Host Material Research Articles

Gas phase alloyed crystalline S–Se dielectrics with high ionic mobility

The advancement of future electronic devices necessitates dielectric materials with enhanced compositional complexity and improved capabilities. We here demonstrate a gas-phase alloying approach that yields ultrathin and crystalline dielectrics with attractive properties for the integration into electronics. A surface-selective deposition process was shown to produce sulfur (S) and selenium (Se) alloys with large-scale uniformity. Through combination of experimental diffraction analysis and materials modeling, we establish the crystallinity of the alloy with a modified lattice structure compared to the host materials. The resulting lattice arrangement endows the alloy dielectric with high ionic mobility as validated by electrochemical impedance spectroscopy. Leveraging this innovative feature, we fabricate memristive devices exhibiting promising performance characteristics. Our findings demonstrate the feasibility of utilizing gas-phase alloying to engineer dielectrics with superior properties and functionality for future device integration.

Polarization-dependent photoluminescence of Ce-implanted MgO and MgAl2O4

Since the qubit’s performance of solid-state spin centers depends highly on the host material, spin centers using new host materials may offer new qubit applications. We investigate the optical properties of Ce-implanted MgO and MgAl2O4 as potential materials holding the optically accessible qubit. We find that the photoluminescence of Ce-implanted MgAl2O4 is more than 10 times brighter than that of Ce-implanted MgO and observe polarization-dependent emission of Ce center in MgAl2O4 with 2% at 4 K under 500 mT, suggesting that the properties required for initializing and reading the state of the spin qubit have been achieved.

Integration of Heterogeneous Interfaces and Multi‐Dimensional Encapsulation Structure in Fe2N@CNTs Enabling Highly Efficient Thermal Management and Microwave Absorption

AbstractThe opposing effects of interface effect on phonon heat conduction and microwave absorption hinder the integration of thermal conduction with microwave absorption. Reconciling this contradiction by rationally optimizing the material structure remains a challenge. Herein, Fe2N@CNTs with heterogeneous interfaces and multi‐dimensional encapsulated structures are fabricated through in situ chemical vapor deposition (CVD) to realize excellent thermal conductivity and microwave absorption. When the mass fraction of active material is 40 wt.%, the thermal conductivity (λ//) of Fe2N@CNTs composite films is 6.69 W m−1 K−1. The minimum reflection loss (RLmin) is up to −54.55 dB at a thickness of 3.43 mm, and the effective absorption bandwidth (EAB) is 5.52 GHz at 1.82 mm. The well‐designed Fe2N@CNTs is an ideal model for gaining insight into electron transportation and phonon multi‐dimensional heat transport. Heterogeneous interface improves the dielectric loss and facilitates microwave and phonon absorption and conversion. The multi‐dimensional encapsulation structure increases the electron transport path and phonon heat transport paths making axial and radial co‐transfer possible. The multi‐dimensional encapsulation structure demonstrates extremely high microwave absorption and thermal management capabilities, which open up new possibilities for multifunctional applications in host materials with internal hollows.

Determination of Sodium Ion Diffusion Coefficient in Tin Sulfide@Carbon Anode Material Using GITT and EIS Techniques

The electroanalytical behavior of SnSx (x = 1, 2) encapsulated into a carbon phase was studied using the galvanostatic intermittent titration technique (GITT) and electrochemical impedance spectroscopy (EIS). These techniques are widely utilized in battery systems to investigate the diffusion of alkali metal cations in anode and cathode materials depending on the concentration of ions in the host material. Here, we report different calculation methods showing how the applied model affects the derived diffusion coefficient. The calculated value of the apparent chemical diffusion coefficient of sodium ions (DNa+) is in the range of 1 × 10−10 to 1 × 10−15 cm2/s depending on the technique, mathematical protocol, geometry of the electrode material, and applied potential.

