Hybrid Magma Research Articles

Evolution of the magma plumbing system of Miyakejima volcano with periodic recharge of basaltic magmas

Defining the variations in petrological characteristics of erupted magmas within a high-resolution chronostratigraphy provides a necessary framework for monitoring the long-term activity and eruption potential of an active volcano. Here, we investigate the evolution of the magmatic system of Miyakejima volcano, Japan, between the last two caldera-forming eruptions, at ~ 2.3 ka and AD 2000, based on new stratigraphic constraints, radiocarbon ages, and whole-rock geochemical data. The activity of Miyakejima during this interval can be divided into three magmatic periods based on cyclic whole-rock compositional trends. Period 1 spans the interval between ~ 2.3 ka and the 7th century, from the Hatchodaira eruption with caldera collapse to immediately before the Suoana–Kazahaya eruption. Period 2 spans the time period between the seventh century and the fourteenth century, from the Suoana–Kazahaya to the Sonei–bokujyo eruptions. Period 3 covers the period from the two major flank eruptions that occurred in the sixteenth century to the end of the twentieth century until the last caldera-collapse event in AD 2000. The eruption rate decreased from 0.5 km3 per 1000 years in Period 1 to ~ 0.2 km3 per 1000 years in Period 2 and 3. Recharge of primitive basaltic magmas into shallower crustal systems triggered extensive basaltic fissure eruptions at the beginning of each period. Progressively increasing whole-rock SiO2 contents of the hybrid magmas in subsequent eruptions indicates continuous fractional crystallization in small shallow magma chambers which formed at the start of each magmatic period. Intermittent injections of basaltic magma into shallow magma chambers induced magma mixing that caused eruption of hybrid basaltic andesite in each period. We suggest that some basaltic magmas formed isolated magma reservoirs at shallow depth, in which rapid fractionation was able to occur. Rupturing of these isolated magma storage regions filled with gas-rich evolved magma can lead to violent ejection of andesitic magmas, such as for the Suoana–Kazahaya eruption in the seventh century. Our results suggest two main scenarios of eruption for the basaltic magma system at Miyakejima and similar mafic volcanoes in the northern Izu–Bonin arc; (1) eruption of voluminous basaltic lavas after the recharge of primitive basaltic magmas into the shallow magmatic system, and (2) explosive fissure eruption by rupturing of isolated magma bodies filled with gas-rich evolved magmas.Graphical

Experimental Annealing of Zircon: Influence of Inclusions on Stability, Intracrystalline Melt Migration, Common Lead Leaching, and Permeability to Fluids.

Zircon derived from crustal rocks can survive dissolution into hot basalts during magma hybridization and rock assimilation if it is shielded as an inclusion phase in early-formed phenocrysts or in minerals from non-disaggregated xenoliths. Under these conditions, zircon can be thermally shocked, triggering recrystallization of metamict domains and reaction with its hosted mineral inclusions. This work simulates this process by performing thermal annealing experiments on zircon grains with variable degrees of metamictization. These were embedded in cristobalite powder under a N2 atmosphere at 1 bar and 1300 °C. The thermal annealing produces recrystallization of metamict domains, melting of multi-phase mineral inclusions, nanopore formation, and microcrack propagation by thermo-elastic stress. The porosity enhances intracrystalline melt mobility, leaching out trace-element and mineral impurities. Baddeleyite was formed at temperatures below the thermal decomposition of pure zircon by two mechanisms: (i) recrystallization of metamict domains assisted by silica migration from the reaction site and (ii) incongruent zircon dissolution into molten mineral inclusions with a high CaO/SiO2 ratio. Highly metamict zircons with elevated common Pb and radiogenic Pb loss, which were impossible to date with SHRIMP, lost all their common Pb and some radiogenic Pb upon annealing, producing well-fitted discordias with a significant upper intercept age.

The roles of partial melting of metasomatised mantle, magma mixing at continental crust level and fractionation in calc-alkaline minette genesis, SE Spain

