migration in the offshore zone was preferentially onshore due to skewed waves over flat bathymetry. Less dense munitions in the offshore zone may have migrated offshore likely still related to the skewed nature of the wave profile causing transport in both directions through the majority of the wave phase. The largest migration distances occurred in the surf zone likely due to downslope gravity. Migration in the surf and swash zones is a balance between skewed/asymmetric forcing and downslope gravity, with downslope gravity tending to be pronounced provided the forcing is sufficient to initiate motion. An exception was sometimes observed in the swash zone where onshore forcing was sufficient to transport munitions to the seaward side of the berm where they became trapped in a bathymetric depression between the dune and berm. Relating overall migration (Lagrangian) to fixed hydrodynamic measurements (Eulerian) was ineffective. Parameters such as the Shields number, wave skewness, and wave asymmetry estimated from the closest measurement location were insufficient to predict migration. Large scatter in the migration data resulting from competing hydrodynamic, morphodynamic, and munitions response processes makes robust deterministic predictions with flow statistics and dimensionless numbers difficult.

Coastal Dune Erosion and Slumping Processes in the Swash‐Dune Collision Regime Based on Field Measurements

AbstractThis paper studies hydrodynamic and morphodynamic field measurements of two storms with dune erosion in the swash‐dune collision regime. It analyses (a) the behavior and change of the total dune profile over the course of both storms (b) the erosion rate at the dune base, (c) the slumping frequency, and (d) the volumes of individual slumps. The erosion rate at the dune base shows a strong positive correlation with the square of the total water levels that were exceeded for 2% of the time, recorded approximately 5–6 m in front of the dune face (r = 0.91). Individual slumping events occurred when nearly all sediments from previous slumps at the dune base were transported away from the dune. A strong positive correlation was found between the time between two consecutive slumps, and the volume of the first slump divided by the mean erosion rate between the two slumps (r = 0.90). As a consequence, smaller slumps were followed more rapidly by a new slump than larger slumps, under identical erosion rates. The majority of the slumping events occurred after the last wave impact before a slumping event, when the instantaneous water level in front of the dune was still retreating. No clear process based on the incident hydrodynamics could be identified that determined the size of individual slumps. Overall, the results of this study suggest that the morphodynamic behavior of the upper dune face and dune crest is primarily steered by the erosion at the dune base.

The interaction between vegetation patchiness and tidal flows in a shortleaf seagrass meadow

AbstractSeagrasses are critical coastal habitats that provide numerous ecosystem services. The inherent patchiness within meadows exerts a significant influence on the flow‐vegetation interaction, which, in turn, affects the array of services provided by these environments. We present field observations of vegetation distribution and hydrodynamic measurements within and surrounding an approximately 2 m diameter gap (bare sediment) in a fragmented seagrass meadow. We show that variability in mean flows and turbulence is correlated with meadow structure at small (O (100 m)) and large (O (102 m)) spatial scales. Our observations reveal that bare gaps within seagrass meadows lead to faster flows and lower bed elevations. Despite slower flow speeds above the dense seagrass adjacent to the gap, the rates of dissipation of turbulent energy above the vegetation are typically around an order of magnitude larger than above the bare bed. Associated with this enhanced dissipation of turbulent energy, we observed a dominance of down‐deceleration events promoting fluid exchange and mixing and driving mass flux into the canopy. Analysis of directional variograms demonstrates that the major continuity axis within NDVI (normalized difference vegetation index) imagery (used as a proxy for vegetation biomass) coincides with the major axis of flow on both gap and meadow scales. Conversely, along the axis of minor flow variance, vegetation remains dense and exhibits greater uniformity. These findings indicate a feedback mechanism between seagrass meadow patchiness and spatial structure through flow modification, which may be beneficial for plant development.

Facile Synthesis of Sodium Alginate (SA)-Based Quaternary Bio-Nanocomposite (SA@Co-Zn-Ce) for Antioxidant Activity and Photocatalytic Degradation of Reactive Red 24