Computational study to investigate effectiveness of titanium substitution in CaFeH3 perovskite-type hydride: An approach towards advanced hydrogen storage system

In recent years, there has been increased interest in hydrogen storage due to the numerous advantages hydrogen offers as an energy source. This study explores the structural, hydrogen storage, electronic, elastic, mechanical, and optical properties of Ca1-xTixFeH3 through DFT. After Ti substitution in the host material, structure phase transformation occurs: cubic → pseudo-cubic → cubic. Study compounds are thermodynamically stable and experimentally synthesizable according to the calculated negative formation energies. Gravimetric hydrogen storage capacities for different concentrations of Ti (x = 0, 0.11, 0.33, 0.55, 1) were calculated as 2.963, 2.938, 2.843, and 2.753 wt%, respectively. The investigation focuses on understanding the material's BS, Fermi level, and DOS, elucidating its metallic characteristics, and non-zero DOS at the Fermi level contributing to electrical and thermal conductivity. Elemental partial density of states reveals hybridization effects with Ti doping, affecting the valence band's atomic contributions. Using cubic symmetry, C11, C12, and C14 elastic constants were used to describe mechanical characteristics, and the Born criteria were met. Thus, mechanical stability was demonstrated for these compounds. Optical analyses exhibit changes concerning Ti concentrations and energy levels, including absorption spectra, conductivity, reflectivity, dielectric function, refractive index, energy loss function, and extinction coefficient. These findings shed light on the material's response to incident radiation and potential applications in hydrogen storage and optoelectronic devices.

Diffusion-induced stress amplification in phase-transition materials for electrodes of lithium-ion batteries

This work sheds the light on the stress amplification in active material particles of electrodes caused by the localized lithium concentration inhomogeneity due to phase transitions. This is a significant issue usually neglected in the literature, as generally the ideal Fickian diffusion model is used to describe the lithium diffusion, which particularly fails when dealing with phase change materials, resulting in the underestimation of the stress. In turn, this results in the underestimation of the fracture behavior of the electrode and the battery degradation, ultimately.To overcome these limitations, this work proposes a mechanical-transport model where the lithium transport is modeled according to the non-ideal solution theory with an equivalent diffusion coefficient depending on the potential of the host material vs Li/Li+. The results show that the proposed model correctly describes the concentration distribution within the particle of phase-change materials (graphite is chosen as a case study), in agreement with the existent experimental measurements. The differences with respect to the traditional Fickian diffusion model is substantial as the stress is up to 85% higher with the proposed model and the concentration distribution can capture the inhomogeneity caused by phase transitions.

Prussian blue analogues wrapped by reduced graphene oxide as an efficient electrocatalyst for lithium-sulfur batteries

In this work, three-dimensional microspheres composed of FeMn prussian blue analogue (FeMn PBA) and reduced graphene oxide (rGO) were realized through spray drying technology. The FeMn PBA@rGO composite shows distinctive microsphere structure with wrinkled surface, in which FeMn PBA polyhedron closely coated by rGO. This unique structure with well rGO coated shell could enhance the structural stability and provide effective charge transfer channels at the cathode/electrolyte interface. Moreover, the polar FeMn PBA could provide abundant adsorptions to capture soluble lithium polysulfides (LiPSs) and catalytic sites to effectively accelerate LiPSs conversion reaction. Benefiting from this rational design, the Li–S cells with FeMn PBA@rGO host material exhibit an initial reversible capacity of 1145 mAh g−1 at 0.2C and good cycling stability. The findings point an effective direction for the development on functional catalysts with distinctive structure and chemical composition for advanced Li–S batteries.

Spirobifluorene Trimers: High Triplet Pure Hydrocarbon Hosts for Highly Efficient Blue Phosphorescent Organic Light‐Emitting Diodes

AbstractPure aromatic hydrocarbon materials (PHCs) represent a new generation of host materials for phosphorescent OLEDs (PhOLEDs), free of heteroatoms. They reduce the molecular complexity, can be easily synthesized and are an important direction towards robust devices. As heteroatoms can be involved in bonds dissociations in operating OLEDs through exciton induced degradation processes, developing novel PHCs appear particularly relevant for the future of this technology. In the present work, we report a series of extended PHCs constructed by the assembly of three spirobifluorene fragments. The resulting positional isomers present a high triplet energy level, a wide HOMO/LUMO difference and improved thermal and morphological properties compared to previously reported PHCs. These characteristics are beneficial for the next generation of host materials for PhOLEDs and provide relevant design guidelines. When used as a host in blue‐emitting PhOLEDs, which are still the weakest link of the field, a very high EQE of 24 % and low threshold voltage of 3.56 V were obtained with a low‐efficiency roll‐off. This high performance strengthens the position of PHC strategy as an efficient alternative for OLED technology and opens the way to a more simple electronic.

