Mantle Plume Research Articles

Petrological models of magma evolution on the formation of mafic-felsic igneous complexes of the Emeishan large igneous province, SW China

Many Late Permian world-class Fe-Ti oxide-bearing layered intrusions in the Pan-Xi region, SW China are commonly considered to be fractionation products of the Emeishan mantle plume-related high-Ti basaltic melts. These layered intrusions coexist spatially and temporally with A-type granitoids, which consist of syenites and granites and are further classified into isotopically depleted metaluminous to peralkaline and isotopically enriched peraluminous to metaluminous groups. The petrogenesis of these mafic-felsic igneous complexes has been controversial. This study investigates geochemical correlations of the microgabbros at the margin of the Baima layered intrusions and the intruding isotopically enriched granitoids. The amphiboles at both sides of the contact zone are calcic (CaO = 10.4 to 12.5 wt.%) and display obvious mixing trends. Thermodynamical modeling using the MAGEMin program indicates that fractionation of basaltic melts compositionally similar to the Baima microgabbros seems incapable to crystallize olivine compositions comparable to those of the layered intrusions, but can be reconciled by early separation of 7.5 to 10 wt.% Fe-Ti-rich melts. Continued differentiation of the basaltic melts may lead to formation of the isotopically depleted granitoids, among which perthite accumulation in water-rich environments could result in the formation of metaluminous granitoids with high Na, K and Al contents and positive Eu anomalies. The isotopically enriched granitoids, on the other hand, can be produced by anatexis of the juvenile mafic lower crust together with the Yangtze ancient lower crust. Our study therefore provides a panoramic view on the complicated petrogenesis of the igneous complexes related to Emeishan mantle plume impingement through thermodynamic modeling.

The Corrugated Hills Continental Flood Basalt: a c. 2.17 Ga flood basalt province related to breakup of the Superior craton

Abstract This study documents a major continental flood basalt province in the central Labrador Trough that produced voluminous mafic magmatism along the palaeo-rifted margin of the Superior craton. This area, representing a preserved magma volume of approximately 25 000 km 3 , is characterized by classic ‘traps’ topography with columnar-jointed flows and sills separated by thin clastic sedimentary layers. A gabbroic sill near the bottom of the sequence yielded a U–Pb zircon age of 2166 ± 4 Ma, and another near the middle of the sequence yielded a 2171 ± 3 Ma U–Pb zircon age. These ages overlap in time with published ages of mafic dyke swarms that radiate outwards into the adjacent Superior craton, namely the Biscotasing (2172–2167 Ma) and Payne River (2170–2160 Ma) dykes, as well as the Otish sills (2172–2162 Ma) and Tasiataq (2170 Ma) dyke. Our data suggest that these central Labrador magmas, named the Corrugated Hills Continental Flood Basalt, were emplaced near or above a mantle plume head, leading to thermal uplift and then rifting of the Superior craton margin. Field relationships suggest that these magmas were erupted through thinned Archean crust as a rift-related continental flood basalt suite. The Corrugated Hills Continental Flood Basalt province represents remnants of one of the oldest continental flood basalt provinces on Earth.

Micropore Structure of Deep Shales from the Wufeng–Longmaxi Formations, Southern Sichuan Basin, China: Insight into the Vertical Heterogeneity and Controlling Factors

The microscopic pore throat structure of shale reservoir rocks directly affects the reservoir seepage capacity. The occurrence and flow channels of shale gas are mainly micron–nanometer pore throats. Therefore, to clarify the microstructural characteristics and influencing factors of the deep organic-rich shales, a study is conducted on the marine shale from the Upper Silurian to Lower Ordovician Wufeng–Longmaxi Formation in the southern Sichuan Basin. Petrographic lithofacies division is carried out in combination with petro-mineralogical characteristics, and a high-resolution scanning electron microscope, low-temperature nitrogen and low-temperature carbon dioxide adsorption, and micron-computed tomography are used to characterize the mineral composition and pore structure qualitatively and quantitatively, upon which the influencing factors of the microstructure are further analyzed. The results show that with the increase in burial depth, the total organic carbon content and siliceous mineral content decrease in the Wufeng formation to Long-11 subsection deep shale, while clay mineral content increases, which corresponds to the change in sedimentary environment from anoxic to oxidizing environment. Unexpectedly, the total pore volume of deep shale does not decrease with the increase in burial depth but increases first and then decreases. Using total organic carbon (TOC), siliceous mineral content showed a good correlation with total pore volume and specific surface area, with correlation coefficients greater than 0.7, confirming the predominant role of these two factors in controlling the pore structure of deep shales. This is mainly because the Longmaxi shale is already in the late diagenetic stage, and organic matter pores are generated in large quantities. Clay minerals have a negative correlation with the total pore volume of shale, and the correlation coefficient is 0.7591. It could be that clay minerals are much more flexible and are easily deformed to block the pores under compaction. In addition, the longitudinal heterogeneity of the deep shale reservoir structure in southern Sichuan is also controlled by the thermal effect of the Emei mantle plume on hydrocarbon generation of organic matter and the development of natural microfractures promoted by multistage tectonic movement. Overall, the complex microstructure in the deep shales of the Longmaxi Formation in the southern Sichuan Basin is jointly controlled by multiple effects, and the results of this research provide strong support for the benefit development of deep shale gas in southern Sichuan Basin.

