Hydration Products Research Articles

Hierarchical bio-inspired design and fabrication of all-dimensional superhydrophobic ultra-lightweight high-volume fly ash cement foams using novel ultrasonic-assisted siloxane-encapsulated pickering emulsions

Ultra-lightweight foamed cement (ULFC) exhibits super-high porosity and excellent thermal-insulation capabilities. However, the thermodynamic instability and high water-absorptivity of ULFC with high-volume fly ash have restricted its large-scale application. Superhydrophobic technology can significantly improve the substrates’ hydrophobicity, among which the nanocoating is a popular option but the water-repellent layer may be easily destroyed due to the mechanical damage. Therefore, the intrinsic superhydrophobization becomes a promising alternative to the coating scheme. Here, the internal superhydrophobic ULFC was formulated through introducing the ultrasonic-assisted siloxane-encapsulated Pickering emulsions, in which two Pickering structures containing n-dodecyltrimethoxysilane were stabilized by hydrophobic SiO2 and C–S–H nanoparticles, respectively. Compared with the SiO2 nanoparticles-stabilized dispersion, the droplets of C–S–H nanoparticles-stabilized Pickering emulsion were more stable and controlled-release in cement hydration environment. As such, the incorporation of the latter showed no negative impact on the setting times and static yield stress of the interstitial matrix, optimizing the homogeneity, mechanical strength and heat conductivity of ULFC. The combination of nanoscale foam stabilizer and Pickering emulsions could form the hierarchical waterproof structure with low surface free energy at the gas-solid interfaces, and the multiscale siloxane-grafted intertwined hydration products were responsible for the inner superhydrophobicity of ULFC. Therefore, under the water vapor-saturated environment, the water absorption of superhydrophobic samples showed only a slight increase as a function of time and the ULFC was still hydrophobic with a reduction of apparent water contact angle from 154.6° to 137.8°. From energy consumption analysis, the all-dimensional superhydrophobic ULFC had a potential application in heat-insulation building.

Preparation of a novel foamed concrete modified with carbon fiber and graphite: Mechanical, electro-magnetic and microstructural characteristics based on X-CT

In this paper, foam concrete is modified using graphite and carbon fiber as absorbents. The mechanical properties are analyzed in conjunction with hydration products, pore size distribution based on XCT test. Additionally, the resistivity, complex permittivity and complex permeability are tested. The results demonstrate that carbon fiber enhances the proportion of pores with diameters less than 200 μm in foam concrete, thereby significantly enhancing its flexural strength. Furthermore, incorporating graphite helps offset the initial retardation of sulfoaluminate cement hydration induced by carbon fibers, leading to an increase in the average pore size and a reduction in compressive strength. The incorporation of carbon fibers at a concentration of 0.6 wt% achieves the percolation threshold, akin to scenarios with singular fiber incorporation. Exceeding 2 wt% graphite content results in negligible influence on the conductivity. The synergistic integration of graphite and carbon fibers significantly improves the electromagnetic wave absorption performance of the composite. At a thickness of 6 mm, the material exhibits an effective bandwidth where the reflection loss is less than −10 dB, extending up to 2.5 GHz, which constitutes 52.08 % of the tested frequency spectrum.

Preparation and property studies of ferric sulfoaluminate cement based on Bayer red mud and phosphogypsum.