Spirobifluorene Trimers: High Triplet Pure Hydrocarbon Hosts for Highly Efficient Blue Phosphorescent Organic Light-Emitting Diodes.

Pure aromatic hydrocarbon materials (PHCs) represent a new generation of host materials for phosphorescent OLEDs (PhOLEDs), free of heteroatoms. They reduce the molecular complexity, can be easily synthesized and are an important direction towards robust devices. As heteroatoms can be involved in bonds dissociations in operating OLEDs through exciton induced degradation processes, developing novel PHCs appear particularly relevant for the future of this technology. In the present work, we report a series of extended PHCs constructed by the assembly of three spirobifluorene fragments. The resulting positional isomers present a high triplet energy level, a wide HOMO/LUMO difference and improved thermal and morphological properties compared to previously reported PHCs. These characteristics are beneficial for the next generation of host materials for PhOLEDs and provide relevant design guidelines. When used as a host in blue-emitting PhOLEDs, which are still the weakest link of the field, a very high EQE of 24 % and low threshold voltage of 3.56 V were obtained with a low-efficiency roll-off. This high performance strengthens the position of PHC strategy as an efficient alternative for OLED technology and opens the way to a more simple electronic.

Highly Efficient Blue Host Compound Based on an Anthracene Moiety for OLEDs

We designed and successfully synthesized a novel anthracene-based host material, 10-(4-(naphthalen-1-yl)phenyl)-9-(naphthalen-3-yl)anthracene (2-NaAn-1-PNa). The 2-NaAn-1-PNa exhibited a PL max at 440 nm in film state and demonstrated a wide band gap of 2.95 eV, indicating its suitability as a blue host material. In an OLED device using 2-NaAn-1-PNa as the host and 3Me-1Bu-TPPDA as the dopant, real blue emission was achieved with an electroluminescence maximum (ELmax) at 460 nm and Commission Internationale de L’Eclairage coordinates of (0.133, 0.141). The device exhibited excellent EL characteristics, with an external quantum efficiency of 8.3% and a current efficiency of 9.3 cd/A at 10 mA/cm2. Furthermore, the efficiency roll-off was limited to only 1.9% up to 4000 nits, demonstrating exceptional performance.

Improving efficiency in RGB phosphorescent and white organic light emitting diodes via donor-spiro-boron acceptor host materials

The universal host material with boron acceptor core structure is exceptionally sparse to be designed for red, green, and blue in efficient phosphorescent organic light emitting diodes (PhOLEDs) accompanying white OLEDs, possessing indistinguishable device feature. Herein, two boron acceptors spiro-host materials namely 1'-(4-(dimesitylboranyl)phenyl)-10-phenyl-10H-spiro[acridine-9,9′-fluorene] (TPA-PBM) and 1-(4-(dimesitylboranyl)phenyl)-3′,6′-dimethylspiro[fluorene-9,8′-indolo[3,2,1-de]acridine] (2MeCz-PBM) were designed and synthesized. The designed rigid donor strategy exhibited good device performance among the reported boron donor-spiro-acceptor (D-spiro-A) skeleton for organic light emitting diodes (OLEDs). In particular, we fabricate RGB three-color phosphorescent OLEDs based on TPA-PBM and 2MeCz-PBM. The red devices exhibit a maximum external quantum efficiency (EQE) of nearly 28 % (26.8 % for TPA-PBM and 27.5 % for 2MeCz-PBM), with an electroluminescence spectrum at 608 nm. The green/blue devices obtain maximum EQEs of 21.2 %/15.3 % and 21.8 % 17.3 %, for TPA-PBM and 2MeCz-PBM, respectively. Furthermore, green devices display an extremely low efficiency roll-off with decreasing 1 % and 3 % at luminance of 5000 cd m−2. Additionally, the two-color white OLED using 2MeCz-PBM exhibits EQEmax and PEmax are 24.5 % and 62.9 lm W−1 respectively, the EQE remain 23.8 % at commercial lighting brightness of 1000 cd m−2. The WOLED also shows a stable white spectrum with CIE varying range of (0.41, 0.47) to (0.39, 0.46) at 100 cd m−2 to 15000 cd m−2. All obtained results confirmed that our targeted molecules have advantage of carrier balance and efficient charge recombination, which might replace many other commercial host materials.

