Leaf area index (LAI) is a key input for many land surface models, ecological models, and yield prediction models. In order to make the model simulation and/or prediction more reliable and applicable, it is crucial to know the characteristics and uncertainties of remotely sensed LAI products before they are input into models. In this study, we conducted a comparison of four global remotely sensed LAI products—Global Land Surface Satellite (GLASS), Global LAI Product of Beijing Normal University (GLOBALBNU), Global LAI Map of Chinese Academy of Sciences (GLOBMAP), and Moderate-resolution Imaging Spectrometer (MODIS) LAI, while the former three products are newly developed by three Chinese research groups on the basis of the MODIS land reflectance product over China between 2001 and 2011. Direct validation by comparing the four products to ground LAI observations both globally and over China demonstrates that GLASS LAI shows the best performance, with R2 = 0.70 and RMSE = 0.96 globally and R2 = 0.94 and RMSE = 0.61 over China; MODIS performs worst (R2 = 0.55, RMSE = 1.23 globally and R2 = 0.03, RMSE = 2.12 over China), and GLOBALBNU and GLOBMAP performs moderately. Comparison of the four products shows that they are generally consistent with each other, giving the smallest spatial correlation coefficient of 0.7 and the relative standard deviation around the order of 0.3. Compared with MODIS LAI, GLOBALBNU LAI is the most similar, followed by GLASS LAI and GLOBMAP. Large differences mainly occur in southern regions of China. LAI difference analysis indicates that evergreen needleleaf forest (ENF), woody savannas (SAV) biome types and temperate dry hot summer, temperate warm summer dry winter and temperate hot summer no dry season climate types correspond to high standard deviation, while ENF and grassland (GRA) biome types and temperate warm summer dry winter and cold dry winter warm summer climate types are responsible for the large relative standard deviation of the four products. Our results indicate that although the three newly developed products have improved the accuracy of LAI estimates, much work remains to improve the LAI products especially in ENF, SAV, and GRA regions and temperate climate zones. Findings from our study can provide guidance to communities regarding the performance of different LAI products over mainland China.