Hybrid Magma Research Articles

Nucleation delay controlling the formation of mafic enclaves and banded pumice

The presence of mafic enclaves and banded pumice reveals key physical processes associated with volcanic eruptions. Here, through the textural and geochemical analyses of the 3550 B.P. Waimihia deposits in Taupō, New Zealand, we demonstrate how disequilibrium crystallization controls the way magmas mix. Andesitic enclaves in pyroclastic deposits from this predominantly rhyolitic eruption consist of microlites that crystallized rapidly during mafic injection into rhyolitic host magma. The variation of microlite textures depends on enclave size, implying that mafic enclaves crystallized as discrete blobs within a host rhyolitic magma. However, gray pumice and dark bands in banded pumice are characterized by a lack of or less plagioclase microlites that should be present if equilibrium crystallization occurred. Our textural and chemical data suggest that the lack of plagioclase in gray pumice and dark bands resulted from the nucleation delay arising from the mixing with rhyolitic magma. After mafic magma broke up in a magma chamber as discrete mafic blobs, the plagioclase-free rim of the blobs was disaggregated by shear flow. The eroded mafic blobs form a hybrid magma by mixing with rhyolitic magma, which further delays the plagioclase nucleation. This hybrid magma eventually erupted as gray pumice or banded pumice, depending on the intensity of magma mingling in the conduit. We use a plagioclase nucleation delay model to calculate residence times of hours to tens of hours prior to eruption. Our mixing model with nucleation delay enables small volumes of mafic magma to mix with large amounts of silicic magma.

Petrology of Granitoids of the Mayorka Massif (Gorny Altay): Contribution to the Problem of High-Silica Magma Formation

Abstract —The paper presents data from a comprehensive study of granitoids identified in the Mayorka intrusion that is located in the western part of the Altai Mountains. It is shown that the massif is composed of rocks of four intrusive phases, the age of these rocks ranges from 391 to 372 Ma, and the intrusion of the main volume of granitoids dates back to a relatively short interval of 386–384 Ma. The massif contains rocks of two geochemical types. The first type is differentiated calc-alkaline granite-leucogranites with near-clark contents of high-field-strength elements and rare earth elements: ɛNd(T) = + 4.3…+ 4.5 and σ18O V-SMOW = +10.7…+11.2 ‰. The second is alkaline and moderately alkaline A-type alaskites, strongly enriched in high-field-strength elements and rare earth elements, having ɛNd(T) + 5.3 and σ18O V-SMOW = +11.6 ‰. Granitoids of the first group are of crustal source, while the rocks of the second group contain a significant portion of mantle material. The near-simultaneous introduction of these melts to the level of formation of the intrusion caused their interaction and the formation of hybrid magmas. Low crystallization temperatures of granitoids (<700 °C) and the presence of syngenetic melt and fluid inclusions in most rock varieties indicate a high fluid saturation of the melts. The abundance of leucogranites, whose geochemical characteristics cannot be explained from the standpoint of shallow differentiation of primary magmas, indicates the leading role of fluid-magmatic interaction processes in the formation of high-silica magmas.

A Geodetically Constrained Petrogenetic Model for Evolved Lavas from the January 1997 Fissure Eruption of Kīlauea Volcano

Abstract Magmatic systems below volcanoes are often dominated by partially crystalline magma over the long term. Rejuvenation of these systems during eruptive events can impact lava composition and eruption style—sometimes resulting in more violent or explosive activity than would be expected, as was the case at Fissure 17 during Kīlauea’s 2018 eruption. Here, we explore how the crystallinity of unerupted intrusion magmas affect hybrid magma compositions and petrological signatures by constructing phase-equilibria models to evaluate mineral and melt compositions of low-MgO lavas erupted along the East Rift Zone of Kīlauea volcano on 30 to 31 January 1997 (Episode 54, Fissures A-F). We then compare calculated mixing proportions and petrologically derived magma volumes to GPS-based geodetic inversions of ground deformation and intrusion growth in an attempt to reconcile geodetic and petrologically estimated magma volumes. Open-system phase-equilibria thermodynamic models were used to constrain the composition, degree of differentiation, and thermodynamic state of a rift-stored, two pyroxene + plagioclase saturated low-MgO magma body immediately preceding its mixing with high-MgO recharge and degassed drainback (lava lake) magma from Pu‘u‘ō‘ō‘, shortly before fissure activity within Nāpau Crater began on 29 January 1997. Mixing models constructed using the Magma Chamber Simulator reproduce the mineralogy and compositions of Episode 54 lavas within uncertainties and suggest that the identity of the low-MgO magma body may be either variably differentiated remnants of un-erupted magmas intruded into Nāpau Crater in October 1968, or another spatially and compositionally similar magma body. We find that magmas derived from a single, compositionally stratified magma emplaced beneath Nāpau Crater in 1968 can mix with mafic Kīlauea magmas to reproduce average Episode 54 bulk lava, mineralogy and mineral compositions without necessitating the interaction of multiple, low-MgO rift-stored magma bodies to produce Episode 54 lava compositions. Further, by constructing phase equilibria-based mixing models of Episode 54, we can better define the pre-eruptive state of the magmatic system. The resultant mineral assemblages and compositions are consistent with the possibility that the now-fractionated, rift-stored magma body was compositionally stratified and ~ 40% to 50% crystalline at the time of mixing. Finally, we estimate the volume of the low-MgO magma body to be ~7.51 Mm3. Phase-equilibria model results corroborate field and geochemical relationships demonstrating how shallow intrusions at intraplate shield volcanoes can crystallize, evolve, and then be remobilized by new, later batches of mafic magma. Most notably, our MCS models demonstrate that the pre-eruptive conditions of an intrusive body may be recovered by examining mineral compositions within mixed lavas. Discrepancies between the geodetic constraints on volumes of stored rift versus newly intruded (recharge) magma and our best-fit results produced by MCS mixing models (which respectively are mmafic:mlow-MgO ≈ 2 vs. mmafic:mlow-MgO ≈ 0.75) are interpreted to highlight the complex nature of incomplete mixing on more localized scales as reflected in erupted lavas, compared to geodetically constrained volumes that likely reflect large spatial scale contributions to a magmatic system. These dissimilar volume relationships may also help to constrain eruptive versus unerupted volumes in magmatic systems undergoing mixing. By demonstrating the usefulness of MCS in modeling past eruptions, we highlight the potential to use it as a tool to aid in petrologic monitoring of ongoing activity.