ABSTRACT Detailed textural and compositional study of calc-alkaline lamprophyres and minettes from Zeneta, SE Spain Neogene Volcanic Province (NVP) are used to unravel the magma sources and differentiation processes involved in their formation. The presence of xenocrysts of various origins indicates a hybrid nature involving mantle-derived alkaline lamproitic and continental crust-derived granitic parental magmas. A new U-Th-Pb zircon age of Zeneta minettes allows contextualizing their generation in time and space during regional lamproite magma intrusion and crustal anatexis in the NVP. Interaction and mixing of these compositionally contrasted magmas resulted in the formation of hybrid calc-alkaline lamprophyre minette. This process is reflected by the phases that crystallized from the hybrid magma, particularly phlogopite, and by the whole-rock composition of the less fractionated rocks. The calculated contribution of lamproitic and crustal-derived magma end-members in minette formation are 30–40% and 60–70%, respectively. Mixing of end-member magmas of contrasting rheological properties was possible only in a calculated thermal-window of 1025–1125°C, after cooling of intruding lamproitic magma and heating of host granitic anatectic region. The calculated thermal window fits with the estimated rheological properties of Zeneta minettes and the crystallization temperature of early minette-derived phlogopite. Furthermore, fractional crystallization was identified for the first time in the Zeneta minettes, based on the observed whole-rock line of descent from the less evolved mixed magmas through intermediate to felsic minettes and associated textural and compositional features of late crystallized phases. Polytope Vector Analysis allowed an integrated quantitative characterization of magma differentiation, including magma mixing and subsequent fractional crystallization. The identification of mixing and fractionation processes in calc-alkaline minettes genesis, which otherwise does not show spatial and temporal association in the field with granitic bodies, opens a new scenario to be considered in understanding the petrogenesis of these rocks.

Two‐Stage Mafic‐Felsic Magma Interactions and Related Magma Chamber Processes in the Arc Setting: An Example From the Enclave‐Bearing Calc‐Alkaline Plutons, Chinese Altai

AbstractA systematic data set of petrography, mineralogy, geochronology, and geochemistry is reported for typical arc granitoids and associated mafic microgranular enclaves (MME) from the Chinese Altai, Central Asian Orogenic Belt. Zircon U‐Pb dating indicates that they crystallized coevally at ∼395 Ma. Magma hybridization modeling suggests that the granitoid parental magma formed by mixing between a mafic and a felsic endmember. The sharp decrease of An values from cores to rims (e.g., from ca. 80 to 40) of plagioclase crystals points to polybaric crystallization accompanied by degassing. Petrographic evidence and plagioclase in situ Sr isotopic compositions ((87Sr/86Sr)i = 0.7053–0.7071) confirm the interaction of at least two isotopically different magmas during the mineral crystallization. A model for the formation of the enclave‐bearing calc‐alkaline plutons in arc settings is presented: At depth, mantle and crustal melting and efficient magma mixing controlled the principal chemical compositions of the granitoid intrusions. Then in the higher level chamber, decompression‐dominated crystallization and the mingling and limited mixing between blobs of mafic magma and the enclosing granitoid magma ultimately determined the texture, mineral composition, and enclave morphology. The MME have (87Sr/86Sr)i of 0.7048–0.7062, εNd(t) of −0.5 to +2.6, and zircon εHf(t) of +2.3 to +5.4, while the host granitoids have similar Sr isotopic compositions ((87Sr/86Sr)i = 0.7054–0.7064), but generally lower whole‐rock εNd(t) and zircon εHf(t) values (−2.2 to +0.4 and +0.6 to +4.6, respectively). The petrogenetic analysis and isotopic characters suggest that granitoid emplacement was a means of crustal growth in the Chinese Altai orogen.

Mesoscopic and Microscopic Magmatic Structures in the Quxu Batholith of the Gangdese Belt, Southern Tibet: Implications for Multiple Hybridization Processes

The Quxu batholith of the Gangdese magmatic belt, southern Tibet, comprises predominantly Early Eocene calc-alkaline granitoids that feature a variety of types of magmatic microgranular enclaves and dikes. Previous studies have demonstrated that magma mixing played a crucial role in the formation of the Quxu batholith. However, the specific processes responsible for this mixing/hybridization have not been identified. The magmatic microgranular enclaves and dikes preserve a record of this magma mixing, and are therefore an excellent source of information about the processes involved. In this study, mesoscopic and microscopic magmatic structures have been investigated, in combination with analyses of mineral textures and chemical compositions. Texturally, most of the enclaves are microporphyritic, with large crystals such as clinopyroxene, hornblende, and plagioclase in a groundmass of hornblende, plagioclase, and biotite. Two types of enclave swarms can be distinguished: polygenic and monogenic swarms. Composite dikes are observed, and represent an intermediate stage between undisturbed mafic dike and dike-like monogenic enclave swarms. Our results reveal three distinct stages of magma mixing in the Quxu batholith, occurring at depth, during ascent and emplacement, and after emplacement, respectively. At depth, thorough and/or partial mixing occurred between mantle-derived mafic and crust-derived felsic magmas to produce hybrid magma. The mafic magma was generated from the primitive mantle, whereas the felsic end-member was produced by partial melting of the preexisting juvenile crust. Many types of enclaves and host granitoids are thus cogenetic, because all are hybrid products produced by the mixing of the two contrasting magmas in different proportions. In the second stage, segregation and differentiation of the hybrid magma led to the formation of the host granitoids as well as various types of magmatic microgranular enclaves. At this stage, mingling and/or local mixing happened during ascent and emplacement. In the final stage, mafic or hybrid magma was injected into early fractures in the crystallizing and cooling pluton to form dikes. Some dikes remained undisturbed, whereas others experienced local mingling and mixing to form composite dikes and eventually disturbed dike-like monogenic enclave swarms. In summary, our study demonstrates the coupling between magmatic texture and composition in an open-system batholith and highlights the potential of magmatic structures for understanding the magma mixing process.

