Horizontal Mirror Research Articles

Деформирующие преобразования изображений и их применение при аугментации данных для обучения глубоких нейронных сетей

The paper focuses on the improvement of the quality of learning for deep neural networks for a small data set in a classification task. One of the possible approaches to improve the quality of learning is researched which is based on the use of data augmentation (artificial reproduction of the data set) by image warping. The presented mathematical model and fast algorithm for warping make it possible to transform the original image while preserving its structural basis. The proposed algorithm is used to augment image data sets containing a small number of training samples. The augmentation consists of two stages including horizontal mirroring and warping of each of the samples. The effectiveness of such augmentation is tested through the training of neural networks of various types: convolutional neural networks (CNN) of a standard architecture and deep residual networks (DRN). A specific feature of the implemented approach for the solution of the problem under consideration consists in the refusal to use pre-trained neural networks with a large number of layers as well as further transfer learning, since their application incurs costs in terms of the computational resources. The paper shows that the efficiency of image classification when implementing the proposed method of augmenting training data on small and medium-sized data sets increases to statistically significant values of the metric used.

Восприятие естественной асимметричности знакомых и незнакомых лиц

Background. Despite the abundance of human face recognition models and research carried out in this area over the past half-century, there are still open questions about the uniqueness of the facial perception processes and about the oneness or difference of the mechanisms of perception of familiar and unfamiliar faces. Objective. Research into the mechanisms of perception of (a)symmetry of familiar and unfamiliar faces. Study Participants. 34 people participated in the study: 25 classmates (11 female and 14 male, Мage = 16, SD = 0,49) and 9 teachers (6 female and 3 male, Мage = 33, SD = 8,71). Methods. Methods of inversion and horizontal mirroring of face images were used to compare the mechanisms of perception of facial symmetry in familiar and unfamiliar faces. Mirroring allowed to change the face itself without violating its recognition and maintaining the overall degree of its (a)symmetry. The inversion impaired the perception of the facial configuration. Study participants assessed the degree of asymmetry in the images of familiar (photographs of classmates) and unfamiliar faces in four presentation conditions: original / mirrored faces presented upright / inverted. Results. The study results demonstrated that when presented upright, familiar mirrored faces are perceived as more asymmetrical than the original ones; no difference was revealed for unfamiliar faces. When inverting images, the ratings of the original and mirrored versions of the faces do not differ significantly for both familiar and unfamiliar faces. A small inversion effect was found in the ratings of original familiar faces: inverted familiar faces were rated as more asymmetrical than upright ones. Conclusions. The study results generally support the hypothesis that the mechanisms of perception of (a)symmetry in familiar and unfamiliar faces differ. Furthermore, there is reason to consider the assessment of a face (a)symmetry as involving not only configural, but also analytical mechanisms of its perception.

The Supersymmetry Genetic Code Table and Quadruplet Symmetries of DNA Molecules Are Unchangeable and Synchronized with Codon-Free Energy Mapping during Evolution.

The Supersymmetry Genetic code (SSyGC) table is based on five physicochemical symmetries: (1) double mirror symmetry on the principle of the horizontal and vertical mirror symmetry axis between all bases (purines [A, G) and pyrimidines (U, C)] and (2) of bases in the form of codons; (3) direct-complement like codon/anticodon symmetry in the sixteen alternating boxes of the genetic code columns; (4) A + T-rich and C + G-rich alternate codons in the same row between both columns of the genetic code; (5) the same position between divided and undivided codon boxes in relation to horizontal mirror symmetry axis. The SSyGC table has a unique physicochemical purine-pyrimidine symmetry net which is as the core symmetry common for all, with more than thirty different nuclear and mitochondrial genetic codes. This net is present in the SSyGC table of all RNA and DNA living species. None of these symmetries are present in the Standard Genetic Code (SGC) table which is constructed on the alphabetic horizontal and vertical U-C-A-G order of bases. Here, we show that the free energy value of each codon incorporated as fundamentally mapping the "energy code" in the SSyGC table is compatible with mirror symmetry. On the other hand, in the SGC table, the same free energy values of codons are dispersed and a mirror symmetry between them is not recognizable. At the same time, the mirror symmetry of the SSyGC table and the DNA quadruplets together with our classification of codons/trinucleotides are perfectly imbedded in the mirror symmetry energy mapping of codons/trinucleotides and point out in favor of maintaining the integrity of the genetic code and DNA genome. We also argue that physicochemical symmetries of the SSyGC table in the manner of the purine-pyrimidine symmetry net, the quadruplet symmetry of DNA molecule, and the free energy of codons have remined unchanged during all of evolution. The unchangeable and universal symmetry properties of the genetic code, DNA molecules, and the energy code are decreasing disorder between codons/trinucleotides and shed a new light on evolution. Diversity in all living species on Earth is broad, but the symmetries of the Supersymmetry Genetic Code as the code of life and the DNA quadruplets related to the "energy code" are unique, unchangeable, and have the power of natural laws.