Petrogenesis of a TTG intrusive suite: the La Dauversière pluton, Abitibi greenstone belt, Canada

Insights into the source and partial melting conditions of tonalite–trondhjemite–granodiorite (TTG) intrusive suites provide essential constraints on the tectonic regimes prevailing before 2.5 Ga. As case studies on individual suites increase, the TTG group becomes more heterogeneous, offering detailed insights into the evolution of the Archean crust. This study focuses on the La Dauversière pluton, a TTG suite in the Chibougamau area, Abitibi greenstone belt, Canada, to unravel complex differentiation processes in a pluton with a relatively limited volume. According to whole-rock and zircon chemistry, the La Dauversière pluton is a TTG suite that contains less Na and light rare earth elements (LREE) than other TTG suites of the Abitibi greenstone belt. Whole-rock chemistry and melt inclusions in zircon also point to an atypical fractional crystallization process that favors K enrichment, contrasting with the Na enrichment trends observed in most TTG suites globally. Magma hybridization, with late magma pulses interacting with early phases partially crystallized at depth, likely explains the chemistry of the La Dauversière pluton. The source of these magmas differs from the basaltic source that gave rise to most TTG suites of the Abitibi greenstone belt, possibly because older basement occurs in the Chibougamau area and is lacking in the rest of the greenstone belt. The La Dauversière pluton underscores the importance of interpreting the petrogenesis of individual TTG suites before inferring global source processes and geodynamic settings.

Geology, fluid inclusion, 40Ar-39Ar geochronology, and isotope constraints on the ore genesis of the Ershiyizhan Cu–Au deposit, Heilongjiang Province, China

The Ershiyizhan Cu–Au deposit, located in the eastern part of the upper Heilongjiang metallogenic belt, north of the Great Xing'an Range, is composed of orebodies from the Mesozoic magmatic rocks and the Ershierzhan group. There are three metallogenic stages of this deposit, (1) Quartz-K-feldspar-polymetallic sulfide stage (stage Ⅰ), (2) quartz-polymetallic sulfide stage (stage II), and (3) quartz-calcite ± pyrite stage (stage Ⅲ). Three types of fluid inclusions (FIs) were discovered in the vein mineral assemblages, liquid-rich two-phase aqueous FIs (L-type), vapor-rich aqueous FIs (V-type), and multi-phase FIs (S-type) with daughter minerals, including S1-type inclusions homogenized through vapor disappearance and S2-type inclusions homogenized by halite dissolution. Quartz of stage I and stage II contains all of these FIs. In contrast, the L-type fluid inclusions of stage III veins are the only ones present in the calcite. The homogenization temperatures and salinities obtained from FIs in stages I, II, and III range from 330 to 563 °C, 223 to 423 °C, and 108 to 225 °C, and 0.88 to 66.18 wt%, 2.41 to 48.59 wt%, and 0.18 to 3.23 wt% NaCl equiv., respectively. δ18O and δD values obtained from stable isotope analyses of K-feldspar and quartz samples collected from stages I, II, and III range from −2.31 to 7.89 and −133.2 to −98.2, respectively. Microthermometry and H-O isotope data from FIs suggest that the ore-forming fluids of the deposit had a magmatic origin, characterized by high temperatures, low–high salinities, an H2O-NaCl fluid system and this fluid system evolved to a low temperature, low salinities fluid through the gradual combination of meteoric water from stages II to III. Trapping pressures estimated from boiling L-type, V-type, and S1-type fluid inclusions in stage Ⅰ were 100–500 bars, corresponding to a mineralization depth of 1.0 to 5.0 km, with fluid boiling and mixing likely being responsible for the precipitation of sulfides and gold. K-feldspar from an auriferous vein of stage I yielded an 40Ar/39Ar isotopic plateau age of 131.21 ± 0.52 Ma, suggesting that the mineralization of the deposit is closely associated with the Early Cretaceous quartz monzonite porphyry. The analysis of the S isotope of metal sulfides in this deposit demonstrate that the sulfur reservoir is primarily derived from a hybrid magma source consisting of both mantle-derived and crustal-derived materials. Lead radioactive isotopic analysis for metal sulfides and various wall rocks also implies the lead source is a mixed source of upper crust and mantle. Thus, S-Pb isotope studies indicate that a crust-mantle mixed source for the mineralization of the deposit, and ore-forming material may originate from both quartz monzonite porphyry and various surrounding rocks including Late Triassic-Early Jurassic monzogranite, granite, quartz syenite, and the Ershierzhan Formation. Considering the geology, geochronology, FI, and H-O-S-Pb isotopic characteristics, the Ershiyizhan Cu–Au deposit is classified as a porphyry deposit formed in an extensional environment due to the delamination of the thickened lower crust following the Mongolian-Okhotsk Ocean closure.