This study introduces a new strategy for the environmentally friendly catalytic degradation of Reactive Red 24 (RR24) dye using sunlight. We developed a cost-effective quaternary nanocomposite by immobilizing a sodium alginate biopolymer over bioengineered Co-Zn-Ce nanoparticles, forming an SA@Co–Zn–Ce nanocomposite (where SA means sodium alginate). This composite also demonstrated an exceptional antioxidant potential of approximately 89%, attributed to the synergistic effect of sodium alginate and green-synthesized Co–Zn–Ce nanoparticles (biosynthesized using Ocimum sanctum leaf extract as a reducing agent). Scanning electron microscopy revealed grain sizes of 28.6 nm for Co–Zn–Ce NPs and 25.59 nm for SA@Co–Zn–Ce nanocomposites (NCs). X-ray diffraction showed particle sizes of 16.87 nm and 15.43 nm, respectively. Co–Zn–Ce NPs exhibited a zeta potential of 1.99 mV, whereas the sodium alginate-anchored Co–Zn–Ce showed −7.99 mV. This indicated the entrapment of negatively charged ions from sodium alginate, altering the surface charge characteristics and enhancing the photocatalytic degradation of RR24. Dynamic light scattering revealed an average particle size of approximately 81 nm for SA@Co–Zn–Ce NCs, with the larger size due to the influence of water molecules in the colloidal solution affecting hydrodynamic diameter measurement. The SA@Co–Zn–Ce NCs exhibited a CO2 adsorption capacity of 3.29 mmol/g at 25 °C and 4.76 mmol/g at 40 °C, indicating temperature-dependent variations in adsorption capabilities. The specific surface area of Co–Zn–Ce oxide NPs, measured using Brunauer–Emmett–Teller (BET) analysis, was found to be 167.346 m2/g, whereas the SA@Co–Zn–Ce oxide nanocomposite showed a surface area of 24.14 m2/g. BJH analysis revealed average pore diameters of 34.60 Å for Co–Zn–Ce oxide NPs and 9.26 Å for SA@Co–Zn–Ce oxide NCs. Although the immobilization of sodium alginate on Co–Zn–Ce oxide NPs did not increase the adsorption sites and porosity of the composite, as evidenced by the N2 adsorption–desorption isotherms, the SA@Co–Zn–Ce oxide NCs still demonstrated a high photocatalytic degradation efficiency of RR24.

Thermal and Hydrodynamic Measurements of a Novel Chaotic Micromixer to Enhance Mixing Performance

In this study, three-dimensional simulations were conducted on a new passive micromixer to assess the thermal and hydrodynamic behaviors of Newtonian and non-Newtonian fluids subjected to low generalized Reynolds numbers (0.1 to 50) and shear-thinning properties. To acquire a more profound comprehension of the qualitative and quantitative fluctuations in fluid fraction using the CFD Fluent Code, the mass mixing index, rheological behavior, performance index, mixing energy cost, mass fraction distributions, temperature contours, and pressure drop were compared to illustrate the importance of the mixer geometry in the context of two miscible fluids with varying inlet temperatures. The selected geometry is characterized by a robust chaotic flow that substantially enhances thermal and hydrodynamic performance across all Reynolds numbers. A mass mixing exceeding 72.5% is obtained when Re = 5, reaching 93.5% when Re = 50. Furthermore, the evolution of thermal mixing for all behavior indexes reaches a step of 98% with minimal pressure losses. This work enabled the demonstration of a chaotic geometry in a highly efficient mixing system, leading to enhanced thermal performance for both Newtonian and non-Newtonian fluids. The results of the hydrodynamic and thermal characterization of the mixing of shear-thinning fluids within the micromixers under investigation are conclusive.

Modelling spillway and weir operation during major overflows. On optical measurements in prototypes: pros and cons

At weirs and dams, the spillway flow is a high-velocity turbulent motion operating at very-large Reynolds numbers and physical measurements are challenging. In these high-speed free-surface flows, the upstream flow is not aerated and some air entrainment takes place downstream of the inception of free-surface aeration. The state-of-the-art knowledge in large dam spillway hydrodynamics currently reaches a major knowledge gap because of a lack of detailed quantitative field measurements in both the non-aerated and air-water flow regions. In this contribution, a review of prototype observations and measurements is presented based upon optical data sets conducted between 2010 and 2022 during floods at several large dam spillways in eastern Australia, with a focus on the key requirements for successful optical velocity measurements in high-velocity (prototype) spillway flows. The experience and expertise gained in these studies provide new insights into the operation of large dam spillways and their modelling. The intricacy of field measurement techniques is discussed using the experience at dam spillways during large floods, encompassing optical velocity measurements of spillway hydrodynamics at two structures. Overall, the paper presents current challenges on the modelling of large dam spillway flows.