W. Jason Morgan (1935-2023).

Discoverer of plate tectonics and mantle plumes.

Petrogenesis and geochemistry of WNW-ESE to NW-SE trending doleritic dykes of the Paleoproterozoic Liptako basement (West African Craton, West Niger)

Doleritic dykes with regional orientations WNW-ESE to NW-SE, cut the Paleoproterozoic Birimian formations of the Liptako basement (Ouest-Niger). Mineralogical compositions studied from these doleritic dykes consist of augite (Wo21-40-En24-45-Fs13-54), pigeonite (Wo8-12-En45-59-Fs31-41), plagioclase, alkali feldspars, titano-magnetite, ilmenite, edenite, apatite, biotite and chlorite. The geochemical affinity of the doleritic dykes in the two trends is similar to oceanic plateau basalts (OPB), with high iron content relative to Mg. Negative Nb, Ti and Ta anomalies and the Y/Nb ratio (1.59–3.15) indicate a continental tholeiitic character for while light rare earth element enrichment, low to moderate Ti contents and the Th/Yb (0.28–0.59) and Nb/Yb (3.25–7.46) ratios suggest sources similar to E-MORB. Their Th/Nb (0.06–0.10), Th/Yb (0.28–0.59), TiO2/Yb (0.54–0.82) ratios suggest that the magma was generated by partial melting (5–17%) of a residual spinel-garnet lherzolite, that could have been part of a mantle plume. Relatively low Mg# (36–51) reflect some degrees of fractional crystallization, with some of this differentiation recorded between the margins and interiors of dykes. This differentiation was accompanied by unusually low degrees of crustal contamination, as indicated by relatively low Th/Ta ratios (1.18–2.03). This petrological and geochemical information provides new constraints on the origin of these WNW to NE trending mafic dykes of the West African Craton.

Crustal and uppermost mantle structure near the Gloria Fault, North Atlantic, from ocean bottom seismometer surface wave observations

SUMMARY In this work, we present both 1-D and 3-D shear wave velocity (Vs) models of the oceanic crust and uppermost mantle below the Deep OCean Test ARray area, located ∼ 70 km north of the central section of the Gloria Fault, in the eastern North-Atlantic Ocean. The velocity models are inferred from the dispersion of surface waves recorded on ocean bottom seismometers. Dispersion measurements are obtained from the analysis of ambient seismic noise at short periods (< 14 s) and teleseismic surface waves at long periods (> 14 s) using the two-station method. The 1-D Vs model is inferred from the joint inversion of Rayleigh wave phase velocities and Love wave group and phase velocities. The 3-D tomographic model is obtained by inversion of 2-D Love wave group velocity maps as a function of depth, further constrained by the average of Love wave phase velocities obtained from ambient noise (4–9 s) and the average Rayleigh and Love wave phase velocities calculated from teleseismic data (14–44 s). The 1-D Vs model shows a sediment layer with a low velocity of 1.05 km s−1, similar to previous studies in the region. Below the sediments, we find an oceanic crust with velocities ranging from 3.3 to 4.5 km s−1. The model reaches an unusually high velocity of 4.9 km s−1 in a 20 km thick layer at depths between 16 and 36 km. We interpret this fast velocity layer as indicative of the presence of harzburgite, a residue of enhanced melting that might have been formed by the proximity between the Mid-Atlantic Ridge and the Azores mantle plume. At greater depths the velocity decreases, forming a low-velocity zone that reaches a minimum at ∼ 70 km depth, which we interpret as the maximum depth for the lithosphere–asthenosphere boundary. The 3-D model shows a structure that is mostly horizontally layered, with Vs isocontours at 3.5–4.5 km s−1 highlighting oscillations of the crustal structure with wavelengths of ∼25–30 km. These oscillations may be due to changes in the rate of mantle upwelling and magma supply rate.