Brittle fragmentation of Fissure 17 enclave magma revealed by fractal analysis

The 2018 LERZ eruption of Kilauea featured a wide range of eruptive styles. In particular, Fissure 17 (F17) displayed activity ranging from Hawaiian fountaining in the eastern part of the fissure to Strombolian explosions in the western part. Lava erupted from F17-West was highly viscous and contained magmatic enclaves. Magmatic enclaves have previously been observed in many other volcanic systems (e.g. Vulcano Island, IT and Sete Cidades Volcano, PT), where they have been attributed to injection of mafic magma into an evolved magma chamber, resulting in viscous fingering, quenching, and break-off into fragments. The F17 enclaves differ from previous studies in that the chemical compositions of the enclave and host magmas are very similar, and that the enclaves have a limited spatial distribution and lack signs of viscous behavior and quenching, pointing to a different formation mechanism than inferred for other volcanic systems.In order to test a different formation hypothesis, we conducted fractal analysis of the size distribution of 84 individual enclaves from F17-West lavas. Our results, including a fractal dimension of fragmentation Df of 2.59, indicate that the F17 enclaves likely formed by brittle fragmentation. Since the enclave and host magmas were at temperatures far above the glass transition during the magma hybridization, high strain rates have to be invoked to explain the brittle fragmentation. This may have caused the enclave magma to transition into solid-state behavior, allowing it to break off into fragments that were subsequently picked up by the host magma and carried to the free surface.The enclaves from F17-West therefore offer a unique insight into the diversity of processes that characterizes the shallow parts of volcanic systems, as well as the importance of strain rates in modulating the rheological behavior of magmas.

Petrological and geochemical evidence for a hot crystallization path and a recharge filtering bypass at Antimilos, Milos volcanic field, Greece

Antimilos volcano in the South Aegean Volcanic Arc, Greece, comprises an andesite–dacite suite that follows a distinct evolutionary path than the main edifice of the Milos volcanic field, despite their proximity. Petrographic and geochemical analyses reveal that basaltic andesite to low-Si dacite lavas have similar phenocryst assemblages that indicate crystallization from hot, relatively dry magmas in an upper crustal storage region. Rare antecrystic high-Mg# clinopyroxene cores with low Y, low Dy, and high Sr contents record the cryptic involvement of amphibole, a phase nominally absent from the erupted products, in the deeper parts of the plumbing system. Low temperature antecrysts with textures recording various degrees of disequilibrium suggest a protracted history of interaction between the upper crustal reservoir and deeper mafic melts, forming mobile hybrid magmas that consequently erupt as highly mingled, crystal-rich lava domes. Antimilos magmas seem to have escaped recharge filtering in the upper crust and prolonged stalling, which is the process that is probably responsible for the paucity of mafic eruptions in the rest of the Milos volcanic system. Large extensional structures offshore of Antimilos promote rapid ascent of mafic melts, inhibiting prolonged stalling and interaction with the arc crust. This model highlights the dominant role of the regional stress field in generating petrologically distinct suites in the marginal parts of some volcanic fields.

Petrogenesis of Late Cretaceous A-type plutonic rocks from the Eastern Pontides Orogenic Belt (NE Turkey): constraints from zircon U-Pb geochronology, zircon Lu-Hf and whole-rock Sr-Nd-Pb-Hf isotopes

ABSTRACT The Late Cretaceous magmatic history of the Eastern Pontides Orogenic Belt (NE Turkey) was generally characterized by common I-type and lesser A-type plutons in varying size and composition. Of these, A-type plutons from the Şebinkarahisar (Giresun) area yield SHRIMP zircon U-Pb age of 77.36 ± 0.96 Ma. The rocks of these plutons display a wide range of SiO2 contents (53.63 to 70.96 wt.%) and Mg-numbers (6.2–32.19) with A-type affinities characterized by enrichment in K2O and Na2O, Ga, Zr, and strong negative Eu anomalies. They also show arc-type petrochemical features including enrichment of large-ion lithophile elements (e.g. Cs, K, Rb) and light rare earth elements (LaN/LuN = 6.27–15.61), but depletion in high strength field elements (e.g. Nb, Ta, Ti, and P). The (87Sr/86Sr)i ratios and ɛNd(i) values of the studied rocks are in the range of 0.705129 to 0.0705347 and −3.64 to −3.12, respectively, while bulk rock ɛHf(i) values are between 1.86 and 4.36. They are characterized by positive zircon ɛHf(i) (1.74 to 10.88) plotting between the chondrite and depleted mantle evolutionary line values. Our data combined with the previous studies suggest that the magmas, that formed the Late Cretaceous plutons, were generated in an extensional tectonic environment due to slap roll-back and trench ward migration of the subduction zone to the south. The generation of hybrid magmas forming the studied plutons is in response to the melts derived from a metasomatized lithospheric mantle source, a relatively deeper mantle source, and the juvenile crust along with the heat transfer and decompression. Multi-sourced magmas rise through the continental crust and reach the final composition by predominantly fractional crystallization processes.

