Humic Organic Carbon Research Articles

How useful are MIR predictions of total, particulate, humus, and resistant organic carbon for examining changes in soil carbon stocks in response to different crop management? A case study

Measures of particulate organic carbon (POC), humus organic carbon (HOC), and resistant organic carbon (ROC) (primarily char) are often used to represent the active, slow, and inert carbon pools used in soil carbon models. However, these fractions are difficult to measure directly, and mid infrared (MIR) spectroscopic techniques are increasingly being investigated to quantify these fractions and total organic carbon (TOC). This study examined the change in MIR-predicted pools of TOC, POC, HOC, and ROC in response to different crop management between two time periods (1981 and 2008) in a long-term wheat cropping trial in Queensland, Australia. The aims were (i) to assess the ability of MIR to detect changes in carbon stocks compared with direct measurements of TOC (LECO-TOC); and (ii) to assess how well the behaviour of POC, HOC, and ROC corresponded with the active, slow, and inert conceptual carbon pools. Significant declines in carbon stocks were observed over time using both LECO-TOC and MIR-predicted stocks of TOC, POC, HOC, and ROC, although MIR-TOC under-estimated loss by 27–30% compared with LECO-TOC. The decline in MIR-POC and MIR-HOC was consistent with the expected behaviour of the active and slow conceptual pools; however, the decline in ROC was not consistent with that of the inert pool. In addition, MIR measurements did not accurately detect differences in the rate of carbon loss under different crop management practices.

Changes in total soil organic carbon stocks and carbon fractions in sugarcane systems as affected by tillage and trash management in Queensland, Australia

The use of sugarcane trash (tops and residue) retention systems has been reported to lead to increases in total soil organic carbon (TOC) stocks. However, these increases have generally been small and confined to the top 0.05 m of the soil profile. It has been hypothesised that the amount of TOC sequestered could be increased if the intensive tillage that occurs at the end of a sugarcane ratoon cycle, which is known to decrease TOC, could be eliminated. This research examined the effect of no-till management and/or trash retention on four trial sites throughout Queensland, to assess the ability of this management to increase TOC stocks. Management effects on particulate organic carbon (POC), humus organic carbon (HOC), and resistant organic carbon (ROC) stocks were also assessed using mid-infrared spectroscopy. No significant changes in TOC, POC, HOC, or ROC were observed over either 0–0.1 or 0–0.3 m depth at any of the sites examined, when sites were considered as a whole. The results indicate that these management practices currently have limited capacity to increase TOC stocks on these soil types over 0–0.1 or 0–0.3 m depth for the purposes of carbon sequestration.

Soil carbon is only higher in the surface soil under minimum tillage in Vertosols and Chromosols of New South Wales North-West Slopes and Plains, Australia

Reduced carbon stock levels in Australian soil due to cropping provide a significant opportunity for carbon sequestration, and the recent initiative to consider soil carbon in domestic emissions trading requires a scientific assessment of soil carbon levels under a range of cropping soil management practices. Some of the previous research in southern and western New South Wales (NSW) showed that the rate of carbon decline in cropping soils is slowed under minimum tillage when the stubble is also retained. However, such comparison is rare in the NSW North-West Slopes and Plains region, particularly on the red soils (Chromosols) which are one of the major soil types in the region. We surveyed 50 dryland Chromosols, 72 dryland Vertosols, and 25 irrigated Vertosols on commercial farms across this region to examine the effects of conventional tillage, minimum tillage, and irrigation on total soil organic carbon. Samples of 0.1 m segments to 0.3 m depth were analysed for total organic carbon and other soil properties. Mid-infrared scans were used to predict the particulate, humus, and resistant soil organic carbon fractions. Bulk density was used to calculate total organic carbon stock for each segment, and equivalent soil mass (ESM) for 0–0.3 m. In Vertosols, for 0–0.3 m ESM, total organic carbon and particulate organic carbon were not different between management practices, whereas humic organic carbon and resistant organic carbon were consistently lower under conventional tillage. However, in 0–0.1 m, total organic carbon was greater under minimum tillage (15.2 Mg ha–1) than conventional tillage (11.9 Mg ha–1) or irrigation (12.0 Mg ha–1), reflecting less soil surface disturbance under minimum tillage. In Chromosols, only total organic carbon was higher under minimum tillage than conventional tillage in the 0–0.3 m ESM (39.8 v. 33.5 Mg ha–1) and in 0–0.1 m (19.7 v. 16.9 Mg ha–1). The strong influences of rainfall, temperature, bulk density, texture, and management history on soil carbon stocks suggested that these environmental and management factors require further consideration when gauging soil carbon sequestration potential under current and novel tillage practices in key regional locations.