Mantle versus crustal contributions in crustal-scale magmatic systems (Sesia Magmatic System, northern Italy) from coupling Hf isotopes and numerical modelling

The growth and evolution of crustal-scale magmatic systems play a key role in the generation of the continental crust, the largest eruptions on Earth, and the formation of metal resources vital to our society. However, such systems are rarely exposed on the Earth’s surface, limiting our knowledge about the magmatic processes occurring throughout the crust to indirect geochemical and petrographic data obtained from the shallowest part of the system. The Hf isotopic composition of accessory zircon is widely used to quantify crust-mantle evolution and mass transfers to and within the crust. Here we combine single-grain zircon Hf isotopic analysis by LA-MC-ICP-MS with thermal modelling to one of the best-studied crustal-scale igneous systems (Sesia Magmatic System, northern Italy), to quantify the relative contribution of crustal- and mantle-derived magmas in the entire system. Zircons from the deep gabbroic units define a tight range of εHf (−2.5 ± 1.5). Granites and rhyolites overlap with this range but tail towards significantly more negative values (down to −9.5). This confirms that the entire system consists of hybrid magmas that stem from both differentiation of mantle-derived magmas and melting of the crust. Thermal modelling suggests that crustal melting and assimilation predominantly occurs during emplacement and evolution of magmas in the lower crust, although melt production is heterogeneous within the bodies both spatially and temporally. The spatial and temporal heterogeneity resolved by the thermal model is consistent with the observed Hf isotope variations within and between samples, and in agreement with published bulk-rock Sr–Nd isotopic data. On average, the crustal contribution to the entire system determined by mixing calculations based on Hf isotopic data range between 10 and 40%, even with conservative assumptions, whereas the thermal model suggests that this space- and time-averaged contribution does not exceed 20%. However, spatial and temporal variations in the crustal melt proportion (from 0 up to 80% as observed in the thermal model) may impart significant isotopic variability to different batches of magma observed on the outcrop scale, emphasizing the need to consider a magmatic system as a whole, i.e., by integrating all spatial and temporal scales, to more precisely quantify crustal growth vs. reworking.

Mixing of cognate magmas as a process for producing high-silica granites: Insights from Guanmenshan Complex in Liaodong Peninsula, China

Ascertaining how high-silica granites form is important for understanding why Earth has a high-silica continental crust and how the composition of the continental crust has evolved through time. This study presents a systematic dataset for the petrology, mineralogy, geochronology, and geochemistry of the granite porphyries and related microgranular enclaves and diabases from the Early Cretaceous Guanmenshan Complex (126–123 Ma) in Liaodong Peninsula, North China Craton, to reveal the complex, multi-stage, magmatic evolution in a shallow silicic magma system prior to and during emplacement of high-silica granites. Zircons from the granite porphyries and microgranular enclaves can be classified into two groups: those with dark-CL cores surrounded by light-CL rims, and those comprising entirely light-CL domains, without dark-CL cores. Our results indicate that dark-CL zircon domains with high Th (46–579 ppm), U (120–1274 ppm), and Hf (6709–12,493 ppm) contents and low Ti contents (1.52–7.85 ppm) and Ti-in-zircon temperatures (TTiZ = 622–751 °C) formed from highly evolved magmas, whereas light-CL zircon domains with low Th (14–157 ppm), U (24–236 ppm), and Hf (4749–10,474 ppm) contents and high Ti contents (7.59–29.36 ppm) and Ti-in-zircon temperatures (TTiZ = 748–885 °C) formed from low evolved magmas. These characteristics, combined with the similar UPb ages and Hf isotopic compositions of the dark-CL zircon cores and light-CL zircon domains and insignificant intra- or inter-grain (87Sr/86Sr)i variations of plagioclase from the granite porphyries and microgranular enclaves, reflect mixing between two cognate magma batches with contrasting evolved signatures. This study presents a model in which the highly evolved magmas were derived from initial interstitial melts that were extracted from a crystal mush leaving behind residual cumulates, whereas the less evolved magmas were the products of re-melting of the cognate cumulates. The diabases likely represent the mafic recharge magma that contributed necessary heat but limited mass to remobilize the cumulate mush, inducing the internal self-mixing and formation of the hybrid high-silica magmas. Feeder-dyke related emplacement of the hybrid magma generated more mafic rocks that became incorporated and dispersed into the high-silica granite porphyries as cognate microgranular enclaves. Our results lend new insights into the important role of cognate magma mixing induced by mafic recharge in generation of high-silica granites.

