Heat transport in catalytic reactors is one of the most important factors in reactor design, especially for highly endo- or exothermic reactions. The limited thermal conductivity of randomly packed beds can be significantly improved when alternative catalyst supports are used. A new generation thereof are periodic open cellular structures (POCS), which are used in this study as catalyst support for the partial oxidation of methanol to formaldehyde, an exothermic gas phase reaction. A comparison to traditional packed bed reactors revealed that a POCS made of the highly conductive alloy AlSi10Mg can significantly reduce the hot-spot temperature, allowing almost isothermal operation at optimal reaction conditions. The improved temperature control allows for operation with higher methanol inlet concentrations and wall temperatures as compared to the commercial process. The beneficial heat transport properties of POCS were used to conduct isothermal kinetic measurements at elevated temperature. Based on these findings and the design freedom of additive manufacturing, an optimized cellular structure was designed and fabricated, which improved the heat transport especially in the critical inlet section of the reactor.
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