Electronic structure and topological phase transition in multi-orbital triangular lattice with rotation and mirror symmetry breaking

Triangular lattice is one of the most generic structures in the two-dimensional (2D) limit with numerous exotic properties, such as magnetic frustration and quantum spin liquid. Here, we investigate the electronic properties of a multi-orbital (p x , p y , p z ) triangular lattice while focusing on the role of rotation and mirror symmetry breaking in regulating the topological phase diagram. The tight-binding modeling reveals that rotation symmetry () breaking splits the Dirac point and preserves the nodal loop. A further inclusion of broken horizontal mirror symmetry () destroys the nodal loop. Consequently, with spin–orbit coupling (SOC), the (p x , p y , p z )-orbital triangular lattice is topologically non-trivial with only or symmetry breaking. With both symmetries breaking, it becomes trivial, except when the SOC is large enough to initiate band inversion. For real materials, we propose that the recently grown AgSe/AgTe monolayer in a binary honeycomb structure is an ideal system to realize the multi-orbital triangular lattice. The first-principles calculations demonstrate that free-standing AgSe and AgTe are Z 2 non-trivial. On the Ag(111) substrate, AgSe becomes trivial because of the breaking of both and symmetries, whereas AgTe remains non-trivial because of the strong SOC of Te. Our work not only provides physical insights into the experimentally synthesized 2D binary honeycomb structures but also highlights the manipulation of electronic and topological properties through symmetry/orbital physics, which are valuable for designing new quantum materials and devices.

Remote wide angle view broad wavelength viewing system compatible with D-T operations in JET

Imaging diagnostics in Joint European Torus have become essential in the study of plasma wall interactions and the protection of the plasma facing components. During deuterium operations, the location of these diagnostics was at close proximity to the vessel. However, for the 50–50 deuterium-tritium operation, the neutron yield impact onto the electronics of these imaging diagnostics would have caused them to fail completely at these locations. Shielding these systems from neutrons is achieved by relocating a selected number of these imaging systems to outside the Torus Hall (i.e. to the other side of the biological shield wall). The relocation encompasses the construction of two new lines of sight crossing through the biological shield wall and each of them using an optical relay which extends to separate ports in the machine. This article starts with a brief description of two new viewing systems. However, it focuses on the optical modelling and engineering design of one of them which is a multiple camera system producing a wide angle view (WAV) of the inside of the vessel. This WAV system has been used successfully during the recent D-T campaign. It operates in a broadband wavelength range extending from the visible to the middle infrared. It also incorporates a novel in-house horizontal kinematic mirror mount made from glass reinforced plastic as part of the optical relay. The operational stability of the WAV system has also been assessed and some post design improvements implemented.

Revisiting the mark test for mirror self-recognition.

Despite half a century of research, few species have exhibited convincing evidence of mirror self-recognition. Several methodological objections to Gallup's mark test have been raised, but empirical studies have shown that methodology does not adequately explain why most species fail to recognize themselves in mirrors. However, a potential issue was constantly overlooked: mirror ecological relevance. Although reflective surfaces in nature are horizontal, previous studies indeed used vertical mirrors. The present study revisited the mark test to address this issue in an experiment with capuchin monkeys (Sapajus apella). Additionally, a new procedure based on sticker exchange was designed to maximize mark attractiveness. Subjects were first trained to exchange stickers, habituated to being head-touched, and exposed to a horizontal mirror. Then, their mirror self-recognition was tested by surreptitiously placing a sticker on their forehead before requesting them to exchange stickers. None of the monkeys removed the sticker from their forehead in the presence of the mirror. In line with previous studies, this result suggests that capuchin monkeys lack the ability to recognize themselves in mirrors. Nonetheless, this modified mark test could prove useful in future studies, including investigation of interindividual variability of mirror self-recognition in self-recognizing species.