Highest terrestrial 3He/4He credibly from the core.

The observation that many lavas associated with mantle plumes have higher 3He/4He ratios than the upper convecting mantle underpins geophysical, geodynamic and geochemical models of Earth's deep interior. High 3He/4He ratios are thought to derive from the solar nebula or from solar-wind-irradiated material that became incorporated into Earth during early planetary accretion. Traditionally, this high-3He/4He component has been considered intrinsic to the mantle, having avoided outgassing caused by giant impacts and billions of years of mantle convection1-4. Here we report the highest magmatic 3He/4He ratio(67.2 ± 1.8 times the atmospheric ratio) yet measured in terrestrial igneous rocks, in olivines from Baffin Island lavas. We argue that the extremely high-3He/4He helium in these lavas might derive from Earth's core5-9. The viability of the core hypothesis relaxes the long-standing constraint-based on noble gases in lavas associated with mantle plumes globally-that volatile elements from the solar nebula have survived in the mantle since the early stages of accretion.

Petrogenesis of alkaline magmas across a continent to ocean transect, northern Ross Sea, Antarctica

The West Antarctic Rift System (WARS) is one of the world's largest active rift systems and alkaline magmatic provinces. The alkaline magmatism crosscuts oceanic and continental lithosphere but maintains generally similar Sr-Nd-Pb isotope signatures. Here we present new major-, trace- and highly siderophile-element (Os, Ir, Ru, Pt, Pd, Re) abundances and Sr-Nd-Pb-Os isotope data for a Miocene to recent WARS alkaline basalt suite from a continental-oceanic transect in the northwest Ross Sea. The samples are geochemically enriched similar to ocean island basalts, with oceanic lavas having higher absolute incompatible trace element abundances than continental lavas. The suite exhibits a large range in measured 187Re/188Os (1.7 to 1305) and age-corrected 187Os/188Os (0.1254 to 1.055) that has a positive, highly curved relationship with measured 87Sr/86Sr (0.70287–0.70331), but a negative, highly curved relationship with both measured 143Nd/144Nd (0.51280–0.51300) and 206Pb/204Pb (19.237–20.237). These data suggest that contamination by a mafic continental lithospheric component has occurred to varying degrees and exerts some control on the geochemistry of the continental lavas. Primitive lavas from the oceanic Adare Basin that have experienced negligible contamination are used to constrain the primary source of northwest Ross Sea alkaline lavas and to assess previously proposed hypotheses regarding the origin of magmatism. Explanations for the origin of WARS alkaline lavas range from plume magmatism to partial melting of continental lithospheric mantle metasomatized by subduction fluids prior to cessation of subduction of the Phoenix Plate underneath the Gondwana margin. Samples from the continental-oceanic transect, however, neither exhibit classic arc-lava geochemical signatures nor provide any evidence to support an active mantle plume source. Rather, they are geochemically enriched magmas generated through partial melting of previously subducted oceanic lithospheric mantle concomitant with continental lithospheric thinning during the Cenozoic.

The origin of the Musicians Seamount Province and its inferences for Late Cretaceous Pacific Plate Motion