Luminescence thermometry based on negative thermal expansion host matrices

In practical applications involving high temperatures in oxides and oxide-based structures, challenges such as flames and aggressive environments are common. Turbine engines, where oxide coatings are crucial, face difficulties in temperature measurement due to rapid part motion. The emergence of luminescence thermometry offers advantages in such scenarios and has been studied extensively. However, thermal quenching (TQ) of luminescence happening at such conditions limits the use of phosphor materials as luminescence thermometers for high-temperature sensing, thereby restricting the achievement of sufficient sensitivities and temperature resolutions. Thus, thermally stable phosphors, or more favorably phosphors with anti-TQ of luminescence, have been explored to address TQ issues of luminescence thermometry in recent years. Particularly, phosphors based on negative thermal expansion (NTE) as host matrices have shown feasibility in luminescence thermometry at temperatures exceeding 600 °C. This review focuses on NTE-based phosphors, addressing their luminescent properties and analytical techniques for extending the temperature measurement range. The aim of this review is for better understanding of the structural changes with temperature of NTE-based phosphors, assessing their potential for temperature sensing in harsh conditions, and ultimately encouraging researchers to explore new NTE-based phosphors.

Hollow Defect-Rich Nanofibers as Sulfur Hosts for Lithium-Sulfur Batteries.

The slow redox kinetics of lithium-sulfur batteries severely limit their application, and sulfur utilization can be effectively enhanced by designing different cathode sulfur host materials. Herein, we report the hollow porous nanofiber LaNi0.6Co0.4O3 as a bidirectional host material for lithium-sulfur batteries. After Co is substituted into LaNiO3, oxygen vacancies are generated to enhance the material conductivity and enrich the active sites of the material, and the electrochemical reaction rate can be further accelerated by the synergistic catalytic ability of Ni and Co elements in the B-site of the active site of LaNi0.6Co0.4O3. As illustrated by the kinetic test results, LaNi0.6Co0.4O3 effectively accelerated the interconversion of lithium polysulfides, and the nucleation of Li2S and the dissolution rate of Li2S were significantly enhanced, indicating that LaNi0.6Co0.4O3 accelerated the redox kinetics of the lithium-sulfur battery during the charging and discharging process. In the electrochemical performance test, the initial discharge specific capacity of S/LaNi0.6Co0.4O3 was 1140.4 mAh g-1 at 0.1 C, and it was able to release a discharge specific capacity of 584.2 mAh g-1 at a rate of 5 C. It also showed excellent cycling ability in the long cycle test, with a single-cycle capacity degradation rate of only 0.08%. Even under the harsh conditions of high loaded sulfur and low electrolyte dosage, S/LaNi0.6Co0.4O3 still delivers excellent specific capacity and excellent cycling capability. Therefore, this study provides an idea for the future development of bidirectional high-activity electrocatalysts for lithium-sulfur batteries.

Wool fiber as an In situ reducing agent towards ZnO-based surface modified fabric development: Durability assessment in the realm of textile applications

The development of a bio-inspired method to fabricate ZnO nanostructure-modified functional wool fabric represents a substantial challenge in the textile field. This article reports for the first time the use of wool as a reducing agent for the synthesis of ZnO nanoparticles. While previous studies have employed alternative natural reducing agents for surface modification of host materials, this investigation uniquely utilizes the host material, wool, as the reducing agent for in-situ ZnO nanoparticle synthesis. In addition to demonstrating the use of wool as a reducing agent, this literature uniquely reports the durability of the modified fabric, achieved through the use of trimethoxy methyl silane. This silane compound acts as a bridging agent, forming a strong interface between the wool fibers and the synthesized ZnO nanoparticles. This innovative approach enhances the adhesion and stability of the ZnO nanoparticles on the wool fabric, a key aspect that contributes to the overall durability and performance of the modified material. The in situ surface modification process employed a metal oxide precursor (zinc acetate dihydrate), capping agents (hexamethylene tetraamine, sodium carbonate, and sodium sulfate), and a coupling agent (trimethyl methoxy silane). The capping agents were used to control the reaction conditions, while the coupling agent was employed to improve the durability of the surface modification. The impact of three different capping agents on the corresponding synthesis process was assessed, and the findings revealed that the choice of capping agent helped to form ZnO nanoparticles with distinct morphologies. Analytical techniques, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), dynamic light scattering (DLS), and attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, were utilized to characterize the synthesized particles and the treated fabric. The XRD analysis coupled with SEM analysis confirmed the successful formation of ZnO nanoparticles. The ATR-FTIR spectroscopy provided evidence of the formation of Si-O-Zn and Si-O-C bonds, observed at around 920 cm−1 and 1040 cm−1 respectively. These spectroscopic findings indicate that the surface modification involving the silane compound has enhanced the durability of the ZnO-modified fabric. The covalent linkages between the ZnO nanoparticles, the silane compound, and the wool fibers, confirmed by SEM analysis before and after washing cycles, have enabled the durable attachment of the nanoparticles to the fabric surface, even after multiple washing cycles. The results suggest a novel pathway to use wool as a reducing agent for the surface modification of the same material. Detailed mechanistic insights into the surface modification process and the corresponding chemical interactions were also discussed.

