Existing mechanistic models for electromagnetic characterization of porous materials filled with two fluids (e.g. oil- and water-filled subsurface geological formation) assume the conductive solid components (e.g. graphite and pyrite particles) and the non-conductive solid components (e.g. clay and sand grains) are completely wetted by only one fluid. However, the wettability of particles constituting the porous material have strong influence on the electromagnetic properties of the fluid-filled porous materials. We developed a new mechanistic model to quantify the effects of wettability (i.e. contact angle) of conductive particles on the multi-frequency complex conductivity/permittivity of the fluid-filled porous material containing both non-conductive and conductive particles. The new mechanistic model accounts for the interfacial polarization phenomena at the interface of the conductive particles having any wettability (ranging from strongly water wet to strongly oil wet) and the pore-filling two-phase fluid for various fluid saturations as a function of the operating frequency of the externally applied electromagnetic field. The newly developed model shows that the frequency dispersions of complex conductivity/permittivity of porous material filled with oil and water reduce with the decrease in water-wetness of the conductive particle and with the decrease in water saturation. Notably, frequency-dependent complex conductivity/permittivity of porous material is more sensitive to change in water wetness (i.e. contact angle) of the conductive particles as compared to change in water saturation. This work has significance and relevance for electromagnetic-based characterization of fluid-filled porous materials; for example, estimation of hydrocarbon pore volume in oil/gas reservoirs and estimation of water saturation in aquifers.
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