Magma hybridization and crust-mantle interaction revealed by mineralogical and geochemical footprints: a case study from the South Qilian Accretionary Belt at the northern Tibetan Plateau

ABSTRACT The relationship between mafic magmatic enclaves (MMEs) and host granitoids is ongoing debate due to their significant roles in understanding deep magmatisms and geodynamic processes. This paper reports on Early Palaeozoic granitoids and associated MMEs from the Delingha pluton in the South Qilian Accretionary Belt (NW China) to constrain their petrogenesis and draw implications. The MMEs, occurring as ellipsoidal to rounded shapes, are andesitic and have the same crystallization age (~445 Ma) and mineral assemblage as the host granitoids. However, minor isotopic differences between them and compositional and textural disequilibria on minerals (e.g. plagioclase and amphibole) do not support a cumulate origin that the MMEs were formed at earlier stage of the same magmatic system, but forcefully reflect magma hybridization processes between mafic and felsic magmas, during which the hybridized magma was broken up into discrete enclaves by convective motion in the host felsic magma. Accordingly, the primitive compositions of the MMEs likely originated from metasomatized mantle wedge source, while mantle-derived melt underplated and partially melted the lower continental crust to form the host rocks with a certain mantle contribution. Thus, the Delingha pluton is the product of crust-mantle interaction at an active continental margin subduction setting rather than syn-collisional environment, indicating that subduction of the South Qilian Ocean located between the Central Qilian Block and the Oulongbuluke Block may have lasted till to ~445 Ma.

Insight into volcanic garnet: origin and significance of garnet as exemplified by a detailed petro-mineralogical study of the Breziny andesite (Central Slovakia Volcanic Field, Western Carpathians, Central Europe)

Almandine-rich garnets from a Neogene andesite of Slovakia can be divided into two main types. Garnet megacrysts are magmatic and form a chemically homogeneous group that contains, on average, about 5 wt% CaO and 4.5 wt% MgO as petrogenetically significant components. Garnets occurring in lithic fragments and garnets aggregated in garnetite lenses are characterised by Ca-poor cores (CaO <= 2 wt%) that testify for a two-step history and correspond respectively to inherited pre-anatectic and peritectic garnets. Available experimental data show that the composition of magmatic garnet megacrysts is compatible with a peritectic origin, through the fluid-absent melting of an immature metasedimentary protolith or a tonalitic gneiss. However, thermal evolution evidenced by zircons shielded in garnet rather suggests that garnet nucleated and grew by cooling of a hybrid magma pool, resulting from the complete mixing of crust- and mantle-derived melts.

Extensive hybridization of mafic and silicic magmas at the confluence of the Cascade Arc and High Lava Plains: The Newberry Volcano of Central Oregon

Newberry volcano lies at the intersection of the north-south trending Cascade Arc with the margin of the High Lava Plains trend. Newberry is unusual as a Cascade volcano in that it is dominantly basaltic and geochemically bimodal between basalt and silicic rocks. The youngest calc-alkaline mafic to intermediate lavas of Newberry Volcano have major and trace element characteristics consistent with up to 35–40 wt% mixing and hybridization of an evolved tholeiitic basalt with silicic magmas similar to that present as domes and flows within the caldera of the volcano. This unusual extensive hybridization is the combined result of voluminous influx of basaltic magma into the crust, fractionation within subvolcanic chambers, anatexsis of crustal rocks to produce silicic magmas, superheating of these silicic magmas, and complex interaction of mafic and silicic magma within the substructure of the volcano and especially within a dike swarm underlying the northwest rift of the volcano.The most primitive basaltic rocks of the volcano include both tholeiitic and calc-alkaline varieties derived from melting of variously subduction-influenced lithospheric mantle at depth. The evolved tholeiitic end member of mixing within the Northwest Rift was produced by fractionation of a primitive tholeiitic parent. This evolved tholeiite mixed substantially with at least two silicic magmas to generate the calc-alkaline intermediate rocks of the Northwest Rift of the volcano.