The Bayer red mud (RM) and phosphogypsum (PG) accumulation have caused significant environmental contamination. However, practical and effective resource utilization technologies are still lacking currently. This work aims to develop ferric sulfoaluminate cement (FSAC) employing low-cost materials including Bayer red mud, phosphogypsum, and other materials. This method effectively improves the utilization rate of Bayer red mud and phosphogypsum. Under the premise of ensuring the performance of FSAC, the utilization rate of solid waste can reach up to 48.56%. The effects of different red mud dosages on cement mineral formation, workability, and mechanical properties are investigated. Then, untreated phosphogypsum is adopted as a retarder for FSAC, and the hydration process, working properties, mechanical properties, types of hydration products, and morphology of FSAC are explored. The results suggest that the crystal transformation of Ye'elemite is promoted with the increase of Bayer red mud content. Cubic crystal system Ye'elemite with higher hydration activity is generated, which increases the early strength of cement but greatly reduces the setting time, hindering the later strength growth. Untreated phosphogypsum can effectively delay the early hydration process of FSAC, prolong the setting time of cement, and increase the strength of FSAC in the later stage. When the dosage of Bayer red mud and phosphogypsum is 17.64% and 9.21%, respectively, with phosphogypsum dosage of 20%, the prepared FSAC has satisfactory mechanical properties, and the 3-day and 90-day compressive strengths are 34.6 MPa and 57.1 MPa, respectively. In addition, the study of heavy metal leaching indicates that the FSAC prepared by Bayer red mud, phosphogypsum, and other raw materials will generate no environment pollution, and the solidification of heavy metal elements in the cement slurry is superior.

Effect of Steel Slag on the Properties of Alkali-Activated Slag Material: A Comparative Study with Fly Ash.

Slag and fly ash (FA) are mostly used as precursors for the production of alkali-activated materials (AAMs). FA is the waste discharged by power plants, while slag and steel slag (SS) both belong to the iron and steel industry. The effects of SS and FA on the strength, microstructure, and volume stability of alkali-activated slag (AAS) materials with different water glass modulus (Ms) values were comparatively investigated. The results show that adding SS or FA decreases the compressive strength of AAS mortar, and the reduction effect of SS is more obvious at high Ms. SS or FA reduce the non-evaporable water content (Wn) of AAS paste. However, SS increases the long-term Wn of AAS paste at low Ms. The cumulative pore volume and porosity increase after adding SS or FA, especially after adding FA. The hydration products are mainly reticular C-(A)-S-H gels. Adding SS increases the Ca/Si ratio of C-(A)-S-H gel but decreases the Al/Si ratio. However, by mixing FA, the Ca/Si ratio is reduced and the Al/Si ratio is almost unchanged. The incorporation of SS or FA reduces the drying shrinkage of AAS mortar, especially when SS is added. Increasing Ms increases the compressive strength and improves the pore structure, and it significantly increases the drying shrinkage of all samples. This study provides theoretical guidance for the application of steel slag in the alkali-activated slag material.

The effects of iron tailings on steel slag-based cementitious systems: Strength, hydration products, and volume stability

To utilize the potential benefits of iron ore tailings (IOT) in the synergistic utilization of multiple solid wastes, this study investigated the mechanism of micro-IOT on steel slag-based cementitious system. The mineral composition, chemical bonding, and microstructure of hydration products were characterized. Measurements also included the flowability, compressive strength, volume stability, and electrical flux of the mortar. Results indicated that an optimal IOT content enhanced the compressive strength and the chloride ion resistance of the steel slag-based cementitious system. IOT acted as a pore filler within the composite system, promoted the generation of ettringite and C–S–H with low Ca/Si, and accelerated the hydration of the steel slag-based cementitious system. Ternary SCMs containing IOT have good volumetric stability and environmental benefits.

Effects of hydrotalcites with different laminate element composition on the properties of sulfoaluminate cement-based materials

Sulfoaluminate cement-based materials (SCBMs) are widely used for grout reinforcement. It is common to use a large water-to-binder ratio in the construction of sulfoaluminate cement-based materials (SAGMs) to obtain good workability and permeability, which results in poor early strength. Nanotechnology has been increasingly employed to enhance the mechanical properties of cementitious materials. Nano Zn-Mg-Al hydrotalcite-like (LDHs) and nano Mg-Al LDHs increased the early compressive strength, while nano Zn-Al LDHs had the opposite effect. However, the reason for this observation remains unclear. In this study, the influence of LDHs structures with different laminar element compositions on the hydration and hardening processes of SCBMs was analysed. The results showed that nano-ZnAl-LDHs, ZnAl-LDHs, and MgAl-LDHs could provide nucleation sites for ettringites. The three hydrotalcite-like materials slowly released different concentrations of zinc and/or magnesium ions and carbonate ions in the cement paste. Zinc ions entered the hydration product of ettringite and aluminum gel and promoted the transformation of amorphous aluminum gel to bayerite, which inhibited the hydration reaction of SCBMs. Magnesium ions could also enter the ettringite, and carbonate ions promoted the formation of calcium carbonate, which facilitated the hydration reaction of SCBMs. The nucleation effect and the release of zinc and/or magnesium ions and carbonate ions acted synergically to influence the hydration rate, pore size distribution, and compressive strength of SCBMs.