Potential Use of Olive Mill Wastewater as Amendment: Crops Yield and Soil Properties Assessment

The traditional olive oil extraction process generates a large amount of liquid by-product that could be recycled as an organic fertilizer. The aim of this 3-year field experiment was to assess the effects of olive mill wastewater (OMWW) application on yields of ryegrass, proteic pea, and clover crops and on soil properties. The following treatments were compared: OMWW at 80 m3 ha−1 (80_OMWW), OMWW at 120 m3 ha−1 (120_OMWW), and an unfertilized control (Contr). The yields of ryegrass increased 40% and 41.6% compared to Contr, for 80_OMWW and 120_OMWW, respectively, while a significant enhancement was found at the lowest level of OMWW in proteic pea (27.0% increase). Clover showed a species-specific sensitiveness, but the OMWW applications increased the protein content 26.3% and 28.7% for 80_OMWW and 120_OMWW, respectively, in comparison with Contr. The OMWW rates also enhanced the total organic content in the soil compared to the unfertilized control. At the end of the 3-year experiment, total extracted carbon and humified organic carbon were greater than the initial ones. The values of available phosphorus (P) and potassium (K) determined at the end of experiment in Contr were almost the same as those recorded at the beginning of the research, confirming that the increases found in 80_OMWW and 120_OMWW plots were due to the OMWW applications. The findings suggest that repeated applications of OMWW could both sustain fodder crop performance and support soil fertility, with the possibility to recycle the organic amendment and reduce the risks of soil degradation.

Alternative sugar beet production using shallow tillage and municipal solid waste fertiliser

The application of conventional agricultural practices, e.g. deep soil tillage and repeated, plentiful mineral fertilisation, can lead to a progressive deterioration of soil fertility, especially in Mediterranean environments characterised by scanty rains and high summer temperatures. As a consequence, to maintain high levels of both crop productivity and soil organic matter and to improve some soil properties, a reduction of agricultural inputs and a greater supply of organic material are needed. In the light of these considerations, we carried out a two-year field experiment in Southern Italy to determine the effects of reduced soil tillage and municipal solid waste compost application on growth parameters, production and quality of sugar beet crops, and on both soil chemical characteristics and mineral nitrogen deficit. Two soil tillage depths were compared: conventional tillage, till 40–45 cm and shallow tillage, at 15–20 cm. Within each soil tillage, the following N-fertilising strategies were tested: (1) mineral fertilisation, with 100 kg N ha−1; (2) organic fertilisation with municipal solid waste compost at 100 kg N ha−1; (3) mixed fertilisation, with 50% of organic N as municipal solid waste compost, and 50% of mineral N; and (4) slow-release organic-mineral N fertiliser, at 100 kg N ha−1. All these treatments were compared with a lower level of mineral fertiliser at 50 kg N ha−1, and with an unfertilised control. Our findings show first the absence of a significant difference in root and sucrose yields between reduced tillage and deep tillage; as shown by roots (36.02 t ha−1) and sucrose (3.41 t ha−1) yields for reduced tillage and 35.76 and 3.51 t ha−1, respectively, for the deepest tillage. Secondly, among the N treatments, the mixed organic-mineral N fertilisation gave productions statistically not different from mineral N fertilisation; as shown by root yields (36.38 versus 36.40 t ha−1) and sucrose yields (3.56 versus 3.65 t ha−1). Third, the mixed organic-mineral N induced a reduction of 13.2% in α-amino N content by comparison with the mineral treatment of 100 kg N ha−1. Fourth, our results showed that the applications of the municipal solid waste compost increased the extracted and the humified organic carbon by +27.7 and +25.4%, compared with the mineral fertiliser, and did not raise the content of heavy metals. These findings highlighted that in Southern Italy it is sustainable to adopt alternative sugar beet production, safeguarding crops’ quantitative and qualitative performance, decreasing the production costs and using the natural resources better.