Major, trace elements and Sr–Nd–Pb isotopes systematics of mafic dykes from the Figuil (northern Cameroon) and Léré (southwestern Chad) areas

In this study, field descriptions of the dolerite dykes cross‐cutting the Pan‐African basement (DPB) and the dolerite and gabbroic dykes cross‐cutting the Cretaceous sedimentary basin (DGCSB) are used together with petrographic, bulk‐rock geochemistry, as well as Sr–Nd–Pb isotopic data to constrain the geodynamic setting and origin of these mafic (basanite, basalt and basaltic andesite in composition) rocks that outcrop in the Figuil–Léré area. The DPB dykes are alkaline with SiO2 of 46.63–49.03 wt% and MgO of 3.93–7.11 wt%. In contrast, the DGCSB dykes are subalkaline with SiO2 ranging between 50.24 and 53.16 wt% and MgO fluctuating between 5.22 and 7.90 wt%, comparable to dykes described in other regions of the Cameroon Line (CL). The rocks studied belong to the tholeiitic series and were emplaced in within‐plate basalts (WPB) and mid‐ocean ridge basalts (MORBs) setting. The variations in major and trace elements from the basanite to basaltic andesite compositions are dependable with fractional crystallization (FC) of different mineral phases such as opaque minerals, olivine, clinopyroxene, amphibole and alkali feldspar. Most samples exhibit negative Nb–Ta and positive Sr anomalies, which together with the negative correlation between MgO and 87Sr/86Sr, and isotopic ratio of 206Pb/204Pb <19.5 (18.27–19.49) suggests interactions of crustal components. Nevertheless, this contamination seems limited because there is a positive correlation between SiO2 and 143Nd/144Nd plot and low Ba contents (72–210 ppm) of the samples compared to the mid‐continental crust (259–628 ppm). Trace element modelling proposes a derivation of the Figuil–Léré dykes from parental melts generated by 4%–15% partial melting of a source containing garnet peridotite in the mixed lithospheric–asthenospheric mantle. The isotopic data of the dykes studied with hybrid magma composition are characterized by more radiogenic 87Sr/86Sr, 143Nd/144Nd and 206Pb/204Pb isotopic ratios with a dominant mixing of depleted MORB mantle (DMM)–enriched mantle 1 (EM1)–enriched mantle 2 (EM2), like those of other mafic dykes of the CL.

Multistage formation of the titanite-centered ocellar texture in magma mixing zones: New insights from field, petrographic and mineralogic evidence in the Paleoproterozoic Mineiro belt, Brazil

The titanite-centered ocellar texture is among the rarest and most intriguing textures associated with magma hybridization zones in plutonic environments. In order to contribute to the discussion regarding its formation process and relation to mixing, we investigated detailed field, petrographic, and mineralogical aspects of two occurrences of ocellar hybrid rocks associated with the Paleoproterozoic Macuco de Minas metagranitoid, Mineiro belt, southern São Francisco Craton. The studied rocks display oriented elliptic leucocratic aggregates composed of quartz, oligoclase (An15-20), microcline, apatite, and zircon, with an up-to centimetric poikilitic or euhedral diamond-shaped titanite crystals in their center (ocelli). The ocelli are often partially connected and immersed in a mesocratic tonalitic matrix composed of quartz, oligoclase (An15-20), Fe-biotite, titanite, allanite, fluorapatite, and zircon. The titanite crystals in the ocelli are enriched in Ti, LREE, Y, Th, and Zr and depleted in Al and F compared to the ones from the matrix, indicating that these compose two distinct groups of titanite. We propose that the development of the titanite-centered ocellar texture is a multi-stage interaction between mafic and felsic end-members, in which a biotite-rich tonalitic hybrid mush is injected by a fractionated leucogranitic melt. The leucogranitic melt migrates through veins that follow the preferred orientation of crystals in the hybrid mush and becomes enriched in Ti by the destabilization of biotite, resulting in the crystallization of the euhedral diamond-shaped titanite crystals. The veins are then disrupted, turning into elliptic ocelli in response to the pressure applied by the denser hybrid mush.

Making Andesite Through Shallow Hybridization of Magmas Derived From Variably Enriched Lithospheric Mantle

AbstractWe integrate textural and in situ compositional information from plagioclase and clinopyroxene (Cpx) phenocrysts together with groundmass compositions in early Cretaceous andesite dykes within the Sulu belt of China to propose a new petrogenetic model for andesite. Plagioclase phenocrysts are mostly andesine; they are depleted in high field strength elements (HFSE). However, Cpx phenocrysts are either reversely zoned (type I) or homogeneous (type II), with the zoned Cpx divided into subtypes IA and IB. All Cpx has high Mg#, low Na2O and generally low Al2O3, with depletions in HFSE and variably high 87Sr/86Sr ratios, suggesting crystallization above the Moho from magmas derived from enriched lithospheric mantle. The cores of type IA/IB and type II Cpx have normal major‐ and trace‐element compositional variations and similar 87Sr/86Sr ratios to each other and to plagioclase, consistent with fractional crystallization from a common magma (magma 1). The rims of type IA and IB Cpx also have normal major‐ and trace‐element compositional variations, but these are not as evolved as the cores, and the rims have lower 87Sr/86Sr ratios, demonstrating crystallization from an isotopically distinct magma (magma 2). Based on modeled major and rare earth element compositions of magmas inferred to have been in equilibrium with different Cpx (±plagioclase) domains, the measured groundmass compositions can be reproduced by variable mixing between the two magmas. Our study demonstrates for the first time that andesite magma can be made through fractionation and shallow hybridization of magmas derived from variably enriched lithospheric mantle.