Solid waste-based low-carbon autoclaved aerated concrete: Relationship between engineering properties and microstructure

A novel low-carbon autoclaved aerated concrete (AAC) was developed to enhance the high valuable use of solid waste in production, incorporating furnace slag, metro shield sand, and quartz tailings sand as 100 % siliceous raw materials, constituting 60 % of the total weight. In this study, comprehensive analyses were conducted on its engineering properties, including density, compressive, flexural, and splitting tensile strengths, and thermal conductivity. Advanced techniques such as X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and high-resolution Industrial CT scanner (X-CT) were employed to examine AAC's material composition, hydration products, and pore structure characteristics at the microscale. The results indicated that the addition of 10 % furnace slag resulted in a specific increase of 5.5 % in compressive strength. However, escalating the furnace slag content to 30 % proved detrimental to the toughness and dry shrinkage of AAC. The microstructure analysis indicates that the use of furnace slag can improve the connectivity and roundness of pores and reduce the probability of large pores (>0.01 mm3), which will reduce the risk of damage localization. Furthermore, furnace slag in AAC enhanced sustainability and cost-effectiveness compared to metro shield sand and quartz tailings sand. Based on the TOPSIS model, an optimal AAC mixture, considering engineering performance, economy, and sustainability, was derived by blending the three types of solid wastes.

Impact of aragonite coral powder on hydration, strength, and rheology of cement paste

Understanding the intricate bonding mechanism between coral reef surfaces and C–S–H is crucial for advancing large-scale engineering applications. This study conducts a comprehensive analysis of the impact of coral powder (CP) on cement paste. Initially, zeta potential experiments were performed to probe ion adsorption from the cement pore solution at the CP interface. We propose a novel model to quantify the adsorption of Ca2+ by CP. Subsequently, the study delves into the morphological properties of C–S–H nucleation and growth at this interface and formulates an equation elucidating the CP and Ca2+ adsorption relationship. Then, the crack extension behavior of cementitious materials was scrutinized. Finally, an examination of CP effects on the rheological properties of fresh cement pastes is presented. The findings indicate that CP particles exhibit a notably weaker adsorption affinity with Ca2+ compared to their interaction with SO42−. Compared to limestone (LP), CP exhibited a 32.1 % reduction in Ca2+ adsorption in Ca(OH)2 solutions, 44.2 % reduction in Ca(OH)2 + 10 mmol/L K2SO4, and 40.6 % reduction in Ca(OH)2 + 50 mmol/L K2SO4 solutions. Higher zeta potential values correspond to stronger Ca2+ adsorption and broader surface coverage of Ca2+. The inferior surface characteristics of CP hinder C–S–H nucleation and growth, leading to a low CH orientation index in cement paste containing CP. These pastes exhibit cracks more frequently between CP and hydration products. An attractive force is observed between CP and cement particles, decreasing cement paste flowability.