Postural and Gestural Synchronization, Sequential Imitation, and Mirroring Predict Perceived Coupling of Dancing Dyads

Body movement is a primary nonverbal communication channel in humans. Coordinated social behaviors, such as dancing together, encourage multifarious rhythmic and interpersonally coupled movements from which observers can extract socially and contextually relevant information. The investigation of relations between visual social perception and kinematic motor coupling is important for social cognition. Perceived coupling of dyads spontaneously dancing to pop music has been shown to be highly driven by the degree of frontal orientation between dancers. The perceptual salience of other aspects, including postural congruence, movement frequencies, time-delayed relations, and horizontal mirroring remains, however, uncertain. In a motion capture study, 90 participant dyads moved freely to 16 musical excerpts from eight musical genres, while their movements were recorded using optical motion capture. A total from 128 recordings from 8 dyads maximally facing each other were selected to generate silent 8-s animations. Three kinematic features describing simultaneous and sequential full body coupling were extracted from the dyads. In an online experiment, the animations were presented to 432 observers, who were asked to rate perceived similarity and interaction between dancers. We found dyadic kinematic coupling estimates to be higher than those obtained from surrogate estimates, providing evidence for a social dimension of entrainment in dance. Further, we observed links between perceived similarity and coupling of both slower simultaneous horizontal gestures and posture bounding volumes. Perceived interaction, on the other hand, was more related to coupling of faster simultaneous gestures and to sequential coupling. Also, dyads who were perceived as more coupled tended to mirror their pair's movements.

Symmetry-Guaranteed High Carrier Mobility in Quasi-2D Thermoelectric Semiconductors.

Quasi-2D semiconductors have garnered immense research interest for next-generation electronics and thermoelectrics due to their unique structural, mechanical, and transport properties. However, most quasi-2D semiconductors experimentally synthesized so far have relatively low carrier mobility, preventing the achievement of exceptional power output. To break through this obstacle, a route is proposed based on the crystal symmetry arguments to facilitate the charge transport of quasi-2D semiconductors, in which the horizontal mirror symmetry is found to vanish the electron-phonon coupling strength mediated by phonons with purely out-of-plane vibrational vectors. This is demonstrated in ZrBeSi-type quasi-2D systems, where the representative sample Ba1.01 AgSb shows a high room-temperature hole mobility of 344 cm2 V-1 S-1 , a record value among quasi-2D polycrystalline thermoelectrics. Accompanied by intrinsically low thermal conductivity, an excellent p-type zT of ≈1.3 is reached at 1012 K, which is the highest value in ZrBeSi-type compounds. This work uncovers the relation between electron-phonon coupling and crystal symmetry in quasi-2D systems, which broadens the horizon to develop high mobility semiconductors for electronic and energy conversion applications.

Tongue crack recognition using segmentation based deep learning

Tongue cracks refer to fissures with different depth and shapes on the tongue’s surface, which can characterize the pathological characteristics of spleen and stomach. Tongue cracks are of great significance to the objective study of tongue diagnosis. However, tongue cracks are small and complex, existing methods are difficult to extract them effectively. In order to achieve more accurate extraction and identification of tongue crack, this paper proposes to apply a deep learning network based on image segmentation (Segmentation-Based Deep-Learning, SBDL) to extract and identify tongue crack. In addition, we have studied the quantitative description of tongue crack features. Firstly, the pre-processed tongue crack samples were amplified by using adding salt and pepper noise, changing the contrast and horizontal mirroring; secondly, the annotation tool Crack-Tongue was used to label tongue crack; thirdly, the tongue crack extraction model was trained by using SBDL; fourthly, the cracks on the tongue surface were detected and located by the segmentation network, and then the output and features of the segmentation network were put into the decision network for the classification of crack tongue images; finally, the tongue crack segmentation and identification results were quantitatively evaluated. The experimental results showed that the tongue crack extraction and recognition results based on SBDL were better than Mask Region-based Convolutional Neural Network (Mask R-CNN), DeeplabV3+, U-Net, UNet++ and Semantic Segmentation with Adversarial Learning (SegAN). This method effectively solved the inaccurate tongue crack extraction caused by the tongue crack’s color being close to the surrounding tongue coating’s color. This method can achieve better tongue crack extraction and recognition results on a small tongue crack data set and provides a new idea for tongue crack recognition, which is of practical value for tongue diagnosis objectification.