Early Cretaceous tectonic transition in South China: Insights from felsic igneous rocks and mafic dikes, eastern Guangdong Province

Large‐scale magmatic activity and associated mineralization in South China are linked to the subduction of the palaeo‐Pacific Plate, although specific processes have remained controversial including the timing of subduction initiation and lithospheric extension. We present new geochemical data and zircon U–Pb and Lu–Hf isotope measurements on volcanic rocks, granites and mafic dikes from coastal south‐eastern China along the Eurasian continental margin. The biotite monzogranites show I–type granitoid affinity and fractional crystallization with zircon εHf(t) values ranging from −10.15 to +0.50, suggesting magma derivation from the melting of lower crust with the addition of juvenile crustal or mantle components. The biotite granites are typical of highly fractionated A‐type granites with εHf(t) values ranging from −3.63 to +1.35, indicating magma hybridization between anatectic granitic and mantle‐derived mafic magmas. The diabase dikes have zircon εHf(t) values ranging from −2.99 to +1.71, with high La/Nb and La/Ta ratios. This suggests derivation from partial melting of a lithospheric mantle metasomatized by fluid from a subducting–slab, with contributions of depleted asthenospheric mantle components. Our data, combined with those from previous studies, suggest that the shallow subduction of the palaeo–Pacific Plate beneath the Eurasian continent had begun by ca. ~170 Ma at least and the subduction orientation changed to oblique with respect to the continental margin. Steepening of the subduction angle likely caused a slab rollback during the Early Cretaceous, resulting in a tectonic transition from compression to extension in South China at ca. 145 Ma.

Zircon U Pb geochronology and Sr-Nd-Pb-Hf isotope geochemistry of the Dahuabei pluton from the northern margin of North China Craton: Implications for petrogenesis, tectonic setting and Au Mo mineralization

The Late Paleozoic Dahuabei Pluton is located in the Wulashan area at the northern margin of the North China Craton (NCC), adjacent to the Hadamengou gold deposit, the largest gold deposit in Inner Mongolia, China. However, its petrogenesis and its relationship with AuMo mineralization remain debatable. In this contribution, a geochemical, isotopic, and geochronological study was carried out on the Dahuabei pluton to constrain its magma sources, petrogenesis, and tectonic setting, and further discuss the linkage between the magmatism and AuMo mineralization. The Dahuabei pluton mainly consists of monzogranite and syenogranite, with abundant mafic microgranular enclaves (MMEs) in the monzogranite. Zircon UPb dating shows that the ages of the Dahuabei pluton range from 357 to 353 Ma, suggesting an Early Carboniferous emplacement. The crystallization age of the MMEs (355.4 ± 3.2 Ma) is nearly simultaneous to that of host monzogranite (356.5 ± 2.0 Ma). Geochemically, the granitoids show high-K calc-alkaline and weakly peraluminous affinities and are classified as highly to moderately fractionated I-type granites. Moreover, they are enriched in light rare earth elements and large ion lithophile elements, depleted in high field strength elements, resembling typical continental arc magmatic rocks. Isotopically, the granitoids have negative εNd(t) (−10.0 to −7.3) and εHf(t) values (−10.0 to −4.4), as well as old Nd (1923–1704 Ma) and Hf (1986–1697 Ma) model ages, suggest that the granitoids were mainly derived from partial melting of ancient mafic lower continental crust, with involvement of mantle-derived components. The sharp contacts, fine-grained igneous textures, numerous xenocrysts from host granites, and similar crystallization ages with host granites of the MMEs suggest a magma mingling process, in which the MMEs represent discrete mafic to hybrid magma globules formed by undercooling after the injection of hotter mafic magma into cooler felsic magma. Geochemical and isotopic data (εNd(t) of −6.2 to −5.4 and εHf(t) of −10.2 to −2.8) indicate that the parental magma of MMEs was derived from partial melting of the enriched subcontinental lithospheric mantle metasomatized by slab-derived fluids and had experienced significant fractional crystallization. The indistinctive chemical and isotopic contrast between MMEs and host monzogranite implies their chemical and isotopic exchange during various degrees of magma mingling. Integrating the geochronological, geochemical, and Pb isotope data of the Hadamengou AuMo deposit and the Dahuebei pluton, we propose that the magmatic-hydrothermal system emanated from the magma mingling event during the emplacement of the Dahuabei pluton might be favorable for the mineralization. The Late Devonian to Early Carboniferous magmatism may have been a trigger for the formation of the AuMo deposits in the northern margin of the NCC.