Study on preparation and performance of brick-concrete recycled sand powder autoclaved aerated concrete

This research aims to prepare autoclaved aerated concrete (AAC) by using brick-concrete recycled sand powder (BCSP) as siliceous material. The effects of BCSP content (0–100 %), fineness (258∼452 m2/kg), brick-concrete (B/C) ratio (10:0∼5:5), cement content (15–23) and CaO-to-SiO2(Ca/Si) ratio (0.69–0.94) on the performance of brick-concrete recycled sand powder autoclaved aerated concrete (BCSP-AAC) were studied by single factor test. Besides, the strength formation mechanism of BCSP-AAC was revealed by means of microscopic test. The results demonstrate that BCSP can be used as a single siliceous material to prepare AAC; Increasing the fineness can effectively stimulate the reactivity of BCSP, but if it is too large, it will cause agglomeration between the powders and hinder the gas generation of the aluminum powder. The optimum fineness is 374 m2/kg; B/C ratio is one of the key factors affecting the performance of BCSP-AAC. As the proportion of waste concrete in BCSP increases, the dry density of AAC gradually decreases, while the strength initially enhances then declines. The optimum B/C ratio is 7: 3; Ca/Si ratio is another key factor affecting the performance of BCSP-AAC, which directly affects the type, quantity and crystallinity of AAC hydration products. With the rise of Ca/Si ratio, the dry density of BCSP-AAC increases gradually, and the strength increases first and then decreases. The optimum Ca/Si ratio is 0.81. At this time, the tobermorite formed in BCSP-AAC exhibits a well-crystallized plate-like structure, and C–S–H gel intersperses in the gaps of tobermorite, forming a dense microstructure. Considering the dry density and compressive strength of BCSP-AAC, when the water-solid ratio is 0.65, the aluminum powder paste is 0.13 %, and the BCSP: quicklime: cement: desulfurization gypsum = 67: 13: 17: 3, a light BCSP-AAC with a dry density of 524 kg/m3 and a compressive strength of 3.68 MPa can be prepared.

Calcined alunite-modified alkali-sulphate-activated slag as a novel binder for high-performance cemented paste backfill

The free water content and pore structure significantly affect the mechanical properties of cementitious materials. Because of high water-to-cement ratio and low binder dosage, cemented paste backfill (CPB) is characterized by high free water content and high porosity, which lead to a low strength. In this study, calcine alunite (CA) was used to modify the alkali-sulphate-activated slag (ASAS) to synthesis high-strength CPB with low porosity and low free water content. The results show that at dosage ≤3 %, CA can significantly enhance the strength of ASAS-CPB, and the strengthening effect becomes more prominent as both the dosage and curing time rise. An addition of 3 % CA leads to a 184 % increase in strength at 14 days. However, excessive CA (5 %) reduces 3-day strength by 65 %, but provides the greatest strength at 56 days. As the dosage increases up to 3 %, the promoting impact of CA on early hydration of ASAS-CPB gradually increases, and the duration of induction stage and acceleration stage gradually decreases. Nevertheless, 5 % CA prolongs the duration of induction stage by 921 %. Electrical conductivity and volume water content can be used to assessing the hydration process of ASAS-CPB. Besides, the addition of CA can promote the hydration of slag, resulting a greater formation of C–S–H and ettringite. The hydration products fill the pores and transform the macropores into micropores. Furthermore, mechanisms of CA-induced enhancement in strength is discussed. The results of this study can offer a reference for the synthesis of high performance CPB.

The Effects of Calcium Nitrite on the Mechanical Properties and Microstructure of Early-Age Frozen Cement Paste.

The objective of this paper is to investigate the effect of calcium nitrite (CN) on improving the mechanical properties and microstructures of early-frozen cement paste. Cement pastes containing 1%, 1.5%, 2%, 2.5%, and 3% CN were prepared. One batch of samples was frozen at -6 °C for 7 days and then cured at 20 °C, and the other batch of samples was directly cured at 20 °C as a control. The compressive strength, ultrasonic pulse velocity, and resistivity of all specimens at different target ages were measured under these two curing conditions. The hydration products and microstructures of typical samples were observed using XRD and scanning SEM. The results showed that the addition of 1.5% CN could promote cement hydration and enhance slurry densification, thereby increasing the compressive strength, ultrasonic pulse velocity, and electrical resistivity of the slurry, and positively affecting the early freezing resistance of the slurry. However, when the CN dosage exceeded 1.5%, the internal structure of the slurry was loose and porous due to the generation of a large amount of nitrite-AFm, which negatively affects the properties of the cement paste. In addition, the effectiveness of CN is only limited to temperature environments above -6 °C. Concrete antifreeze suitable for lower temperatures still requires further research.