Pseudoternary Phase Diagram and Antibacterial Activity of Microemulsion-Based Citronella Oil

Citronella oil (CTO) is extracted from citronella leaves by maceration or steam distillation process, which has antibacterial and insect-repellent activities. However, the use of CTO is limited and requires modification in other formulations, such as microemulsion (ME), to increase its bioactivities. ME consists of oil, water, surfactant and/or cosurfactant and is commonly applied in food and beverages, cosmetics, and carrier for drug delivery applications. CTO was used as the oil phase for ME with nonionic surfactant and ethanol as a cosurfactant for lowering interfacial tension between oil and water phase. Subsequent observations regarding stability and antibacterial tests were carried out on ME formulations with surfactant/cosurfactant mixture of 2 due to its largest ME area. A hydrodynamic diameter analysis was also carried out to see the stability of the ME within a period of 50 d. ME with 10% CTO, 30% surfactant mixture, and 60% water showed the best formulation observed from the consistent hydrodynamic diameter measurement. In addition, ME with different formulations could inhibit the growth of Escherichia coli and Staphylococcus aureus by more than 90%. From this research, CTO-based ME potentially improve and develop drug carrier applications, especially via topical route.

Quantifying Wave-Induced Hydrodynamics Near A Saltmarsh Cliff: An Experimental Piv Study

Nature-based flood defences receive increasing interest as a viable option for improving flood safety worldwide. A contemporary case is using the ability of saltmarshes to attenuate waves during storm conditions for strengthening coastal flood defences. To ensure a long-term reinforcement of flood protection, it is important to understand the erosion mechanisms of saltmarshes during storms. One of the critical locations for erosion is at the transition between the saltmarsh and the bare mudflat, often characterized by a vertical step or cliff. These cliffs vary between 0.2 to 2.0 m in height, depending on soil characteristics and local hydrodynamics. However, wave-induced hydrodynamics that controls the (mass) erosion at the saltmarsh cliff are not fully understood. Also the role of saltmarsh vegetation on these near-cliff hydrodynamics are not clearly quantified. In this research, we present high-resolution measurements of wave-induced hydrodynamics at a saltmarsh cliff performed in a scaled wave flume experiment.

Quantitative Measurement of Hydrodynamics in a Binary Fluidized Bed by Capacitance Probes

Quantitative Measurement of Hydrodynamics in a Binary Fluidized Bed by Capacitance Probes

Exploring Host-Guest Interactions within a 600 kDa DegP Protease Cage Complex Using Hydrodynamics Measurements and Methyl-TROSY NMR.

The DegP protease-chaperone operates within the periplasm of Gram-negative bacteria, where it assists in the regulation of protein homeostasis, promotes virulence, and is essential to survival under stress. To carry out these tasks, DegP forms a network of preorganized apo oligomers that facilitate the capture of substrates within distributions of cage-like complexes which expand to encapsulate clients of various sizes. Although the architectures of DegP cage complexes are well understood, little is known about the structures, dynamics, and interactions of client proteins within DegP cages and the relationship between client structural dynamics and function. Here, we probe host-guest interactions within a 600 kDa DegP cage complex throughout the DegP activation cycle using a model α-helical client protein through a combination of hydrodynamics measurements, methyl-transverse relaxation optimized spectroscopy-based solution nuclear magnetic resonance studies, and proteolytic activity assays. We find that in the presence of the client, DegP cages assemble cooperatively with few intermediates. Our data further show that the N-terminal half of the bound client, which projects into the interior of the cages, is predominantly unfolded and flexible, and exchanges between multiple conformational states over a wide range of time scales. Finally, we show that a concerted structural transition of the protease domains of DegP occurs upon client engagement, leading to activation. Together, our findings support a model of DegP as a highly cooperative and dynamic molecular machine that stabilizes unfolded states of clients, primarily via interactions with their C-termini, giving rise to efficient cleavage.

Molecular Dynamics and In Vitro Studies Elucidating the Tunable Features of Reconfigurable Nanodiscs for Guiding the Optimal Design of Curcumin Formulation.