The obscuring effect of magma recharge on the connection of volcanic-plutonic rocks

Abstract The current debate on volcanic-plutonic connection is centered on whether efficient liquid-crystal segregation dominates the evolution of a mushy reservoir to produce evolved, crystal-poor rhyolite and cumulate leftover. However, magma recharge may remarkably influence the evolution of a mushy reservoir and obscure the evidence of liquid-crystal segregation. This complexity poses a challenge to exploring the connection of volcanic-plutonic rocks. This study investigates the Qinzhou Bay granitic complex (~250–248 Ma) from South China, which contains crystal-poor (<19 vol%) peraluminous rhyolites and subsequent crystal-rich (28–54 vol%) porphyries. Although the rhyolite and porphyry units have a close spatio-temporal link, they do not share a fractionation trend and similar whole-rock Sr-Nd-O isotopic compositions; thus, a direct connection is not evidenced. We further present textural analyses, mineral and melt inclusion compositions, thermobarometry (the combination of Ti-in-zircon thermometer and Ti-in-quartz thermobarometer), and thermodynamic modeling to examine the alternative interpretations, i.e., the two units may have intrinsically independent origins or the connection of the two units has been obscured. For the rhyolite unit, thermobarometric results reveal a polybaric storage system consisting of middle (>600 ± 80 MPa) and upper (~150 ± 40 and ~60 ± 20 MPa) crustal reservoirs. Variations in quartz Fe content and chlorine-rich, metaluminous melt inclusions suggest that magma hybridization with less-evolved metaluminous magmas occurred at both crustal levels. In particular, the elevated Fe contents in the quartz population that crystallized at the shallowest level (~60 ± 20 MPa) suggest that recharge magmas were directly injected into the shallowest reservoir. Deviation of the whole-rock composition from the liquid evolution trend recorded in melt inclusions suggests a combined effect of magma mixing and crystal-melt segregation processes in upper crustal reservoirs. Thermodynamic modeling and mass balance calculations suggest that the whole-rock composition of the rhyolite could be reproduced by mixing between regionally exposed dacites and segregated melts at crystallinities of 50–60% (using parental magma represented by the least-evolved melt inclusion). For the porphyry unit, thermobarometric results reveal magma storage at middle (more than 450 ± 40 to 550 ± 40 MPa) and upper (110 ± 20 to 140 ± 20 MPa) crustal levels. The small-scale oscillatory zonation of plagioclase, the pervasive resorption of quartz and alkali feldspar, and the presence of peraluminous microgranular enclaves in the porphyries suggest a recharge event of metasediment-sourced magmas, triggering reactivation and convection of the reservoir. Autoclastic and overgrowth textures of quartz, plagioclase, and alkali feldspar phenocrysts and development of columnar jointing suggest that the reactivated porphyritic magmas ascended and emplaced at ultrashallow levels (~30 ± 10 MPa). Because of the similar storage pressures, the porphyries may represent remobilized cumulates of rhyolitic magmas, whereas the texture and geochemistry of the cumulate-liquid pair were modified, a key factor rendering a cryptic connection between the rhyolite and porphyry. Alternatively, the plumbing systems feeding the rhyolite and porphyry units are horizontally independent or vertically discrete, but this circumstance is inconsistent with the same evolution trend of quartz Fe and Al contents of the rhyolite and porphyry. Our study highlights that whole-rock composition may record blended information of complex processes, and caution should be taken when whole-rock composition is used to extract information of a single process. Multi-method constraints are required to evaluate the influence of recharge processes on the modification of liquid-cumulate records, and big data analysis on the basis of geochemistry should be conducted with caution to avoid biased understanding.

Metallogeny and exploration strategy for volcanic rocks hosting world class Be-U-F mineralization at Spor Mountain, Utah, U.S.A.

We report new geochemical data (major-elements, trace-elements, and Nd-Pb isotopes) for the Spor Mountain Formation (SMF), a volcanic sequence that hosts the largest deposit of beryllium in the world. Understanding the genesis of the deposit is critical for improved recognition of regional exploration targets containing additional volcanic-hosted beryllium resources. The deposit occurs in an area of extensive alkalic rhyolitic ash flow tuffs and calderas underlain by Paleozoic and older limestone, dolomite, shale, and quartzite. The lower fluorite and bertrandite-rich tuff and upper topaz-rich rhyolite of the SMF have overlapping zircon crystallization ages (25.59 + 0.29/−0.45 Ma). Enrichment of Be, U, and F is a key attribute of the SMF inherited from melting heterogeneous source materials and magma hybridization in the continental lithosphere. Two mineralization stages are implicated: magmatic, and hydrothermal/metasomatic. The magmatic stage occurred early, as indicated by the high beryllium content in early-crystallizing zircon. The post-magmatic/hydrothermal stage involved F-rich fluids that reacted with glass and carbonate nodules in the tuff to form bertrandite (and U-rich fluorite and opal) and high-grade mineralization. The rhyolite best displays the magmatic stage of enrichment. The SMF is alkaline. Chondrite-normalized REE patterns for tuff and rhyolite are regular, stacked subparallel, and imply a shared source derivation and evolution. The tuff and rhyolite plot along a sub-vertical array for Pb isotopes and suggest they are cogenetic; both have negative values of εNd. Pb isotopic ratios for SMF do not match the slopes, initial isotopic values, or estimated basement ages of precious and base metal mining districts in Utah; thus, they do not share a source region or evolution. Crustal ages from Nd isotopes (average TDM ~ 2.29 Ga) are older than basement ages obtained by Pb isotopes. The deposit occurs in a transitional area of thinned crust near the boundary between two basement domains, the eastern Great Basin and Colorado Plateau, which have contrasting ages. Many geochemical attributes are shared between SMF and the Ermakovka deposit in Russia: they represent the world's major commercial Be deposits. Rare-metal indices of granite-related mineralization show that SMF resembles other global beryllium-bearing granitic deposits. Despite this coincidence, none of these examples matches the mineralogy, geologic setting, or type of rare metal mineralization at Spor Mountain.

