Kitaev Honeycomb Model Research Articles

Microscopic theory of field-tuned topological transitions in the Kitaev honeycomb model

Microscopic theory of field-tuned topological transitions in the Kitaev honeycomb model

Exact Deconfined Gauge Structures in the Higher-Spin Yao-Lee Model: A Quantum Spin-Orbital Liquid with Spin Fractionalization and Non-Abelian Anyons.

The nonintegrable higher spin Kitaev honeycomb model has an exact Z_{2} gauge structure, which exclusively identifies quantum spin liquid in the half-integer spin Kitaev model. But its constraints for the integer-spin Kitaev model are much limited, and even trivially gapped insulators cannot be excluded. The physical implications of exact Z_{2} gauge structure, especially Z_{2} fluxes, in integer-spin models remain largely unexplored. In this Letter, we theoretically show that a spin-S Yao-Lee model [a spin-orbital model with SU(2) spin-rotation symmetry] possesses a topologically nontrivial quantum spin-orbital liquid ground state for any spin (both integer and half-integer spin) by constructing exact deconfined fermionic Z_{2} gauge charges. We further show that the conserved Z_{2} flux can also demonstrate the intriguing spin fractionalization phenomena in the non-Abelian topological order phase of the spin-1 Yao-Lee model. Its deconfined Z_{2} vortex excitation carries fractionalized spin-1/2 quantum number in the low-energy subspace, which is also a non-Abelian anyon. Our exact manifestation of spin fractionalization in an integer-spin model is rather rare in previous studies, and is absent in the Kitaev honeycomb model.

Anisotropic magnetic interactions in a candidate Kitaev spin liquid close to a metal-insulator transition

In the Kitaev honeycomb model, spins coupled by strongly-frustrated anisotropic interactions do not order at low temperature but instead form a quantum spin liquid with spin fractionalisation into Majorana fermions and static fluxes. The realization of such a model in crystalline materials could lead to major breakthroughs in understanding entangled quantum states, however achieving this in practice is a very challenging task. The recently synthesized honeycomb material RuI3 shows no long-range magnetic order down to the lowest probed temperatures and has been theoretically proposed as a quantum spin liquid candidate material on the verge of an insulator to metal transition. Here we report a comprehensive study of the magnetic anisotropy in un-twinned single crystals via torque magnetometry and detect clear signatures of strongly anisotropic and frustrated magnetic interactions. We attribute the development of sawtooth and six-fold torque signal to strongly anisotropic, bond-dependent magnetic interactions by comparing to theoretical calculations. As a function of magnetic field strength at low temperatures, torque shows an unusual non-parabolic dependence suggestive of a proximity to a field-induced transition. Thus, RuI3, without signatures of long-range magnetic order, displays key hallmarks of an exciting candidate for extended Kitaev magnetism with enhanced quantum fluctuations.

Vacancies in Generic Kitaev Spin Liquids.

The Kitaev honeycomb model supports gapless and gapped quantum spin liquid phases. Its exact solvability relies on extensively many locally conserved quantities. Any real-world manifestation of these phases would include imperfections in the form of disorder and interactions that break integrability. We show that the latter qualitatively alters the properties of vacancies in the gapless Kitaev spin liquid: (i)Isolated vacancies carry a magnetic moment, which is absent in the exactly solvable case. (ii)Pairs of vacancies on even or opposite sublattices gap each other with distinct power laws that reveal the presence of emergent gauge flux.

Kitaev honeycomb antiferromagnet in a field: quantum phase diagram for general spin

We use tensor-network methods and high-order linked-cluster expansions to explore the quantum phase diagram of the antiferromagnetic Kitaev honeycomb model in a magnetic field for general spin S values. Tensor network calculations for the pure Kitaev model confirm the absence of fluxes and spin-spin correlations beyond nearest neighbors, while revealing discrete orientational symmetry breaking for S ∈ 1, 3/2, 2, consistent with the semiclassical limit. An intermediate region between Kitaev phases and the high-field polarized phase is identified for all considered spin values, showing a sequence of potential phases characterized by distinct local magnetization patterns while the total magnetization increases smoothly as a function of the field. Linked-cluster expansions for the high-field zero-momentum gap and spectral weight indicate a quantum critical breakdown of the polarized phase, suggesting exotic physics at intermediate Kitaev couplings.

Probing Majorana Wave Functions in Kitaev Honeycomb Spin Liquids with Second-Order Two-Dimensional Spectroscopy.

Two-dimensional coherent terahertz spectroscopy (2DCS) emerges as a valuable tool to probe the nature, couplings, and lifetimes of excitations in quantum materials. It thus promises to identify unique signatures of spin liquid states in quantum magnets by directly probing properties of their exotic fractionalized excitations. Here, we calculate the second-order 2DCS of the Kitaev honeycomb model and demonstrate that distinct spin liquid fingerprints appear already in this lowest-order nonlinear response χ_{yzx}^{(2)}(ω_{1},ω_{2}) when using crossed light polarizations. We further relate the off-diagonal 2DCS peaks to the localized nature of the matter Majorana excitations trapped by Z_{2} flux excitations and show that 2DCS thus directly probes the inverse participation ratio of Majorana wave functions. By providing experimentally observable features of spin liquid states in the 2D spectrum, our Letter can guide future 2DCS experiments on Kitaev magnets.