Nitrogen Utilization, Yield, Quality and Soil Properties In a Sugarbeet Crop Amended With Municipal Solid Waste Compost

The aim of this research was to study different ways of nitrogen (N) fertilization and soil tillage management to ensure high yield, quality and correct usage of the available resources. Therefore, a two-year field experiment (2001 and 2003) was carried out on a sugarbeet crop grown in a Mediterranean environment to evaluate the effects of two soil tillage depths (10-15 and 40-45 cm) and of a municipal solid waste (MSW) compost application, compared to mineral N fertilization. The following fertilization treatments were compared: MSW compost at 100 kg N ha−1 (Ncom); mineral N fertilizer at 50 kg ha−1 (N50) and at 100 kg ha−1 (N100); MSW compost combined with mineral N fertilizer (Nmix) (50 kg ha−1 as organic N plus 50 kg ha−1 as mineral N); slow release organic-mineral fertilizer (Nslow) and an unfertilized control (Contr). In each trial year, growth parameters, plant and soil N indicators, yield, quality, N uptake and N efficiency, soil chemical characteristics and N mineral deficit in the soil were determined. The findings of this research highlighted that MSW compost was an important N source for sugarbeet, especially when MSW compost was combined with mineral N fertilizer. In fact, the Nmix treatment did not determine any significant reduction in root (32.5 vs. 36.4 t ha−1 of N100) and sucrose yields (3.56 and 3.65 ha−1). Furthermore, it presented a significantly lower amount of one of the most important qualitative parameters, the alfa amino N (1.74 and 1.97 meq 100 g−1 of N100), and ensured the least soil N deficit in 2003. The application of MSW compost significantly increased the extracted organic carbon in both 2001 (37% of increase for compost treatment in respect to unfertilized control) and 2003 (24%). Higher values were also recorded for total organic carbon in 2001 (20% of increase) and for humified organic carbon in 2001 (27%) and in 2003 (16%), whereas its application did not increase the total content of heavy metals. Finally, among plants and soil N indicators tested, the petiole nitrate content was the only one significantly and positively correlated with root and sucrose yields, indicating that it was an effective tool to monitor N supply.

Compost Organic Amendments in Fodder Crops: Effects on Yield, Nitrogen Utilization and Soil Characteristics

Agronomic value and environmental impact of two composts were evaluated in a three-year field experiment (2002, 2003 and 2004) on alfalfa and cocksfoot in Southern Italy. The effects of Municipal Solid Waste compost (MSW), Olive Pomace Compost (OPC), mineral fertilizer (Min) (phosphorus as 75 kg ha−1 for alfalfa and nitrogen as 50 kg ha−1 for cocksfoot) and an unfertilized treatment (Contr) were compared on crop yield, soil characteristics and environment impact. During the cropping cycles, fresh and dry weights, plant nitrogen status (leaves SPAD readings and petiole nitrate content) and plant total N content were determined for calculating the protein content and the plant N uptake. Moreover, at the beginning and the end of the research, chemical soil characteristics and heavy metal levels were also determined. The results indicated that in cocksfoot fertilized with MSW and OPC composts, the mean cumulative dry weight increased by 20.85 and 16.51%, respectively compared to the control, but it was significantly lower than Min treatment. In the alfalfa crop, the mean cumulative dry weight of Control, MSW and OPC treatments were very similar and lower than mineral fertilizer (−7.86, −7.09 and −10.31%, respectively). At the end of the experiment, (2004) the soil total N increased significantly in alfalfa (from 1.32 to 1.45 g kg−1) while no significant difference was found for the cocksfoot. After three years of compost application, the total soil organic carbon increased significantly in both crops (23.98% for cocksfoot, and 43.17% for alfalfa in respect to the control), indicating that MSW and OPC amendments positively affected the organic matter. Furthermore, total organic carbon (in both crops) and humified organic carbon (in alfalfa) were significantly lower in the Contr treatment than on the MSW and OPC treatments.

Exploratory Analysis of the Effects of Particulate Characteristics on the Variation in Partitioning of Nonpolar Organic Contaminants to Marine Sediments