Early Paleozoic granodiorites and gabbros related to asthenosphere upwelling in the eastern Wuyi-Yunkai Orogen, South China

The early Paleozoic Wuyi-Yunkai Orogen (WYO) developed in the inner part of the South China Block (SCB) and underwent large scale felsic magmatism. Different tectonic models have been proposed to explain the evolution of the WYO, including intracontinental and collisional orogenesis. The debates focus on whether the asthenospheric materials were involved during evolution of the WYO. We conducted detailed petrographic and geochemical analyses on gabbros from the Qiaotou pluton and granodiorites and the hosted MMEs from the Xinsi pluton in the eastern WYO, and present the first evidence of asthenosphere upwelling that induced significant lithosphere remobilization in the SCB during early Paleozoic. Granodiorites from the Xinsi pluton (441 ± 2 Ma) contain abundant amphibole and are metaluminous, which originated from the igneous basement in the Cathaysia Block. The hosted MMEs (440 ± 2 Ma) have variable SiO2 and enriched Sr-Nd isotopic compositions with high zircon δ18O values, which were formed through hybridization of felsic melts and mafic magmas from the enriched lithosphere mantle. Gabbros from the Qiaotou pluton (448 ± 8 Ma) have low K2O with insignificant Nb-Ta-Ti anomalies and show variable Sr-Nd-O isotopic compositions. They were derived from the depleted asthenosphere and underwent crustal assimilation. The asthenosphere upwelling may be induced by slab breakoff during the collision between the western Cathaysia Block and an unknown block near northern Gondwana. The continental collision possibly transferred compressional stress and caused crustal uplifting along the weak zone in the inner SCB. The asthenosphere upwelling provided tremendous heat for the lithosphere remobilization and voluminous magmatism in the WYO.

Magma hybridization and crystallization in coexisting gabbroic and granitic bodies in the mid-crust, Akechi district, central Japan

Petrological and geochemical features of gabbros and fine-grained mafic rocks (mafic microgranular enclaves; MMEs) in the Inagawa Granite of the Ryoke Plutonic Complex were investigated to assess the interactions between coexisting mafic and silicic magmas, and the petrogenetic relationships between the MMEs and surrounding gabbros. The MMEs exhibit mingling textures that imply the coexistence of mafic and silicic magmas that did not undergo complete mixing, but the geochemical compositions of the MMEs require substantial hybridization and homogenization. The gabbroic rocks exhibit disequilibrium textures and mineral compositions, such as quartz–hornblende ocellar textures and patchy plagioclase crystals with bimodal anorthite contents. These textures and compositions record an abrupt decrease in crystallization temperature and mechanical mixing between crystallizing gabbroic mush and silicic (granitic) melt. Geochemical variations of the gabbroic rocks can be explained by hybridization and fractional crystallization (HFC) processes between crystallizing gabbroic mush and granitic melt. Extrapolation of the mixing trend to a basaltic composition suggests that the primitive mafic end-member was a low-K basaltic magma. Given that HFC yields magnesian andesite by the addition of a small amount of silicic melt to a primitive mafic end-member, the compositional modification of mafic magmas by magma mixing might be an essential process in the formation of andesitic magma in arc crust.

Petrology of Mt. Kıra continental alkali lavas with arc-like signature, Batman, SE Anatolia, Turkey: Evidence for mafic juvenile lower crust assimilated intraplate basalts in the collision- and mantle flow-driven geodynamic setting of Arabian Foreland