Exploring rare-earth Kitaev magnets by massive-scale computational analysis

The Kitaev honeycomb model plays a pivotal role in the quest for quantum spin liquids, in which fractional quasiparticles would provide applications in decoherence-free topological quantum computing. The key ingredient is the bond-dependent Ising-type interactions, dubbed the Kitaev interactions, which require strong entanglement between spin and orbital degrees of freedom. Here we investigate the identification and design of rare-earth materials displaying robust Kitaev interactions. We scrutinize all possible 4f electron configurations, which require up to 6+ million intermediate states in the perturbation processes, by developing a parallel computational program designed for massive-scale calculations. Our analysis reveals a predominant interplay between the isotropic Heisenberg J and anisotropic Kitaev K interactions across all realizations of the Kramers doublets. Remarkably, instances featuring 4f3 and 4f11 configurations showcase the prevalence of K over J, presenting unexpected prospects for exploring the Kitaev quantum spin liquids in compounds, including Nd3+ and Er3+, respectively.

Magnetocaloric effect of topological excitations in Kitaev magnets

Traditional magnetic sub-Kelvin cooling relies on the nearly free local moments in hydrate paramagnetic salts, whose utility is hampered by the dilute magnetic ions and low thermal conductivity. Here we propose to use instead fractional excitations inherent to quantum spin liquids (QSLs) as an alternative, which are sensitive to external fields and can induce a very distinctive magnetocaloric effect. With state-of-the-art tensor-network approach, we compute low-temperature properties of Kitaev honeycomb model. For the ferromagnetic case, strong demagnetization cooling effect is observed due to the nearly free Z2 vortices via spin fractionalization, described by a paramagnetic equation of state with a renormalized Curie constant. For the antiferromagnetic Kitaev case, we uncover an intermediate-field gapless QSL phase with very large spin entropy, possibly due to the emergence of spinon Fermi surface and gauge field. Potential realization of topological excitation magnetocalorics in Kitaev materials is also discussed, which may offer a promising pathway to circumvent existing limitations in the paramagnetic hydrates.

Quantum phase transition between spin liquid and spin nematics in spin-1 Kitaev honeycomb model

Besides the exactly solvable spin-1/2 Kitaev model, higher spin-S ones, not exactly solvable, are promising playgrounds for researches on the quantum spin liquid as well. One of the main interests in higher spin-S cases is the interplay between the Kitaev spin liquid (KSL) and spin nematics. We probe this interplay in a spin-1 model on the honeycomb lattice with competing bilinear-biquadratic and Kitaev interactions. Utilizing the 2D infinite projected entangled-pair state (iPEPS), we map out the phase diagram for the ferro-biquadratic interaction. In the phase diagram, we discover the direct phase transitions between the KSL phases and ferro-quadrupolar ordered spin nematic phase, which we call the FQ phase. It has been revealed that the ferro KSL exhibits robustness against perturbations from ferro-quadrupolar interactions. Also, the FQ phase is extended to the parameter region near the antiferro-Kitaev limit. Published by the American Physical Society 2024

Fidelity of the Kitaev honeycomb model under a quench

Fidelity of the Kitaev honeycomb model under a quench

Gauge symmetry of excited states in projected entangled-pair state simulations

While gauge symmetry is a well-established requirement for representing topological orders in projected entangled-pair state (PEPS), its impact on the properties of low-lying excited states remains relatively unexplored. Here we perform PEPS simulations of low-energy dynamics in the Kitaev honeycomb model, which supports fractionalized gauge flux (vison) excitations. We identify gauge symmetry emerging upon optimizing an unbiased PEPS ground state. Using the PEPS adapted local mode approximation, we further classify the low-lying excited states by discerning different vison sectors. Our simulations of spin and spin-dimer dynamical correlations establish close connections with experimental observations. Notably, the selection rule imposed by the locally conserved visons results in nearly flat dispersions in momentum space for excited states belonging to the 2-vison or 4-vison sectors. Published by the American Physical Society 2024

Effective models for dense vortex lattices in the Kitaev honeycomb model

Effective models for dense vortex lattices in the Kitaev honeycomb model

Extracting Higher Central Charge from a Single Wave Function.