Linear chains of seamounts, sourced from mantle plume processes, have the potential to refine plate motion models because the hotspot remains fixed relative to the moving lithospheric plate. However, to define plate motion, consistent seamount age progression and geometry are required. Some seamount chains, such as the Musician Seamount Province (MSP), have complex geometries and age distributions, which complicates calibrating plate motion. The MSP resides northwest of the Hawaiian Islands and is composed of seamounts and volcanic elongated ridges (VERs) that cover ∼420,000 km2 of Pacific seafloor. Here we provide new 40Ar/39Ar age determinations for a series of lava flows recovered from the MSP during expedition EX1708 of the National Oceanic and Atmospheric Administration's Ocean Exploration program. The MSP was built by four distinct volcanic processes: (1) age-progressive hotspot volcanism associated with the Euterpe Plume (ca. 98–79 Ma). (2) VER formation from plume-ridge channelization (ca. 97–94 Ma; 86–79 Ma) where the VERs only form when the hotspot is within ∼600 km of the ridge. (3) Eocene volcanism driven by extension during the ca. 50 Ma change in Pacific rotation poles (ca. 54–47 Ma). (4) Some near-ridge shear-driven upwelling or diffuse extensional volcanism that preceded the southern MSP lithosphere overriding the plume (ca. 86–84 Ma). By filtering lava flows with only robust statistically concordant 40Ar/39Ar age determinations as well as geologic setting, we develop a dataset of samples valuable for constraining Pacific plate motion. A local plate velocity of 42 ± 9 km/Ma for the 98–81 Ma time frame is calculated. Furthermore, the seamount track indicates that large shifts in Pacific rotation pole locations are required prior to 98 Ma and at ca. 81 Ma.

Revisiting the South China Sea MORBs: Mg isotope and whole-rock geochemical constraints

Mid-Ocean Ridge Basalts (MORBs) from the South China Sea (SCS) have attracted great attention from geologists in the past decade, but their petrogenesis still remains controversial. Here, we show that the Mg isotopes of MORBs from Integrated Ocean Drilling Program (IODP) Sites U1431, U1433 and U1434 are heterogeneous and present the mechanisms causing such heterogeneity. The MORBs from Sites U1431, U1433 and U1434 have δ26Mg values ranging from −0.35‰ to −0.21‰, from −0.34‰ to −0.13‰, and from −0.30‰ to −0.20‰, respectively. Together with all the published data, we found the MORBs at Site U1431 with high MgO contents (> 9 wt%) usually have δ26Mg values that are generally lower than the normal mantle (−0.25‰ ± 0.04‰), whereas some of the Site U1433 MORBs are higher than the normal mantle. Shallow-level geological processes like seawater alteration have negligible effects on the Mg isotope fractionation of our samples. Elemental ratio indicative of the degree of partial melting (like Sm/Nd) from the same site also shows no relationship with the δ26Mg variations. Olivine is proposed to have light Mg isotopes. Considering the high MgO (> 9 wt%) contents of low-δ26Mg samples and the petrographic evidence, we propose that their slightly light Mg isotopic compositions of U1431 MORBs may result from the enrichment of olivine, rather than reflecting the mantle source. Moreover, low Ce/Pb ratios and most variable δ26Mg values of some U1433 MORBs suggest that lower continental crustal materials have contributed to their source. As all the previously published MORBs are evolved, we use the Revpet to estimate the mantle melting conditions of SCS MORBs, including the Site U1500 samples recovered from the northern margin of SCS. Compared with the global MORBs data, there is no thermal anomaly in SCS MORBs. Together with our new Mg isotope data, therefore, we propose that the role of the Hainan mantle plume in the opening and spreading of the SCS may be insignificant.

Origin of the Songpan–Garzê terrane, Tibetan Plateau: a perspective from the tectonic evolution of the Palaeo-Tethys Ocean

Abstract The Songpan–Garzê terrane is the largest Triassic remnant flysch basin on Earth and formed as the Palaeo-Tethys Ocean closed during the final amalgamation of the Pangaea supercontinent. However, the origin of the Songpan–Garzê terrane is highly controversial. A synthesis of the tectonic evolution of the Palaeo-Tethys Ocean and its branches surrounding the Songpan–Garzê terrane is presented, which clarifies the nature and relationships among the many Palaeo-Tethys sutures. Provenance analyses suggest that branches of the Palaeo-Tethys near the Songpan–Garzê terrane closed before the Early Triassic. In contrast, the main Palaeo-Tethys Ocean (Longmu Co-Shuanghu) did not close until the beginning of the Late Triassic. This study argues against the Songpan–Garzê terrane being a remnant ocean basin, and proposes that it was a back-arc basin of the main Palaeo-Tethys Ocean. It initially underwent extension by the combined effects of the main Palaeo-Tethys Ocean subduction and the Emeishan mantle plume in the Late Permian, and subsequently developed into a back-arc basin in the Triassic, into which huge turbiditie units were deposited derived from all surrounding terranes and orogens. The final closure of the main Palaeo-Tethys Ocean in the beginning of the Late Triassic and subsequent continent–continent collision led to basin inversion in the Late Triassic.

