This paper proposes a model predictive current control (MPCC) method of six-phase permanent magnet synchronous hub motor (PMSHM) using auxiliary voltage vectors. First of all, 26 voltage vectors can be obtained from the switching states of six inverters, and 24 auxiliary voltage vectors can be generated by combining them. Second, four virtual voltage vectors can be found through the required locations, and the two vectors with the lowest cost will be selected by cost function. Then, additional current error correction module can better track the current. Finally, the proposed method is compared with the conventional MPCC method and another method with virtual voltage vectors. The innovation of this paper is that the recombination of vectors can better track and predict the current. A current error compensation module is added to reduce the error between the actual current and the predicted current. And the experimental results show that the proposed method has better performance such as smaller torque ripple and current THD both in steady and dynamic states. Finally, the strategy proposed in this paper was applied to the vehicle model through HIL test platform. The possibility of applying the strategy proposed in this paper to pure electric vehicles was verified under New European Driving Cycle (NEDC).