In this study, we advance our exploration of Apolipoprotein A-I (apoA-I) peptide analogs (APAs) for their application in nanodisc (ND) assembly, focusing on the dynamic conformational characteristics and the potential for drug delivery. We explore APA-ND interactions with an emphasis on curcumin encapsulation, utilizing molecular dynamic simulations and in vitro assessments to evaluate the efficacy of various APA-ND formulations as drug carriers. The methodological approach involved the generation of three unique apoA-I α-11/3 helical mimics, resulting in fifteen distinct APAs. Their structural integrity was rigorously assessed using ColabFold-AF2, with particular attention to pLDDT and pTM scores. Extensive molecular dynamics simulations, covering 1.7 μs across 17 ND systems, were conducted to investigate the influence of APA sequence variations on ND stability and interactions. This study reveals that the composition of APAs, notably the presence of Proline, Serine, and Tryptophan, significantly impacts ND stability and morphology. Oligomeric APAs, in particular, demonstrated superior stability and distinct interaction patterns compared to their monomeric counterparts. Additionally, hydrodynamic diameter measurements over eight weeks indicated sequence-dependent stability, highlighting the potential of specific APA configurations for sustained colloidal stability. In vitro study successfully encapsulated curcumin in [AA]3/DMPC ND formulations, revealing concentration-dependent stability and interaction dynamics. The findings underscore the remarkable capability of APA-NDs to maintain structural integrity and efficient drug encapsulation, positioning them as a promising platform for drug delivery. The study concludes by emphasizing the tunability and versatility of APA-NDs in drug formulation, potentially revolutionizing nanomedicine by enabling customized APA sequences and ND properties for targeted drug delivery.

Decreased transport of nano- and micro-plastics in the presence of low-molecular-weight organic acids in saturated quartz sand

Low-molecular-weight organic acids (LMWOAs) and nano- and micro-plastics (NPs and MPs) are both widely distributed in terrestrial systems. To better understand the influence of LMWOAs on the transport of NPs and MPs, the effects of 0.5 mM citric- (CA), malic- (MA), and tartaric- (TA) acid on the transport of nano- (0.51 μm, PS NPs) and micro- (1.1 μm, PS MPs) polystyrene particles (2 mg L−1) in saturated quartz sand were investigated. All three LMWOAs decreased the transport of PS NPs and MPs, regardless of ionic composition or strength (0.1–10 mM NaCl and 0.1–1 mM CaCl2). Further investigation revealed that the interfacial interactions between PS-quartz sand surfaces and PS-PS were altered by LMWOAs. LMWOAs adsorbed to quartz sand surfaces could serve as new deposition sites, as evidenced by the decreased transport of PS NPs and MPs in quartz sand that was subjected to pre-equilibration with selected MA, the low inhibition of PS transport with low concentrations of LMWOAs (0.1 mM), and also the adsorption of LMWOAs onto quartz sand surfaces by batch experiments. Meanwhile, the adsorption of LMWOAs on PS, hydrodynamic measurement and visual TEM observation together clarified the slight aggregation of PS NPs and MPs in suspensions, inducing the subsequent decrease in transport. Among them, the adsorption of LMWOAs onto quartz sand surfaces was found to be the main factor dominating the decreased transport of both PS NPs and MPs in saturated quartz sand.

Measurements of morphodynamics of a sheltered beach along the Dutch Wadden Sea

Abstract. A field campaign was carried out at a sheltered sandy beach with the aim of gaining new insights into the driving processes behind sheltered beach morphodynamics. Detailed measurements of the local hydrodynamics, bed-level changes and sediment composition were collected at a man-made beach on the leeside of the barrier island Texel, bordering the Marsdiep basin that is part of the Dutch Wadden Sea. The dataset consists of (1) current, wave and turbidity measurements from a dense cross-shore array and a 3 km alongshore array; (2) sediment composition data from beach surface samples; (3) high-temporal-resolution RTK-GNSS beach profile measurements; (4) a pre-campaign spatially covering topobathy map; and (5) meteorological data. This paper outlines how these measurements were set up and how the data have been processed, stored and can be accessed. The novelty of this dataset lies in the detailed approach to resolve forcing conditions on a sheltered beach, where morphological evolution is governed by a subtle interplay between tidal and wind-driven currents, waves and bed composition, primarily due to the low-energy (near-threshold) forcing. The data are publicly available at 4TU Centre for Research Data at: https://doi.org/10.4121/19c5676c-9cea-49d0-b7a3-7c627e436541 (Van der Lugt et al., 2023).