Petrogenesis of two episodes of Neoarchean TTG gneisses (∼2.72 Ga and 2.56–2.54 Ga) from the Zhongtiao Mountains, North China Craton: Implications for crustal evolution

The petrogenesis of tonalite-trondhjemite-granodiorite (TTG) suites can provide key clues for the formation and evolution of continental crust. Neoarchean TTG gneisses are widely distributed in the Zhongtiao Mountains (ZTM), North China Craton (NCC). In this contribution, to better understand Neoarchean crustal evolution of the NCC, two discrete episodes of TTG gneisses (∼2.72 Ga and ∼2.56–2.54 Ga) from the ZTM are investigated. New results approve that the two episodes of TTG gneisses are all characterized by high SiO2, Na2O contents, (La/Yb)N and Sr/Y values, but low K2O/Na2O ratios. These geochemical features are similar to the Archean TTG suites and Phanerozoic high-SiO2 adakites, suggesting that they were both derived from partial melting of mafic rocks. The characteristics of trace elements (e.g., La/Yb, Sr/Y, Y/Yb, (Ho/Yb)N and Nb/Ta ratios) imply that both of them correspond to MP-TTGs, and garnet-amphibole exist in the residue phase. The ∼2.72 Ga TTGs show high Mg# values (ave. = 51), Cr (4.87–104 ppm) and Ni (6.37–55.7 ppm) contents, and negative Nb, Ta anomalies. Some high Nb/Ta ratios (up to 17.6) imply that rutile might be involved in the residual phase, which should require a higher pressure. Zircons from these rocks yield positive εHf(t) values of +4.0 ∼ +6.8 (ave. = +5.6), with two-stage Hf model ages (TDM2) of ∼2.85–2.70 Ga, indicating a juvenile basaltic crustal source. Hence, we interpret that ∼2.72 Ga TTGs in the ZTM were derived from partial melting of mafic rocks, and more likely related to subduction process. In contrast, the ∼2.56–2.54 Ga TTGs have lower Mg# values (39–54, mostly <45), Cr (6.02–22.8 ppm) and Ni (4.93–15.7 ppm) contents. They exhibit more evolved zircon Hf (average εHf(t) = +3.21) and whole-rock Nd (εNd(t) = +1.87) isotopic compositions, and their TDM2 ages are concentrated at ∼2.85–2.68 Ga. These ∼2.5 Ga TTGs in the ZTM show similar geochemical features with contemporary TTGs in the XQL, DF and EZT of the southern NCC, identical to melts from partial melting of mafic rocks under a thickened lower crust. The ∼2.5 Ga TTGs, A-type granites and mafic rocks in the ZTM jointly indicate a complicated crust-mantle process at different depths related to mantle plume activity during the late Neoarchean. Based on comparison of the spatial-temporal distribution and geochemical features of ∼2.7 Ga and ∼2.5 Ga TTGs in the NCC, we propose that Neoarchean crustal evolution of the ZTM is similar to the whole NCC, which recorded a significant crustal growth event at ∼2.7 Ga, and an important crustal reworking event associated with some juvenile crustal growth at ∼2.5 Ga.

Major, trace element and Sr-Nd isotope evidence for a sublithospheric mantle source for the Umkondo large igneous province