The historical Corrente gold deposit, Minas Gerais, Brazil: Geological characteristics and a reconnaissance study of nugget effect

Corrente is a historical underground working in Minas Gerais, Brazil, mined for gold in the nineteenth century, for which little geological information is available. Retrieval of unpublished exploration reports from the 1980s has enabled the recognition of a 7-km-long linear cluster of historical underground and open-cast workings, here referred to as the Cata Branca–Corrente goldfield. Gold production ceased at Cata Branca, the most economically relevant deposit of the goldfield, in 1844. Both Corrente and Cata Branca are auriferous quartz-lode deposits. Geological characteristics of the Corrente deposit are presented, as well as reconnaissance whole-rock analyses for Au using a variety of analytical methods, including conventional fire assay, atomic absorption spectrometry, instrumental neutron activation analysis and laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) on pressed-powder pellets (PPPs). Corrente is characterised as a gold-only deposit. The Corrente auriferous quartz lode, hosted in the Archaean greenstone belt sequence of the Rio das Velhas Supergroup, is extensively oxidised and has conspicuous wall-rock alteration to fine-grained muscovite. The resulting sericite phyllite shows overprint by low-temperature kaolinitisation, likely the product of wall-rock hydration mediated by acidic water derived from sulfide oxidation at depth, below the modern weathering zone. The Corrente gold deposit has a high nugget effect. Time-resolved results of LA–ICP–MS on PPPs indicate the presence of particulate gold even in barren kaolinitised wall-rock phyllite.

Investigation on the Impacts of Three Sea Salt Ions on the Performance of CSA-OPC Binary System

This study aimed to explore the impact of three corrosive ions—SO42−, Cl−, and Mg2+—on the hydration property of calcium sulphoaluminate (CSA) cement. Cement paste was prepared using three types of sea salt ion solutions with varying concentrations as mixing water. The experimental program encompassed assessments of porosity, compressive/flexural strength, heat of hydration, pH of pore solution, XRD, and SEM analysis. To modulate the hydration environment, Ordinary Portland cement (10%) was incorporated to elevate the pH and enhance the stability of ettringite, thereby facilitating the formation of additional C-S-H gel for the observation of M-S-H and other compounds. Findings revealed that the Cl− accelerated the hydration of CSA, resulting in heightened heat release. However, it also decreased the length-to-diameter ratio of ettringite, leading to cracking in CSA test blocks. The addition of SO42− resulted in elevated internal alkalinity, prompting alterations in hydration product types and subsequent reduction in CSA strength. Conversely, Mg2+ was observed to ameliorate the microstructure of CSA test blocks, diminishing porosity and augmenting strength.

Migration characteristics and geohazards risk analysis of swelling clay in clayey silt hydrate sediments

The safe and long-term hydrate production in loose clayey silt sediments with high clay content is one of the research priorities, in which the fines migration is one of the key factors. The characteristics of montmorillonite swelling and dispersion make its migration behavior more challenging, which causes the evolution of reservoir seepage properties and potential geohazards risk cannot be predict. The migration behavior of montmorillonite induced by pore water was investigated, and discusses its potential impact on the geomechanical properties of the reservoir. The results show that the combined effects of montmorillonite swelling, which creates favorable conditions for blockage, and migration, which exacerbates permeability decline, make montmorillonite have a much greater effect on seepage characteristics in clayey silt sediments than illite. Higher montmorillonite content and low salinity increase the particle concentration in the pore water, which creates a source of particles for blockage. The low reynolds number indicates that the particles mainly detach from the pore wall with rolling in laminar flow and the lifting force can be neglected. As a result of this combined effect, the montmorillonite is more likely to readsorb and block the pore throat with bridging. This work will help to understand the migration behavior of montmorillonite in clayey silt formations with low permeability, which needs to be paid attention to when formulating gas production schemes and safety control strategies.