Large-scale spatial reconstitution of groundwater fluxes in a karst aquifer on the basis of hydrodynamic and hydrodispersive measurements

This article presents a multiphysics-based approach for a large-scale spatial reconstitution of head and tracer tests responses measured in a regional scale karst aquifer in Southern France. The main dataset consists in hydraulic heads measured in 11 wells during 6 weeks and 4 tracer tests. A pump station withdraws groundwater from this aquifer at varying flow rates during days and nights to supply water to Montpellier agglomeration, generating a periodic signal which propagates in the whole aquifer. Some of the measurements show a periodic response, some others not. As a first step, this specificity is exploited to localize spatially the preferential flow paths network with a structural deterministic inversion approach. Then, inversions of the weekly averaged head variations are performed on the first and the last weeks of the dataset (showing different drawdown trends) to assess the hydraulic diffusivity field. Finally, the tracer restitutions at the spring are inverted in order to optimize the conduits diameters associated to the fastest flow paths.The proposed approach permits a satisfying reproduction of the hydraulic heads and tracer measurements. Simulations with the optimized model on a week of the dataset not used in the inversion allows to validate the inversion result. The inverted model suggests that daily periodic responses represent efficient constraints for the localization of the preferential flows, while the integration of weekly head variations provides a characterization of the hydraulic properties between each well and the closest preferential flow paths, and tracer restitutions permit to characterize the velocities in the preferential paths.

PIV measurement of cavitating flow around a pitching hydrofoil

Particle Image Velocimetry (PIV) and hydrodynamic measurements were applied to investigate the cavitating flow of a pitching hydrofoil in the form of triangular wave motion (mean incidence α 0=10°, amplitude Δα=5° and pitching frequency f*=2Hz). The Reynolds number is Re=4.5×105. The cavitation number is set to σ=2.3, 1.36. Different typical cavity patterns are observed by PIV images in the whole pitching period, including sub cavitation, inception cavitation, sheet cavitation and cloud cavitation. As the σ decreases, the cavity area increases. And the the corresponding time and position of cavitation patterns also changed significantly. In the instantaneous velocity field of an oscillating hydrofoil, the low velocity zone (LVZ) and the mainstream zone (MZ) are observed. The LVZ corresponds to the cavitation region and changes with the change of cavitation morphology. Meanwhile, the LVZ has a large velocity gradient. The velocity gradient in the MZ is larger along the direction parallel to the incoming flow, and the velocity tends to increase first and then decrease gradually downstream. With the decrease of cavitation number, the area of LVZ increases. And the distribution of LVZ is more uneven, which is mainly caused by oscillation motion and uneven water vapor mixing.

Visual and Hydrodynamic Feedback Control of a Robotic Fish for Inline Swimming

This paper develops a method to control the downstream position of the sensor-equipped follower in a pair of two robotic fish swimming in an inline configuration. To swim against the incoming flow, the follower estimates the relative flow velocity using a Bayesian filter with pressure measurements and sets it as the reference to control its flapping amplitude. To maintain its downstream position relative to the leader, the follower extracts the oscillation frequency, phase, and separation distance of the leader from onboard camera images. Water tunnel experiments confirm the feasibility of using hydrodynamic and visual measurements for swimming speed and downstream position control.

Direct hydrodynamic measurements at the upper shoreface of a sandy beach in Paraná - Brazil

Direct hydrodynamic measurements at the upper shoreface of a sandy beach in Paraná - Brazil

Designing Bifunctional Oxygen Electrocatalysts Using Prussian Blue Analogue and Carbon Nanostructure Hybrids: Understanding the Role of Individual Components for Oxygen Reduction and Evolution Reactions

The incorporation and identification of active sites for OER and ORR is required for designing an efficient bifunctional oxygen electrocatalyst for low cost and high activity of electrochemical devices such as metal air batteries and regenerative fuel cells. In this work, we synthesized CoHCF/GO/f-CNT nanocomposite which showed excellent bi-functional activity with a low overvoltage of 0.8 V between the oxygen evolution reaction (E10 mA/cm 2) and the oxygen reduction reaction (E1/2). The specific functions of CoHCF and GO/f-CNT were described using hydrodynamic voltammetry measurements. For comparison, the pristine CoHCF and the composites with multiwalled carbon nanotubes (CoHCF/f-CNT) and graphene oxide (CoHCF/GO) were also synthesized and thoroughly characterised for physico-chemical and electrochemical properties. It was observed that CoHCF itself had poor ORR activity which increased on addition of GO/f-CNT. Electrochemical analysis suggested that CoHCF is primarily responsible for the OER activity in nanocomposites. The carbon nanostructure, due to strong metal support interactions (SMSI) and electrical conductivity helped in maximising the utilization of PBA active sites on the surface along with acting like a co-catalyst for ORR. The nanoscale geometries of the PBA and GO/CNT further enhanced the metal support and charge transfer interactions, thereby enhancing the activity. The findings of this study provide an insight for developing more effective PBA based nanocomposites for bifunctional OER/ORR electrocatalysis.