The Mesoproterozoic (1.11 Ga) Umkondo large igneous province (LIP) in southern Africa and Antarctica was emplaced in < 5 Myr and is dominated by low-Ti tholeiitic doleritic-gabbroic sills. It is of particular interest because it is the least studied LIP in southern Africa with both sublithospheric and lithospheric mantle sources proposed and it coincides with the early assembly of Rodinia, so it has importance in understanding the nature of magmatism and tectonics in and around the Kalahari craton during the Mesoproterozoic. In this study, we compiled a large database of existing (∼750) and new (∼100) major and trace element data for the Umkondo province, as well as 42 new Sr-Nd isotopic measurements, to provide constraints on its magma sources and geochemical evolution. Major element compositional variations in the low-Ti tholeiites are explained by low-pressure (1 kbar) three-phase fractional crystallisation (olivine, clinopyroxene and plagioclase) of a parent magma with ∼ 10 wt.% MgO in oxidising conditions (QFM + 1). Inverse models show that the low-Ti tholeiitic magmas were derived as residual melts after the crystallization of 12%–33% olivine from primary komatiitic-basaltic magmas (up to ∼ 20 wt.% MgO) in equilibrium with mantle olivine (Fo90). Low Sm/Yb and TiO2/Yb-Nb/Yb indicate that the primary magmas were derived by 2%–20% shallow (40–50 km) partial melting of spinel lherzolite. High Sm/Yb is restricted to dyke swarms and may imply limited magma production from deeper (up to ∼ 70 km) garnet lherzolite-like sources. The low-Ti tholeiites of the Umkondo province are enriched in large ion lithophile elements (Rb-Sr-Cs-K) and depleted in high-field strength elements (Zr-Hf-Nb-Ta), indicating the involvement of crustal material and/or the subcontinental lithospheric mantle. This is supported by covariations in Th/Nb, Nb/Yb, Nb/La and Ce/Sm with generally negative ΔNb. Sr-Nd isotopes lend support to the notion that the Umkondo magmas were derived from depleted and/or enriched sublithospheric mantle sources and subsequently contaminated by enriched lithospheric material during emplacement (initial (at 1.11 Ga) 87Sr/86Sr between 0.704820 and 0.737464 and εNd between −8.9 and +5.3). The Vredefort sills are significant as they display the most depleted Sr-Nd isotopic signatures (average initial 87Sr/86Sr of 0.705342 and average εNd of 0.4) and are the least contaminated magma suite in the Umkondo province. Because of (i) the large volume of low-Ti magmas, (ii) evidence of a primary hot and MgO-rich (komatiitic) magma, and (iii) the short duration of magmatism, we suggest that the Umkondo province was formed by plume-induced melting of the sublithospheric mantle beneath the Kalahari craton in an extensional setting. This contrasts with previous suggestions that the heat source developed in response to the “thermal insulation” of the mantle beneath a thickened Kalahari craton in the absence of a mantle plume. There is further evidence from the elevated Zn/Fe that the sublithospheric mantle was lithologically heterogeneous and consisted of mixed peridotite and pyroxenite domains. There is a general lack of ultramafic cumulates in the low-Ti magma suite that may imply there was deeper ponding and storage of the primary magmas that fractionated large quantities of ultramafic rocks. There is also a paucity of high-Ti rocks in the Umkondo province that may reflect limited direct melting of the lithospheric mantle or that they are simply not as well-preserved in this province compared to the Karoo province. The similar trace element and Sr-Nd isotopic compositions of the Umkondo sills in southern Africa with the Borgmassivet sills in Antarctica support the concept that the Kalahari craton and Grunehogna terrane were adjoined at 1.11 Ga. The timing of the Umkondo province indicates there was localised lithospheric extension and upwelling asthenospheric mantle during a time of dominantly compressional tectonics on Earth at the end of the ‘boring billion’.

Emergence of the Loa Mantle Component in the Hawaiian Islands Based on the Geochemistry of Kauaʻi Shield‐Stage Basalts

AbstractKauaʻi shield‐stage lavas are central to understanding the origin of the distinct Kea and Loa Hawaiian geochemical trends in Hawaiian basalts. These trends reflect two geochemically distinct sides in the Hawaiian plume, with Loa to the southwest and Kea to the northeast. The geochemistry and Sr‐Nd‐Hf isotopic compositions of shield‐stage lavas from Kauaʻi show a transition from Kea to Loa across the island with the Loa mantle source becoming dominant as the volcano grew. This geochemical transition is gradual from west to east Kauaʻi and supports the hypothesis that the Kauaʻi volcano sampled both sides of the bilateral Hawaiian plume, a phenomenon that is unusual for a Hawaiian volcano. Notably, Kauaʻi marks the arrival of progressively larger volumes of Loa compositions within the Hawaiian mantle plume. The new data from Kauaʻi, combined with an updated and comprehensive database of Hawaiian shield‐stage major element oxides, trace element concentrations, and isotopic compositions normalized to the same standard values, allows for the Pb‐Sr‐Nd‐Hf isotopic compositions of the Average Loa (‘ALOA’) common geochemical component to be estimated. Despite the bilateral Loa‐Kea geochemical trend beginning at Molokaʻi, Loa compositions dominate the erupted volume of Hawaiian volcanoes younger than 3 Ma, validating the volumetric importance of the Loa source in the lower mantle portion of the Hawaiian plume.