Effect of organic phosphonate types on performance of alkali-activated slag-based materials and its mechanism

The strong early hydration reaction and short setting time of alkali-activated slag composites limit its practical engineering application. Compared with traditional chemical admixture, organic phosphates show higher efficiency in delaying the hydration rate of alkali-activated slag system. However, there is limited research on the performance of alkali-activated materials modified by different organic phosphonate type, and their modification mechanism is also unclear. In this study, three typical organic phosphonates, hydroxyethylidene diphosphonic acid Tetrasodium (HEDP-4Na), aminotris (methylene phosphonic acid) tetrasodium (ATMP-4Na), and diethylenetriamine penta (methylene phosphonic acid) pentasodium (DTPMP-5Na), were selected to clarify the effect of organic phosphonate type on the properties of alkali-activated slag materials (AASM) and its mechanism under different dosage and alkali content. The results indicate that DTPMP-5Na has the most significant effect on the improvement of fresh properties of AASM, compared to other two types of organic phosphonates. Using 0.3 % DTPMP-5Na can delay the initial and final setting time of AASM by 240 % and 190 % respectively, increase the slump flow by 20 %, and reduce yield stress and plastic viscosity by 57 % and 65 % respectively. This was because DTPMP-5Na has the largest number of monomolecular phosphonic acid groups, which can chelate Ca2+ in AASM, form stable complex and cover the surface of slag particles to prevent further hydration reaction. The phosphonate reduced the hydration rate and increased the surface negative potential of slag particles. The use of phosphonates and the increase in alkali content can significantly enhance the mechanical properties of AASM. Using 0.3 % of ATMP-4Na increased the 28-day compressive and flexural strengths of AASM made with 5 % alkali content by 155 % and 53 %, respectively, compared to the reference AASM with 3 % alkali content. Additionally, the 28-day compressive and flexural strengths of reference at 7 % alkali content increased by 115 % and 12 %, respectively, compared to that at 3 % alkali content. This improvement was mainly attributed to the consumption of organic phosphonates at the early stage, which provides more activation channels for slag later, resulting in a denser structure and improved pore structure of AASM, thus enhancing its long-term mechanical properties. However, with the increase of alkali content, the effect of organic phosphonates in strengthening fresh and hardened properties of AASM decreased. The use of 0.3 % HEDP-4Na increased 28-day compressive and flexural strengths of AASM with 3 % alkali contents increased by 25 % and 27 %, respectively, compared to the reference AASM. Such improvement was limited to 4 % and 19 % for AASM made with 5 % alkali content. This can be attributed to the significant promotion of OH− concentration in the system, increasing the yield of hydration products at early age on the surface of slag, and reduced activation channels for slag over the long term. In summary, the use of ATMP-4Na is recommended in AASM, as it can significantly improve the fresh properties of AASM and provide excellent mechanical properties.

Effect of mechanical properties and microscopic mechanism of cement-stabilized macadam under variable temperature environment with early strength agent