Single atom intercalation in 2D triazine-based (g-C6N6) and boroxine-based (B6O6) porous covalent organic framework bilayers and heterostructures

Covalent organic frameworks (COFs) are new class of organic porous materials with tunable pore size and low weight density, demonstrating remarkable potential applications in gas storage, gas separation, and catalysis. The inherent periodic porosity of COF monolayers (MLs) establishes anchoring sites for single atoms. Using first-principles calculations, we study the structural and electronic properties of atom-embedded C6N6 and B6O6 MLs. Subsequently, the intercalation of atoms between C6N6 and B6O6 bilayers (BLs) and their heterostructure (HTS) are investigated. Our findings show the significant effects of embedded atoms on the structural parameters of the host material. Notably, the Li atom anchors within the pore region of C6N6 ML without forming bonds, while it establishes two σ bonds with O atoms in B6O6 ML. The Cs atom forms six bonds in both MLs and resides between layers in BLs. In the HTS, the Cs atom forms six bonds with N atoms of the C6N6 layer, positioning in the middle of the layers. Calculations reveal that Li and Cs atoms induce a red shift in energy, leading to a semiconductor–metal transition. Conversely, the insertion of an F atom induces a blue shift in energy, creating a midgap state at the Fermi energy.

Electronic Nose and GC-MS Analysis to Detect Mango Twig Tip Dieback in Mango (Mangifera indica) and Panama Disease (TR4) in Banana (Musa acuminata)

Volatile organic compounds (VOCs), as a biological element released from plants, have been correlated with disease status. Although analysis of VOCs using GC-MS is a routine procedure, it has limitations, including being time-consuming, laboratory-based, and requiring specialist training. Electronic nose devices (E-nose) provide a portable and rapid alternative. This is the first pilot study exploring three types of commercially available E-nose to assess how accurately they could detect mango twig tip dieback and Panama disease in bananas. The devices were initially trained and validated on known volatiles, then pure cultures of Pantoea sp., Staphylococcus sp., and Fusarium odoratissimum, and finally, on infected and healthy mango leaves and field-collected, infected banana pseudo-stems. The experiments were repeated three times with six replicates for each host-pathogen pair. The variation between healthy and infected host materials was evaluated using inbuilt data analysis methods, mainly by principal component analysis (PCA) and cross-validation. GC-MS analysis was conducted contemporaneously and identified an 80% similarity between healthy and infected plant material. The portable C 320 was 100% successful in discriminating known volatiles but had a low capability in differentiating healthy and infected plant substrates. The advanced devices (PEN 3/MSEM 160) successfully detected healthy and diseased samples with a high variance. The results suggest that E-noses are more sensitive and accurate in detecting changes of VOCs between healthy and infected plants compared to headspace GC-MS. The study was conducted in controlled laboratory conditions, as E-noses are highly sensitive to surrounding volatiles.

Investigation of structural and optoelectronic integrity of Sm3+ doped CaWO4 for LED applications