Lithospheric density structure beneath the dyke swarm region of the southern Bastar craton reveals a possible Proterozoic mantle plume: Inference from gravity and geoid study

Lithospheric density structure beneath the dyke swarm region of the southern Bastar craton reveals a possible Proterozoic mantle plume: Inference from gravity and geoid study

Does the Ollo de Sapo magmatic event support Furongian‒Tremadocian mantle plume activity fringing NW Gondwana?

ABSTRACT We propose that the 495-470 Ma Ollo de Sapo magmatism in the Iberian Massif was the result of a mantle plume event in the Furongian-Early Ordovician. This plume was located beneath the northwestern margin of Gondwana and caused rapid and extensive melting of Ediacaran arc-related crustal rocks and their derived sediments. Mafic magmas due to plume partial melting underplated the crust and were emplaced at mid-lower crustal levels (~15km), and provided the heat for crustal melting. Manifestations of the plume include (i) pronounced magnetic anomalies in the region which match the distribution of Ollo de Sapo rocks, (ii) the Toledanian unconformity (and gap), which is attributed to thermal doming, and (iii) the significant thickness variations in Lower to Middle Ordovician sedimentary successions in adjacent areas. In a more regional context, we infer that the plume was one of a cluster of plumes impacting the Gondwana periphery and that it contributed to the birth and development of the Rheic Ocean throughout Gondwana margin breakup.

South Mid-Atlantic Ridge 25.3–27.7°S segment basalts: Implications for entrainment of the Tristan plume material in the mid-ocean ridge system

We present new major and trace element and Sr-Nd-Pb isotope data for basalts from the 25.3–27.7°S segments of the South Mid-Atlantic Ridge (SMAR). A fractional crystallization model shows that olivine, plagioclase, and clinopyroxene crystals crystallized in the magmatic chamber underlying the SMAR 27.1°S and 27.7°S segments, while the SMAR 25.3°S segment basaltic lavas are dominated by fractional crystallization of olivine and plagioclase. Their Ce/Yb, (Tb/Yb)N, and Fe/Mn ratios suggest a mantle source lithology dominated by spinel-lherzolite. The linear correlations between Mg# and TiO2, Ba, and Zr/Nb indicate that SMAR basalts in this study have primary mantle melts with similar chemical compositions and partial melting extents. The along-ridge variations in the fractionation-corrected incompatible element (Ba, Zr/Nb, (La/Sm)N) and Sr-Nd-Pb isotope compositions of the SMAR 20–40°S basalts show that Tristan mantle plume materials exist in the SMAR asthenosphere and gradually decrease from the southern SMAR 35°S segment in the vicinity of Tristan Island to the northern SMAR 25.3–27.7°S segments. The mixing models of the fractionation-corrected Ba contents, (La/Sm)N ratios and radiogenic Sr-Nd-Pb isotope ratios show that variable degrees of contamination by the Tristan mantle plume contribute to the heterogeneous SMAR 20–40°S mantle source. The proportion of Tristan plume-related materials retained in the SMAR 20–40°S asthenosphere is <10%, which gradually decreases from south to north. By integrating the evolution of the South Atlantic and the historical interaction between the SMAR system and the Tristan mantle plume, we demonstrate that the systematic variations in the geochemical compositions of the SMAR 25.3–27.7°S basalts are induced by the presence of the Tristan mantle plume materials in the southern SMAR asthenosphere.

Kerguelen carbonatite tuff sourced from deep recycled material

Carbonatites are mantle-derived rocks associated with rare earth element deposits and their origin is debated. The majority of carbonatites are found in proximity to old continental crust and generally exhibit more geochemically enriched Sr and Nd isotopes relative to the prevalent mantle, with only a few known carbonatite occurrences found in intra-oceanic settings such as that in Cape Verde and Canary Island in the Atlantic Ocean. These oceanic carbonatites are moderately depleted with isotopic signatures similar to the prevalent mantle, indicating that Sr and Nd isotopic enrichment observed in continental carbonatites is controlled by the continental lithospheric mantle, metasomatized by melts and fluid over billions of years. Here we report a newly discovered intra-oceanic dolomite tuff unit with carbonatitic affinity, from the Kerguelen Archipelago, the emerged part of the long-lived Cretaceous Kerguelen Plateau. The Kerguelen dolomite tuff erupted at 24.1 ± 0.4 Ma after the main building phase of the northern Kerguelen Plateau and was fed by the Kerguelen mantle plume. The dolomite tuff shows strong Sr and Nd isotopic enrichments consistent with the presence of recycled material in the deep mantle source of the Kerguelen plume, possibly enriched during the assembly and breakup of the supercontinent Pangaea. These new data show a significant role of geodynamic processes in controlling deep material recycling, location of mantle plumes, and composition of carbonatitic melt.

