The scalar potential of a multi-Higgs model can possess a rich structure of minima and saddle points, which evolves in an intricate way as the parameters change. In the hot early Universe, it could trigger multistep phase transitions, with exotic intermediate phases and peculiar domain wall configurations. Here, we provide a glimpse into this richness with the example of the three-Higgs-doublet model with the symmetry group Σ(36), either exact or softly broken. We present its phase diagram tracking not only the global minimum but all of its extrema. In particular, we reveal parameter space regions in which the deepest saddle point is charge breaking. This naturally leads to phase transitions between neutral vacua which involve expanding and colliding charge-breaking bubble walls. We also comment on opportunities of multistep phase transitions, on charge-breaking intermediate phases, and on phase transitions between different charge-breaking vacua. We illustrate the general discussion with two benchmark models, one of which possesses competing saddle points and allows for emergence of bubbles of the same true vacuum but with bubble walls of different nature. The intriguing cosmological implications of all these possibilities deserve dedicated study. Published by the American Physical Society 2024
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