Electric-field induced half-metallic properties in an experimentally synthesized CrSBr monolayer.

Two-dimensional (2D) half-metallic materials are highly desirable for nanoscale spintronic applications. Here, we propose a new mechanism that can achieve half-metallicity in 2D ferromagnetic (FM) materials with two-layer magnetic atoms by electric field tuning. We use a concrete example of an experimentally synthesized CrSBr monolayer to illustrate our proposal through first-principles calculations. It is found that half-metallic properties can be achieved in CrSBr within an appropriate electric field range, and the corresponding amplitude of electric field intensity can be realized experimentally. Janus monolayer Cr2S2BrI is constructed, which possesses a built-in electric field due to broken horizontal mirror symmetry. However, Cr2S2BrI without and with an applied external electric field is always a FM semiconductor. A possible memory device is also proposed based on the CrSBr monolayer. Our work will stimulate the application of 2D FM CrSBr in future spintronic nanodevices.

An innovative optical element for X-ray beam aperture, monitoring, and diagnostic at the CARNAÚBA beamline at SIRIUS/LNLS

The CARNAÚBA beamline is the tender-to-hard X-ray nanoprobe under commissioning for the new source Sirius at the Brazilian Synchrotron Light Laboratory (LNLS). The all-achromatic optics relies on horizontal deflection mirrors, a horizontal secondary source aperture (SSA), and Kirkpatrick–Baez (KB) mirrors to reach beam size down to ~30x30 nm2 at the sample position. To handle the highly focused power density of the pink beam and reach the desired stability for the horizontal secondary source, essential for the desired focusing and coherent properties at the sample position, we present here an SSA device based on a cryogenically cooled Si crystal in a channel-cut geometry. The crystal slabs define the channel aperture, which is controlled by a fine rotation. Simultaneously to the aperture function, the device plays the key role of beam position monitor and beam diagnostic. The scattered signal from the slabs is used to monitor the horizontal beam position during experiments and serves as a feedback input for the pitch control system of the upstream focusing mirror to stabilize the beam intensity and wavefront. The Bragg magnifier geometry of the device spreads the beam over the slabs, allowing the diffracted image of the beam to be collected by an area detector. The beam spread on the slabs also reduces the power density reaching the device, keeping it stable and under controlled temperatures.

TM2B3 monolayers: Intrinsic anti-ferromagnetism and Dirac nodal line semimetal

Searching for two-dimensional materials combining both magnetic order and topological order is of great significance for quantum devices and spintronic devices. Here, a class of two-dimensional transition metal borides, TM2B3 (TM = Ti–Ni), with high stability and stable antiferromagnetic (AFM) orders was predicted by using the first-principles method. The result shows that they possess large magnetic anisotropy energy and high critical temperature. Interestingly, Mn2B3 monolayer is confirmed to be AFM Dirac node line semimetal with several Dirac points near the Fermi level. Detailed analysis of the irreducible representations shows that the nodal lines are protected by the horizontal mirror symmetry Mz. Our findings provide an excellent platform for exploring topological and magnetic materials ready for the next generation of spintronic devices.

Topological phase diagram and materials realization in triangular lattice with multiple orbitals

Triangular lattice, with each site coordinating with six neighbors, is one most common network in two-dimensional (2D) limit. Manifestations of peculiar properties in the lattice, including magnetic frustration and quantum spin liquid, have been restricted to single-orbital tight-binding (TB) model so far, while the orbital degree of freedom is largely overlooked. Here, by combining TB modeling with first-principles calculations, we demonstrate the rich electronic structures of triangular lattice with multiple (p_{x}, p_{y}, p_{z}) orbitals. Type I/II Dirac point, quadratic nodal point and nodal-loops are observed, and the topological phase diagram is mapped out by manipulating the horizontal mirror symmetry, spin-orbit coupling and energy position of relevant orbitals. Remarkably, we show that large-gap quantum spin Hall phase (∼0.2 eV) can be realized in experimentally achievable systems by growing indium monolayer on a series of semiconducting substrates, such as C/Si/Ge(111) and SiC(0001) surfaces, and the proposed materials capture the TB parameter space well. Our work not only provides physical insights into the orbital physics in 2D lattices, but also sheds light on the integration of novel quantum states with conventional semiconductor technology for potential applications, such as dissipationless interconnects for electronic circuits.