The partitioning of nonpolar organic contaminants to marine sediments is considered to be controlled by the amount of organic carbon present. However, several studies propose that other characteristics of sediments may affect the partitioning of contaminants. For this exploratory analysis, we measured 19 sediment characteristics from five marine sediments and 11 characteristics of humic acids extracted from the sediments. These characteristics included elemental composition, grain size, soot carbon, polarity indices and molar ratios. Each individual characteristic and combinations of these characteristics were then used to normalize partition coefficients ( K p) generated for three organic contaminants: lindane, fluoranthene and a tetrachlorinated biphenyl (PCB). A coefficient of variation (CV) was then calculated for each contaminant to determine which normalization characteristic (individually or in combination) resulted in the lowest variability in partitioning between study sediments. For lindane and the PCB, normalization by the amount of sediment organic carbon resulted in the lowest variability in partition coefficients with CVs of 16.2% and 37.7%, respectively. However, normalization of fluoranthene by silt content resulted in lower CVs than those generated by organic carbon normalization: 31.0% vs. 37.6%. Normalization of contaminants K p's by combined values of sediment characteristics resulted in lower CVs but only by a few percent. Using humic acid characteristics, humic organic carbon reduced variability between sediments most effectively. But only the normalized fluoranthene values had a CV (i.e., 25.4%) lower than the one based on normalization by sediment characteristics. When combined, humic acid characteristics resulted in lower CVs than normalization by individual or combinations of sediment characteristics for fluoranthene and the PCB with CVs of 19.3% and 28.7%, respectively. This analysis indicates variability associated with the partitioning of some organic contaminants to marine sediments can be further reduced when normalization by sediment characteristics other than organic carbon are utilized.

Changes in some soil properties in a Vertic Argiudoll under short-term conservation tillage

The purpose of this work was to determine whether some soil physical and chemical properties, and microbial activity were affected by two conservation tillage systems in a Chernozemic clay loam soil (Vertic Argiudoll), after 5 years of trial initiation. Two crop sequences, corn ( Zea mays L.)–wheat ( Triticum aestivum L.)/soybean ( Glycine max (L.) Merr.) and wheat/soybean, under chisel plowing (ChP) and no till (NT) were evaluated. Physical and chemical properties were also analyzed taking the same soil without disturbance as reference. The Hénin instability index (HI) was larger in ChP than in NT in both corn–wheat/soybean (C–W/S) and wheat/soybean (W/S) sequences ( P≤0.05). The C–W/S sequence differed from W/S ( P≤0.01) in total organic carbon (TOC). As regards organic carbon fractions, no differences were found in labile organic carbon (LOC), while W/S under ChP showed the lowest value ( P≤0.01) of humified organic carbon (HOC). No differences were found in microbial respiration either in crop sequences or in tillage systems. Soil physical and chemical properties differentiated crop sequences and tillage treatments from the undisturbed soil when a Student’s t-test was performed. Five years elapsed since the beginning of this trial was time enough to detect changes in some of the soil properties as a consequence of management practices. An important reduction in the soil structural stability was observed as related to the undisturbed soil. However, the C–W/S sequence under NT resulted in lower soil degradation with respect to the other treatments.

Parámetros físicos del suelo en condiciones no perturbadas y bajo laboreo

Se estudió el efecto de dos sistemas de labranza sobre algunas propiedades del suelo y el rendimiento de soja. La experiencia se realizó sobre un Argiudol típico durante 1996. Los tratamientos fueron: siembra directa (SD), labranza vertical (LV) y un control no laboreado (T). Sedeterminó: densidad del suelo (DS); densidad máxima (DSMAX); compactación relativa (CR); porosidad estructural (PE); carbono orgánico total (COT), humificado (COH) y libre (COL) y humedad gravimétrica (HG). Se realizó el perfil cultural en LV y SD. La DS en SD fue significativamente mayor (P<=0,01) en superficie y en profundidad (1,22 y 1,37 Mg m-3, respectivamente). La PE en superficie fue LV>T>SD, mientras que en profundidad fue T>LV>SD. Hubo relación inversa entre CR y PE (r²=0,87). El perfil cultural mostró un 40% de agregados sin porosidad interna enSD. En superficie T presentó mayor COT, COH y COL. La DSMAX se correlacionó negativamente con el COT (r²=0,88). Al inicio del cultivo, SD presentó mayor HG (P<=0,01) que LV; en floración LV presentó mayor HG (P<=0,01). Si bien SD presentó mayor COT, COH y COL que LV, la mayor compactación observada en SD pudo incidir negativamente en el rendimiento del cultivo (fue el 50% de LV).

Soil Cleanup by In-Situ Aeration. XXII. Impact of Natural Soil Organic Matter on Cleanup Rates

Abstract A mathematical model for soil vapor extraction of volatile organic compounds from soils rich in natural humic organic carbon by means of a single vertical well screened along its length and operating underneath an impermeable cap is described. The model includes a distributed diffusion treatment of diffusion kinetics. Partitioning of volatile organic compounds between the aqueous phase and the natural organic carbon is handled by a linear isotherm or by a Freundlich isotherm. Freundlich isotherm exponents n f chosen on the basis of published data lead to substantially more prolonged remediations than result from use of a similar linear isotherm.

The contribution of humic substances to the acidity of colored natural waters

An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated.