Hot Foam Research Articles

Laser Weeding Technology in Cropping Systems: A Comprehensive Review

Weed infestations pose significant challenges to global crop production, demanding effective and sustainable weed control methods. Traditional approaches, such as chemical herbicides, mechanical tillage, and plastic mulches, are not only associated with environmental concerns but also face challenges like herbicide resistance, soil health, erosion, moisture content, and organic matter depletion. Thermal methods like flaming, streaming, and hot foam distribution are emerging weed control technologies along with directed energy systems of electrical and laser weeding. This paper conducts a comprehensive review of laser weeding technology, comparing it with conventional methods and highlighting its potential environmental benefits. Laser weeding, known for its precision and targeted energy delivery, emerges as a promising alternative to conventional control methods. This review explores various laser weeding platforms, discussing their features, applications, and limitations, with a focus on critical areas for improvement, including dwell time reduction, automated navigation, energy efficiency, affordability, and safety standards. Comparative analyses underscore the advantages of laser weeding, such as reduced environmental impact, minimized soil disturbance, and the potential for sustainable agriculture. This paper concludes by outlining key areas for future research and development to enhance the effectiveness, accessibility, and affordability of laser weeding technology. In summary, laser weeding presents a transformative solution for weed control, aligning with the principles of sustainable and environmentally conscious agriculture, and addressing the limitations of traditional methods.

Heat Treatment of Seeds to Control Invasive Common Ragweed (Ambrosia artemisiifolia), Narrow-Leaved Ragwort (Senecio inaequidens) and Giant Hogweed (Heracleum mantegazzianum)

The intended or unintentional transport of soil material contaminated with weed seeds is one of the most important drivers in the spreading dynamics of invasive alien plants (IAPs). This phenomenon can be observed at any kind of construction site. Typical transfer of soil contaminated with IAP seeds can be observed along with road construction (soil translocation) or road maintenance services (deposit of mown plant biomass). Thus, an effective inactivation of these seeds by heating can avoid the spread of IAPs substantially. In the present study, the effects of various thermal control techniques (dry air heating and wet heating with hot steam, hot water, and hot foam) on seed survival of the widespread European IAPs common ragweed (Ambrosia artemisiifolia), narrow-leaved ragwort (Senecio inaequidens), and giant hogweed (Heracleum mantegazzianum) are discussed. Dry and wet seeds which were either uncovered or covered with soil were tested for survival at different treatment temperatures and different exposure times. Results revealed that particularly dry seeds of all three species could withstand temperatures of 100 °C for at least 6 h in climate chambers. Dry seeds of common ragweed and narrow-leaved ragwort survived exposure times of up to 48 h. Wet seeds were significantly more susceptible to heat treatments. Giant hogweed seeds were completely killed after 12 h at 70 °C. The exposure of IAP seeds to hot water was generally more effective than the treatment with hot steam. The treatment with hot foam was only effective when seeds were lying unprotected on the soil surface. Dry seeds of all the three species survived hot foam application in the field when they were covered by vegetation and leaf litter or soil. Due to the robustness of the seeds, a preventive management of IAPs by an efficient control before seeds formation is substantial to avoid their further dispersal.

The Current Status of Weed Resistance to Herbicides and The Discovery of New Herbicides With Novel Modes of Action Necessary to Combat Them

In 2016 and after retiring from a fulltime career in Herbicide Research and Development, I wrote an article for Outlooks addressing the question ‘Can we expect new herbicides with novel modes of action in the foreseeable future?’ and I would like to use this editorial to investigate if we are any closer to answering this question which is important because of the increasing problems of weeds evolving resistance to existing herbicides. Weed management is still essential to maximise crop yields in agriculture. Yield losses of up to 40% across the major global food crops can occur without effective weed control, due to competition between the weeds and crops for nutrients and light, as well as interfering with crop harvest and quality. Herbicides are essential tools in integrated weed management (IWM) but their effectiveness is being eroded due to widespread weed resistance, in part due to overuse of the limited number of herbicide products currently available to the grower. Cultural methods for control of weeds such as, changing rotations, use of cover crops; deep ploughing; manual removal of weeds and chemical mulching are clearly part of the IWM toolbox. However, deep ploughing (and any type of physical disturbance of soil) and chemical mulching, whilst potentially effective, are not applicable throughout global crop production and also are not sustainable environmentally friendly options. Similarly, other non-chemical methods, such as electro-physical and heat treatments including high energy light, boiling water, steam, fire, flame weeding and hot foam have been sold as having potential to replace herbicides, but I question their suitability in main stream row-crop agriculture and also the environmental impact of their use, particularly if they would be regulated as herbicides and needed the extensive catalogue of ecotoxicology studies to investigate adverse effects on non-target organisms and environmental fate studies. Biological approaches are receiving increasing interest in pest management for control of diseases and insects, but these appear not to be an option for weed control.

Hot foam: Evaluation of a new, non-chemical weed control option in perennial crops

Hot foam applications represent a new, smart concept in the field of thermal weed control. The aim of this study was to evaluate the efficacy of hot foam and other weed control methods in two olive groves in southern Greece (Pyrgos and Kalamata). The experiment was laid out in a randomized complete block design (RCBD) with six treatments and three replicates. Treatments were applied in the areas between trees, in the row and included mowing with a disc–flail mower, mulching with pruning residues (2.65 kg m–2), glyphosate (at 1,440 g a.e. ha–1), hot foam (13.33 L m–2), pelargonic acid (at 1,088 g a.i. ha–1; twice), and an untreated control. Two experimental runs were conducted at each site using the same treatment list. Malva parviflora L. and Sinapis arvensis L. were the predominant weeds in Pyrgos, while Urtica urens L., Galium aparine L., and Parietaria officinalis L. dominated in Kalamata. Site–experimental runs and treatments significantly affected NDVI and weed biomass (P–Value ≤ 0.001). Hot foam reduced weed biomass by up to 81, 88, 90, and 96% compared to mulching, mowing, pelargonic acid, and the untreated control, respectively. This treatment also reduced M. parviflora biomass by 75–88 and 92–93% compared to mowing and pelargonic acid, respectively, in Pyrgos and P. officinalis biomass by more than 80% in Kalamata compared to the above treatments. In all site–experimental runs, hot foam and glyphosate resulted in the lowest NDVI and weed biomass. The overall performance of hot foam was comparable to glyphosate, suggesting that this method is an environmentally friendly and effective, alternative method to control weeds in olive groves. Further research is required to optimize the use of hot foam for weed control in more perennial crops and under different soil and climatic conditions.

Hot Foam and Nitrogen Application to Promote Spring Transition of “Diamond” Zoysiagrass (Zoysia matrella (L.) Merr.) Overseeded with Perennial Ryegrass (Lolium perenne L.)

In transition areas, cool season turfgrasses are overseeded in autumn to maintain the high quality of dormant warm season turfgrasses, while in spring several agronomic methods (scalping, coring, topdressing, verticutting, irrigation, and targeted fertilization) or chemical desiccation are adopted to remove the cool season turfgrasses from the stand. To reduce chemical applications, several methods of “thermal weeding” have been experimented with, but little is known about these methods in zoysiagrass (Zoysia spp. Willd) spring transition. A study was conducted at the University of Pisa, Italy, on Manila grass (Zoysia matrella (L.) Merr., cv “Diamond”) (Zm) overseeded with perennial ryegrass (Lolium perenne L.) (Lp) with the aim of comparing different methods of cool season grass suppression (scalping and hot foam) and different application rates of nitrogen. To assess treatment effect, green cover, turf quality, turf color, shoot density, and some vegetation indices (GLI, DGCI and NDVI) were determined. An average green cover of at least 90% was obtained on all plots seven weeks after the treatments. While scalping had minor effects on turf appearance and on polystand composition, hot foam had a stronger effect on turf color, green cover, and turf quality in the weeks following application. Once it had recovered from the hot foam treatments, the turf had a greater number of Zm shoots and a relevant reduction of Lp shoots. The hot foam was very effective in suppressing Lp while maintaining Zm recovery capacity.

Hot foam and hot water for weed control: A comparison

Thermal weed control plays an important role in managing weeds in synthetic herbicide-free systems, particularly in organic agriculture and in urban areas where synthetic herbicides are prohibited. This study compares the impact on weed control of increased doses of hot water and hot foam (i.e. 0, 0.67, 1.67, 3.33, 5.00, 6.67 and 8.33 kg m–2). The doses were applied using the same machine. The temperatures, weed control effectiveness, weed regrowth after the death of the aboveground vegetative weed tissues, and weed dry biomass 30 days after the treatments were studied in two experimental fields with a different weed composition (i.e. Site I and Site II). The results showed that difficult weeds to control, such as Cynodon dactylon (L.) Pers., Digitaria sanguinalis (L.) Scop. and Taraxacum officinale Weber, like all the other species in the initial weed populations in the two experiments, died after lower doses of hot foam compared to hot water. Adding foam to hot water made it possible to lower the required dose of water by at least 2.5-fold compared to hot water used alone. By insulating the weeds, the foam led to higher peak temperatures and slower temperature decay, thus determining an effective weed control with lower doses compared to hot water. Starting from 11 days and 16 days after treatments (for Site I and Site II, respectively), there were no statistically significant differences in weed regrowth between hot foam and hot water at all the doses applied. There were no differences between the dry biomass of weeds collected 30 days after treatments when the same doses of hot foam and hot water were used.

Flaming, Glyphosate, Hot Foam and Nonanoic Acid for Weed Control: A Comparison

Synthetic herbicides are commonly used in weed management, however, 70 years of use has led to weed resistance and environmental concerns. These problems have led scientists to consider alternative methods of weed management in order to reduce the inputs and impacts of synthetic herbicides. The aim of this experiment was to test the level of weed control using four weeding methods: glyphosate applied at an ultra-low volume, the organic herbicide nonanoic acid, flaming, and hot foam. The results showed that weed control was effective only when flaming and hot foam were applied (99% and 100% weed control, respectively). Nonanoic acid at a dose of 11 kg a.i. ha−1 diluted in 400 L of water did not control developed plants of Cyperus esculentus (L.), Convolvulus arvensis (L.) and Poa annua (L.). Glyphosate at a dose of 1080 g a.i. ha−1 (pure product) only controlled P. annua (L.), but had no effect on C. esculentus (L.) and C. arvensis (L.). After the aboveground tissues of weeds had died, regrowth began earlier after flaming compared to hot foam. There was no regrowth of P. annua (L.) only after using hot foam and glyphosate. Hot foam was generally better at damaging the meristems of the weeds. In one of the two experiment sites, significantly more time was needed after the hot foam to recover 10% and 50% of the ground compared to flaming. The time needed to recover 90% of the ground was on average 26–27 days for flaming and hot foam, which is the time that is assumed to be required before repeating the application. A total of 29 days after the treatments, weeds were smaller after flaming, glyphosate and hot foam compared to nonanoic acid and the control, where they had more time to grow.

Operative and environmental performance of a hot-foam machine for the herbicide-free weeding of the vineyard

The elimination of chemical herbicides use is a key factor in vineyards, particularly in the case of biological cultivation. The machines employed for mechanical weeding under the vine row are often characterised by low travelling speeds and therefore also by a low working capacity. A new solution is the application of hot foam, to transmit heat to weeds. A hot-foam machine for the herbicide-free weeding of vineyards was then developed, to produce and deposit foam directly onto weeds. The foam strips produced were approximately 40 cm width and 20-25 cm height, with a temperature exceeding 75°C. The future success of this environmentally sustainable technique will be the identification of a 100% naturally biodegradable and long-lasting foam, to maximize heat transmission to weeds.

The Use of Different Hot Foam Doses for Weed Control

Thermal weed control technology plays an important role in managing weeds in synthetic herbicide-free systems, particularly in organic agriculture. The use of hot foam represents an evolution of the hot water weed control thermal method, modified by the addition of biodegradable foaming agents. The aim of this study was to test the weeding effect of different five hot foam doses, in two sites of different weed composition fields [i.e., Festuca arundinacea (Schreb.), Taraxacum officinale (Weber) and Plantago lanceolata (L.)], by evaluating the devitalisation of weeds, their regrowth, the weed dry biomass at the end of the experiment and the temperature of hot foam as affected by different foam doses. The results showed that the effect of the hot foam doses differed with the different infested weed species experiments. In the Festuca arundinacea (Schreb.) infested field, all doses from 3.33 L m−2 to 8.33 L m−2 led to a 100% weed cover devitalisation and a lower weed dry biomass compared to the dose of 1.67 L m−2, whereas the weed regrowth was similar when all doses were applied. In the Taraxacum officinale (Weber) and Plantago lanceolata (L.) infested fields, doses from 5.00 L m−2 to 8.33 L m−2 in site I and from 3.33 L m−2 to 8.33 L m−2 in site II led to 100% of weed cover devitalisation. The highest doses of 6.67 L m−2 and 8.33 L m−2 led to a slower weed regrowth and a lower weed dry biomass compared to the other doses. The time needed for weeds to again cover 50%, after the 100% devitalisation, was, on average, one month when all doses were applied in the Festuca arundinacea (Schreb.) infested field, whereas in the Taraxacum officinale (Weber) and Plantago lanceolata (L.) fields, this delay was estimated only when doses of 6.67 L m−2 and 8.33 L m−2 were used in site I and a dose of 8.33 L m−2 in site II. Thus, in the Festuca arundinacea (Schreb.) field experiments hot foam doses from 3.33 L m−2 to 8.33 L m−2 were effective in controlling weeds, and the use of the lowest dose (i.e., 3.33 L m−2) is recommended. However, for Taraxacum officinale (Weber) and Plantago lanceolata (L.) the highest doses are recommended (i.e., 6.67 L m−2 and 8.33 L m−2), as these led to 100% weed devitalisation, slower regrowth, and lower weed dry biomass than other doses. A delay in the regrowth of weeds by 30 days can lead to the hypothesis that the future application of hot foam as a desiccant in no-till field bands, before the transplant of high-income vegetable crops, will provide a competitive advantage against weeds.

Pore-Scale Experiment on Blocking Characteristics and EOR Mechanisms of Nitrogen Foam for Heavy Oil: A 2D Visualized Study

How to enhance heavy oil recovery to meet the oil consumption is a popular issue around the world, and it has attracted widespread attention. A two-dimensional visualized model was adopted to study the pore-scale mechanisms and development effects of foam for enhancing oil recovery in steam injection processes for heavy oil. Experimental images visually presented that small bubbles gather together to form bigger foams, thus blocking the small pores and throats and leading to fluid diversion in porous media. As a result, the sweep efficiency was improved from 46.18% to 77.93% after foam injection. Foams could effectively improve the mobility ratio between oil and water and decreased water cut after foam injection, which was significant for decaying the decline of oil production. As for the pore-scale level, after foams were injected into the visualized model, the residual oil caused by steam flooding entered into the main streamline under the disturbance of foams and was carried out by the following displacement fluid. The heavy oil was emulsified into O/W emulsions that had lower viscosity under the action of foams; hence, more trapped oil was mobilized and displaced. As a result, the micro oil displacement efficiency increased from 72.76% to 84.01%. In order to provide a reference for the choice of foam injection, experiments that investigated development effects of cold foam and hot foam were also conducted. Compared with the incremental of oil recovery caused by cold foam, that induced by hot foam was 41.51% higher, demonstrating that the coinjection of steam and foam was more advantageous to heavy oil production.

Hot foam for weed control—Do alkyl polyglucoside surfactants used as foaming agents affect the mobility of organic contaminants in soil?

Use of alkyl polyglucosides (APGs) as a foaming agent during hot water weed control may influence the environmental fate of organic contaminants in soil. We studied the effects of the APG-based foaming agent NCC Spuma (C8-C10) on leaching of diuron, glyphosate, and polycyclic aromatic hydrocarbons (PAHs) in sand columns. We also examined how APG concentration affected the apparent water solubility and adsorption of the herbicides and of the PAHs acenaphthene, acenaphthylene and fluorene. Application of APGs at the recommended concentration of 0.3% did not significantly affect leaching of any of the compounds studied. However, at a concentration of 1.5%, leaching of both diuron and glyphosate was significantly increased. The increased leaching corresponded to an increase in apparent water solubility of diuron and a decrease in glyphosate adsorption to the sand. However, APG addition did not significantly affect the mobility of PAHs even though their apparent water solubility was increased. These results suggest that application of APG-based foam during hot water weed control does not significantly affect the mobility of organic contaminants in soil if used according to recommendations. Moreover, they suggest that APGs could be useful for soil bioremediation purposes if higher concentrations are used.

Vegetation removal and seed addition contribute to coastal sandplain grassland establishment on former agricultural fields

Creating native‐species‐rich grasslands to replace agricultural grasslands can be an important strategy for supplementing the area of grasslands, which are in decline in many regions. In the northeastern United States, sandplain grasslands support a diverse plant community and rare plant and animal species that are declining because of reductions in historical disturbances such as fire and grazing. We designed an experiment on Martha's Vineyard, Massachusetts, to test methods of establishing native‐species‐rich coastal sandplain grassland on former agricultural land. We tested the efficacy of: (1) tilling, herbicide, hot foam, and plastic cover in removing initial nonnative vegetation, and (2) combinations of tilling and seeding for establishing native species. We measured native and nonnative species richness and percent cover before and for 5 years after treatment. Herbicide, plastic cover, and spring, summer, and fall tilling were about equally effective in reducing nonnative species cover and promoting native species cover. Tilling and seeding each increased native species richness and percent cover, and seeding and tilling together increased native species richness and cover more than either treatment alone. Combined seeding and disturbance also reduced the cover of nonnative species, but nonnative species cover remained higher than in adjacent reference sandplain grassland. Results indicated that native species establishment was enhanced by the availability of seeds and by reduction of initial nonnative plant cover. The most efficient method of converting coastal agricultural grasslands to sandplain grassland with a higher number and proportion of native species is a single season of plant removal and seeding.