Influence of Host Marble Rocks on the Formation of Intrusive Alkaline Rocks and Carbonatites of Sangilen (E. Siberia, Russia)

The study of the O and C isotope composition of calcite from nepheline syenites, ijolites and carbonatites of the Chik intrusion and the intrusions of the Erzin–Tarbagatay group of Sangilen (Eastern Siberia, Russia) showed derivation from alkaline melts enriched with a carbonate component from the host marbleized sedimentary rocks. The calculations showed that about 40% of the initial mass of carbonates involved in the interaction with silicate melts have remained after decarbonation. During the assimilation of the carbonate, an oxygen isotope exchange took place between the residual carbonate material and the silicate phase. Crystallization products of such hybrid magmas are carbonatite veins, calcite-rich nepheline rocks and their pegmatites with a calcite core.

Early cretaceous crust–mantle interaction in the Middle-lower Yangtze River Metallogenic Belt, east China: Li–Nd–Sr isotopic and elemental constraints

The petrogenesis of adakitic rocks and their implications for the crust–mantle interaction remain enigmatic. To provide important insights into these issues, we carried out a detailed investigation of Li–Nd–Sr isotopes and elements for the Early Cretaceous intermediate rocks and related mafic microgranular enclaves (MMEs) from the southwestern Middle–Lower Yangtze River Metallogenic Belt, central eastern China. The intermediate rocks in the Edong district are characterized by high SiO2, MgO, and K2O and low Na2O concentrations of 61.5–66.1 wt%, 0.4–2.3 wt%, 2.8–7.4 wt%, and 2.3–5.5 wt%, respectively, enrichment in LREEs and LILEs (e.g., Sr and La concentrations of 414.99–1619.45 ppm and 20.41–53.88 ppm), and relative depletion in Y (7.84–19.20 ppm) and Yb (0.59–1.73 ppm), endowed with both the high silica adakitic and high-K calc-alkaline affinities. The MME-bearing adakitic rocks exhibit wide ranges of (87Sr/86Sr)i, εNd(t) and δ7Li values (0.7028–0.7087, −8.9 to −3.0 and − 2.0‰ to +9.9‰, respectively), indicating a mixing process between felsic melts from a juvenile lower crust and mafic melts from an enriched mantle source. They were subsequently subjected to significant fractional crystallization of pyroxene and hornblende and minor crustal contamination during the ascent. High Sr/Y and La/Yb ratios, the salient geochemical peculiarities of adakitic rocks, might be inherited from magma sources and then be strengthened by fractionation of ferromagnesian phases. Hybrid magmas with high water content, and high oxygen and sulfur fugacity facilitate Cu ± Mo ± Au polymetallic mineralization. The adakitic rocks and related deposits in central eastern China could be related to upwelling of asthenospheric mantle caused by the subduction of the Paleo-Pacific plate during the Early Cretaceous and its induced reactivation of sub-continental lithosphere. The crust–mantle interaction model is probably applicable to formation of the adakitic rocks worldwide.

Magma hybridization, mingling, and recycling in the Manzanillo plutonic complex, Mexican Cordillera

ABSTRACT The Manzanillo Plutonic Complex (MPC) forms part of the Mexican Cordilleran plutonic belt at ~ 19°N. A special feature of the MPC is more than 125 km2 outcrops of gabbroic rocks, thus constituting the largest body of this lithology along the belt. The overall MPC composition is heterogeneous including gabbros and granitoids with or without hybridization structures and minor alkali-rich granites. In contrast to other Cordilleran plutons, MPC intrusives are often strongly deformed and foliated heterogeneous structures with evidence of magma mingling and mixing. U-Pb emplacement and Rb-Sr and K-Ar cooling ages are between 59 and 73 Ma. Four U-Pb gabbro ages from 63 to 65 Ma define the peak of the hybridization event. Although geochemical analyses display considerable differences within MPC members, their Sr-Nd isotopic signatures are highly homogeneous with magmatic primitive εNd parameters between +5 and +6 and low 87Sr/86Sr around 0.7035. Geothermobarometric data provide information for a hot environment for the gabbroic pulse at 3.4–4.9 Kb and >900°C, indicative for depths ~15 km. On the other hand, granitoids show typical Cordilleran characteristics with lower temperatures and shallow emplacement conditions. The MPC shows a unique petrogenetic evolution in the Cordilleran arc; there is no evidence for a relation to other events such as the Early Cretaceous Alisitos arc.