In this study we illustrate the structural, electronic and optical integrity of Ca1-xSm(2/3)xWO4 (x = 0.00, 0.02, 0.04, 0.06 and 0.08) crystals for optoelectronic applications via experimental and first principles approach. According to our experimental outcomes, CaWO4 crystallizes in scheelite type tetragonal structure devoid of impurity which depends on the A-site cationic radius and dopant-host compatibility. As a result, the dopant induced lattice distortion occur due to symmetric and asymmetric stretching of (Ca, Sm)—O and W–O bonds within [CaO8] and [WO4] cluster. According to our FT-IR and Raman spectral analysis, the non-centrosymmetric vibration within the [WO4]2- complex gives rise to internal modes while the Ca2+/Sm3+ cationic displacement and rigid molecular ionic group constitutes the external modes which equally impacts the electronic and optical characteristics of the host material. While the forbidden gap extends due to Sm3+ substitution, the delocalization of W-5d orbitals on the other hand occur due to rising distortions within the WO4 cluster. As a result, the polarization between [WO4] and [CaO8] cluster and difference in the electronic transitions controls the optical characteristics of the host material. According to our experimental and theoretical predictions, a noticeable decrease in the optical band gap (5.96–5.83 eV) occurs due to heterovalent cationic substitution (Sm3+), difference in structural order-disorder and charge carrier density. As a result, a broad photoluminescence (PL) spectrum among acceptor doped samples verifies the impact of multi-phonon or multi-level processes on the luminosity of the host material.

Conductivity and Chemiresistive H2S Gas Sensitivity of Graphene (75 wt%)/ Cu (25 wt%) Composite Thin Film

This paper studies the conductivity and chemiresistive H2S gas sensitivity of graphene (75wt%)-Cu(25wt%) composite thin film, using self-made chamber and common laboratory apparatus. The method adopted involves mixture of 2 drops of ethanol with the synthesized composite and prepared on a glass substrate by tape casting method. Two small copper metal sheets were used as electrodes for clipping of crocodile which were also connected to digital meter for resistance readings and its changes. The X-ray Diffraction (XRD) shows thatannealing temperature reduced the crystallite sizes. The Fourier Transform Infrared Radiation (FTIR) spectra show the functional groups present to be transition metal carbonyls or aromatic combination bands, terminal alkyne (monosubstituted), isothiocyanate and that between 2300 and 2400 cm-1 indicates N=C=S functional group and evidence of CO2 interaction with external surface of the material or intercalating in the interlayer of the host material Also, increase in the conductivity was observed due to decrease in resistivity. The response/sensitivity peak of the sensor to hydrogen sulfide was seen to rise proportionally as temperature rose with percentage 3.97% for as grown, annealed at 200°C is at 12.98% while the annealed at 400°C is at 27.34%.

Modulating selective interaction of NiOOH with Mg ions for high-performance aqueous batteries

Aqueous Mg-ion batteries (AMIBs) featuring advantages of good safety, low cost, and high specific energy have been recognized as a promising energy-storage technology. However, the performance of AMIBs is consistently limited by sluggish diffusion kinetics and structural degradation of cathode materials arising from the strong electrostatic interactions between high-charge-density Mg2+ and host materials. Here, layered-structured NiOOH, as traditional cathodes for alkaline batteries, is initially demonstrated to realize proton-assisted Mg-(de)intercalation chemistry with a high discharge platform (0.57 ​V) in neutral aqueous electrolytes. Benefiting from the unique core/shell structure, the resulting NiOOH/CNT cathodes achieve a high capacity of 122.5 mAh g−1 and long cycle stability. Further theoretical calculations reveal that the binding energy of hydrated Mg2+ is higher than that of Mg2+ with NiOOH, resulting in that Mg2+ is easily intercalated/de-intercalated into/from NiOOH. Benefiting from the freestanding design, the assembled fiber-shaped “rocking-chair” NaTi2(PO4)3//NiOOH AMIB shows a high energy density and satisfactory mechanical flexibility, which could be woven into a commercial fabric and power for fiber-shaped photoelectric sensors.

Cavity-enhanced single artificial atoms in silicon

Artificial atoms in solids are leading candidates for quantum networks, scalable quantum computing, and sensing, as they combine long-lived spins with mobile photonic qubits. Recently, silicon has emerged as a promising host material where artificial atoms with long spin coherence times and emission into the telecommunications band can be controllably fabricated. This field leverages the maturity of silicon photonics to embed artificial atoms into the world’s most advanced microelectronics and photonics platform. However, a current bottleneck is the naturally weak emission rate of these atoms, which can be addressed by coupling to an optical cavity. Here, we demonstrate cavity-enhanced single artificial atoms in silicon (G-centers) at telecommunication wavelengths. Our results show enhancement of their zero phonon line intensities along with highly pure single-photon emission, while their lifetime remains statistically unchanged. We suggest the possibility of two different existing types of G-centers, shedding new light on the properties of silicon emitters.