High-temperature nodal ring semimetal in two-dimensional honeycomb-kagome Mn2N3 lattice

The search for two-dimensional (2D) nodal ring semimetallic materials is a current research hotspot in spintronics, and designing a 2D nodal ring (NR) material with high Curie temperature (T C) and strong robustness to spin–orbit coupling (SOC) is an even greater challenge. Here, based on the first-principles calculations and symmetry analysis, we predict that 2D Mn2N3 is a nodal ring semimetal (NRSM) with three energy bands near the Fermi energy level consisting of electrons in the same spin channel. An electron-like energy band and two hole-like energy bands near the Fermi plane cross to form two NRs centered at the point Γ. Symmetry analysis shows that the spin-polarized NR semimetal is robust to SOC due to the conservation of horizontal mirror symmetry. Monte-Carlo simulations further demonstrate that the T C of the 2D Mn2N3 reaches 530 K, well above the room temperature. Notably, the 2D Mn2N3 remains an NRSM on h-BN substrate. Our results not only reveal a general framework for designing 2D NR materials, but also promote further research in the direction of multifunctional quantum devices for spintronics.

Two-dimensional tetragonal ZnB: A nodalline semimetal with good transport properties

Nodal-line semimetals have become a research hot-spot due to their novel properties and great potential application in spin electronics. It is more challenging to find 2D nodal-line semimetals that can resist the spin–orbit coupling (SOC) effect. Here, we predict that 2D tetragonal ZnB is a nodal-line semimetal with great transport properties. There are two crossing bands centered on the S point at the Fermi surface without SOC, which are mainly composed of the p xy orbitals of Zn and B atoms and the p z orbitals of the B atom. Therefore, the system presents a nodal line centered on the S point in its Brillouin zone (BZ). And the nodal line is protected by the horizontal mirror symmetry Mz . We further examine the robustness of a nodal line under biaxial strain by applying up to −4% in-plane compressive strain and 5% tensile strain on the ZnB monolayer, respectively. The transmission along the a direction is significantly stronger than that along the b direction in the conductive channel. The current in the a direction is as high as 26.63 μA at 0.8 V, and that in the b direction reaches 8.68 μA at 0.8 V. It is interesting that the transport characteristics of ZnB show the negative differential resistance (NDR) effect after 0.8 V along the a (b) direction. The results provide an ideal platform for research of fundamental physics of 2D nodal-line fermions and nanoscale spintronics, as well as the design of new quantum devices.

The aesthetics of frieze patterns: Effects of symmetry, motif, and element size.

Frieze patterns appear frequently in architectural designs and ornamental patterning but their aesthetic qualities have never been studied experimentally. In the first experiment, 39 undergraduates used a seven-point rating scale to assess the perceived beauty of the seven basic frieze types presented at a horizontal orientation. The friezes consisted of individual curved and linear motifs as well as random textures. Friezes that filled the entire pattern region and which contained emergent global features were preferred the most. In a second experiment, we utilized horizontal texture friezes that were completely filled and which varied in size and number of elements. Participants preferred patterns with larger features, probably because they make detection of the symmetric transformations more visible. The frieze with the greatest number of symmetries was preferred most but symmetric complexity by itself could not completely account for the predicted preference ordering. In both studies, friezes containing horizontal mirrors (translation, 180° rotation, horizontal mirror, vertical mirror, and glide reflection and translation, horizontal mirror, and glide reflection) were preferred far more than any other condition. Horizontal symmetry may enhance perceived beauty in these cases because it runs parallel to and so emphasizes the overall frieze orientation.