Evidence of crustal disequilibrium melting, mingling processes, layering and deformation in UHT conditions: The marginal zone of the Egersund-Ogna massif-type anorthosite (S. Norway)

Septa of banded gneisses crop out along the margin of the Proterozoic Sveconorwegian Egersund-Ogna (EGOG) anorthosite pluton. They permit the observation of the effects of a diapiric intrusion of anorthosite on its envelope of gneisses. The rocks are mylonitic and result from a strong deformation in UHT granulite facies conditions due to contact metamorphism. Concordance of the foliations in the septa and in the leuconoritic margin of the anorthosite suggests that the deformation was linked to the ballooning of the anorthosite. The septa lithology is dominated by noritic gneisses interleaved with felsic gneisses and comprises minor amounts of mafic granofels, metaquartzites and metagreywackes. A charnockitic dyke is cutting across the foliated structure. Geochemical data (major and trace elements) indicate that the noritic gneisses did not result from the metamorphism of amphibolites belonging to the high-grade gneiss complex characteristic of the wall rocks of the Rogaland anorthosite province. Instead they have strong similarities with a high-alumina basalt that is the possible parental magma of the EGOG anorthosite. Slight variations from norite to leuconorite compositions were induced by metamorphic differentiation. The felsic rocks encompass a large interval of rock types from granite to tonalite and quartz diorite. They compare with leucogranitic enclaves occurring in the charnockitic upper part of the Bjerkreim-Sokndal layered intrusion. Most felsic lithologies show the signature (including high positive Eu anomalies) of anatectic processes in disequilibrium melting conditions and rapid extraction from the source rocks. Flowage differentiation in the emplacement process explains the various compositions, as commonly observed in migmatite leucosomes. The metaquartzites show a relatively high Ti concentration and the Ti-in-quartz geothermometer records a minimum temperature of 820 °C. The study brings evidence that the high-alumina basalt and the felsic magmas were aggregated but did not interacted to yield hybrid magmas, possibly because the time interval was too short. They mingled in various proportions to form the norito-felsic gneisses. The aggregated magmas were intimately linked to the EGOG intrusion in which they played a role as a lubricating agent. They were injected into the wall rocks and were deformed by ballooning from superheated UHT conditions down to subsolidus conditions where mylonitic structures developed. Finally, a charnockitic magma was still able to intrude at a lower temperature below the ductile-brittle transition.

Compositional Evolution of the Variscan Intra-Orogenic Extensional Magmatism in the Valencia del Ventoso Plutonic Complex, Ossa-Morena Zone (SW Iberia): A View from Amphibole Compositional Relationships

The Ossa-Morena Zone (OMZ), SW Iberia, has numerous Lower Carboniferous compositionally zoned plutons that formed in a Variscan intra-orogenic extensional setting. This magmatism shows a wide compositional variation comprising alkaline, transitional, and calc-alkaline suites. The calc-alkaline suite was produced by hybridization of alkaline magmas with felsic melts generated by crustal anatexis related to the intrusion of mafic magmas in the middle crust. In this work, we present a textural and mineralogical study of the Variscan Valencia del Ventoso main pluton from the OMZ to track the compositional evolution of magmas during hybridization using constraints from amphibole compositions and to determine the P-T conditions of emplacement using amphibole-based thermobarometry. This pluton exhibits reverse zoning with an inner facies containing alkaline dolerites, gabbros, and quartz diorites, an intermediate facies with transitional diorites, and an outer facies with calc-alkaline quartz diorites to monzogranites. Magmas from the intermediate and border facies crystallized under oxidizing conditions at relatively low temperatures (range: 640–760 °C) and ca. 280–300 MPa, implying near H2O-saturated conditions. These rock facies show mineralogical evidence of hybridization between alkaline to mildly alkalic and calc-alkaline magmas. The former is inferred from the occurrence of antecrysts of labradorite-andesine, high-Ti pargasite-hastingsite, and biotite with deficiency in tetrahedral-site occupancy, a distinctive feature of biotite from the inner facies alkaline dolerites. This contrasts with later crystallization from the calc-alkaline magma of andesine-oligoclase, low-Ti magnesiohornblende-edenite, and biotite with full tetrahedral-site occupancy. Constraints from amphibole-melt compositional relationships in antecrystic high-Ti amphibole suggest that the alkaline magmatic component could have a high- to ultra-K affinity.