Mineral phase variations and compositions of Early Pliocene (40Ar39Ar ages ranges 5.092 ± 0.030–4.892 ± 0.024 Ma) continental alkali basalts cropped out on Mt. Kıra, NE of Batman Province, SE Anatolia, and located approximately 75 km east of well-known Karacadağ Volcanic Complex (KVC) in Diyarbakır Province, record indications of pre-eruptive assimilation of the lower crust by OIB-like basaltic magmas from Arabian Foreland, which are proved by available data of juvenile lower crustal xenoliths in northern Syria Cenozoic basalts. Diopsitic augites with low Mg#’s (0.65–0.73) in Mt. Kıra basalts depict a compositional prone to clinopyroxenes (Mg#, 0.60–0.76) in Syrian lower crustal xenoliths and coexist with Ca- and Mn-rich fayalitic olivines (Fo63–36), Ca-poor (An72–13) plagioclases, and FeTi oxides. Mt. Kıra lavas, classified as hawaiites, are characterized by the narrow ranges of low SiO2 (46.30–47.68 wt%), Al2O3 (13.74–14.41 wt%), MgO (3.48–4.16 wt%), and high total alkali (Na2O + K2O, 5.26–5.89 wt%), Fe2O3 (13.97–15.38 wt%), TiO2 (3.44–3.61 wt%), CaO (7.20–8.99 wt%), and P2O5 (1.54–1.71 wt%) contents, and with low Cr (< 14 ppm) and Ni (< 20 ppm) values. Except for unusual ZrHf depletion, they exhibit typical arc-like (or crust-like) sharp negative anomalies of NbTa and Ti and possess high concentrations of Y (45–51 ppm), Sc (28–33 ppm), and Heavy REE (e.g., Dy, 9.25–10.73 ppm; Er, 4.74–5.27 ppm; Yb, 3.79–4.44 ppm). Two-component mixing model, and radiogenic 87Sr/86Sr (0·7,044,010–0.705396) and 143Nd/144Nd (0.512676–0.512812) isotopic compositions, which overlap with bulk-silicate earth, for Mt. Kıra basalts, provide evidence for the mafic juvenile lower crustal assimilation by OIB-like basaltic magmas derived from a common enriched mantle source. High Ba/La, Ba/Ta, Ba/Nb, Zr/Nb, and low Nb/La, La/Sm, Nb/Th, La/Yb, and Dy/Yb ratios, which coincide with those of Syrian lower crustal xenoliths, appears as geochemical hallmarks for decoupling of juvenile lower crust assimilated Mt. Kıra, NW Syria and some of KVC basalts from least contaminated ones in Arabian Foreland. The enrichments in Y, Fe, and Ti and depletions in Al and Sr in Mt. Kıra lavas, however, are attributed to post-eruptive chemical weathering processes. Based on petrological and tectonic data, it is proposed that the northern Arabian Foreland Cenozoic volcanism was triggered by the combined effect of both collision- and mantle flow-driven forces with a kinematic linkage. Asthenospheric mantle flow and upwelling, which supply a thermal source, caused the deep mantle processes and interaction between asthenosphere and lithosphere, which was formed the amphibole-bearing garnet lherzolitic (asthenospherized) metasomes (mantle flow-induced metasomatism) at the base of the SCLM accreted from the ductile asthenosphere, prior to partial melting. Partial melting of such re-fertilized metasomes and surrounding wall rock was most likely produced hybrid parental magmas via mixing variable proportions of melt fractions from a garnet lherzolite source with melt fractions from an amphibole-bearing garnet lherzolite source. On the other hand, concurrently running of collision-induced temporarily changing regional stress -compressional or extensional- regimes caused i) the development of surface tectonic structures in a dynamic topography that reactivated the pre-Neogene deep tectonic structures, ii) multiphase rapid uplifts, and iii) prominent deep channeling for the upwelling enriched mantle-derived hybrid magmas to penetrate. The shallow level lower crustal assimilation of this OIB-like hybrid mantle melts, generated the Mt. Kıra, NW Syria, and some of KVC basalts in the Arabian Foreland, during magmas en route to the surface.

Petrology of Koko Rift basalts: Hawai‘i's most recent and atypical rejuvenation stage eruptive sequence

Rejuvenated volcanism is a worldwide phenomena occurring on many volcanic oceanic islands in all of the major ocean basins (e.g., Samoa, Madeira, Mauritius). This plume-related volcanism follows the main edifice-building stage after a hiatus of variable duration (e.g., 0.6–2 Myrs in Hawai‘i). Hawaiian rejuvenated basalts typically have high MgO contents (>10 wt%) and carry upper mantle xenoliths. Thus, these magmas are assumed to have ascended rapidly through the crust. The basalts erupted along the Koko Rift in Honolulu, Hawai‘i are unusual in their large range in MgO (5.4–11.4 wt%), absence of mantle xenoliths and history of magma mixing. The Koko Rift is the youngest area of rejuvenated volcanism in Hawai‘i (67 ± 2 ka) and its best developed rejuvenation-stage rift system (15-km long rift with 12 major and several minor subaerial and submarine eruptive centers). Here we report on the first systematic petrologic investigation of the Koko Rift basalts to better understand this most recent example of Hawaiian rejuvenated volcanism. New textural and mineral chemical evidence indicates magma was stored along the rift and later mixed to produce the subaerial lavas with 10–11 wt% MgO. The lower MgO (5–6 wt%) subaerial lavas were probably byproducts of the initial hybrid magma, subsequent crystal fractionation and then a second magma mixing event. The absence of mantle xenoliths in Koko Rift lavas and the relatively moderate forsterite contents (84–85%) in the higher MgO lavas may be related to the development of a crustal magma system within the rift. The record of crustal magma storage and crystal fractionation, and two magma mixing episodes in the Koko Rift lavas is unique among Hawaiian rejuvenated volcanism.

Dynamics and timescales of mafic\u2013silicic magma interactions at Soufri\xe8re Hills Volcano, Montserrat

Mafic magma intrusions into silica-rich magmatic reservoirs are commonly proposed to drive the eruptions of andesitic hybrid magmas that characterise many arc volcanoes. However, interactions between contrasting magmas involve large gradients of physical and chemical properties that change over time, and the details of such processes have proven difficult to constrain. In this paper we investigate the dynamics of magma mingling and mixing using chemical and textural zoning patterns recorded in plagioclase crystals from the February 2010 eruption at Soufrière Hills Volcano, Montserrat. This eruption is considered a classic example of interactions between the andesite magma that constitutes the bulk of the erupted volume and the basaltic andesite that occurs as enclaves. We find that plagioclase crystals are characterised by two well-defined zones that record mafic–silicic magma interaction: a crystal interior, often identified by a patchy, dusty and oscillatory zoning, and an overgrowth zone (rim) of a different composition. We use the anorthite and Mg contents to track the thermal and compositional changes experienced by the crystals over time. Our results reveal that the crystal rims formed a few hours to days prior to eruption, during co-eruptive magmatic interactions. The interaction between the two magmas with contrasting rheology is likely increased by a narrowing conduit geometry towards the surface, which facilitates convection and additional interface contact of the two magmas. Our findings shed new light on the nature and timing of magmatic interactions driving the final eruptive phase at Soufrière Hills Volcano and help to propose an interpretative framework of the monitoring signals.