Anomalous Thermal Transport Driven by Electron–Phonon Coupling in 2D Semiconductor h‐BP

AbstractThe electron–phonon coupling (EPC) in semiconductors is typically much weaker than phonon–phonon scattering and its effect on lattice thermal conductivity κl has long been considered negligible. Herein, using first‐principle calculations, it is discovered that the EPC can be significant or even dominant over the intrinsic phonon–phonon scattering via doping in 2D semiconductor hexagonal boron phosphorus (h‐BP). Filling electron pocket till van Hove singularity gradually strengthens the EPC and consequently diminishes the room‐temperature κl by 25% and 80% for monolayer and bilayer h‐BP, respectively. Strikingly, at high doping levels, the EPC drives phonon transport in bilayer h‐BP to an anomalous regime where κl becomes nearly temperature (T) independent deviated from the intrinsic 1/T trend. This distinctive behavior is governed by the joint effects of horizontal mirror symmetry breaking, and weak phonon–phonon scattering stemming from the predominance of normal processes. Further considering electronic contributions, the abnormal T‐independent thermal conductivity is still reserved, thereby facilitating the experimental exploration of EPC effect on κl. This study unveils the exotic thermal transport phenomenon in one‐atom‐thick 2D semiconductors and offers a unique avenue to manipulate heat flow by externally controlling the EPC, which calls for future experimental verification.

VERDI: VERsatile DIffractometer with wide-angle polarization analysis for magnetic structure studies in powders and single crystals.

The VERsatile DIffractometer will set a new standard for a world-class magnetic diffractometer with versatility for both powder and single crystal samples and capability for wide-angle polarization analysis. The instrument will utilize a large single-frame bandwidth and will offer high-resolution at low momentum transfers and excellent signal-to-noise ratio. A horizontal elliptical mirror concept with interchangeable guide pieces will provide high flexibility in beam divergence to allow for a high-resolution powder mode, a high-intensity single crystal mode, and a polarized beam option. A major science focus will be quantum materials that exhibit emergent properties arising from collective effects in condensed matter. The unique use of polarized neutrons to isolate the magnetic signature will provide optimal experimental input to state-of-the-art modeling approaches to access detailed insight into local magnetic ordering.

High-Precision Ion Beam Figuring of X-Ray Plane Mirrors for the Bendable KB Focusing System

Two trapezoidal plane mirrors of 240 mm in length were fabricated by ion beam figuring (IBF) technology for application in a bendable KB focusing system. The correction of surface height and slope errors in different spatial frequency ranges of the mirrors was studied systematically. After one to two iterations of IBF, the figure height errors of the vertical focusing mirror (VFM) and horizontal focusing mirror (HFM) were improved from 32.4 and 65.4 nm to 2.7 and 7.2 nm (RMS), respectively. If the best-fit sphere of the surface profile was subtracted, the residual two-dimensional height errors were only 1.1 and 1.2 nm (RMS). The slope errors in the low spatial frequency range were corrected much faster than the middle frequency ones (f = ∼1 mm−1), which make the low-frequency slope error much smaller. After IBF, the two-dimensional slope errors of the two mirrors calculated with a spatial interval of 1 and 10 mm were reduced to approximately 0.29 and 0.08 μrad, respectively. Full spatial frequency characterization of the VFM before and after IBF showed that the low-frequency figure errors (f < 1 mm−1) were significantly reduced while the middle- and high-frequency morphologies (f > 1–2 mm−1) remain almost the same as before figuring. The fabricated plane mirrors were applied in the hard X-ray micro-focusing beamline in the Shanghai Synchrotron Radiation Facility (SSRF), which realized a focal spot of 2.4 μm × 2.8 μm at 10 keV.

Nonlinear Optical and Photocurrent Responses in Janus MoSSe Monolayer and MoS2-MoSSe van der Waals Heterostructure.

Two-dimensional (2D) transition metal dichalcogenides are promising materials platforms for a variety of optoelectronic device applications. Janus 2D materials are a rising class of 2D materials with low symmetry, which leads to the emergence of out-of-plane electric polarization and piezoelectricity. Using first-principles density functional theory, we show that monolayer and bilayer heterostructure Janus MoSSe moieties exhibit strong nonlinear optical responses that are vanishing in the non-Janus form. The absence of horizontal mirror plane symmetry enables a circular photocurrent as well as a large out-of-plane second harmonic generation (SHG) and shift photocurrent. Through a comparative study of the Janus heterostructure MoS2-MoSSe on five distinct stacking configurations, we find that the magnitude of the out-of-plane SHG in the Janus heterostructure is enhanced due to the interlayer coupling and interference effect compared to that of monolayer MoSSe. Thus, Janus 2D materials offer a unique opportunity for exploring nonlinear optical phenomena and designing configurable layered nonlinear optical materials.