Magma mixing, zircon U–Pb ages and Hf isotopes: Insights for the Miocene magmatic plumbing system in the Soroche Porphyry, Puna Argentina, Central Andes

This research highlights the importance to study the magmatic plumbing systems in Southern Puna, NW Argentina, emphasizing the significance of understanding the genesis of sub-volcanic bodies and their implications for the crustal assimilation and recycling processes. In the southeastern edge of Ratones salar, Southern Puna, there is an intrusive body cropping out, named Soroche Porphyry. This intrusion is formed by porphyritic rhyodacitic, basaltic andesites, and porphyritic andesitic rocks, with magma mixing relations between the mentioned lithologies. The main features of the Soroche Porphyry are described to interpret the dynamic aspects of magma mixing, identify and define textural, mineralogical, and geochemical features, directly related to the mentioned process. Taking into account these features, the results showed that a hybrid magma (homogeneous porphyritic andesite) was produced by mixing processes between basaltic andesitic and rhyodacitic magmas, whereas, the heterogeneous porphyritic andesite represent mingling areas, whereby the end members are easily identified. Furthermore, we dated the main rocks of the porphyry using zircon U–Pb methodology by LA-MC-ICP-MS, complemented by Hf isotopes analyses. The geochronological data evidenced magmatic activity around ~15 Ma, allowing the correlation of the Soroche Porphyry with the Inca Viejo Formation. The basaltic andesites yielded a zircon U–Pb age of 15.63 ± 0.08 Ma, the heterogeneous porphyritic andesites displayed an age of 15.52 ± 0.16 Ma, and the rhyodacites showed an age of 15.13 ± 0.12 Ma. The isotopic ƐHf (15 Ma) values from the rhyodacite between −4.9 and −11.3, suggested a great amount of crustal components, evidencing that the rhyodacitic magmas derived from assimilating and recycling crustal rocks probably from the lower Paleozoic rocks.

Sr‐Enriched Glassy Picrites From the Karoo Large Igneous Province are Evolved, not Primitive Magmatic Rocks

AbstractMagmatic products of the Karoo Large Igneous Province can be divided into a volumetrically dominant, compositionally uniform low‐Ti tholeiitic suite, and a subordinate, geographically restricted, compositionally diverse, incompatible‐rich high‐Ti suite. High‐Ti picrites contain up to 2,400 ppm Sr, 1,900 ppm Ba, and 550 ppm Zr, which seems unusual for olivine‐enriched rocks. We studied six Karoo picrites to determine the phase(s) in which Sr resides. Samples consist of 10–30% olivine phenocrysts in a groundmass of brown glass, augite, feldspar, ilmenite, and apatite. Glass compositions vary, but are generally evolved, ranging from basaltic trachyandesite to dacite. X‐ray intensity maps demonstrate that most of the Sr resides in the glasses, and to a lesser extent, in feldspars, if present. Some samples contain two texturally and compositionally distinct glasses, best modeled in terms of magma hybridization: variably accumulated olivine phenocrysts surrounded by evolved Sr‐rich (to 9,470 ppm) Type 2 melts formed by extensive olivine fractionation were infiltrated by chemically distinct Type 1 melts. Upon eruption, Type 2 melt quenched to minor glass around olivine phenocrysts, and the dominant Type 1 glass acquired its evolved composition by quench crystallization of groundmass mineral phases. Both glasses are rich in H2O (up to 3.8 wt. %) but are nearly devoid of CO2. Calculated parental melts have much higher K2O and incompatible trace elements (e.g., Sr or Ba >1,200 ppm) relative to low‐Ti tholeiites. The unusual parental melt compositions imply derivation by small degrees of partial melting from SCLM mantle sources enriched in Sr and other incompatibles.

Archean continental crust formed by magma hybridization and voluminous partial melting

Archean (4.0–2.5 Ga) tonalite–trondhjemite–granodiorite (TTG) terranes represent fragments of Earth’s first continents that formed via high-grade metamorphism and partial melting of hydrated basaltic crust. While a range of geodynamic regimes can explain the production of TTG magmas, the processes by which they separated from their source and acquired distinctive geochemical signatures remain uncertain. This limits our understanding of how the continental crust internally differentiates, which in turn controls its potential for long-term stabilization as cratonic nuclei. Here, we show via petrological modeling that hydrous Archean mafic crust metamorphosed in a non-plate tectonic regime produces individual pulses of magma with major-, minor-, and trace-element signatures resembling—but not always matching—natural Archean TTGs. Critically, magma hybridization due to co-mingling and accumulation of multiple melt fractions during ascent through the overlying crust eliminates geochemical discrepancies identified when assuming that TTGs formed via crystallization of discrete melt pulses. We posit that much Archean continental crust is made of hybrid magmas that represent up to ~ 40 vol% of partial melts produced along thermal gradients of 50–100 °C/kbar, characteristic of overthickened mafic Archean crust at the head of a mantle plume, crustal overturns, or lithospheric peels.