Oceanic serpentinites: A potentially critical reservoir for deep nitrogen recycling

Abstract Serpentinized oceanic peridotites might be an important reservoir delivering volatile elements including nitrogen (N) into the mantle via subduction. To determine N sources and estimate the budget of alteration-added secondary N in the oceanic mantle peridotite reservoir, we examined oceanic serpentinites from four Ocean Drilling Program (ODP) sites in the Pacific and Atlantic Oceans. Our results showed that, despite large variation in serpentinization condition (high temperatures up to &amp;gt;350 °C at Holes 895D, 1271B, and 920D; low temperatures &amp;lt;150 °C at Hole 1274A), serpentinites from all sites displayed ubiquitous and similar magnitude of N enrichment (3.2–18.6 ppm) from sediments/seawater sources (δ15N = –3.3‰ to +4.4‰), and these values were significantly elevated relative to the low N concentration (0.04–2.0 ppm) and δ15N value (−5‰ ± 2‰) of the depleted mantle. Based on these data, the serpentinized oceanic mantle is estimated to contribute 0.4 ± 0.2–14.7 ± 6.9 × 109 mol N annually to global subduction zones. Although this flux is smaller than that of subducting sediments (57 × 109 mol·yr–1), comparison between oceanic serpentinites and meta-serpentinites from subduction zones suggests that N can be effectively retained in serpentinites during prograde metamorphism. This implies that the serpentinized slab mantle could be a critical reservoir to deliver N enriched in 15N to the mantle (at least 70 km depth) and potentially to the deepest portions of the mantle sampled by deep-rooted mantle plumes.

Decoupling of short-lived radiogenic and helium isotopes in the Marquesas hotspot

The short-lived radiogenic 182Hf/182W (t½ = 9 Ma) and 146Sm/142Nd (t½ = 103 Ma) systems are useful tools to investigate differentiation processes in Earth's early history. Mantle reservoirs that have been preserved over long geological timescales could carry signatures formed early on in Earth's history and later could act as sources to modern mantle plumes. Negative μ182W anomalies in combination with high 3He/4He ratios have been detected globally as differently sloping negative trends in plume-derived ocean island basalts (OIB) from individual hotspots. Large low shear velocity provinces (LLSVP) and ultra-low velocity zones (ULVZ) are seismically anomalous regions in the lower mantle that have been suggested as sources of primordial mantle components near the core-mantle boundary (CMB) and accessed by deep-rooted mantle plumes.In this work, seven samples from the islands Hiva Oa and Fatu Hiva of the Marquesas Archipelago, showing a range in 3He/4He ratios, have been investigated motivated by its location above the Pacific LLSVP and a recently discovered “mega-ULVZ”. Despite elevated 3He/4He ratios of up to 14.4 R/RA, new high precision measurements using thermal ionization mass spectrometry revealed non-anomalous μ182W (−0.9 ± 4.9 ppm) and μ142Nd (1.3 ± 2.4 ppm, 95% confidence interval (c.i.)). These mark the Marquesas Archipelago as the first hotspot to show a decoupling of 3He/4He ratios and μ182W in OIB. A mixing model between an elevated 3He/4He-negative-μ182W and an EM2 or a HIMU endmember suggest that the addition of recycled material is not responsible for this decoupling. Instead, like many previously studied OIB, the Marquesas plume is most likely dominated by an LLSVP component proposed to contain high 3He/4He ratios and μ182W of 0. The unique observed absence of negative μ182W anomalies, on the other hand, implies a lack of involvement of the ULVZ source in the plume's melting region, despite the hotspot being located above a recently discovered mega-ULVZ. This may imply that the expression of ancient mantle domains in hotspot geochemistry is temporally variable, thus, delaying the arrival or involvement of ULVZ material in the origin of the Marquesas OIB.