A (2+1)D topologically ordered phase may or may not have a gappable edge, even if its chiral central charge c_{-} is vanishing. Recently, it was discovered that a quantity regarded as a "higher" version of chiral central charge gives a further obstruction beyond c_{-} to gapping out the edge. In this Letter, we show that the higher central charges can be characterized by the expectation value of the partial rotation operator acting on the wave function of the topologically ordered state. This allows us to extract the higher central charge from a single wave function, which can be evaluated on a quantum computer. Our characterization of the higher central charge is analytically derived from the modular properties of edge conformal field theory, as well as the numerical results with the ν=1/2 bosonic Laughlin state and the non-Abelian gapped phase of the Kitaev honeycomb model, which corresponds to U(1)_{2} and Ising topological order, respectively. The Letter establishes a numerical method to obtain a set of obstructions to the gappable edge of (2+1)D bosonic topological order beyond c_{-}, which enables us to completely determine if a (2+1)D bosonic Abelian topological order has a gappable edge or not. We also point out that the expectation values of the partial rotation on a single wave function put a constraint on the low-energy spectrum of the bulk-boundary system of (2+1)D bosonic topological order, reminiscent of the Lieb-Schultz-Mattis-type theorems.

Signatures of a Majorana-Fermi surface in the Kitaev magnet Ag3LiIr2O6

Detecting Majorana fermions in experimental realizations of the Kitaev honeycomb model is often complicated by non-trivial interactions inherent to potential spin liquid candidates. In this work, we identify several distinct thermodynamic signatures of massive, itinerant Majorana fermions within the well-established analytical paradigm of Landau-Fermi liquid theory. We find a qualitative and quantitative agreement between the salient features of our Landau-Majorana liquid theory and the Kitaev spin liquid candidate Ag3LiIr2O6. Our study presents strong evidence for a Fermi liquid-like ground state in the fundamental excitations of a honeycomb iridate, and opens new experimental avenues to detect itinerant Majorana fermions in condensed matter systems.

An exact chiral amorphous spin liquid

Topological insulator phases of non-interacting particles have been generalized from periodic crystals to amorphous lattices, which raises the question whether topologically ordered quantum many-body phases may similarly exist in amorphous systems? Here we construct a soluble chiral amorphous quantum spin liquid by extending the Kitaev honeycomb model to random lattices with fixed coordination number three. The model retains its exact solubility but the presence of plaquettes with an odd number of sides leads to a spontaneous breaking of time reversal symmetry. We unearth a rich phase diagram displaying Abelian as well as a non-Abelian quantum spin liquid phases with a remarkably simple ground state flux pattern. Furthermore, we show that the system undergoes a finite-temperature phase transition to a conducting thermal metal state and discuss possible experimental realisations.

Oddness in the spin-S Kitaev honeycomb model

Oddness in the spin-S Kitaev honeycomb model

Quantum computation at the edge of a disordered Kitaev honeycomb lattice

We analyze propagation of quantum information along chiral Majorana edge states in two-dimensional topological materials. The use of edge states may facilitate the braiding operation, an important ingredient in topological quantum computations. For the edge of the Kitaev honeycomb model in a topological phase, we discuss how the edge states can participate in quantum-information processing, and consider a two-qubit logic gate between distant external qubits coupled to the edge. Here we analyze the influence of disorder and noise on properties of the edge states and quantum-gate fidelity. We find that realistically weak disorder does not prevent one from implementation of a high-fidelity operation via the edge.

Effect of ring-exchange interactions in the extended Kitaev honeycomb model

Effect of ring-exchange interactions in the extended Kitaev honeycomb model

Fractionalized Prethermalization in a Driven Quantum Spin Liquid.

Quantum spin liquids subject to a periodic drive can display fascinating nonequilibrium heating behavior because of their emergent fractionalized quasiparticles. Here, we investigate a driven Kitaev honeycomb model and examine the dynamics of emergent Majorana matter and Z_{2} flux excitations. We uncover a distinct two-step heating profile-dubbed fractionalized prethermalization-and a quasistationary state with vastly different temperatures for the matter and the flux sectors. We argue that this peculiar prethermalization behavior is a consequence of fractionalization. Furthermore, we discuss an experimentally feasible protocol for preparing a zero-flux initial state of the Kiteav honeycomb model with a low energy density, which can be used to observe fractionalized prethermalization in quantum information processing platforms.

Z_{2} Spin Liquids in the Higher Spin-S Kitaev Honeycomb Model: An Exact Deconfined Z_{2} Gauge Structure in a Nonintegrable Model.

The higher spin Kitaev model prominently features the extensive locally conserved quantities the same as the spin-1/2 Kitaev honeycomb model, although it is not exactly solvable. It remains an open question regarding the physical meaning of these conserved quantities in the higher spin model. In this Letter, by introducing a Majorana parton construction for a general spin-S we uncover that these conserved quantities are exactly the Z_{2} gauge fluxes in the general spin-S model, including the case of spin-1/2. Particularly, we find an even-odd effect that the Z_{2} gauge charges are fermions in the half integer spin model, but are bosons in the integer spin model. We further prove that the fermionic Z_{2} gauge charges are always deconfined; hence, the half integer spin Kitaev model would have nontrivial spin liquid ground states regardless of interaction strengths in the Hamiltonian. The bosonic Z_{2} gauge charges of the integer spin model, on the other hand, could condense, leading to a trivial product state, and this is indeed the case at the anisotropic limit of the model.