Abstract Surveys in the Middle Estuary of the St Lawrence have yielded a data base consisting of more than 15,000 T‐S pairs distributed over 62 13‐h profiling stations. Although the T‐S curves at each station are remarkably linear, the variability of the slopes and intercepts of the lines is considerable. The means and standard deviations of the temperature and salinity at each individual station are not explicable in terms of linear combinations of the parameters for location in the Estuary, the upstream water properties, the phase of the spring‐neap cycle and the tidal energies. It is shown that the tidally‐averaged density structure is separable into horizontal and vertical components and that its vertical variation over the whole Estuary may be explained by any one of three different functional forms. However, its horizontal variation is not explicable in terms of linear combinations of the parameters mentioned in the paragraph above. Plots of the horizontal variations in temperature, salinity or dens...