A tale of five enclaves: Mineral perspectives on origins of mafic enclaves in the Tuolumne Intrusive Complex

AbstractThe widespread occurrence of mafic magmatic enclaves (mme) in arc volcanic rocks attests to hybridization of mafic-intermediate magmas with felsic ones. Typically, mme and their hosts differ in mineral assemblage and the compositions of phenocrysts and matrix glass. In contrast, in many arc plutons, the mineral assemblages in mme are the same as in their host granitic rocks, and major-element mineral compositions are similar or identical. These similarities lead to difficulties in identifying mixing end members except through the use of bulk-rock compositions, which themselves may reflect various degrees of hybridization and potentially melt loss. This work describes the variety of enclave types and occurrences in the equigranular Half Dome unit (eHD) of the Tuolumne Intrusive Complex and then focuses on textural and mineral composition data on five porphyritic mme from the eHD. Specifically, major- and trace-element compositions and zoning patterns of plagioclase and hornblende were measured in the mme and their adjacent host granitic rocks. In each case, the majority of plagioclase phenocrysts in the mme (i.e., large crystals) were derived from a rhyolitic end member. The trace-element compositions and zoning patterns in these plagioclase phenocrysts indicate that each mme formed by hybridization with a distinct rhyolitic magma. In some cases, hybridization involved a single mixing event, whereas in others, evidence for at least two mixing events is preserved. In contrast, some hornblende phenocrysts grew from the enclave magma, and others were derived from the rhyolitic end member. Moreover, the composition of hornblende in the immediately adjacent host rock is distinct from hornblende typically observed in the eHD. Although primary basaltic magmas are thought to be parental to the mme, little or no evidence of such parents is preserved in the enclaves. Instead, the data indicate that hybridization of already hybrid andesitic enclave magmas with rhyolitic magmas in the eHD involved multiple andesitic and rhyolitic end members, which in turn is consistent with the eHD representing an amalgamation of numerous, compositionally distinct magma reservoirs. This conclusion applies to enclaves sampled <30 m from one another. Moreover, during amalgamation of various rhyolitic reservoirs, some mme were evidently disrupted from a surrounding mush and thus carried remnants of that mush as their immediately adjacent host. We suggest that detailed study of mineral compositions and zoning in plutonic mme provides a means to identify magmatic processes that cannot be deciphered from bulk-rock analysis.

Successive magma mixing in deep-seated magma chambers recorded in zircon from mafic microgranular enclaves in the Triassic Mishuling granitic pluton, Western Qinling, Central China

Abstract Extensive Mesozoic magmatism in the Qinling orogenic belt, Central China, has produced voluminous granitic plutons. In Western Qinling, the Triassic Mishuling pluton contains abundant mafic microgranular enclaves (MMEs), recording magma mixing processes in the generation of the pluton. The Mishuling pluton is composed of quartz monzonite, whereas the MMEs are mainly diorite and monzonite. In this study, zircons from the MMEs are all dated by LA-ICP-MS at ca. 215 Ma, clearly consistent with the crystallization age of the host pluton. Quartz monzonites have low Mg# (43–48), Cr (30–64 ppm), and Ni (11–39 ppm) and high Th/U relative to the MMEs. Quartz monzonites are considered to have been produced by melting of Neoproterozoic mafic rocks in the northwestern part of the Yangtze Block, whereas the MMEs were likely the products of mixed mafic and felsic magmas. The mafic magmas may have been derived from partial melting of the enriched lithospheric mantle. Both the MMEs and host quartz monzonites have nearly identical Sr-Nd isotopic compositions, indicating that the hybrid melts and felsic magmas may have reached Sr-Nd isotopic equilibrium due to magma mixing. Zircon grains from the MMEs can be further divided into three types on the basis of internal texture and eHf(t). Overall, all these types of zircon grains have Th/U ranging from 0.18 to 1.63, typical of magmatic origin. Type-1 zircon grains show well-developed {1 0 0} and {1 1 0} prisms as well as {1 0 1} and {2 1 1} pyramids, whereas Type-2 zircon grains show well-developed {1 0 1} pyramids and {1 1 0} prisms. Types-1 and 2 zircon grains have slightly higher eHf(t) (–0.2 to –4.4) than those of the zircon grains from quartz monzonites (eHf(t) = –2.7 to –5.4), indicating crystallization from different hybrid magmas. Type-3 zircon grains have morphology and eHf(t) similar to and Hf concentrations lower than those of the zircon grains from quartz monzonites. We interpret that the Type-3 zircon grains were likely captured from less evolved granitic magmas and are thus xenocrysts in the MMEs. Therefore, the three types of zircon grains from the MMEs record successive magma mixing processes in deep-seated magma chambers. Such a scenario may have broad implications for magma mixing in the generation of granitic plutons.