The early strength formation of Cement-Stabilized Macadam (CSM) base materials in cold regions is affected by environmental changes. At the same time, the curing temperature of CSM in the actual service environment did not meet the laboratory standard temperature curing environment (ST-CE). This study explores the evolution law of CSM performance and the influence of an early strength agent (ESA-I) on the early performance of CSM under variable temperature curing environment (VT-CE) in cold regions. The actual service environment for CSM curing was simulated in the laboratory, and CSM specimens with five ESA-I dosages of 0%, 5%, 10%, 15%, and 20% were prepared. The effect of ESA-I on the early properties of CSM under VT-CE was analyzed. The micro mechanism of CSM under different curing environments and ESA-I dosages was investigated based on X-ray diffraction, Fourier transform infrared spectroscopy, and Scanning electron microscope. The experimental results indicated that the early strength formation of CSM was slow in VT-CE, and the 7-day unconfined compressive strength did not meet the construction quality control indicators of CSM material under heavy traffic conditions. It was necessary to extend the curing period to meet the construction requirements. Adding ESA-I could enhance the strength, modulus, frost resistance, and fatigue performance of CSM under different curing environments. Compared with the ST-CE, the VT-CE would weaken the improvement effect of ESA-I on the performance of CSM. The recommended range for ESA-I in VT-CE was 10% −15% based on comprehensive compressive strength and resilient modulus indicators. Microscopic experiments show that under a VT-CE, the hydration rate of cement decreases, the Ettringite content in the hydration products is higher, and the microstructure is loose. Adding ESA-I improves the hydration rate of cement under VT-CE, and the microstructure contains more C-S-H hydration products.

Preparation and Hydration Properties of Sodium Silicate-Activated Municipal Solid Waste Incineration Bottom Ash Composite Ground-Granulated Blast Furnace Slag Cementitious Materials.

The production of municipal solid waste incineration bottom ash (MSWIBA) is substantial and has the potential to replace cement, despite challenges such as complex composition, uneven particle size distribution, and low reactivity. This paper employs sodium silicate activation of MSWIBA composite Ground-granulated Blast Furnace slag (GGBS) to improve the reactivity in preparing composite cementitious materials. It explores the hydration performance of the composite cementitious materials using isothermal calorimetric analysis, Fourier-transform infrared (FTIR) spectroscopy, XRD physical diffraction analysis, and SEM tests. SEM tests were used to explore the hydration properties of the composite gelling. The results show that with an increase in MSWIBA doping, the porosity between the materials increased, the degree of hydration decreased, and the compressive strength decreased. When the sodium silicate concentration increased from 25% to 35%, excessive alkaline material occurred, impacting the alkaline effect. This inhibited particle hydration, leading to a decrease in the degree of hydration and, consequently, the compressive strength. The exothermic process of hydration can be divided into five main stages; quartz and calcite did not fully participate in the hydration reaction, while aluminum did. The vibrational peaks of Si-O-Ti (T = Si and Al) were present in the material. The vibrational peaks of XRD, FTIR, and SEM all indicate the presence of alumosilicate network structures in the hydration products, mainly N-A-S-H and C-A-S-H gels.

The basic characteristics of paste backfill materials based on highly active mineral admixtures: Part I. Preliminary study on flow, mechanics, hydration and microscopic properties

The cost performance of backfill materials in coal mines has long limited the widespread use of backfill technology. Therefore, developing backfill materials that are both cost-effective and high-performing is a pressing scientific issue that requires immediate attention. This study proposes replacing ordinary Portland cement (OPC) with highly active mineral admixtures, such as mineral powder and limestone powder, to prepare a green, low-cost, and high-performance coal mine backfill material. The use of mineral admixtures can improve the performance of the backfill material while reducing its environmental impact. The proposed approach is cost-effective and environmentally friendly. The study employed experimental tests and microscopic characterization methods, such as the slump test, hydration heat test, uniaxial compressive strength test, and microstructure test, to clarify the synergistic reaction mechanism of highly active mineral admixture-based paste backfill material (HAM-PBM). This clarification is helpful in regulating the macroscopic properties of hardened paste. The results show that: (1) The rheological properties of fresh HAM-PBM slurry are consistent with the Herschel-Bulkley model, and its fluidity meets the technical requirements for coal mine backfilling. The slump of fresh HAM-PBM slurry ranges from 140 to 145 mm, and the yield stress ranges from 3.188 to 12.819 Pa. (2) Highly active mineral admixtures significantly affect the early hydration process of HAM-PBM. The parameters of the hydration characteristics during the initial dissolution stage, acceleration stage, deceleration stage, and stabilization stage gradually decrease, while the duration of the induction stage gradually increases. This confirms that the early hydration activity of mineral powder (MP) and limestone powder (LF) is lower than that of OPC. (3) The uniaxial compressive strength (UCS) of the MP series exhibits an "anti-hook" change pattern, while the UCS of the LF series shows a decreasing change pattern. The microstructure, including the number of hydration products, microscopic density, and other characteristics, follows the same change pattern as the UCS. (4) Based on the synergistic reaction mechanism of hardened slurry, it is recommended that MP replace a maximum of 10 % of OPC and LF replace a maximum of 5 % of OPC. The need for composite replacement of OPC with MP and LF is clarified, resulting in a cost-effective coal mine backfill material. This study has contributed to the national "double carbon" policy and the low-cost backfilling application of coal mines.