Characteristics Analysis of Cold Foam and Hot Foam During Steam Flooding in Heavy Oil Reservoirs

Hot foam with steam following in the process of foam injection and cold foam without steam following are investigated. Through static and dynamic evaluation experiments, foaming agents are screened and the effects of factors on foam blocking capacity are studied. Then the blockage and displacement experiments of cold and hot foam are conducted. The results show that cold foam has larger blocking strength and is preferred to start up low permeability contrast layers. Hot foam is recommended to use in higher ones and due to the temperature sensitivity of heavy oil, the oil production of hot foam is larger than that of cold foam, whatever continuation or slug injection.

Self-defending anti-vandalism surfaces based on mechanically triggered mixing of reactants in polymer foils

Inspired by the Bombardier beetle a self-defending foil was developed, which strikes back upon a mechanical stimulus by emitting corrosive, hot foam.

Global Tangent Visibility Analysis for Polyhedral Computer Aided Design Models

Visibility analysis is broadly used in milling and casting process planning and in coordinate measuring machine applications. However, standard visibility analysis (which involves determining visibility from a given viewpoint), cannot be applied directly to in-line cutting systems such as wire electrical discharge machines or hot wire foam cutters. The motivation of this paper is to accurately calculate the tangent visibility for objects represented by polygonal surfaces. In this paper we define a new type of visibility - tangent visibility. We develop an algorithm to calculate the global tangent visibility for in-line cutting systems, and several models are tested to verify its accuracy. Several polyhedral models are tested to verify the correctness of the tangent visibility algorithm; and the complexity of the algorithm is also discussed.

Characteristics of supersonic jets in LD steelmaking

In the Linz–Donawitz (LD) steelmaking process supersonic oxygen jets expand into the surroundings formed by hot and dense slag foam thus it is necessary to understand the innate characteristics of supersonic jets when expanding into such surroundings. In this study, the individual influences of both the elevated temperature and high density of the surrounding medium on the jet characteristics are presented. It was found that the supersonic jet characteristics were not affected significantly by the expansion into hot environments with no correlation between the Mach number profiles and changes in surrounding temperature. However, the influence of the dense surroundings on the jet characteristics was profound. The jet velocity was reduced when expanding into a dense medium in comparison with that expanding into a gaseous medium. The peak value of momentum at any cross-section of the jet was not at the axis but in the gas/dense medium interface. The confluence of these factors, i.e. severe reduction in jet velocity and the location of peak momentum within the jet, are expected to change the present understanding of flow dynamics within LD vessels and its influence on refining reactions. Further studies in this area are recommended for better understanding of these phenomena.

Durability of Flexible Molded Polyurethane Foams

In recent years, we have developed highly resilient (HR) flexible molded foams with superb durability, resilience and vibration characteristics, and we have reported that these improvements were based on control of cross link degree of polymer, morphology and mobility of hard and soft segments. This paper describes factors that dominantly influence the durability and the mechanism of fatigue by investigation of cross linking by covalent and hydrogen-bonds and the morphology of hard/soft segments. In this study, we use molded foams with different durabilities. These are TDI-based high performance/conventional HR, MDI-based high-performance/conventional HR, and hot molded foams. On the whole, a small apparent viscosity coefficient, which is calculated from vibration characteristics of the foam, and a higher cross link degree of foam polymer make static and dynamic durability of flexible molded foam better. Mobility of the soft segment, estimated by solid state NMR, also dominates dynamic durability. Accordingly, hydrogen-bonds of the hard segment contribute against creep as a cross link point in static/dynamic durability test, and tight hydrogen-bonds of hot molded foam are durable against rupture or rebonding by water molecules in the wet compression set oven. The drop in cross link degree of foam polymer was not observed during vibration durability test. Accordingly, the mechanism of fatigue could be the change of state in hydrogen-bonds or tangling of polymer-chains, or relatively macro rupture.

Dynamic Consolidation of Combustion‐Synthesized Alumina‐Titanium Diboride Composite Ceramics

A mixture of TiO2, B2O3, and Al powders was reacted exo‐thermically to form a low‐density Al2O3–TiB2 foamed product. After the cessation of the combustion synthesis reaction, this hot foam was densified by the pressure waves generated by the detonation of an explosive charge. The delay time between the initiation of the combustion synthesis and detonation of the explosive, the thickness of the explosive charge, and the strength of sample confinement were found to influence the effectiveness of the consolidation. Analysis of the combustion synthesis reaction temperature histories and microscopy of the reacted product sponge are used to develop additional information about this reaction/consolidation process. These results, and the microstructural properties of the combustion‐synthesized and dynamically consolidated products, are discussed.