Adsorption behavior and solidification mechanism of Pb(II) on synthetic C-A-S-H gels with different Ca/Si and Al/Si ratios in high alkaline conditions

Calcium silicate aluminate hydrate (C-A-S-H) is the main hydration product and its porous adsorption property can effectively inhibit Pb(II) leaching from alkaline pore solution of alkali-activated municipal solid waste incineration (MSWI) fly ash compacts. The study examines how different ratios of Ca/Si and Al/Si in C-(A)-S-H affect Pb(II) adsorption behavior and mechanism in high alkaline conditions. The results showed that Al-doped C-A-S-H gels have increased specific surface area and cumulative pore volume, and slightly decreased average pore size. Pb(OH)3- adsorption by C-A-S-H was mainly chemisorption with spontaneity. Temperature, pH value, Al/Si and Ca/Si ratios of C-A-S-H affected Pb(II) adsorption. Equilibrium adsorption capacity (Qe) initially increased then decreased with higher Al/Si for C-A-S-H with Ca/Si 0.60 but decreased with higher Al/Si for Ca/Si 1.20. Active Si-OH (Q1 or Q2b) and Al-OH (Q2(1Al)) in aluminosilicate tetrahedra chains dehydrate and condense with Pb(OH)3- to form Si-O-Pb or Al-O-Pb bonds. Higher interlayer water content in low Ca/Si and Al/Si C-A-S-H facilitated ion exchange during Pb(II) adsorption. After adsorption, aluminosilicate tetrahedra chain length increased while interlayer water content decreased. Ca(II) and Pb(II) in C-A-S-H underwent partial ion exchange during the adsorption process. Simulation results indicate Pb(OH)3- was more likely to polycondensate with silica tetrahedral bridging oxygen in Si2AlO2(OH)8 to form Si-O-Pb than Al-O-Pb bonds. These findings provide theoretical support for designing dosages of alkali activators and doped aluminosilicate minerals to improve the solidification efficiency of Pb(II) in alkali-activated MSWI fly ash compacts.

Properties and Microstructure of a Cement-Based Capillary Crystalline Waterproofing Grouting Material

Cement grout is traditionally used for treating water leakage distress in tunnels. However, traditional cement grout has the disadvantages of a poor anti-seepage performance, long setting time, and slow strength gain. To this end, a high-performance cement-based capillary crystalline waterproofing (CCCW) grouting material was synthesized using cement, capillary crystalline material, and several admixtures. The influences of the material proportions on the viscosity, bleeding rate, and setting time of the fresh grout, as well as the permeability coefficient of the grouted aggregate and the unconfined compression strength of the hardened grout material, were systematically studied. The mineralogy and microstructure of the CCCW grouting material were examined using X-ray diffraction, industrial computed tomography, and scanning electron microscopy. The results indicated that the capillary crystalline material PNC803 was not suitable for mixing with bentonite, sodium chloride, and triethanolamine in cementitious slurries, but it can produce excellent synergistic effects with sulfate, calcium chloride, and triisopropanolamine. An analysis of the microstructure of the CCCW grouting material showed that the PNC803 and additives can promote the hydration of cement, which yields more hydration products, sealing water passage and filling micro voids and therefore leading to enhanced waterproofing and strengthening effects. These research results could improve the applicability of CCCW material in tunnel engineering.